Quantum Physics
Papers
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Tuesday 24 March
Coherent Ising machines (CIMs) have emerged as specialized quantum hardware for large-scale combinatorial optimization. However, for large instances that remain challenging for classical methods, some platforms support only finite-precision inputs, and the required scaling and quantization can degrade solution quality. Dynamic portfolio optimization (DPO) can be formulated as a quadratic unconstrained binary optimization (QUBO) problem, but large instances are especially vulnerable to precision loss under global scaling. We propose a block coordinate descent method that decomposes the DPO model along the time dimension and iteratively solves compact time-block subproblems on the device. Experiments on finite-precision CIM hardware show that the method enables these instances to be solved under hardware precision limits, yields portfolios competitive with classical benchmark solvers, and reduces runtime through fast CIM solution of the resulting subproblems. These results demonstrate the promise of finite-precision CIMs as a practical and scalable approach to structured large-scale combinatorial optimization.
Quantum Physics
Quantum speedup from nonclassical polarization
We develop a framework for identifying nonclassical speedups in systems with polarization, likewise spin degrees of freedom. By confining the dynamics to the manifold of angular momentum coherent states, which act as the classical reference in this case, we compute the speed limit that bounds the rate of change of the state achievable without generating quantum coherence. A comparison with the unrestricted quantum speed limit enables the quantitative identification of speedups arising from polarization nonclassicality. We apply this framework to the cross-Kerr interaction, demonstrating a persistent speedup scaling as $\mathcal{O}(\sqrt{N})$ with the photon number $N$, with a parity effect in favour of even photon numbers. The results establish polarization nonclassicality as a genuine dynamical resource, linking quantum coherence to quantum-enhanced evolution speeds in nonlinear photonic systems.
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Quantum Physics
Metastability, chaos and spectrum tomography for Bose-Hubbard rings and chains
We analyze the metastability of Bose-Hubbard condensates for finite-size one-dimensional ring lattices and open chains, using a semiclassical tomographic perspective that emphasizes the relation of the many-body spectrum to the underlying classical phase-space structures. In order to address quantum ergodicity in far-from-equilibrium scenarios of experimental interest, we inspect both local aspects (via Bogoliubov analysis) and global aspects (mixed regular-chaotic dynamics). In particular, we highlight the roles of the two parameters that control metastability, clarify the essential differences between low- and high-dimensional chaos, and show how the dynamical instabilities diminish in the limit of the Gross-Pitaevskii equation. It is somewhat frustrating that with more degrees of freedom, the dynamically metastable islands become better distinct from the ergodic sea, while their borders become ill-defined topologically. This stands in opposition to the very structured phase-space of two-degree-of-freedom systems, as reflected in the tomographic quantum spectrum.
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Quantum Physics · Cross-listed from stat.ML
High-Resolution Tensor-Network Fourier Methods for Exponentially Compressed Non-Gaussian Aggregate Distributions
Characteristic functions of weighted sums of independent random variables exhibit low-rank structure in the quantized tensor train (QTT) representation, also known as matrix product states (MPS), enabling up to exponential compression of their fully non-Gaussian probability distributions. Under variable independence, the global characteristic function factorizes into local terms. Its low-rank QTT structure arises from intrinsic spectral smoothness in continuous models, or from spectral energy concentration as the number of components $D$ grows in discrete models. We demonstrate this on weighted sums of Bernoulli and lognormal random variables. In the former, despite an adversarial, incompressible small-$D$ regime, the characteristic function undergoes a sharp bond-dimension collapse for $D \gtrsim 300$ components, enabling polylogarithmic time and memory scaling. In the latter, the approach reaches high-resolution discretizations of $N = 2^{30}$ frequency modes on standard hardware, far beyond the $N = 2^{24}$ ceiling of dense implementations. These compressed representations enable efficient computation of Value at Risk (VaR) and Expected Shortfall (ES), supporting applications in quantitative finance and beyond.
