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Physics Condensed Matter

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Monday 7 September

Statistical Mechanics

Reverse engineering of mechano-kinetic parameters from stochastic force profiles in heterogeneous ensembles of molecular motors and tracks

Heterogeneity in contractile systems of molecular motors interacting with their tracks plays a key role in numerous cellular physiological and pathological processes. However, its effects cannot be captured by theoretical models assuming identical mechano-kinetic properties for all motors. We developed a stochastic framework to describe heterogeneous ensembles of myosin motors comprising two populations with distinct mechano-kinetic properties. Assuming that motors interact with the actin filament (their track) as independent force generators, we derived the probability distribution of the isometric force and characterised the statistics of finite-size force fluctuations. The proposed framework includes an estimation procedure that simultaneously infers the mechano-kinetic parameters and the size of the motor ensemble, eliminating the need to prescribe it a priori. Validation against synthetic and experimental data shows the model accurately captures force fluctuations and provides realistic estimates of the ensemble size. Furthermore, the framework enables a quantitative assessment of ensemble heterogeneity and the inference of an unknown motor species properties. This approach provides a quantitative tool for characterising heterogeneous actin-myosin systems, such as those arising from the co-presence of different protein isoforms in cardiac and skeletal muscle, or from the partial replacement of native proteins with mutation-derived or engineered variants.
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All authors Valentina Buonfiglio, Irene Pertici, Pasquale Bianco, Duccio Fanelli, Stefano Gherardini

Materials Science · Cross-listed from quant-ph

Electron beam driven collective self hybridized exciton polaritons

Self-hybridized exciton polaritons in layered semiconductors emerge from the hybridization of excitonic resonances with confined photonic modes in films and provide a versatile platform for controlling light–matter interactions at the nanoscale. Yet, the nature of exciton–photon interactions and the collective and synchronous strong coupling of multiple excitons to the same photonic mode remain largely unexplored. Here, we use complementary momentum-resolved photoluminescence and cathodoluminescence spectroscopy to compare self-hybridized exciton polaritons in Ruddlesden–Popper perovskite flakes under optical and electron-beam excitation. We find that cathodoluminescence exhibits remarkably larger polaritonic level repulsion than photoluminescence, revealing an enhanced effective coupling strength under electron-beam excitation. We attribute this enhancement to the collective coherent excitation of multiple excitons by fast electrons, which couple to the same photonic mode and increase the interaction strength according to a $g_N=g_1\sqrt{N}$ scaling, with an effective number of up to $N\approx23$ coherently coupled excitonic oscillators. By reducing the electron kinetic energy, we further uncover a crossover to a partially incoherent excitation regime in which higher-order Fabry–Pérot exciton-polariton resonances disappear, leaving only the lowest polariton branches while coherent transition radiation persists. This transition arises because low-energy electrons excite excitons over extended spatial volumes, washing out the phase coherence required to sustain collective coupling and form polaritonic resonances. Our work shows that electron beams can actively modify collective light–matter coupling in layered semiconductors and establishes cathodoluminescence as a route to access excitation regimes beyond all-optical excitation schemes.
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All authors Parsa Darman, Maximilian Black, Prabhdeep Singh, Masoud Taleb, Victor DeManuel-Gonzalez, Sara Darbari, Fatemeh Chahshouri, Nahid Talebi

Quantum Gases

Nonequilibrium full counting statistics of multicomponent strongly-interacting quantum gases with defects

We investigate the full counting statistics of a one-dimensional multicomponent impenetrable gas released from a bipartite state in the presence of a local defect. Spin–charge separation reduces the multivariate generating function to an exact Fredholm determinant whose kernel is built from time-evolved single-particle orbitals. Expressing these orbitals in terms of scattering data gives access to both transient dynamics and the nonequilibrium steady state. We derive the leading long-time asymptotics and identify persistent oscillations in densities and currents caused by multiple bound states at the junction. We argue that interactions between components lead to a linear low-temperature correction to the current, in contrast to the quadratic correction in the single-component case. At equilibrium, we obtain the M-Wright distribution of spin transfer with $t^{1/4}$ scaling.
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Soft Condensed Matter · Cross-listed from physics.bio-ph

Self-Organized Dynamic Reactors: Product-Condensate Feedback Accelerates Reactions

Condensates can accelerate reactions by concentrating reactants, yet product accumulation can eliminate this advantage. We show that product-induced suppression of condensation generates rotating, deforming, and propagating condensate domains through spontaneous symmetry breaking. Their reorganization shifts reaction sites away from accumulated products while retaining reactant enrichment, yielding rates above those of static condensates and homogeneous states. Reaction flows can thus self-organize condensates into dynamic reactors, with implications for biological and synthetic systems.
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Statistical Mechanics

