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Friday 13 March

Physics and Society

LLM-DR: An On-Demand Delivery Simulation Framework for Studying Heterogeneous Rider Behavior and Collective Mobility with Persona-Grounded Large Language Model Agents

On-demand delivery platforms are computational social systems in which dispatch rules and repeated rider actions jointly shape service and urban mobility. Riders choose whether to reject offers, accept one order, or bundle several orders; assignments then change their availability and other riders' opportunities. Modeling this feedback requires empirical rider heterogeneity, shared-order interaction, and road-network execution to be represented together. Delivery optimization and large language model (LLM) mobility generation provide useful foundations, but leave this combination insufficiently examined. We develop Large Language Models as Delivery Riders (LLM-DR), an agentic simulation framework for benchmarking rider policies under a common order stream and dispatch protocol. Persona-grounded LLM agents provide a reference implementation, using empirical profiles, local observations, short-term memory, and route-tool estimates to propose order actions. The environment resolves assignment conflicts, constructs pickup and drop-off sequences, and executes tool-supported routes. Analysis of 9,025 Beijing orders and a sample of 2,508 routed delivery waves identifies four rider personas. A controlled single-day reconstruction places 60 agents, equally distributed across personas, in an observed stream of 8,656 orders. Persona groups complete 16-30 orders per rider, with average bundle sizes of 1.116-2.212. Distributional comparisons retain several empirical persona orderings in order volume, bundling, and routed-wave distance. Fleet-level outcomes show displaced demand, service-occupancy, and completion peaks, alongside a shared central service core and differentiated spatial reach. These results connect data-derived rider strategies to executable action chains and collective mobility patterns within a shared computational social system.
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All authors Chengbo Zhang, Zekai Jin, Kaihan Zhang, Zihan Yang, Qinyu Cui, Zuopeng Xiao, Jiangbo Yu

Physics and Society

Involution game with migration and spatial heterogeneity of social resources

Involution – a phenomenon of excessive competition with diminishing returns – has become a pressing socio-economic concern in contemporary China, prompting both academic inquiry and policy interventions. This paper proposes an evolutionary game model of involution that incorporates agent migration and spatial heterogeneity in resource distribution. The model captures realistic features such as effort-based resource allocation, local interactions on a lattice, and mobility driven by payoff comparisons. We explore how varying conditions of migration and resource allocation influence the dynamics of involution. The key findings from our simulations are as follows: when total resources are held constant, similar resource levels across different regions tend to suppress involution, whereas a large disparity between regions promotes it. Furthermore, increasing the total amount of resources exacerbates involution. In addition, the probability of migration does not significantly affect the final evolutionary outcome. We further identify threshold effects in the effort ratio and utility multiplier, revealing critical conditions under which involution emerges or subsides. To further elucidate these simulation results, we conduct a theoretical analysis using mean-field theory, which provides analytical expressions for the equilibria and stability conditions. The theoretical predictions are in excellent qualitative agreement with simulation outcomes. Finally, we discuss real-world counterparts of the model, including competition among food delivery riders and between stores offering similar services.
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Computational Physics · Cross-listed from cs.LG

Scaling Laws and Pathologies of Single-Layer PINNs: Network Width and PDE Nonlinearity

We establish empirical scaling laws for Single-Layer Physics-Informed Neural Networks on canonical nonlinear PDEs. We identify a dual optimization failure: (i) a baseline pathology, where the solution error fails to decrease with network width, even at fixed nonlinearity, falling short of theoretical approximation bounds, and (ii) a compounding pathology, where this failure is exacerbated by nonlinearity. We provide quantitative evidence that a simple separable power law is insufficient, and that the scaling behavior is governed by a more complex, non-separable relationship. This failure is consistent with the concept of spectral bias, where networks struggle to learn the high-frequency solution components that intensify with nonlinearity. We show that optimization, not approximation capacity, is the primary bottleneck, and propose a methodology to empirically measure these complex scaling effects.
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Computational Physics

Reduced-Order Variational Deterministic-Particle-Based Scheme for Fokker-Planck Equations in Microscopic Polymer Dynamics