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Quantum Physics
Propagation of optical vector vortices of slow light in a coherently prepared tripod configuration
We investigate the propagation of optical vector vortices of slow light in a coherently prepared four-level tripod atomic system. The vector vortex consists of superposed pulse pairs with opposite circular polarizations and orbital angular momentum (OAM) charges $\pm l$, weakly interacting with an atomic medium initially prepared in a coherent superposition of two ground states. A third unoccupied state is coupled to a stronger control laser without OAM, creating a phase-dependent configuration. In the linear regime, the vortex OAM is mapped onto the medium, producing symmetrical azimuthally structured absorption patterns, with losses significantly reduced by the control field. For small detunings, complementary spatially dependent amplification and absorption occur for the two circular polarization components. This OAM-structured coherence induces a dynamical anisotropy, affecting both the intensity and polarization of the slow-light vortex. Polarization states evolve periodically between left-circular, linear, and right-circular polarizations during propagation. Once the beam reaches a stationary regime, the ring-shaped intensity transforms into a petal-like structure, and the final polarization states stabilize according to the initial superposition. The rate of polarization transitions is tunable via the control field strength, demonstrating flexible control over slow-light vector vortex dynamics.
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Quantum Physics
Geometric Structure of Bell Correlations in Bohmian Mechanics: A Configuration-Space Analysis of EPR Experiments
We develop an explicit configuration-space formulation of EPR-Bell experiments within the framework of de Broglie-Bohm theory, in which joint measurement outcomes arise from a deterministic mapping from initial particle configurations to outcome pairs. This construction induces a partition of the hidden-variable configuration space into domains associated with the different measurement outcomes. Using a reduced-dimensional Stern-Gerlach model, we derive the structure of these domains and identify the corresponding separatrices that define their boundaries. We show that Bell correlations emerge from the geometry of these partitions: the domain boundaries depend nonlocally on the measurement settings, while the marginal outcome distributions remain invariant, providing a direct dynamical realization of no-signaling. Analytical results are supported by numerical simulations, which exhibit quantitative agreement with the predicted domain structure as a consequence of the underlying partition of configuration space induced by the measurement dynamics. This approach provides an explicit configuration-space representation of nonlocal correlations in Bohmian mechanics, linking trajectory dynamics, measurement processes, and statistical predictions within a unified framework.
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Quantum Physics · Cross-listed from cond-mat.stat-mech
Basis dependence of eigenstate thermalization
Eigenstate thermalization refers to the property that an energy eigenstate of a many-body system is indistinguishable from a thermal equilibrium ensemble at the same energy as far as expectation values of local observables are concerned. In systems with degeneracies, the choice of an energy eigenbasis is not unique and the fraction of basis states exhibiting eigenstate thermalization can vary. We present a simple example where this fraction vanishes in the thermodynamic limit for one basis choice, but remains nonzero for another choice. In other words, the weak eigenstate thermalization hypothesis is satisfied in the first, but violated in the second basis. We furthermore prove that degeneracies must abound whenever a system is simultaneously symmetric under spatial translations and reflection. Finally, we derive general bounds on how strongly eigenstate thermalization may depend on the choice of the basis, and we reveal some interesting implications regarding the temporal relaxation properties of such systems.
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Quantum Physics
Zero-Uncertainty States Relative to Observable Algebras
We study zero-uncertainty states with quantum memory from an operator-algebraic perspective, which naturally accommodates degenerate projective-valued measurements. In the equal-dimension setting, we prove a rigidity theorem for purity and maximal entanglement. We then analyze two mechanisms by which this rigidity can fail: one arising from proper observable subalgebras, and the other from allowing larger memory dimensions. In these cases, we give corresponding algebraic decomposition and representation-theoretic descriptions, and compare their mathematical structure with their physical interpretation. Finally, we present an example from quantum steering to illustrate how our framework helps resolve a concrete physical question in a specific setting.
