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Friday 10 April

Quantum Physics

Detuning-Controlled Phase Transition from Passive to Active Regimes in Non-Markovian Quantum Batteries

We investigate a two-qubit quantum battery where coherent charger-battery coupling competes with non-Markovian environmental interactions. By tuning the coupling strengths and detuning, we identify regimes in which environmental memory enhances energy storage and charging power, while strong dissipation suppresses ergotropy by driving the battery into passive states. We show that detuning plays a dual role: reducing dissipation and inducing a phase shift in the memory kernel that controls the interference between coherent energy exchange and environment-induced backflow. As a result, although the stored energy varies smoothly, the extractable work exhibits a discontinuous onset at a critical detuning, signaling a first-order phase transition in ergotropy. The corresponding phase diagram in the coupling-detuning plane reveals a sharp boundary between thermodynamically inactive and work-producing regimes. Our results demonstrate that phase-controlled coherence and non-Markovianity provide a powerful mechanism for optimizing work extraction in open quantum batteries, offering practical strategies for noise-resilient quantum energy storage.
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Quantum Physics

Q-PIPE: A Practical Quantum Phase Encoding Method

Efficient loading of classical data into quantum states remains a central bottleneck of quantum computing. We propose Quantum-Gray Phase Injection for Pixel Encoding (Q-PIPE), which writes continuous data into the eigenphases of a diagonal oracle by phase kickback and converts them coherently into computational-basis states by quantum phase estimation. Sums and differences between data sets are obtained by sequential oracle application, without quantum arithmetic circuits. We apply Q-PIPE to quantum image processing, using edge detection by directional finite differences as a proof of concept. Synthesized with uniformly controlled rotations, the oracle requires O(qN) controlled-NOT gates without ancillas for N pixels and q estimation qubits. This is the same scaling as optimized preparation of the novel enhanced quantum representation, whose output form Q-PIPE reproduces. A half-spectrum normalization removes phase aliasing, and a probability threshold derived from the phase-estimation kernel and scaled with image size controls spectral leakage. In ideal simulation, edge detection is exact for inputs commensurate with the estimation register and has low mean absolute error for continuous data. Under device noise models, multi-controlled-phase synthesis drives the output close to the maximally mixed state. The uniformly controlled synthesis instead reduces the compiled depth by a factor of 53–59 and preserves the edge structure (Pearson correlation r = 0.99 with the classical gradient). The limiting resource on current hardware is therefore the compiled oracle depth, not the encoding principle.
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All authors Brian García Sarmina, Emmanuel Martínez-Guerrero, Janeth De Anda Gil, Sun Guo-Hua, Dong Shi-Hai

Quantum Physics

Protein-Ligand Free Energy Perturbation on Quantum Hardware

The use of free energy perturbation (FEP) methods to study protein-ligand complexes is one of the most important tools in structure-based drug design. Because FEP methods typically rely on force fields, they may suffer from force field parameter-related issues. Herein, we present a quantum mechanics/molecular mechanics (QM/MM) hybrid method to overcome deficiencies in force-field models by using QM bookending approaches on both classical and quantum hardware. In the MM part of this QM/MM FEP method, AMBER is used to simulate the protein receptor and the unperturbed moiety of the ligand, with the ff19SB and GAFF2 force fields. In the QM part, QUICK was used to conduct Hartree-Fock (HF) calculations, followed by heat-bath configuration interaction (HCI) as a benchmark on classical devices. To enable the HCI function in QUICK, we developed a Python-based interface to execute HCI from IBM's qiskit-addon-dice-solver. Moreover, the same interface also enabled this work to execute QM/MM FEP calculations on quantum hardware using the Local Unitary Cluster Jastrow (LUCJ) ansatz, followed by sample-based diagonalization (SQD) and extended-SQD (extSQD) post-processing. Using a series of thermolysis inhibitors as an example, we find reasonable agreement with experiment between the classical HCI method and the LUCJ-SQD/extSQD method, with the latter yielding a result closer to the experimental value. The execution time between the HCI-based FEP method and the LUCJ-SQD/extSQD-based FEP method is also comparable, indicating a high potential for utility in the noisy intermediate-scale quantum (NISQ) era.
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All authors Zhen Li, Milana Bazayeva, Thaddeus Pellegrini, Subhamoy Bhowmik, Susanta Das, Danil Kaliakin, Fangchun Liang, Akhil Shajan, Kenneth M. Merz Jr