This study proposes an acceleration technique for the computational challenges in extending the variational deterministic-particle-based scheme (VDS) [Bao et al., Journal of Computational Physics 522 (2025) 113589] to 3D complex fluid simulations with multi-bead polymers. While the original VDS effectively captures configuration space dynamics for 2D dumbbell polymers, its direct extensions reveal critical scalability limitations. The growing configuration space dimensionality necessitates prohibitively large particle ensembles to maintain distributional accuracy, so its quadratic computational cost scaling impedes practical applications. In this paper, we develop a model reduction framework integrating proper orthogonal decomposition (POD) to speed up the computation of the VDS for microscopic Fokker-Planck equations. Numerical validation using bead-spring chain models in simple shear flow demonstrates that the computational efficiency of the reduced model increases systematically with molecular complexity. The reduced-order model introduces about $6\%$ relative error in predicting the dynamics while requiring only about $6\%$ of the original computational time for $4$-bead chain polymers, where the relative numerical error of the reference dynamics is about $5\% \sim 10\%$, and the degrees of freedom can be reduced significantly to about $0.1\%$ of the original model, which means the low-dimensional structure is found by POD. This establishes a practical pathway for multiscale and complex fluid simulations.
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All authors L. Fang, X. Bao, Z. Song, S. Xu, H. Huang

Optics

Electron confinement within a fluctuation "box" in liquid water

Electron confinement within a small volume is intriguing as a realization of the particle-in-a-box system, which appears in every quantum mechanics textbook. While the electron confinement is readily imaginable in solid-state systems, it also occurs in liquids, where the local voids in the liquid serve as confining "boxes." Confinement within these flexible cavities in liquids is expected to differ fundamentally from that in solids. Here, we experimentally investigate the electrons confined in liquid water, which are called hydrated electrons, using transient two-dimensional electronic spectroscopy. Our experiment reveals the large nonuniformity of the shape and the size of hydrated electrons with significant fluctuation at the timescale shorter than 30 fs.
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Biological Physics · Cross-listed from cond-mat.soft

Polymer-Residue Accessibility Shapes Sequence Dependence of Critical Temperatures for Phase Separation

Biological polymers, such as intrinsically disordered proteins, play a central role in cellular biology, including mediating phase separation and controlling activity of biological condensates. The physical properties and functions of biopolymers are determined by their residue sequence. Recently, significant computational and theoretical efforts have been devoted to characterizing the combinatorially complex sequence dependence of biopolymer phase diagrams. Here, we quantitatively show that monomer accessibility is central to determining the strength of pair interactions. We formulate an analytical perturbative approach, phenomenologically precluding two polymers' centers of mass from overlapping within a correlation hole. This theory yields the correction to the strength of mean-field interactions in terms of a residue-accessibility parameter (RAP), which accounts for the limited availability of inner monomers to interactions. RAP rationalizes the variations in critical temperatures found in extensive Monte Carlo simulations for thousands of two-letter polymer solutions of varying lengths and sequences. RAP may thus be effective for deciphering the polymer-sequence dependence of phase diagrams given any polymer length, set of monomer types, and polymer mixtures.
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All authors J. Pedro de Souza, Benjamin Sorkin, Amala Akkiraju, Athanassios Z. Panagiotopoulos, Howard A. Stone

Thursday 12 March

Optics

Magneto-optic perturbation theory for near-complete violation of Kirchhoff's law of thermal emission at low magnetic fields

Magneto-optic photonic systems can violate Kirchhoff's law of thermal emission by breaking Lorentz reciprocity. We develop a dispersive perturbation theory yielding an analytical expression for magneto-optical resonance frequency shifts in plasmonic semiconductors under applied magnetic fields. This expression shows the shift is governed by the overlap of the mode's optical spin density with the magneto-optical material. We use this expression to design a III-V metasurface that achieves nonreciprocal emissivity contrast of 0.8 at only 0.1 T, and demonstrate that the theory can explain order-of magnitude differences in magnetic field sensitivity between different photonic structures.
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Applied Physics

Capacitive Pixelated CMOS Electronic Nose

Although some of the human senses can nowadays be replaced by low-cost electronic sensors such as microphones and image sensors, a compact low-cost electronic nose (E-nose) remains elusive. In this work, an E-nose is presented that can capacitively detect volatile organic compounds (VOCs). The E-nose consists of an array of 1024 capacitive microelectrodes on a complementary metal-oxide-semiconductor (CMOS) chip, functionalized by inkjet printing. The pixels are coated with a UV-curable ink and metal-organic frameworks (MOFs: ZIF-8, MIL-101(Cr), MIL-140A) to create chemically diverse microdomains that generate gas-specific response patterns through adsorption-driven dielectric loading. ZIF-8 exhibits the highest response to 2-butanone, whereas the UV-curable layer responds most strongly to toluene; both show low cross-sensitivity to water vapor, enabling operation under humid conditions. After calibration in pure gases, reproducible responses to controlled binary mixtures of toluene and 2-butanone are observed. The device operates at low power, combines a large 1024-pixel array with CMOS integration, and offers application-specific functionalization by inkjet printing, providing both low cost and versatility. By further extending the range of functionalization materials, the E-nose can be applied to analyze a wide variety of gases, with potential applications in safety monitoring, health, agriculture, and robotics.
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All authors M. A. Basyooni-M. Kabatas, Tao Shen, Kai Betlem, Chunyu Huang, Monique A. van der Veen, Frans Widdershoven, Murali K. Ghatkesar, Peter G. Steeneken