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Quantum Physics · Cross-listed from cond-mat.quant-gas
Transformation of the Talbot effect in response to phase disorder
Bose-Einstein condensates initially arranged in a long chain freely expand and interfere. If the initial phases of the condensates are identical, the initial density distribution is restored periodically during the expansion, giving rise to the Talbot effect. Even a slight disorder in the initial phases leads to a transformation of the interference pattern. In response to the phase disorder, the spectrum of the spatial density distribution acquires peaks that are absent in the case of identical phases. We derive an analytical expression for the spectrum of the spatial density distribution for an arbitrary phase disorder. We show that the new peaks emerging due to the phase disorder originate from pairwise interferences of the condensates. The positions of these peaks coincide with the wave vectors of the density modulations (wavelets) generated by such pairwise interferences. The absence of these peaks, when the initial phases are identical, is explained by the mutual destruction of the overlapping wavelets during their summation.
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Quantum Physics
Local and Global Master Equations through the Lens of Non-Hermitian Physics
We investigate the relation between non-Hermitian Hamiltonian and Lindblad dynamics in nonequilibrium open quantum systems. Non-Hermitian models can extend phase diagrams and enable sensing advantages, but such effects often rely on postselection, raising questions about their relevance for unconditional dynamics. Using a minimal two-qubit setup mediating a heat current, we compare local and global Markovian master equations with their non-Hermitian counterparts. We observe that exceptional points emerge only in the local master equation and in the corresponding non-Hermitian Hamiltonian at sufficiently strong nonequilibrium. We further consider hybrid configurations, where one bath is treated with a Lindblad description and the other with a non-Hermitian approach, interpolating between the two extremes. Our results contribute understanding the role of quantum jumps and exceptional points in nonequilibrium open quantum systems and identify a simple, experimentally accessible architecture, realizable, for instance, in circuit-QED platforms, for their exploration.
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Quantum Physics
Connection-topology–dependent energy transport and ergotropy in quantum battery networks with reciprocal and nonreciprocal couplings
The realization of scalable quantum battery architectures requires concern not only with how much energy can be stored, but also with how energy is transported, distributed, and converted into extractable work across connected battery nodes. While previous studies mainly focused on collective charging in multi-cell quantum batteries, the topology-dependent transport law and the corresponding work-oriented performance of quantum battery networks remain largely unexplored. In this work, we investigate quantum battery networks with engineered reciprocal and nonreciprocal couplings and compare different connection topologies, including cascaded and parallel architectures, within a unified transport framework. In the nonreciprocal regime, the optimal coupling follows distinct scaling laws for the two connection topologies, namely $J_{\rm op}^{c}\propto N$ for cascaded transport and $J_{\rm op}^{p}\propto N^{-1/2}$ for parallel charging in the large-$N$ limit. In reciprocal cascaded networks, a parity-dependent spectral response produces an odd-even transport effect that is absent in the nonreciprocal and parallel configurations. We further analyze the role of thermal and squeezed reservoirs and show that thermal noise mainly increases passive energy, whereas squeezing enhances ergotropy and thus the useful fraction of stored energy. These results shift the emphasis from charging enhancement to transport engineering and provide architecture-level design principles for quantum battery networks.
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Quantum Physics · Cross-listed from cond-mat.mes-hall
Exploring Spectral Singularities in Dirac Semimetals: The Role of Non-Hermitian Physics and Dichroism
In this study, motivated by recent advancements in non-Hermitian physics, we explore new characteristics of Dirac semimetals (DSMs) using the spectral singularities by means of scattering techniques, with the goal of uncovering additional unique properties. To achieve this, we investigate how the axion texture of a DSM affects its topological properties by analyzing its interaction with electromagnetic waves. We examine the transverse electric (TE) mode configuration, where the magneto-electric effect induces a dichroic property in these materials. This behavior is particularly interesting and commonly seen in potential DSM candidates. Consequently, we report for the first time that a dichroic DSM generates 12 unique topological laser types. We discover that surface currents are generated by topological terms on the surface of the DSM slab. Furthermore, we examine how the {\theta} term associated with axions in topological materials contributes to these topological properties. Our study reveals distinct topological role of the {\theta} term more clearly than ever before. Our results confirm that the topological properties of DSMs with a single Dirac cone remain stable under external influences and that a topologically robust DSM laser can be developed accordingly
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Quantum Physics
Dynamical Evolution of Quantum Correlations and Decoherence in Coupled Oscillators Interacting with a Thermal Reservoir