Quantum Physics

A Logarithmic-Depth Quantum Multiplier

We present a quantum algorithm for multiplying two $n$-bit integers with overall circuit depth and $T$-depth both bounded by $O(\log n)$, while using $O(n^2)$ gates and ancillary qubits. Our construction generates partial products via indicator-controlled copying and adds them using a tree of reversible $3$-to-$2$ adders followed by one quantum carry-lookahead adder. Building on the carry-save adders of Kim et al., we combine full input fanout, workspace reuse, and phase-corrected gate implementations to reduce $T$-depth. We provide explicit circuit constructions, proofs of correctness, and concrete closed-form resource bounds.
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Quantum Physics

Polarization Tracking and Active Compensation Using Classical Headers in Quantum Wrapper Networking

Quantum wrapper networking (QWN) is an emerging quantum networking protocol that wraps qubits in classical header bits to enable switching/routing, monitoring, and control without detecting the quantum signal. In this work, we encode header bits with two nonorthogonal polarization references to track and actively compensate for the changing birefringence of a 48 km deployed fiber link. Our method is analytical and deterministic, using motorized waveplates and a variable phase retarder to accurately and stably compensate the channel. We verify successful compensation by measuring the polarization stability of single photon qubits and the visibility of entangled photon pairs under both slow birefringence drift due to environmental fluctuations and large sudden changes designed to emulate those that occur during packet switching and rerouting over different fiber paths. For large, sudden changes, our compensator recovers the Stokes vector of single photons to within 10 degrees of the target state on the Poincaré sphere and restores the two-photon interference visibilities to their original levels on the deployed fiber link. Additionally, experiments monitoring long-term compensation over 44 hours show that active polarization compensation maintains the two-photon interference visibility, whereas disabling the compensator leads to visibility degradation over time, particularly in the diagonal-antidiagonal basis, where the average raw visibility decreases by 7.7%. These results add a polarization-control layer to QWN and illustrate that information-carrying headers can enable deterministic physical-layer compensation in the quantum channel over long-distance deployed fiber links.
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All authors Gamze Gül, James van Howe, Gregory S. Kanter, Shannon G. Tan, Liam E. Beaudoin, Mehmet Berkay On, Roberto Proietti, S. J. Ben Yoo, Prem Kumar

Quantum Physics

Planted-solution SAT and Ising benchmarks from integer factorization

We present a family of planted-solution benchmark instances for satisfiability (SAT) solvers and Ising optimization derived from integer factorization. Given two primes $p$ and $q$, the construction encodes the arithmetic constraints of $N = p \times q$ as a conjunctive normal form (CNF) formula whose satisfying assignments correspond to valid factorizations of~$N$. The known pair $(p,q)$ serves as a built-in ground truth, enabling unambiguous verification of solver output. We show that for two $d$-bit primes the total number of carry contractions is on the order of $d^4$. Empirical benchmarks with SAT solvers show that median runtime grows exponentially in the bit-length of the factors over the range tested. The construction provides a scalable, structured, and verifiable benchmark family controlled by a single parameter, accompanied by open-source generation software.
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Quantum Physics

Discovery of the Solution to the "Einstein-Podolsky-Rosen Paradox"

In 1935, Albert Einstein, Boris Podolsky and Nathan Rosen (EPR) published a thought experiment that is entirely correct, has been demonstrated in real experiments, and is now the most famous in quantum physics. Their pioneering work described, for the first time, quantum correlations and can be regarded as a very early glimpse into today's 'deep' quantum technologies, by which I mean those that enhance functionality by making use of quantum correlations. However, their work also contains a paradox that Erwin Schroedinger had already recognised as such in 1935 and which has since been cemented by the so-called Bell experiments. Here, I am now able to pinpoint the origin of the paradox within the chain of reasoning, which ultimately resolves the paradox.
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Quantum Physics