Instrumentation and Detectors

The ATLAS Trigger System

The ATLAS Trigger system is a key component of the ATLAS experiment at the CERN Large Hadron Collider (LHC), designed to reduce the event rate from the 40 MHz proton-proton bunch crossing frequency to an output suitable for offline storage and analysis. During Run-3 (2022-2026), major upgrades were implemented in both the hardware-based Level-1 (L1) Trigger and the software-based High Level Trigger (HLT), to cope with increased luminosity and pile-up conditions. This paper summarises the main features of the ATLAS Trigger system, its performance in Run-3, and its role in enabling precision measurements and new physics searches.
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Optics

Trajectory probing of complex-frequency scattering with chirped analytic pulses

Characterizing resonant scatterers is challenging because their poles and zeros usually lie away from the real-frequency axis, whereas most measurements sample only real frequencies and infer off-axis behavior from fitted models. Here we introduce complex-frequency chirped pulses: finite-energy analytic waveforms that probe a device continuously along a prescribed contour in the complex-frequency plane. We give a direct synthesis rule for an in-phase/quadrature (I/Q) waveform and show that finite-duration windowing deterministically distorts the realized trajectory, which makes it necessary to analyze only a central time interval where the window contribution is small. For stable linear time-invariant devices, we extract a time-local least-squares input–output ratio and identify when it follows the continued complex-frequency response, with errors that grow at higher traversal speeds and near resonant poles. Numerical tests on a coupled-mode resonator validate the method and show that closed contours enable an integer phase-winding consistency check. We also outline an implementation based on standard arbitrary waveform generation, I/Q modulation, coherent reception, and digital signal processing.
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Fluid Dynamics · Cross-listed from cs.LG

Learning Pore-scale Multiphase Flow from 4D Velocimetry

Multiphase flow in porous media underpins subsurface energy and environmental technologies, including geological CO$_2$ storage and underground hydrogen storage, yet pore-scale dynamics in realistic three-dimensional materials remain difficult to characterize and predict. Here we introduce a multimodal learning framework that infers multiphase pore-scale flow directly from time-resolved four-dimensional (4D) micro-velocimetry measurements. The model couples a graph network simulator for Lagrangian tracer-particle motion with a 3D U-Net for voxelized interface evolution. The imaged pore geometry serves as a boundary constraint to the flow velocity and the multiphase interface predictions, which are coupled and updated iteratively at each time step. Trained autoregressively on experimental sequences in capillary-dominated conditions ($Ca\approx10^{-6}$), the learned surrogate captures transient, nonlocal flow perturbations and abrupt interface rearrangements (Haines jumps) over rollouts spanning seconds of physical time, while reducing hour-to-day–scale direct numerical simulations to seconds of inference. By providing rapid, experimentally informed predictions, the framework opens a route to ”digital experiments” to replicate pore-scale physics observed in multiphase flow experiments, offering an efficient tool for exploring injection conditions and pore-geometry effects relevant to subsurface carbon and hydrogen storage.
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All authors Chunyang Wang, Linqi Zhu, Yuxuan Gu, Robert van der Merwe, Xin Ju, Catherine Spurin, Samuel Krevor, Rex Ying, Tobias Pfaff, Martin J. Blunt, Tom Bultreys, Gege Wen