We investigate the dynamical evolution of quantum discord, entanglement and purity in an open quantum system of two coupled asymmetric harmonic oscillators interacting with a thermal environment. Using the Kossakowski-Lindblad master equation we analyze the time evolution starting with a squeezed vacuum state. In contrast to our previous study on entanglement evolution in asymmetric oscillators, the present work introduces XY-type position-position coupling together with a systematic joint analysis of quantum discord and purity alongside entanglement. We examine the combined effects of the squeezing parameter, asymmetry parameter, coupling constant, dissipation rate and temperature. We find that quantum discord and entanglement exhibit, in general, a non-monotonic decrease over time. Increasing temperature consistently accelerates the degradation of both quantum correlations and purity, whereas increasing dissipation accelerates the degradation of quantum correlations but leads to higher steady-state purity. Increasing the squeezing parameter provides a protective effect by enhancing initial correlations and prolonging entanglement survival time, while increasing the coupling constant leads to higher quantum correlations. The asymmetry parameter exhibits only a weak influence on the correlation evolution. Our analysis reveals that quantum discord demonstrates stronger resilience than entanglement, which can present more complex behaviour including entanglement sudden death and possible temporary revivals and re-suppressions. These findings provide valuable insights for developing robust quantum information protocols and strategies for preserving quantum correlations in realistic open quantum systems, with potential extensions to non-Markovian regimes and multi-mode architectures.
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Quantum Physics
Imprecise quantum steering inequalities in tripartite systems
Quantum steering, as a manifestation of nonlocal quantum correlations, plays a crucial role in enabling various quantum information processing tasks. However, practical implementations are often hindered by significant challenges arising from imperfect or untrusted measurement devices. This study investigates the impact of measurement inaccuracies on quantum steering, with a particular focus on errors in the untrusted party's measurement devices. We first analyze how such errors affect the evaluation of steering inequalities, and then derive bipartite steering inequalities based on correlation matrices under imperfect measurements. Our findings show that even small measurement errors can significantly compromise the certification of quantum steerability, an effect that becomes particularly pronounced as the system dimension increases. Furthermore, by extending the proposed steering inequality to a modified tripartite scenario via correlation matrices, we demonstrate that the influence of measurement imperfections is far more severe in multipartite quantum steering than in the bipartite case. Our results underscore the critical need to account for measurement imperfections in experimental quantum steering and provide a theoretical framework for characterizing and mitigating these effects in high-dimensional quantum systems.
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Quantum Physics · Cross-listed from physics.atom-ph
In-orbit Test of the Weak Equivalence Principle with Atom Interferometry
The Weak Equivalence Principle (WEP) is a central pillar of general relativity. Its precise test with quantum systems in space offers a unique window onto new physics. Here we report the first in-orbit quantum test of the WEP. A dual-species (85Rb/87Rb) atom interferometer is realized aboard the China Space Station. Methods of platform motion suppression, fluorescence detection switching, and two-photon detuning switching are developed to eliminate phase noise and improve measurement accuracy. A test uncertainty of 2.8*10-8 is obtained from 280 days of WEP test data, and a test result of (-3.1+/-4.6)*10-7 is achieved after error estimation. This improves prior atom-interferometric WEP tests in microgravity by three orders of magnitude. This work paves the way for space-borne quantum inertial sensors and their application to future fundamental physics in space.
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Quantum Physics
A PAC-Bayesian approach to generalization for quantum models
Generalization is a central concept in machine learning theory, yet for quantum models, it is predominantly analyzed through uniform bounds that depend on a model's overall capacity rather than the specific function learned. These capacity-based uniform bounds are often too loose and entirely insensitive to the actual training and learning process. Previous theoretical guarantees have failed to provide non-uniform, data-dependent bounds that reflect the specific properties of the learned solution rather than the worst-case behavior of the entire hypothesis class. To address this limitation, we derive the first PAC-Bayesian generalization bounds for a broad class of quantum models by analyzing layered circuits composed of general quantum channels, which include dissipative operations such as mid-circuit measurements and feedforward. Through a channel perturbation analysis, we establish non-uniform bounds that depend on the norms of learned parameter matrices; we extend these results to symmetry-constrained equivariant quantum models; and we validate our theoretical framework with numerical experiments. This work provides actionable model design insights and establishes a foundational tool for a more nuanced understanding of generalization in quantum machine learning.