Optimising Quantum Error Correction Using Morphing Circuits

Quantum error correction (QEC) codes are traditionally defined and searched for without specifying the manner in which its syndrome extraction circuits are executed using elementary gates and measurements. We show how morphing circuits introduced in Refs. [1-3] provide a way of optimising syndrome extraction circuits and codes directly in terms of connectivity, choice of two-qubit gate (ISWAP versus CNOT) and number of physical qubits. We discuss morphing circuits in code optimisation among Abelian two-block group algebra (2BGA) codes, handling boundaries for 2D codes, codes with single-shot properties, and improving performance in stability experiments against measurement and reset errors. We show that alternating syndrome extraction circuits - executed with alternating time-reversed rounds - can be viewed as a two-round morphing circuit whose fault-tolerant properties are computationally much easier to examine than non-alternating syndrome extraction circuits. Our methods find new codes and syndrome extraction circuits of practical interest, including Abelian 2BGA morphing circuits with better code parameters and connectivity than existing circuits. [1] Matt McEwen, Dave Bacon, and Craig Gidney. Relaxing hardware requirements for surface code circuits using time-dynamics. Quantum, 7:1172, 2023. [2] Craig Gidney and Cody Jones. New circuits and an open source decoder for the color code, 2023. [3] Mackenzie H. Shaw and Barbara M. Terhal. Lowering connectivity requirements for bivariate bicycle codes using morphing circuits.
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Quantum Physics

Resist-free shadow deposition using silicon trenches for Josephson junctions in superconducting qubits

Superconducting qubit fabrication innovations continue to be explored to achieve higher performance. Despite improvements to base layer fabrication and processing, resist-based Josephson junction (JJ) schemes have largely remained unchanged. The polymer mask during deposition causes chemical contamination and limits in situ and ex situ surface preparation, junction materials, and scalability. Here, we demonstrate a resist-free approach to junction fabrication based on etched silicon trenches that is CMOS compatible and easily integrated into existing innovations in qubit base layer fabrication and chemical processing. We fabricate Al-AlOx-Al JJs and qubits using this method, measuring median energy relaxation times up to 184 microseconds. We find minimal contamination at the substrate-metal interface and fluctuations of energy relaxation on a 35 hour timescale that are narrow and normally distributed. The method widens the process window for substrate preparation and new materials platforms.
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All authors Tathagata Banerjee, Stephen Daniel Funni, Saswata Roy, Judy J. Cha, Valla Fatemi

Quantum Physics · Cross-listed from hep-ph

Visible Neutrino Decay As An Open Quantum System

Decays of heavier neutrino mass eigenstates into lighter ones, while very slow in the Standard Model, can be significantly enhanced in scenarios with more than three neutrino flavours, or in models with new ultra-light particles such as Majorons. A full theoretical description is challenging due to the intricate interplay between oscillations and decay, interference between different decay channels, and the possibility of multi-step decay cascades. In this paper, we develop a fully general description of arbitrarily complex systems of oscillating and decaying neutrinos using methods from the theory of open quantum systems. Notably, we demonstrate how such systems can be implemented using the Lindblad master equation, the Liouvillian superoperator, as well as Kraus operators. The last two methods eschew the need for solving a differential equation, thereby showing superior numerical performance.
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Quantum Physics

Rigorous quantum state tomography for distributed quantum computing

Distributed quantum computing offers a promising approach to scaling quantum devices by networking multiple quantum processors. We present a quantum state tomography protocol tailored for distributed quantum computers that avoids assuming remote entanglement as a primitive resource. The protocol extends projected least-squares (PLS) tomography based on projective 2-designs to systems composed of multiple quantum processors, using only local operations within each processor and classical communication between nodes. Assuming entanglement within each individual quantum processor is trusted, the protocol can be executed using mutually unbiased bases. We derive rigorous, non-asymptotic trace-norm error bounds for the PLS estimator, with explicit exponential dependence on the number of nodes. In addition, we establish certified error bounds for estimating entanglement negativity from the PLS estimator. Numerical simulations for systems of up to seven qubits distributed across several devices validate the theoretical error bounds.
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Quantum Physics