Atmospheric and Oceanic Physics

Recent Weakening of the Global Radiative Feedback

Earth's climate stability, characterized by the global radiative feedback parameter ($\lambda$), varies decadally due to changing surface temperature patterns. Recent variations in $\lambda$ are poorly understood as coordinated model simulations typically end in 2014. We apply a convolutional neural network trained on climate model simulations to observation-based surface temperature reconstructions to estimate variations in $\lambda$ up to 2025. We find that $\lambda$ reached a minimum (maximum stability) around the mid 1990s ($\lambda\simeq -3 {\rm Wm^{-2}/K}$), but has since weakened significantly ($\lambda\simeq -2\, {\rm Wm^{-2}/K}$). We confirm these results with climate model simulations extended to 2022. The recent $\lambda$ weakening is not significantly affected by El Niño Southern Oscillation or Pacific Decadal Oscillation. Attribution reveals that warming in the subtropical Northeast Pacific is an important driver of the recently weakened feedback, confirmed by targeted experiments in E3SMv2. Our approach enables near real-time monitoring of Earth's climate stability.
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All authors Senne Van Loon, Maria Rugenstein, Mark D. Zelinka, Timothy Andrews

Optics

Physics-Guided Inverse Design of Optical Waveforms for Nonlinear Electromagnetic Dynamics

Structured optical waveforms are emerging as powerful control fields for the next generation of complex photonic and electromagnetic systems, where the temporal structure of light can determine the ultimate performance of scientific instruments. However, identifying optimal optical drive fields in strongly nonlinear regimes remains challenging because the mapping between optical inputs and system response is high-dimensional and typically accessible only through computationally expensive simulations. Here, we present a physics-guided deep learning framework for the inverse design of optical temporal waveforms. By training a light-weighted surrogate model on simulations, the method enables gradient-based synthesis of optical profiles that compensate nonlinear field distortions in driven particle-field systems. As a representative application, we apply the approach to the generation of electron beams used in advanced photon and particle sources. The learned optical waveform actively suppresses extrinsic emittance growth by more than 52% compared with conventional Gaussian operation and by approximately 9% relative to the theoretical flattop limit in simulation. We further demonstrate experimental feasibility by synthesizing the predicted waveform using a programmable pulse-shaping platform; incorporating the measured optical profile into beamline simulations yields a 31% reduction in the extrinsic emittance contribution. Beyond accelerator applications, this work establishes a general way for physics-guided inverse design of optical control fields, enabling structured light to approach fundamental performance limits in nonlinear photonic and high-frequency electromagnetic systems.
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All authors Hao Zhang, Jack Hirschman, Randy Lemons, Nicole R. Neveu, Joseph Robinson, Auralee L. Edelen, Tor O. Raubenheimer, Dan Wang, Ji Qiang, Sergio Carbajo

Plasma Physics

Non-dimensional confinement scaling in similar negative triangularity plasmas on the DIII-D and TCV tokamaks

Similarity experiments were performed on the DIII-D and TCV tokamaks to explore the scaling of energy confinement in negative triangularity plasmas using non-dimensional variables. Near up-down symmetric plasmas with large top-bottom averaged negative triangularity were created in a lower single null configuration, with the shape of the separatrix being closely matched between the two devices. The normalized energy confinement is found to weakly improve at increasing collisionality and, between the two devices, shows a machine size scaling behavior between Bohm and gyro-Bohm. Engineering scaling on a large DIII-D dataset is in agreement with the non-dimensional experiment.
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All authors A. Marinoni, C. Chrystal, S. Coda, R. Coosemans, C. Marini, M. Podesta, O. Sauter, M. Agostini, M.E. Austin, E. Belli, J. Candy, M. Gorelenkova, D. Hamm, A.W. Hyatt, M. Knolker, M. La Matina, P. Lunia, S. Mordijck, A.O. Nelson, T.H. Osborne, C. Paz-Soldan, L. Porte, U. Sheikh, F. Scotti, K.E. Thome, M. Van Zeeland, the DIII-D, TCV Teams

Space Physics

CLARE: Classification-based Regression for Electron Temperature Prediction

Electron temperature (Te) is an important parameter governing space weather in the upper atmosphere, but has historically been underexplored in the space weather machine learning literature. We present CLARE, a machine learning model for predicting electron temperature in the Earth's plasmasphere trained on AKEBONO (EXOS-D) satellite measurements as well as solar and geomagnetic indices. CLARE uses a classification-based regression architecture that transforms the continuous Te output space into 150 discrete classification intervals. Training the model on a classification task improves prediction accuracy by 6.46% relative compared to a traditional regression model while also outputting uncertainty estimation information on its predictions. On a held out test set from the AKEBONO data, the model's Te predictions achieve 69.67% accuracy within 10% of the ground truth and 46.17% on a known geomagnetic storm period from January 30th to February 7th, 1991. We show that machine learning can be used to produce high-accuracy Te models on publicly available data.
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All authors Michael Liang, Blake DeHaas, Naomi Maruyama, Xiangning Chu, Takumi Abe, Koh-Ichiro Oyama