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Quantum Physics · Cross-listed from cond-mat.str-el
Non-Hermitian skin effect in periodic, random, and quasiperiodic systems
The non-Hermitian skin effect (NHSE), which drives bulk states toward system boundaries, modifies bulk-boundary correspondence and complicates the identification of topological edge modes. Although breaking translational symmetry is known to influence this behavior, a systematic comparison of different structural classes remains limited. Here we investigate periodic, random, and quasiperiodic (Fibonacci) systems using a one-dimensional non-Hermitian quantum walk model. By matching the local scattering parameters in a topologically nontrivial regime, we isolate the role of spatial structure in the presence of the NHSE. We find that periodic systems exhibit pronounced boundary accumulation of bulk states. Random systems suppress this accumulation through Anderson localization, but the topological gap becomes partially filled with localized in-gap states. In contrast, the Fibonacci quasiperiodic system suppresses large-scale boundary accumulation while maintaining a well-defined topological gap. Analysis of the wave functions suggests that the hierarchical quasiperiodic structure fragments bulk states across multiple length scales, thereby mitigating the NHSE. These results identify deterministic quasiperiodicity as a distinct structural regime for controlling non-Hermitian skin dynamics and isolating topological boundary modes.
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Quantum Physics
STAR-Magic Mutation: Even More Efficient Analog Rotation Gates for Early Fault-Tolerant Quantum Computer
We introduce STAR-magic mutation, an efficient protocol for implementing logical rotation gates on early fault-tolerant quantum computers. This protocol judiciously combines two of the latest state preparation protocols: transversal multi-rotation protocol and magic state cultivation. It achieves a logical rotation gate with a favorable error scaling of $\mathcal{O}(\theta_L^{2(1-\Theta(1/d))}p_{\text{ph}})$, while requiring only the ancillary space of a single surface code patch. Here, $\theta_L$ is the logical rotation angle, $p_{\text{ph}}$ is the physical error rate, and $d$ is the code distance. This scaling marks a significant improvement over the previous state-of-the-art, $\mathcal{O}(\theta_L p_{\text{ph}})$, making our protocol particularly powerful for implementing a sequence of small-angle rotation gates, like Trotter-based circuits. Notably, for $\theta_L \lesssim 10^{-5}$, our protocol achieves a two-order-of-magnitude reduction in both the execution time and the error rate of analog rotation gates compared to the standard $T$-gate synthesis using cultivated magic states. Building upon this protocol, we also propose a novel quantum computing architecture designed for early fault-tolerant quantum computers, dubbed “STAR ver.~3". It employs a refined circuit compilation strategy based on Clifford+$T$+$\phi$ gate set, rather than the conventional Clifford+$T$ or Clifford+$\phi$ gate sets. We establish a theoretical bound on the feasible circuit size on this architecture and illustrate its capabilities by analyzing the spacetime costs for simulating the dynamics of quantum many-body systems. Specifically, we demonstrate that our architecture can simulate biologically-relevant molecules or lattice models at scales beyond the reach of exact classical simulation, with only a few hundred thousand physical qubits, even assuming a realistic error rate of $p_{\text{ph}}=10^{-3}$.
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Quantum Physics
RC-HEOM Hybrid Method for Non-Perturbative Open System Dynamics
The Hierarchical equations of motion (HEOM) method is an important non-perturbative technique, allowing numerically exact treatment of open quantum systems with strong coupling and non-Markovian memory. However, its encoding of bath memory into auxiliary density operators often limits direct access to detailed bath information. In contrast, the reaction-coordinate (RC) mapping allows direct and transparent access to the dominant collective bath mode, but its perturbative and often Markovian treatment of the residual bath restricts its reliability. In this work, we introduce RC-HEOM, a hybrid method that unifies the strengths of both approaches by combining RC mapping with a fully non-perturbative HEOM description of the residual bath. RC-HEOM simultaneously retains exact non-Markovian memory and access to the RC mode, which enables analysis of system-RC information. Applying this method to the Anderson impurity models, we directly track the emergence of the Kondo singlet from the growth of the Kondo resonance and uncover a nontrivial RC-mediated coherence revival. These results demonstrate that RC-HEOM is a promising method for characterizing open quantum systems in regimes that are difficult to access with conventional master-equation methods.