Leggett-Garg Inequality Violations Bound Quantum Fisher Information

We prove that a violation of a Leggett-Garg inequality for bounded observables in stationary pure states and thermal states yields a rigorous lower bound on the quantum Fisher information. This turns a qualitative foundations test of realism in quantum systems into a quantitative witness of useful quantum sensitivity and, in the collective setting, into a lower bound on multipartite entanglement depth in many-body systems. We further demonstrate that Leggett-Garg violations are constrained by the same spectral moments, susceptibilities, and $f$-sum-rule bounds that organize many-body response. Our results show that temporal correlations of a single collective observable can serve as an experimentally accessible witness of many-body quantum coherence, without requiring full state reconstruction.
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All authors Nick Abboud, Yuntao Guan, Barry Bradlyn, Jorge Noronha

Quantum Physics

Sector length distributions of recursively definable graph states through analytic combinatorics

The sector length distribution or Shor-Laflamme distribution (SLD) of quantum states is governed by the $k$-body correlations amongst the different systems, and has been used to study entanglement and error correction. A succinct description of a quantum state's SLD can be obtained by representing it through the coefficients of an appropriate weight enumerator polynomial, yielding bounds on fidelity under depolarizing noise and on multipartite entanglement. However, such expressions quickly grow out of hand and are generally difficult to achieve analytically, reflecting the computational hardness of the SLD. We sidestep this problem and, instead of a single state's SLDs, encode a family of quantum state's SLD as a generating function. We then find closed-form expressions for a large class of graph states which we call `recursively definable' and which include many common graphs such as path graphs, cycle graphs, star graphs, grid graphs, and more. As direct corollary, we obtain analytical expressions for such graph states' concentratable entanglement, bounds on their depolarizing fidelity, and a multipartite entanglement criterion. Our work opens up the use of generating functions and more generally analytic combinatorics to solve problems in quantum information theory.
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All authors Eloïc Vallée, Kenneth Goodenough, Paul E. Gunnells, Tim Coopmans, Jordi Tura

Quantum Physics

Generative Circuit Design for Quantum-Selected Configuration Interaction

Quantum-selected configuration interaction (QSCI) has emerged as a feasible approach for approximating electronic ground states on noisy quantum devices toward large-system demonstrations. In QSCI, Slater determinants are sampled from a quantum-prepared state, and the Hamiltonian is then diagonalized in the sampled subspace. To create a high-quality subspace under hardware constraints, the design of the state-preparation circuit is crucial. Here, we present a Generative Quantum Eigensolver (GQE)-based framework that optimizes ansatz structures using a Transformer policy trained on the QSCI subspace energy. We validate the framework on N2 in active spaces of up to 32 qubits. We found that the optimized circuits reach chemical precision with substantially lower gate counts than time-evolved circuits. Quantitatively, this corresponds to an average reduction of 98% in the required two-qubit gate count relative to the single-step first-order Trotterized approximation and 83% relative to the qDRIFT approximation. Furthermore, the resulting wavefunctions are competitive with heat-bath configuration interaction (HCI) in terms of compactness. In stretched-bond, strongly correlated regimes, they achieve chemical precision with subspaces that are 50% smaller than those required by HCI.
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All authors Ryota Kemmoku, Qi Gao, Shu Kanno, Kimberlee Keithley, Ikko Hamamura, Naoki Yamamoto, Kouhei Nakaji