Probing magnetic correlations in space and time within predefined topological sectors of a macroscopic spin liquid

The triangular Ising antiferromagnet, with its residual entropy density and critical correlations at absolute zero, is the archetype of a two-dimensional spin liquid. Its ground state is partitioned into topological sectors connected by global spin flip events that wrap the lattice boundaries, and become statistically irrelevant in the thermodynamic limit where magnetic fluctuations are restricted to the dominant sector. Thus far, these properties have been mainly investigated from a theoretical perspective, and one might wonder to what extent they can be transposed to real materials. Here, we present experimental observations obtained in an artificial, macroscopic realisation of the seminal triangular Ising antiferromagnet that consists of a lattice of millimeter-sized NdFeB cylinders put into motion by a mechanical shaker. Specifically, we demonstrate that the very-low-energy physics and the true ground state of this model can be reached experimentally. Besides, we are able to probe, in space and time, the magnetic properties within manually preselected pockets of the ground-state manifold that emulate, to a good approximation, the behaviour in distinct topological sectors. Our approach opens new avenues for naked-eye visualisation and hand manipulation of many-body phenomena associated to frustrated magnetism and models of statistical physics.
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All authors Rémy Dangoisse, Jeanne Colbois, Laurent Del Rey, Nicolas Rougemaille, Johann Coraux

Materials Science

Coupled structural and electronic evolution under pressure in CuIr2Se4, CuRh2S4, and CuRh2Se4

Spinel chalcogenides provide a platform for investigating the interplay among metallic, superconducting, and pressure-induced insulating states. Here, we combine synchrotron powder X-ray diffraction and electrical-resistivity measurements to investigate the pressure evolution of CuIr2Se4, CuRh2S4, and CuRh2Se4 over pressure ranges extending beyond those previously explored. High-pressure diffraction reveals closely related monoclinic supercells in all three compounds. For CuIr2Se4 and CuRh2S4, constrained profile fits based on structural models relaxed using density functional theory are compatible with Phase-IV-type bond-disproportionated structures, whereas the data for CuRh2Se4 establish a compatible monoclinic unit cell without resolving its atomic-scale ordering pattern. Insulating-like transport develops abruptly over a narrow pressure range in CuIr2Se4 but more gradually over broader pressure ranges in the Rh-based compounds, in close correspondence with their respective structural transformations. We also establish previously unreported bulk superconductivity in CuIr2Se4 at ambient pressure: zero resistance is attained at 0.29 K, and the accompanying ac diamagnetic response is consistent with nearly complete superconducting shielding. These results establish a close relationship between the formation of the high-pressure monoclinic phases and the evolution toward insulating transport, and demonstrate that transition-metal and chalcogen substitutions tune the characteristic pressure scales and the competition with superconductivity within a closely related structural framework.
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All authors M. Emi, M. Shiomi, K. Kojima, K. Sugimoto, T. Karasawa, H. Suzuki, M. Takahashi, K. Oka, H. Kadobayashi, S. Kawaguchi-Imada, N. Hirao, T. Ohashi, D. Ito, T. Kubo, M. Matsushita, M. Nohara, K. Matsubayashi, N. Katayama

Materials Science

Excitons probe intrinsic flat band Mottness in a van der Waals heterostructure

Excitons provide a sensitive optical probe of electronic correlations in nearby two-dimensional materials, yet their coupling to intrinsic flat-band Mott systems remains largely unexplored. Here we combine gate-tunable optical spectroscopy with first-principles calculations to study monolayer WSe$_2$ in direct contact with the van der Waals Mott insulator Nb$_3$Cl$_8$. The gate evolution of WSe$_2$ excitonic resonances reveals signatures of a correlation-reconstructed Mott gap in Nb$_3$Cl$_8$ that is absent from the single-particle band picture. In the electron-doped regime, the WSe$_2$ 2s Rydberg exciton undergoes a multistage evolution and develops into interlayer attractive and repulsive polaron branches, showing that a Rydberg exciton can be dressed by strongly correlated flat-band electrons in an adjacent Mott layer. Under an out-of-plane magnetic field, spin-polarized Nb$_3$Cl$_8$ states further induce valley-selective exciton coupling, producing a strongly enhanced circular polarization of the WSe$_2$ exciton emission. These results extend exciton-based sensing and exciton-polaron physics to intrinsic flat-band Mott materials, providing an optical route to probe and engineer correlation-driven interfacial quasiparticles.
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All authors Xinyue Huang, Xintong Tan, Haowei Chen, Yingzhou Huang, Yushen Zhou, Yuchen Gao, Zhijie Ma, Chengxin Xiao, Kenji Watanabe, Takashi Taniguchi, Jianpeng Liu, Zuxin Chen, Youguo Shi, Wang Yao, Yu Ye