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Quantum Physics
Encoded Quantum Signal Processing for Heisenberg-Limited Metrology
Entangled quantum probes can achieve Heisenberg-limited measurement precision, but this advantage is typically destroyed by noise. We address this issue by introducing a framework that we call encoded quantum signal processing, which unifies quantum error detection and quantum signal processing into an effective single-qubit framework, and provides a paradigm for constructing logical sensors that are robust to noise while remaining sensitive to the signal of interest. We show that encoding sensor qubits into a repetition code and using syndrome measurements as a signal-processing primitive restores Heisenberg scaling under realistic noise, without applying recovery operations. We prove that product-state sensing with syndrome post-processing is fundamentally limited to standard quantum limit (SQL) scaling, and develop four protocols that overcome this barrier through entanglement or sequential signal amplification, achieving Heisenberg-limited precision with exponential error suppression in code distance. For spatially inhomogeneous fields, Bayesian marginalization preserves Heisenberg scaling provided noise decreases sufficiently with system size. The underlying mechanism, which we formalize as encoded quantum signal processing, reduces multi-qubit metrology to an effective single-qubit problem where syndrome measurement implements nonlinear signal transformations. Numerical simulations validate the theoretical predictions: syndrome-based inference achieves near-Heisenberg scaling at noise levels where bare probes approach the SQL, and a concatenated protocol maintains this scaling under joint transverse noise and longitudinal inhomogeneities.
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Quantum Physics
Exponential Separation of Quantum and Classical One-Way Numbers-on-Forehead Communication
Numbers-on-Forehead (NOF) communication model is a central model in communication complexity. As a restricted variant, one-way NOF model is of particular interest. Establishing strong one-way NOF lower bounds would imply circuit lower bounds, resolve well-known problems in additive combinatorics, and yield wide-ranging applications in areas such as cryptography and distributed computing. However, proving strong lower bounds in one-way NOF communication remains highly challenging; many fundamental questions in one-way NOF communication remain wide open. One of the fundamental questions, proposed by Gavinsky and Pudlák (CCC 2008), is to establish an explicit exponential separation between quantum and classical one-way NOF communication. In this paper, we resolve this open problem by establishing the first exponential separation between quantum and randomized communication complexity in one-way NOF model. Specifically, we define a lifted variant of the Hidden Matching problem of Bar-Yossef, Jayram, and Kerenidis (STOC 2004) and show that it admits an ($O(\log n)$)-cost quantum protocol in the one-way NOF setting. By contrast, we prove that any $k$-party one-way randomized protocol for this problem requires communication $\Omega(\frac{n^{1/3}}{2^{k/3}})$. Notably, our separation applies even to a generalization of $k$-player one-way communication, where the first player speaks once, and all other $k-1$ players can communicate freely.
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Quantum Physics
Quantum Random Forest for the Regression Problem
The Random Forest model is one of the popular models of Machine learning. We present a quantum algorithm for testing (forecasting) process of the Random Forest machine learning model for the Regression problem. The presented algorithm is more efficient (in terms of query complexity or running time) than the classical counterpart.