Quantum Physics

Explicit Block Encoding of Difference-of-Gaussian Operators on a Periodic Grid

The Difference-of-Gaussian (DoG) is a widely used operator across applications, including image processing (feature and edge detection), quantum machine learning, and finite-difference methods (approximations of the Laplacian-of-Gaussian). In this paper, we construct an explicit quantum block encoding of the DoG operator on a periodic grid, exploiting its natural probabilistic structure. The central observation is that the DoG admits a natural decomposition to two normalized Gaussian distributions, each preparable by explicit and efficient circuits, with the negation encoded using a single Pauli-$Z$ gate on a branch-indicator qubit. This enables the operator's block encoding to be directly mapped to the Linear Combination of Unitaries framework without requiring signed amplitude loading, quantum random-access memory, or any other black-box oracles. The proposed method achieves a constant subnormalization factor $\lambda = 2$ independent of the grid size $N$, the spatial dimension $D$, and the stencil width. Additionally, we show that the DoG operator is diagonalized by the discrete Fourier basis, which allows us to derive an exact closed-form expression for the block-encoding success probability in terms of the input signal's power spectrum, weighted by the operator's transfer function. Finally, we prove that the expression reduces to $O(h^4)$ scaling with respect to grid spacing $h$ as the periodic grid becomes finer. This implementation provides an explicit construction method for a tunable, wide-stencil bandpass filter whose frequency response is controlled by two Gaussian scale parameters.
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All authors Jishnu Mahmud, John Winship, Tom Lash, James Ostrowski, Rebekah Herrman

Quantum Physics · Cross-listed from cs.DM

On Worst-Case Optimal Polynomial Intersection

The Optimal Polynomial Intersection (OPI) problem is the following: Given sets $S_1, \ldots, S_m \subseteq \mathbb{F}$ and evaluation points $a_1, \ldots, a_m \in \mathbb{F}$, find a polynomial $Q \in \mathbb{F}[x]$ of degree less than $n$ so that $Q(a_i) \in S_i$ for as many $i \in \{1, 2, \ldots, m\}$ as possible. Decoded Quantum Interferometry (DQI) is a quantum algorithm that efficiently returns good solutions to the problem, even on worst-case instances (Jordan et. al., 2025). The quality of the solutions returned follows a semicircle law, which outperforms known efficient classical algorithms. But does DQI obtain the best possible solutions? That is, are there solutions better than the semicircle law for worst-case OPI instances? Surprisingly, before this work, the best existential results coincide with (and follow from) the best algorithmic results. In this work, we show that there are better solutions for worst-case OPI instances over prime fields. In particular, DQI and the semicircle law are not optimal. For example, when the lists $S_i$ have size $\rho p$ for $\rho \sim 1/2$, our results imply the existence of a solution that asymptotically beats the semicircle law whenever $n/m \geq 0.6225$, and we show that an asymptotically perfect solution exists whenever $n/m \geq 0.7496$. Our results generalize to Max-LINSAT problems derived from any Maximum Distance Separable (MDS) code, and to any $\rho \in (0,1)$. The key insight to our improvement is a connection to local leakage resilience of secret sharing schemes. Along the way, we recover several re-proofs of the existence of solutions achieving the semicircle law.
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Quantum Physics

Quantum Randomized Subspace Iteration

Resolving degenerate quantum eigenspaces - including topologically ordered ground states and frustrated magnets - requires preparing high-fidelity states that span every direction of the target manifold. Existing variational and projective algorithms do not naturally cover a multi-dimensional degenerate subspace without sequential orthogonality constraints. We introduce the quantum randomized subspace iteration (QRSI), a fully parallel construction that conjugates the Hamiltonian by independent random unitaries across as many branches as the degeneracy g, then invokes any chosen eigenstate-preparation primitive on each branch. The target subspace is identified from the resulting ensemble via standard subspace estimation, either classically through the coefficient matrix or on hardware through Gram-matrix measurements. We prove that the construction spans the full eigenspace almost surely and preserves the spectral gap exactly on every branch. For practical use, we show that these guarantees hold whenever the random rotations satisfy an anti-concentration condition over the degenerate manifold, substantially weaker than full Haar randomness. We demonstrate QRSI on the toric code, recovering all four topological ground states, and on random Hamiltonians with planted degeneracies.
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All authors Stefano Scali, Brian Coyle, Giuseppe Buonaiuto, Michal Krompiec