Optics · Cross-listed from cond-mat.mes-hall

Annihilation of Dirac points and its topological obstruction in a photonic Kagome lattice

Dirac points (DPs) are topological singularities that determine the extraordinary properties of two-dimensional materials. They are generally classified by discrete topological invariants, which determine the possibility of DPs' annihilation upon their collision. Here, we study the behaviors of DPs within a photonic Kagome lattice created in atomic vapor. With optically engineering the potential difference among three sites constituting the Kagome unit cell while preserving time-reversal symmetry and the stability of an isolated DP, the DPs move in reciprocal space. By employing conical diffraction to measure their position and the topological invariant (Euler number), we demonstrate an obstruction to DPs' annihilation during collision and a transition to a case where the Euler number changes and annihilation occurs. Such topological transition is induced by a non-Abelian frame rotation of the eigenstates around the Brillouin zone torus. The associated conversion of the DP quaternionic charges during their motion explains the change of Euler number.
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All authors Zhaoyang Zhang, Matthieu Finck, Changchang Li, Shun Liang, Jerome Dubois, Yumin Tian, Jiahao Wen, Yanpeng Zhang, Guillaume Malpuech, Dmitry Solnyshkov

Classical Physics · Cross-listed from nlin.CD

An angular-momentum preserving dissipative model for the point-mass N -body problem

A simple mathematical model emulating energy dissipation due to tidal effects is proposed. In this model, forces acting between masses remove energy but preserve the total angular momentum of the system. We study the effect of such forces on the particular family of orbits in central configurations, and show that a specific dependence on the mutual distances between the bodies leads to homographic equations equivalent to those of the two-body problem with dissipation. We then describe in detail the topology of solutions of the dissipative two-body system via Poincaré compactification. Finally, we present equations averaged over Keplerian motion showing no influence of the dissipation on periapsis precession.
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Atmospheric and Oceanic Physics

FloeNet: A mass-conserving global sea ice emulator that generalizes across climates

We introduce FloeNet, a machine-learning emulator trained on the Geophysical Fluid Dynamics Laboratory global sea ice model, SIS2. FloeNet is a mass-conserving model, emulating 6-hour mass and area budget tendencies related to sea ice and snow-on-sea-ice growth, melt, and advection. We train FloeNet using simulated data from a reanalysis-forced ice-ocean simulation and test its ability to generalize to pre-industrial control and 1% CO2 climates. FloeNet outperforms a non-conservative model at reproducing sea ice and snow-on-sea-ice mean state, trends, and inter-annual variability, with volume anomaly correlations above 0.96 in the Antarctic and 0.76 in the Arctic, across all forcings. FloeNet also produces the correct thermodynamic vs dynamic response to forcing, enabling physical interpretability of emulator output. Finally, we show that FloeNet outputs high-fidelity coupling-related variables, including ice-surface skin temperature, ice-to-ocean salt flux, and melting energy fluxes. We hypothesize that FloeNet will improve polar climate processes within existing atmosphere and ocean emulators.
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All authors William Gregory, Mitchell Bushuk, James Duncan, Elynn Wu, Adam Subel, Spencer K. Clark, Bill Hurlin, Oliver Watt-Meyer, Alistair Adcroft, Chris Bretherton, Laure Zanna

Optics · Cross-listed from quant-ph

Doppler-induced tunable and shape-preserving frequency conversion of microwave wave packets

In superconducting electronics, the ability to control the frequency of microwave wave packets is crucial for several applications, such as the operation of superconducting quantum processors and the readout of superconducting sensors. We introduce a new approach to microwave frequency conversion that harnesses a dynamic Doppler effect induced by a propagating front that separates regions of different phase velocities. Employing a high-kinetic-inductance superconducting transmission line in a travelling-wave geometry, we were able to implement frequency shifts of microwave wave packets at 500$\,$MHz and 4$\,$GHz of up to 3.7$\,$% while fully preserving their temporal shape. In contrast to conventional methods based on frequency-mixing, our Doppler-induced frequency-conversion method avoids spurious mixing products, is continuously tunable by a quasi-dc current amplitude, and allows to imprint arbitrary patterns on the instantaneous frequency profile of temporally long wave packets. By engineering transmission lines that allow for larger phase-velocity changes and/or by cascading multiple Doppler-induced frequency conversions, an unlimited amount of frequency shifting is in principle attainable. These features demonstrate the potential of our frequency-conversion technique as a promising tool for advanced control of microwave wave packets for different quantum applications.
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All authors Felix Ahrens, Enrico Bogoni, Renato Mezzena, Andrea Vinante, Nicolò Crescini, Alessandro Irace, Andrea Giachero, Gianluca Rastelli, Iacopo Carusotto, Federica Mantegazzini