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Quantum Physics
Understanding Bugs in Quantum Simulators: An Empirical Study
Quantum simulators are a foundational component of the quantum software ecosystem. They are widely used to develop and debug quantum programs, validate compiler transformations, and support empirical claims about correctness and performance. In the absence of large-scale quantum hardware, simulator outputs are often treated as ground truth for algorithm development and system evaluation. However, quantum simulators also introduce unique implementation challenges. They must faithfully emulate quantum behavior while executing on classical hardware, requiring complex representations of quantum state evolution, operator composition, and noise modeling. Yet, we still lack a large-scale and in-depth study of failures in quantum simulators. To bridge this gap, this work presents a comprehensive empirical study of bugs in widely used open-source quantum simulators. We analyze 394 confirmed bugs from 12 simulators and manually categorize them based on root causes, failure manifestations, affected components, and discovery mechanisms. Our study reveals several key findings. First, bug discovery is largely user-driven, with most crashes, exceptions, and resource-related failures not detected by automated testing and identified after deployment. Second, logical correctness failures are widespread and often silent, producing plausible but incorrect outputs without triggering crashes or explicit error signals. Third, many critical failures originate in classical simulator infrastructure, such as memory management, indexing, configuration, and dependency compatibility, rather than in core quantum execution logic. These findings provide new insights into the reliability challenges of quantum simulators and highlight opportunities to improve testing and validation practices in the quantum software ecosystem.
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Quantum Physics
Enabling Chemically Accurate Quantum Phase Estimation in the Early Fault-Tolerant Regime
Quantum simulation of molecular electronic structure is one of the most promising applications of quantum computing. However, achieving chemically accurate predictions for strongly correlated systems requires quantum phase estimation (QPE) on fault-tolerant quantum computing (FTQC) devices. Existing resource estimates for typical FTQC architectures suggest that such calculations demand millions of physical qubits, thereby placing them beyond the reach of near-term devices. Here, we investigate the feasibility of performing QPE for chemically relevant molecular systems in an early-FTQC regime, characterized by partial fault tolerance, constrained qubit budgets, and limited circuit depth. Our framework is based on single-ancilla, Trotter-based QPE implementations combined with partially randomized time evolution. Within this framework, we develop a novel Hamiltonian optimization strategy, termed unitary weight concentration, that reduces algorithmic cost by reshaping linear-combination-of-unitaries representations. Applying this framework to active-space models of iron-sulfur clusters, cytochrome P450 active sites, and CO$_2$-utilization catalysts, we perform end-to-end resource estimation using the latest version of the space-time efficient analog rotation (STAR) architecture. Our results indicate that ground-state energy estimation for active spaces of approximately 20 to 50 spatial orbitals, well beyond the reach of classical full configuration interaction, is achievable using $\sim 10^5$ physical qubits, with runtimes on the order of days to weeks. These findings demonstrate that while full-fledged fault-tolerant quantum computers will be required for even larger molecular simulations, chemically meaningful quantum chemistry problems are already within reach in an experimentally relevant, early-FTQC regime.
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Quantum Physics
Charging efficiency bursts in a quantum battery with cyclic indefinite causal order
Enhancement of quantum battery performance is a popular subject in quantum thermodynamics. An interesting phenomenon is the quick charging effect [Phys. Rev. Res. 6, 023136 (2024)], which has been explored by utilizing a quantum interferometric technique known as superposition of trajectories. A similar technique used to boost quantum battery performance is indefinite causal order. Here, we propose a new charging protocol that utilizes cyclic indefinite causal order, whereby $N$ charging sequences are superposed when utilizing $N$ chargers. We observe charging efficiency bursts when implementing our cyclic indefinite charging protocol. The duration of these bursts increase with $N$. Additionally, we present a circuit model to implement our charging protocol for the two-charger scenario and perform proof-of-concept demonstrations on IonQ, Quantinuum and IBMQ quantum processors. The results validate the existence of charging efficiency bursts as shown by our theoretical analysis and numerical simulations.
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Quantum Physics
Boundary-sensitive non-Hermiticity of Floquet Hamiltonian: spectral transition and scale-free localization
We report a novel mechanism of boundary-sensitive PT symmetry breaking in one-dimensional Floquet systems. By designing a time-periodic driving protocol, we realize a Floquet Hamiltonian that is Hermitian under periodic boundary conditions yet acquires non-Hermitian boundary terms under open boundary conditions due to the non-commutativity of driving Hamiltonians. We establish that a PT symmetry breaking transition occurs when the quasienergy bandwidth expands to cover the entire frequency Brillouin zone. This condition highlights a crucial difference from static non-Hermitian systems, where such transitions typically require band touching. Furthermore, we demonstrate that in the PT-broken phase, the eigenstates exhibit scale-free localization, a phenomenon arising from the specific system-size scaling of non-Hermitian terms. Finally, we provide a general framework for constructing multi-band models that exhibit this boundary-induced phase transition.