Mesoscale and Nanoscale Physics

Theory of staggered damping-like spin-orbit torque on synthetic antiferromagnetic domain walls

The Néel, or staggered, spin-orbit torque (SOT) enables an efficient electrical manipulation of antiferromagnetic order. However, it has been tied to special crystal structures, and only its field-like component is established. We develop a theory of staggered damping-like SOT, which arises generically in synthetic antiferromagnets sandwiched by the same heavy metal on both sides. Deriving a Néel-vector Lagrangian, we obtain the domain-wall (DW) velocity in closed form: bilinear in current and in-plane field, opposite in sign for Néel and Bloch walls, and tunable through the interlayer exchange coupling. DW structure thus becomes a control knob for DW motion, while the DW motion, in turn, offers an electrical readout of its structure. Micromagnetic simulations confirm the theory. The predicted sign reversals and scaling laws of the DW velocity, together with the thresholds for the Néel-Bloch transition, give immediate experimental targets.
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Statistical Mechanics

Irreversibility of many-body harmonic oscillators characterized by generalized Husimi's adiabaticity parameter

In a classical paper [K. Husimi, Prog. Theor. Phys. 9, 381 (1953)], Husimi showed that, for a single harmonic oscillator with a time-dependent angular frequency and initial conditions sampled from an equilibrium distribution, the averaged energy cannot decrease after a cyclic operation. This irreversibility is quantified by Husimi's adiabaticity parameter constituted with adiabatic invariants. In this work, we generalize Husimi's framework to a many-body system of one-dimensional harmonic oscillators coupled on an arbitrary connected network, with all spring constants sharing a common time dependence. For a system attached to a fixed wall, the dynamics can be decomposed into independent normal modes by transforming to mass-weighted coordinates and diagonalizing the resulting positive definite matrix, with each mode characterized by its own Husimi's adiabaticity parameter. By defining the generalized Husimi's adiabaticity parameter as their arithmetic mean, we derive the exact time evolution of the averaged energy and establish its non-decrease under cyclic operations. Numerical simulations confirm these results for both a uniform nearest-neighbor chain and a heterogeneous network.
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Materials Science · Cross-listed from physics.class-ph

Formation of grain boundaries in ductile single crystals under plane-strain simple shear: a block-coordinate finite element method

Large plastic deformation can drive an initially uniform single crystal to spontaneously subdivide into misoriented grains separated by thin dislocation walls – a pattern-forming instability rooted in the loss of convexity of the crystal's elastic energy at large strain. We study this phenomenon for a ductile crystal in plane-strain simple shear within continuum dislocation theory, using a polyconvex (Ciarlet–Geymonat) elastic energy that guarantees existence of minimizers for the coupled deformation–slip problem. Minimizing over the plastic slip yields a condensed energy of double-well form whose non-quasiconvexity favours a lamellar microstructure; the gradient of the geometrically necessary dislocation density regularizes it, giving the grain boundaries a finite thickness and energy as functions of the misorientation angle. A block-coordinate finite element scheme – alternating a convex non-smooth solve for the slip with a Levenberg-regularized Newton solve for the deformation – resolves this microstructure numerically and detects its spontaneous onset, reproducing the lamellar grain structure in agreement with the closed-form analysis.
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Statistical Mechanics

Relaxation of Sliding Friction from a Statistical Model of Aging Contacts

Frictional relaxation after a sudden velocity change underlies the phenomenological laws that describe the stability of steady sliding and of seismic faults. To connect this relaxation with measurable statistics of microscopic contacts, we introduce a minimal model incorporating logarithmic aging of contact forces and a power-law contact-size distribution reflecting fractal interface roughness, and derive the relaxation function analytically. Depending on the power-law exponent $\alpha$, the intermediate-time response exhibits a plateau, logarithmic decay, or power-law decay, in contrast to the exponential decay assumed in the phenomenological laws. The theory provides experimentally testable links between microscopic contact statistics and macroscopic frictional relaxation.
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Materials Science