Physics and Society · Cross-listed from econ.GN

Topology as information: Network effects in corporate lending

A central challenge in financial economics is understanding how credit networks form under informational noise. We introduce the concept of topological capital, arguing that banks increasingly rely on topological certification, interpreting a borrower's connectivity as a primary proxy for creditworthiness. Using a novel dataset of bank-firm relationships manually extracted from Italian financial statements, we implement a multi-stage empirical framework, benchmarking empirical patterns against a maximum-entropy benchmark, to separate the determinants of credit access from those of loan volumes. Our results indicate that network topology systematically outperforms traditional fundamentals. In the link-formation stage, connectivity breeds further connectivity through an amplified preferential attachment mechanism. In the loan-sizing stage, network strength absorbs the explanatory power of balance-sheet metrics, documenting a profound network substitution effect where topological signals effectively replace physical collateral across all corporate segments. For SMEs, we identify a critical signal divergence: reported debt acts as a risk signal, while network footprint serves as market validation. Furthermore, we reveal a diversification paradox: while firms fragment debt to avoid hold-up risks, over-diversification leads to a complexity penalty that stagnates credit depth and inflates systemic Loss Given Default. Ultimately, our findings signal the twilight of the balance sheet as the primary anchor of corporate lending, calling for a shift toward topological macro-prudential supervision to manage vulnerabilities invisible to traditional bilateral indicators.
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All authors Anna Pirogova, Anna Mancini, Tiziano Squartini, Giulio Cimini

Plasma Physics

Combination of quasi-isodynamic and piecewise omnigenous magnetic fields

Due to their simultaneous optimization for radial and parallel neoclassical transport, quasi-isodynamic fields have been the main choice of stellarator magnetic configuration for most fusion reactor candidates in recent years. However, achieving a high degree of quasi-isodynamicity often comes at the cost of a strong shaping of the flux surfaces of the stellarator and complex coil geometries. In this work, the concepts of quasi-isodynamicity and piecewise omnigenity are combined to form QI-pwO fields. These fields are quasi-isodynamic in the low-field region of the magnetic surface, whereas they significantly depart from quasi-isodynamicity in the high-field region without sacrificing the neoclassical transport properties of quasi-isodynamic fields. This departure could make it easier to integrate the optimization of neoclassical transport with other physical and technological aspects of a stellarator reactor.
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All authors J. L. Velasco, I. Calvo, V. Fernández-Pacheco, M. Padidar, H. Liu, E. Sánchez, G. Yu, C. Zhu

Chemical Physics

Nuclear-Electronic Quantum Dynamics in a Plasmonic Nanocavity

Plasmonic nanocavities are a promising platform for strong light-matter coupling and enhanced spectroscopies at the single-molecule level. These nanoscale environments are challenging to model due to their strongly multimodal character and short cavity lifetimes. Herein, we study the effects of these environments using real-time nuclear-electronic orbital time-dependent density functional theory (RT-NEO-TDDFT) coupled to multiple classical cavity modes in a manner that includes cavity loss. In RT-NEO-TDDFT, the quantum mechanical densities of all electrons and specified nuclei, typically protons, are propagated in real time. We show that a cavity with many modes at different frequencies can be used to probe and modify the nuclear-electronic quantum dynamics of chemical systems. Ultrafast excited-state proton transfer reactions can be probed through the time- and energy-resolved cavity emission of a multimode cavity. Under strong coupling conditions, the cavity can modify the dynamics, in some cases suppressing proton transfer and exhibiting Rabi-like oscillations of the cavity emission due to polariton formation. Utilizing the spectral density for an experimentally relevant nanoparticle-on-mirror single-molecule cavity, we show that an excited-state proton transfer system can evolve into resonance with the cavity even when initially out of resonance with the dominant cavity peak. In this case, tuning the dominant cavity peak to be resonant with the electronic transition leads to polariton formation for a small collection of molecules. The RT-NEO framework with multimode cavities enables the efficient simulation of chemical reactions in physically realistic electromagnetic environments, providing fundamental insights into the dynamics and associated spectroscopic signatures.
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All authors Jonathan H. Fetherolf, Tim Duong, Tao E. Li, Sharon Hammes-Schiffer