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Quantum Physics
Interference-induced state engineering and Hamiltonian control for noisy collective-spin metrology
Interference provides a fundamental mechanism for generating and manipulating entanglement in many-body quantum systems. Here, we develop an interference framework in which the nonlinear dynamics of collective spin-$\tfrac{1}{2}$ ensembles are mapped onto phase accumulation and self-interference in phase space, providing a direct and physically transparent description of entanglement formation. Within this framework, one-axis twisting produces Greenberger-Horne-Zeilinger (GHZ) states, while two-axis twisting generates multi-component GHZ superpositions relevant for multiparameter quantum metrology. Building on this interference-based description, we analyze metrological performance under realistic Markovian noise, including local and collective emission, pumping, and dephasing, and examine the role of Hamiltonian control based on linear and nonlinear interactions. We show that the optimal control enhances sensitivity in both single- and multiparameter estimation across noise-dependent regimes. These results establish interference as a unifying principle linking nonlinear dynamics, entanglement generation, and metrological performance. This framework offers a broadly applicable route to robust quantum-enhanced sensing in noisy many-body systems.
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Quantum Physics
Sub-nanometer resolution of the nitrogen-vacancy center by Fourier magnetic imaging
Solid-state spins in diamond are promising building blocks for quantum computing and quantum sensing, both of which require precise nanoscale addressing of individual spins. To explore the resolution limit of this approach, we demonstrate Fourier magnetic imaging of nitrogen-vacancy centers in diamond under state-of-the-art conditions. We constructed a highly compact experimental platform featuring thermal drift compensation under ambient conditions and generated a pulsed magnetic field gradient of up to 13.5 G/$\mu$m. By implementing the Fourier magnetic imaging protocol, we achieved localization of a single nitrogen-vacancy center with a spatial resolution of 0.28 $\pm$ 0.10 nm and a magnetic field measurement deviation of 9 nT. This technique holds potential for applications such as localizing spins within proteins and cells.
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Quantum Physics
Optimal filtering for a giant cavity in waveguide QED systems
In waveguide quantum electrodynamics (QED) systems, a giant cavity can be engineered to interact with quantum fields by multiple distant coupling points so that its non-Markovian dynamics are quite different from traditional quantum optical cavity systems. Towards feedback control this system, this paper designs an optimal filter for the giant cavity systems to estimate its state evolution under continuous quantum measurements. Firstly, the Langevin equation in the Heisenberg picture are derived, which is a linear continuous-time system with both states and inputs delays resulting from the unconventional distant couplings. Compared to existing modeling approaches, this formulation effectively preserves the nonlocal coupling and multiple delay dynamic characteristics inherent in the original system. In particular, the presence of coupling and propagation delays leads to noncommutativity among the system operators at different times, which prevents the direct application of existing quantum filtering methods. To address this issue, an optimal filter is designed, in which the delayed-state covariance matrices are computed. By iteratively evaluating the delayed-state covariance over successive time intervals, the resulting optimal filter can be implemented in an interval-wise backward recursion algorithm. Finally, numerical simulations are conducted to evaluate the tracking performance of the proposed optimal filter for the giant cavity. By comparing between the evolutions of Wigner functions of coherent and cat states and the filter, the effectiveness of the optimal filter is validated.
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Quantum Physics
Deterministic quantum master equation for non-Markovian signal processing
In this work, we derive a deterministic master equation to model a general, possibly non-Markovian, feedback. The master equation describes a system with a general evolution and measurement operation, with feedback being applied in terms of signal processing. The feedback signal has an arbitrary structure with dimensionality that indicates the degree of non-Markovianity of the information processing. We present examples to illustrate how such a master equation can be used to model systems with memory feedback and non-trivial frequency dependence.