Quantum hot carrier spectra in plasmonic catalysis

Vibrational activation of admolecules on metal nanoparticles is an elementary step in plasmonic catalysis, yet the underlying dynamics driven by hot carriers is not fully understood in the quantum regime. Using an atomistic description of plasmonic hot carrier generation, we investigate vibrational excitation and dissociation of oxygen on silver nanoparticles as a function of diameter D. As D reduces from the classical to quantum-sized regime, quantized distribution of hot carriers emerges with increasing population in the high-energy regions. These highly energetic hot carriers deliver more efficient vibrational coupling and dissociation. The rate of vibrational excitation shows a linear 1/D scaling, which results from Landau damping. It turns nonlinear at elevated light intensities due to vibrational heating generated by multiple electron scattering. The finding of quantized distribution of hot carrier in plasmonic catalysis opens new avenues for selective control and nonthermal energy conversion.
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All authors Yu Chen, Hanwen Jin, Fei Gao, Johannes Lischner, Shiwu Gao

Materials Science

Metastable polar order and phase competition in Carpy-Galy LaTaO4

Carpy-Galy LaTaO$_4$ undergoes a structural sequence linking the antipolar monoclinic $P2_1/c$ ground state and the polar orthorhombic $Cmc2_1$ phase through an incommensurately modulated regime. First-principles calculations identify a metastable polar monoclinic $P2_1$ phase as a commensurate intermediate in the phase-transition landscape. As a common subgroup of $P2_1/c$ and $Cmc2_1$, $P2_1$ provides a symmetry-connected route between the established polymorphs. Mode-resolved energy surfaces for these symmetry-breaking pathways show that coupling between the respective primary order parameters and an isosymmetric relaxation stabilizes the $P2_1$ minimum along both pathways. Consequently, the $P2_1/c\rightarrow P2_1$ transformation has a finite energy barrier, while a restricted soft-mode model retains competing $P2_1$ and $Cmc2_1$ basins over an illustrative range of harmonic stiffness. Lattice-metric and neutron-diffraction comparisons indicate a shared displacement character between the calculated commensurate state and the experimental IC-o modulation, supporting the use of $P2_1$ as a commensurate structural reference for IC-o. Finally, composition-dependent energetics suggest chemical routes for tuning polar-antipolar competition.
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Mesoscale and Nanoscale Physics

Self-Trapping Enabled Highly Bright Momentum-Indirect Interlayer Excitons

Interlayer excitons in two dimensional material heterostructures exhibit large exciton binding energies and long lifetimes, making them ideal platforms for studying excitonic devices and many body quantum phenomena. However, the spatially separated electron and hole nature of IXs reduces their oscillator strength by two orders of magnitude compared to intralayer excitons. Achieving high efficiency IX emission remains challenging and requires optimal material selection with appropriate momentum matching and meticulous device fabrication. Here we demonstrate a highly bright momentum indirect IX emission within heterostructures formed between 2D perovskites and monolayer transition metal dichalcogenides. The quantum yield of IX emission reaches 35.2% on average, over 50 times higher than that of the corresponding constituent TMD monolayer, with the highest value exceeding 60%. Notably, the radiative recombination efficiency of this momentum indirect IX exceeds that of momentum direct IXs in monolayer TMD-based heterostructures by two orders of magnitude. We suggest that the remarkably bright IX emission in our heterostructure originates from IX self trapping, induced by strong exciton phonon coupling arising from the soft lattice nature of the 2D perovskite. Our findings provide new insights into achieving high IX emission efficiency and open new avenues for exploring long lifetime excitonic devices.
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All authors Dong Yang, Zisheng Gong, Hao Wen, Yue Hu, Kaichen Jiang, Baixu Xiang, Weibo Gao, Qihua Xiong, Dehui Li

Materials Science · Cross-listed from physics.atm-clus

Core-Level Spectroscopy Decodes Bond-Alternation Dynamics of Cyclo[18]Carbon

The advent of X-ray free-electron lasers and high-harmonic generation has made time-resolved X-ray spectroscopy a powerful tool for probing local atomic environments, yet whether localized core excitations can report on global collective distortions remains open. Cyclo[18]carbon (C$_{18}$), with its polyynic ground state (D$_\text{9h}$) and cumulenic transition state (D$_\text{18h}$), provides an ideal model to address this long-standing issue in bond-length alternation (BLA) dynamics. Mapping two-dimensional potential energy surfaces by first-principles simulations, we find that core ionization symmetrizes the ground-state double-well potential along the BLA coordinate. Our calculated X-ray spectra reveal remarkable sensitivity to bond-length variations: C1s ionization potentials vary by up to 2.4~eV across the BLA coordinate (1.1–1.4~Å), with a 0.9~eV variation for minima predicted by different functionals, while NEXAFS $\pi^*$ peaks shift by up to 4~eV across the same coordinate. These predicted signatures provide a quantitative spectroscopy–structure dictionary for decoding transient structures in future ultrafast X-ray experiments and monitoring bond-alternation dynamics in real time.
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All authors Minrui Wei, Zeyu Liu, Sheng-Yu Wang, Jun-Rong Zhang, Lu Zhang, Guoyan Ge, Weijie Hua