Computational Physics · Cross-listed from cond-mat.mtrl-sci

Optimal Experimental Design for Reliable Learning of History-Dependent Constitutive Laws

History-dependent constitutive models serve as macroscopic closures for the aggregated effects of micromechanics. Their parameters are typically learned from experimental data. With a limited experimental budget, eliciting the full range of responses needed to characterize the constitutive relation can be difficult. As a result, the data can be well explained by a range of parameter choices, leading to parameter estimates that are uncertain or unreliable. To address this issue, we propose a Bayesian optimal experimental design framework to quantify, interpret, and maximize the utility of experimental designs for reliable learning of history-dependent constitutive models. In this framework, the design utility is defined as the expected reduction in parametric uncertainty or the expected information gain. This enables in silico design optimization using simulated data and reduces the cost of physical experiments for reliable parameter identification. We introduce two approximations that make this framework practical for advanced material testing with expensive forward models and high-dimensional data: (i) a Gaussian approximation of the expected information gain, and (ii) a surrogate approximation of the Fisher information matrix. The former enables efficient design optimization and interpretation, while the latter extends this approach to batched design optimization by amortizing the cost of repeated utility evaluations. Our numerical studies of uniaxial tests for viscoelastic solids show that optimized specimen geometries and loading paths yield image and force data that significantly improve parameter identifiability relative to random designs, especially for parameters associated with memory effects.
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Accelerator Physics

The N=126 Factory: A New Multi-Nucleon Transfer Reaction Facility

Multi-nucleon transfer (MNT) reactions between two heavy ions offer an effective method of producing heavy, neutron-rich nuclei that cannot currently be accessed efficiently using traditional production techniques. These nuclei are important for understanding many astrophysical phenomena, such as the formation of the r-process $A\sim 195$ abundance peak. The N=126 Factory currently commissioning at Argonne National Laboratory's ATLAS facility will make use of these reactions to allow for the study of these nuclei. To convert MNT reaction products, which have a wide angular distribution, into a collimated, bunched beam suitable for experiments, a series of apparatus will be used. These start with a large-volume gas catcher for stopping the reaction products, which are then extracted through a radiofrequency quadrupole ion guide, undergo preliminary dipole magnetic separation, cooling and bunching in a Cooler-Buncher, and final separation using a multi-reflection time-of-flight mass separator, before final delivery to experimental systems.
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All authors A.A. Valverde, M.S. Martin, W.S. Porter, A.M. Houff, M. Brodeur, J.A. Clark, Y. Cho, A. Jacobs, R.A. Knaack, F. Köhler, K. König, O.S. Kubiniec, A. LaLiberte, B. Liu, B. Maass, A. Mitra, P. Mueller, C. Müller-Gatermann, W. Nörtershäuser, M.B. Oberling, J. Palmes, C. Quick, E.S.C. Ribeiro, J. Rohrer, G. Savard, J. Spahn

Applied Physics · Cross-listed from quant-ph

A Traveling-Wave Parametric Amplifier With Integrated Diplexers

Traveling-Wave Parametric Amplifiers (TWPAs) are ubiquitous in superconducting circuit readout, providing high gain with near-quantum-limited noise performance across a wide bandwidth. Their operation, however, relies on a strong microwave pump tone that is typically delivered using off-chip passive components, such as directional couplers or diplexers. These external elements add loss, increase system complexity, and limit scalability. Here, we present a traveling-wave parametric amplifier that incorporates on-chip input and output diplexers for pump routing. This co-fabricated architecture offers a compact and scalable solution for superconducting-circuit readout.
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All authors C. Denney, K. Genter, K. Cicak, J. D. Teufel, J. Aumentado, F. Lecocq, M. Malnou

Computational Physics · Cross-listed from hep-ph

All-electron dark matter-electron scattering with random-phase approximation dielectric screening and local field effects

Accurate predictions for dark matter-electron scattering in solids require an all-electron treatment together with a faithful description of dielectric screening beyond simple approximations. In particular, local field effects, arising from microscopic inhomogeneities of the electronic response, can significantly modify scattering rates across relevant momentum and energy scales. We present an all-electron framework for computing dark matter-electron scattering rates that incorporates dielectric screening at the random-phase approximation (RPA) level, including local field effects. Using crystalline silicon as a benchmark, we show that local field effects play an important role both at large momentum transfers, spanning multiple Brillouin zones, and at low momentum near the plasmon resonance. We compute electron recoil spectra and projected sensitivities for non-relativistic halo dark matter and for boosted dark matter or other dark-sector particles, which are sensitive to the impact of local field effects in these high and low momentum regimes, respectively. We further present RPA dielectric functions including local field effects for Ge, GaAs, SiC, and diamond, enabling a systematic comparison across target materials. These developments are implemented in the open source code QCDark2.
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All authors Cyrus Dreyer, Rouven Essig, Marivi Fernandez-Serra, Megan Hott, Aman Singal