Materials Science

Restoring the Surface Magnetic Gap in MnBi$_2$Te$_4$

A widespread experimental realization of quantized anomalous transport in the intrinsic magnetic topological insulator MnBi$_2$Te$_4$ is hindered by its elusive surface magnetic gap. Uncovering the origin of the gapless states is essential for accessing its topological properties. Here we show that surface defects lower the electrostatic potential, drive topological surface states into subsurface layers, suppress exchange interactions, thereby closing the gap. Tuning the surface electrostatic potential via external electric fields or interfacial fields in van der Waals heterostructures restores the expected gap and enables control of its topology. This is confirmed by model calculations and validated in defective MnBi$_2$Te$_4$ films interfaced with polar insulators, explaining the enhanced quantum anomalous Hall effect under AlO$_x$ capping observed in recent experiments. Our theory identifies electrostatically driven surface-state delocalization as a competitive origin of gap suppression and proposes displacement-field engineering for robust quantized transport.
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Materials Science

Scalable machine learning framework for multiphase identification from powder X-ray diffraction

X-ray diffraction (XRD) is the primary tool for identifying crystalline phases following synthesis, but automated phase identification remains challenging, particularly for multiphase samples with overlapping peaks and experimental artifacts. While deep-learning methods have been proposed to improve upon classical search-match algorithms, most formulate phase identification as a single closed-set classification problem, requiring one shared model to discriminate among all candidate phases. Here we introduce GALAXI, which instead decouples the identification task into independent one-versus-all binary classifiers that each specialize in recognizing a single phase. These pre-trained classifiers first narrow the search space to a small set of plausible phases, which are then evaluated through Rietveld refinement to identify the combination of phases that best explains the full diffraction pattern. On a curated set of experimental patterns, GALAXI identifies the correct phases with a micro-F1 score of 0.935, outperforming classical search-match and prior deep-learning models. The method remains robust to common experimental artifacts, including low impurity phase fractions, small crystallite size, peak shifts, sample displacement, and texture, and performs well when applied to time-resolved in-situ XRD data from solid-state reactions. Moreover, because the phase-specific models are independent, GALAXI can expand to large reference libraries without retraining existing models. This modular architecture enables us to train classifiers for 64,594 structures from the Crystallography Open Database and deploy them through a public web interface at https://galaxi-xrd.com.
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All authors Xinyang Tong, Ethan Jin, Jiahan Xu, Aditya Rao, Pengcen Jiang, Nathan J. Szymanski

Strongly Correlated Electrons

Spin–orbit-enhanced correlation sensitivity and anomalous magnetic response in non-dimerized $4d^4$ ilmenite CdRuO$_3$

We report the synthesis and physical properties of CdRuO$_3$, a nominal Ru$^{4+}$ $4d^4$ ilmenite with edge-sharing RuO$_6$ honeycomb layers. Powder X-ray diffraction establishes a crystallographically non-dimerized $R\bar{3}$ structure with equivalent Ru-Ru bonds and a strongly distorted RuO$_6$ environment. The compacted-pellet resistivity is nonmetallic but non-Arrhenius, while the heat capacity contains a finite residual linear term. Matched nonmagnetic calculations show that PBE+$U$ without spin-orbit coupling remains metallic or semimetallic up to $U_{\mathrm{eff}} = 3$ eV, whereas PBE+SOC+$U$ exhibits a strong $U_{\mathrm{eff}}$ dependence and opens a direct gap of approximately 55 meV at $\Gamma$ for $U_{\mathrm{eff}} = 2.5$ eV. Spin-orbit coupling therefore markedly enhances the correlation sensitivity of the non-cubic Ru $t_{2g}$ manifold. After subtraction of a dilute Curie-Weiss defect contribution, the susceptibility remains weakly nonmonotonic and is inconsistent with both an ordinary Pauli response and independent spin-only $S = 1$ moments. CdRuO$_3$ thus realizes the non-dimerized structural branch predicted for ruthenium ilmenites, but not a simple robust multiorbital metal.
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Materials Science

Human-agent discovery of reconfigurable in-plane ferroelectric superdomain control

Automated experimentation is most effective when the observables, available actions, and objective are defined before the experiment starts, as is the case for Bayesian optimization. However, in many exploratory experiments, the variables that describe the sample must be extracted from the data, new operations emerge during the experiments, and the instrument budget is too small to learn the problem by trials. Here we introduce the Scanning Probe Agentic Research Cycle (SPARC) framework, in which a coding agent and a human operator share one microscope, one notebook, and two persistent memory files. FINDINGS.md stores graded conclusions about the experiment, whereas PITFALLS.md records learned failure modes of analysis and instrument. We apply SPARC to reconfigure the in-plane superdomain direction of a (111)-oriented PbZr0.2Ti0.8O3 film. In an operator-supervised campaign, the agent reanalyzed earlier manual measurements and developed an oriented lattice of stationary bias pulses with alternating polarity to reconfigure the superdomain direction. In a subsequent agent-controlled campaign, PITFALLS.md entries were compiled into checks that validate a design before any write. The experiments showed that spatial polarity alternation, instead of the exact matching between the lattice and lamellar periods, determines directional selection. Combining a raster scan with a masked pulse lattice printed the letters UTK into the superdomain orientation. The campaign also identified practical requirements for agentic experimentation where physical verification of instrument execution, the conditions under which stored findings remain valid, validation of new observables on instrument data, and robust control protocols.
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All authors Yu Liu, Boris Slautin, Ching-Che Lin, Jaegyu Kim, Lane W. Martin, Sergei V. Kalinin

Other Condensed Matter

On average stress within sub-regions of granular media

The paper concerns computation of average stress within small sub-regions of a larger static granular assembly, where the sub-region's boundary is allowed to pass through the assembly's particles. An exact average is computed for certain stress components and for certain categories of sub-regions. The paper also identifies those choices of sub-regions for which exact stress components may be exactly computed, but when these conditions are not met, provides reasonable bounds on the error.
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Sunday 6 September

Disordered Systems and Neural Networks

Localization Landscapes as Operator-Induced Geometry for Heterogeneous Systems

Heterogeneous operators often organize response through hidden barriers, wells, and weakly communicating compartments that are not faithfully described by Euclidean distance or raw graph connectivity alone. We study this structure through the localization landscape, obtained from a single source solve, and the associated effective potential $W_{\mathrm{eff}} = 1/u$. Starting from both discrete Schrödinger-type operators and heterogeneous reaction-diffusion operators, we show how $W_{\mathrm{eff}}$ induces effective wells, basin partitions, and Agmon-type neighborhoods that serve as an operator-aware geometry for localization and transport. This geometry explains the spatial support of low-energy eigenmodes, produces adaptive receptive fields on a fixed graph, sharpens locality in attention-like interactions, and yields bottleneck-sensitive modulation of diffusion. We also include a finite-element reaction-diffusion example with strongly compartmentalized coefficients, demonstrating that the same framework extends beyond simple grid operators to heterogeneous continuum systems. The results support a precise conclusion: localization-landscape geometry is a strong inductive bias when relevance is controlled by confinement, barriers, and low-energy accessibility, but its benefits are task-dependent rather than universal.
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Materials Science · Cross-listed from cs.SE

The Double Measurement Confound in Agent Benchmarks: De-Scaffolding, Ground-Truth Scoring, and Reliability Beyond the Mean

Agent benchmarks are increasingly used to compare large language models (LLMs) and guide deployment decisions, yet benchmark scores are meaningful only if they measure model capability rather than properties of the evaluation pipeline. We identify a double measurement confound: execution-critical decisions are performed by a fixed scaffold instead of the model, while the scorer evaluates outputs using criteria that may not reflect task correctness. We unify these issues within a measurement-theoretic framework that characterizes when benchmark scores can be interpreted as evidence of model capability, and instantiate it with an audit-and-repair protocol that (i) transfers execution-critical decisions from the scaffold to the model, (ii) replaces shape-based evaluation with seeded ground-truth scoring, and (iii) reports reliability beyond the mean through worst-case and tail-risk metrics. Experiments on ComtradeBench show that the joint intervention transforms a nearly flat leaderboard into a reliability spectrum that distinguishes both average performance and robustness across seeds. Applying the audit to existing benchmarks further shows that scorer validity is benchmark-specific, whereas scaffold ownership is an uncontrolled axis wherever we probed it. Our results suggest that benchmark scores should be interpreted together with their scaffolding level, scoring criterion, and reliability profile, providing a practical framework for more valid evaluation of LLM agents.
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All authors Yonghong Zhang, Shadi Motaali, Vu Phong Dinh, Avin Piroutiniya, Jorge E. López de Vergara, Luis de Pedro, Ricardo Correia, Isabel M. Parra, Yong Xie