Data Analysis and Statistics

Classifying hadronic objects in ATLAS with ML/AI algorithms

The identification of hadronic final states plays a crucial role in the physics programme of the ATLAS Experiment at the CERN LHC. Sophisticated artificial intelligence (AI) algorithms are employed to classify jets according to their origin, distinguishing between quark- and gluon-initiated jets, and identifying hadronically decaying heavy objects such as W bosons and top quarks. This contribution summarises recent developments in constituent-based tagging architectures, including graph neural networks (GNNs) and transformer-based approaches, their performance in simulated and real data, and future perspectives towards data-driven optimisation and model-independent tagging strategies.
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Optics · Cross-listed from quant-ph

Transition from Statistical to Hardware-Limited Scaling in Photonic Quantum State Reconstruction

The theoretical efficiency of classical shadow tomography is predicated on a perfect Haar-random unitary ensemble, yet this mathematical ideal remains physically unattainable in near-term hardware. Here, we report the experimental discovery of a fundamental accuracy bound on integrated photonic processors: a “Hardware Horizon” where the reconstruction error undergoes a sharp phase transition. While the error initially obeys the predicted statistical scaling $\mathcal{O}(M^{-1/2})$, it abruptly saturates at a floor determined by the spectral distortions of the realized unitary group. By deriving a phenomenological error model, we decouple the competing mechanisms of static coherent spectral distortion and dynamic decoherence, demonstrating that this intrinsic noise floor imposes a hard bound that statistical accumulation cannot overcome. These findings establish that the utility of shadow tomography on NISQ (noisy intermediate-scale quantum) hardware is defined by a specific scaling law involving hardware parameters, necessitating active compensation strategies to bridge the gap between theoretical purity and the noisy reality of integrated photonics.
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All authors Attila Baumann, Zsolt Kis, János Koltai, Gábor Vattay

Chemical Physics

Permutation invariant multi-scale full quantum neural network wavefunction

Solving the intricate quantum behavior of interacting particles is key to unlocking the mysteries of condensed matter, but capturing their complex correlations across different scales remains a monumental challenge. We introduce a neural network framework that overcomes this barrier by modeling the full quantum wavefunction of a system, including electrons, nuclei and muons, directly capturing the full quantum effects beyond the Born-Oppenheimer approximation. The neural network approximates joint wavefunction of different interacting particles with a rigorous handling of permutation invariance, enabling simultaneous treatment of nuclear quantum effects and electron-nucleus-muon couplings without explicit excited states. Validated on molecular systems, this approach offers a computationally feasible way to model full quantum phenomena in complex many-body systems, establishing a direct connection between fundamental particle properties and emergent material behavior.
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All authors Pengzhen Cai, Yubing Qian, Li Deng, Weizhong Fu, Lei Yang, Zhiyu Sun, Xin-Zheng Li, En-Ge Wang, Liangwen Chen, Weiluo Ren, Ji Chen

Biological Physics · Cross-listed from cond-mat.stat-mech

Non-Markovian Entropy Dynamics in Living Systems from the Keldysh Formalism

Living systems are open nonequilibrium systems that continuously exchange energy, matter, and information with their environments, leading to stochastic dynamics with memory and active fluctuations. In this study, we develop a non-Markovian theoretical framework for the entropy dynamics of living systems based on the Keldysh functional formalism and stochastic thermodynamics. The approach naturally incorporates colored environmental noise, memory-dependent dissipation, and many-body interactions, yielding generalized Langevin dynamics and non-Markovian master equations. Within this framework we derive an exact frequency-domain expression for the entropy production rate and show that violations of the fluctuation-dissipation relation provide a direct thermodynamic signature of active biological fluctuations. We further demonstrate that environmental memory enhances low-frequency fluctuations and entropy production, leading to critical slowing down near dynamical instability. These results provide a microscopic physical foundation for the entropy "bathtub" picture of living systems and connect entropy evolution with development, aging, and death in nonequilibrium dynamics.
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All authors Feiyi Liu, Min Guo, Hongwei Tan, Yang Wang