Materials Science

Magneto-spin-orbit graphene: Chern topology and photoinduced Hall response

Magneto-spin-orbit graphene can host Chern phases due to proximity interactions, but in realistic heterostructures these depend on substrate chemistry, local stacking registry and may be altered by buried-interface reconstruction. Investigation of these effects requires special efforts to take into account the long-range moire patterns that often arise for these heterostructures. We address this question using first-principles calculations and effective four-band models for four out-of-plane magnetized Gr/(Au, Pt)/(Co, Mn) heterostructures in commensurate (2 x 2) and moire (9 x 9) supercells where the latter include misfit dislocations for the Co-based interfaces. The commensurate cells overestimate charge transfer and exaggerate valley asymmetry, whereas moire averaging strongly reduces both effects while preserving sizable spin splittings. The Pt spacer mediates stronger proximity interactions than Au, while replacing Co by Mn substantially changes the balance of the effective exchange interactions in a spacer-dependent manner. Introduction of misfit dislocations into the Co-based structures is selective and tunes the Dirac gap in Gr/Au/Co or spin splittings in Gr/Pt/Co. Graphene in Gr/Pt/Co exhibits effective ferromagnetic Chern phase with C = 2 in all studied supercells. By contrast, the moire models of the other three compositions are ferrimagnetic and topologically trivial, with C = 0. Nevertheless, they exhibit helicity-dependent photoinduced Hall responses, which are strongly enhanced by misfit-dislocation reconstruction in Gr/Au/Co. This work demonstrates that moire-scale stacking controls the effective Chern phase and Hall conductivity, whereas buried-interface defects tune the photoinduced Hall response without changing the topology.
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Other Condensed Matter · Cross-listed from hep-ph

Geometric Phases in Two-Level Mixing: From Neutral Mesons to Holonomic Qubits and Topological Majorana Modes

We investigate the geometric structure of a Hermitian two-level mixing Hamiltonian motivated by neutral meson oscillations and its connections with qubit, fermionic, and topological descriptions. Mapping the Hamiltonian to an effective qubit representation, we analyze the geometric phase associated with cyclic parameter evolution on the Bloch sphere. Without identifying the complex mixing phase with a physical CP-violation observable, we interpret it as a CP-like geometric parameter controlling the azimuthal orientation of the Hamiltonian vector and its reversal under phase conjugation. Third-order Bargmann invariants constructed from the eigenstates yield an associated discrete phase whose dependence on the mixing parameters is examined alongside the continuous geometric construction. The cyclic evolution is also represented as a single-qubit $R_z$ phase operation and expressed through Majorana bilinears. Extending the construction to the momentum-dependent Bogoliubov-de Gennes Hamiltonian of the Kitaev chain, we relate momentum-space winding to the topological regimes and the quantized Berry (Zak) phase in the real-parameter model, while the corresponding Bargmann construction approaches the global phase in the continuum limit. Together, these results provide a geometric perspective connecting phase structure, qubit operations, fermionic representations, and momentum-space topology within related two-level Hamiltonians.
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Materials Science

A Novel Nb-Based Eutectic Superalloy with Exceptional Ultrahigh-Temperature Mechanical Properties

Refractory alloys operating above 1300 {\deg}C, beyond the limit of Ni-based superalloys, must balance high-temperature strength, thermal stability, low density, low cost, and room-temperature tensile ductility, a combination that existing refractory alloys have yet to achieve. Here we report a castable Nb-based eutectic superalloy, Nb-10Mo-9.5C (at. %, NMC-1), comprising a uniform lamellar structure of Nb-Mo solid solution and Nb2C carbide phases. NMC-1 achieves 0.2% yield strengths of ~300 MPa and ~200 MPa at 1300 {\deg}C and 1500 {\deg}C, respectively, among the highest reported for Nb-based alloys, with pronounced strain hardening, non-zero room-temperature tensile ductility, and no observed microstructural coarsening after 100 h at 1400 {\deg}C. Its low density (8.65 g/cc) and cost (~$85/kg) yield a specific-strength-per-cost merit index that far surpasses commercial Nb, Mo, Ta, and W alloys, establishing a new design paradigm for ultrahigh-temperature structural materials.
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All authors Ayeman M. Nahin, Alfredo Navarrete, Xiaokun Yang, Eric A. Lass, Mingwei Zhang

Statistical Mechanics

Improved mean squared displacement analysis for anomalous single particle trajectories

The mean squared displacement (MSD) is a cornerstone in the analysis of diffusion processes in complex media. When the system is heterogeneous and, in particular, when single-particle trajectories are short, it is essential to extract maximal information from each measured trajectory. This is typically done by time-averaging squared increments and examining the scaling of the time-averaged MSD in log-log space. However, classical regression methods perform poorly in this setting because time-averaging introduces correlations aggravated by those inherent to anomalous diffusion. We tackle these limitations by applying a generalized least squares framework, which substantially reduces variance and bias in diffusion parameter estimates, especially for short (around 100 points) and ultra-short (around 10 points) trajectories. The method is fully automated and requires no supervision. Furthermore, it enables prediction of estimation error probability density, which is asymptotically Gaussian, for both classical and enhanced approaches. Leveraging this prediction, we introduce a specialized deconvolution algorithm that reconstructs the underlying particle ensemble structure from experimental data.
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All authors Jakub Ślęzak, Joanna Janczura, Diego Krapf, Ralf Metzler

Quantum Gases · Cross-listed from astro-ph.GA

Fractional Bose-Einstein Condensate Dark Matter Cores: Numerical GPP Solutions and SPARC Rotation Curves

We investigate a fractional Bose Einstein condensate dark matter scenario in which an ultralight bosonic component forms a self gravitating core embedded in a predominantly cold dark matter halo. The stationary GPP system solved numerically beyond the TF approximation leads to energetically bound equilibrium configurations and good phenomenological fits to the selected rotation curves from 30 SPARC galaxies.
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Superconductivity

Symmetry-selective field-induced triplet superconductivity in Ising-superconductor monolayer NbSe$_2$

We investigate superconductivity in monolayer NbSe$_2$, an Ising superconductor, under an in-plane Zeeman field $h_x$, focusing on the emergence of symmetry selected equal-spin triplet pairing. Using a self-consistent Bogoliubov–de Gennes approach with realistic hopping parameters for monolayer NbSe$_2$ on a triangular lattice, we determine the energetically favored singlet pairing states in a range of chemical potentials $\mu$ for onsite, nearest-neighbor, and next-nearest-neighbor pairing channels, and map the resulting phase diagram in $(h_x,\mu)$ plane. A momentum-resolved analysis reveals distinct dominant contributions in order parameters arise from the surroundings of $\Gamma$, $K$, and $K'$ points of the Brillouin zone. We find that an in-plane magnetic field helps to induce a triplet pairing whose symmetry is determined by the parent singlet state, upon opening the triplet interaction channel. For the nonlocal pairing channels, chiral-$d$ pairing is energetically favored and it induces chiral-$p$ equal-spin triplet component with opposite chirality. We further find that Rashba spin-orbit coupling, relevant to substrate coupling and electrostatic gating, suppresses the superconducting orders and reduces the critical field. Our results establish a direct link between the symmetry of the parent singlet condensate and the emergent triplet superconductivity, highlighting monolayer NbSe$_2$ as a promising platform for field-tunable mixed-parity superconducting states.
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Strongly Correlated Electrons

Ginzburg-Landau Theory for Non-Invertible Symmetry-Breaking Transitions

Recently, a generalized Landau paradigm has been proposed, in which a broad class of "unconventional" phase transitions lying beyond the original symmetry-breaking framework of Landau are understood as the symmetry-breaking transitions of generalized symmetries. In particular, in (1+1)D, such "topological" or "deconfined" transitions can be mapped to the symmetry-breaking transitions of non-invertible symmetries. How to extract the universal dynamical properties of the transitions from this understanding? In this paper, we follow the Ginzburg-Landau philosophy and develop a field-theoretic description of such critical points in terms of the fluctuations of local order parameters, now of non-invertible symmetries. The Symmetry Topological Field Theory formalism plays a central role in our analysis, allowing us to identify the algebra of local order parameters from the Lagrangian algebra of a (2+1)D topological order. We illustrate the key ideas and the full steps of this generalized Ginzburg-Landau procedure using the transitions between gapped phases with a simple non-invertible symmetry — the Rep($S_3$) symmetry.
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Materials Science

Collective Excitonic Structure Governs Anomalously Weak Thermal Optical Dephasing in Conjugated Polymers

Conjugated polymer aggregates exhibit optical decoherence in the presence of strong vibronic coupling and substantial diversity in chemical structure, solid-state organization, and excitonic character. Here, we use coherence-detected and population-detected two-dimensional electronic spectroscopies to examine the temperature dependence of the homogeneous optical linewidth across a series of semiconducting polymers. Despite substantial differences in molecular architecture and solid-state organization, all polymers studied exhibit remarkably weak thermal linewidth scaling over the measured temperature range. Comparison between complementary detection modalities further shows that, while this weak temperature dependence is obust, the absolute homogeneous linewidth depends on the measured observable. This behavior reflects the different ways in which coherence- and population-detected measurements project population relaxation and pure dephasing onto the spectroscopic response. These results establish the weak thermal scaling of optical decoherence across a diverse series of conjugated polymers and show that its experimental manifestation must be interpreted in the context of the detection observable.
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All authors Henry J. Kantrow, Elizabeth Gutiérrez-Meza, Eric R. Bittner, Hao Li, Carlos Silva-Acuña