Quantum Physics · Cross-listed from cond-mat.mes-hall

Probing Electrostatic Disorder via g-Tensor Geometry

Low-frequency charge noise induced by fluctuating electrostatic disorder is a major limitation for semiconductor hole spin qubits. Here, we analyze the quasistatic response of a hole spin qubit to individual two-level fluctuators (TLFs). We show that, due to the anisotropy of the g-tensor, the qubit response depends on the geometry of the fluctuator-induced dipolar perturbation. We then propose a readout protocol that isolates selected g-tensor components through an accumulated Berry phase and estimate, within our readout model, an order-unity signal-to-noise ratio with a total protocol time in the tens of microseconds. Finally, using microscopic simulations, we compute the quantum Fisher information (QFI) to identify magnetic field directions and confinement regimes in which the qubit is most sensitive to disorder-induced variations of selected g-tensor components.
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All authors Edmondo Valvo, Christian Ventura-Meinersen, Michele Jakob, Stefano Bosco, Tereza Vakhtel, Maximilian Rimbach-Russ

Quantum Physics

Nonlocal Games Revisited: A Representation-Theoretic Path from Bell Locality to Quantum Pseudo-Telepathy

Nonlocal games provide a unified framework for studying the distinction between classical, quantum, and more general no-signaling correlations. In this work, we develop this perspective by connecting the Bell-locality framework to several complementary mathematical representations of nonlocal games and quantum strategies. We begin with local hidden-variable models, the CHSH inequality, and the role of Bell nonlocality as a device-independent witness of entanglement, and then introduce nonlocal games through the standard predicate/verifier formalism. We next examine a set of representative examples, including XOR games, the GHZ game, graph-based coloring games, the Mermin-Peres magic square game, and Hardy's paradox as a related logical manifestation of nonlocality. Building on this foundation, we compare four closely related representation frameworks: conditional-probability and correlation descriptions, Bell-functional formulations, entangled-value optimization, and the quantum-operator approach together with the Navascues-Pironio-Acin (NPA) hierarchy. These viewpoints are then instantiated for the CHSH, magic square, and GHZ games, showing how each representation emphasizes a different aspect of the same underlying task. Taken together, these examples show that nonlocal games can be studied simultaneously as geometric objects in correlation space, optimization problems over entangled resources, and operator-theoretic constructions. This multi-representation viewpoint clarifies the relation between Bell inequality violations, perfect quantum strategies, pseudo-telepathy, and semidefinite relaxations of quantum correlations.
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Quantum Physics · Cross-listed from hep-th

Relativistic single-electron wavepacket in quantum electromagnetic fields II: Quantum radiation emitted by a uniformly accelerated electron

We compute the quantum radiation emitted by wavepackets of relativistic single electrons, both at rest and undergoing uniform acceleration in the Minkowski vacuum of the electromagnetic field. We find that the cubic terms in the original nonlinear action of electrodynamics should be considered in obtaining the quantum radiation to the leading order. We show that the quantum radiation from a single-electron wavepacket at rest vanishes exactly. For a uniformly accelerated electron, the quantum radiated power has secular growth in the long-time regime. We demonstrate that this secular growth has a classical interpretation, and argue that the resummed quantum radiation at late times would not diverge. Regarding experimental proposals for the detection of the Unruh effect from the quantum radiation in the `blind spots' of classical radiation we ascertain that quantum corrections in the two blind spots are fully contributed by the transverse deviation correlators, where the dominant contributions are irrelevant to the Unruh effect in electron microscopes.
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Quantum Physics · Cross-listed from cs.IR

On the Representational Limits of Quantum-Inspired 1024-D Document Embeddings: An Experimental Evaluation Framework

Text embeddings are central to modern information retrieval and Retrieval-Augmented Generation (RAG). While dense models derived from Large Language Models (LLMs) dominate current practice, recent work has explored quantum-inspired alternatives motivated by the geometric properties of Hilbert-like spaces and their potential to encode richer semantic structure. This paper presents an experimental framework for constructing quantum-inspired 1024-dimensional document embeddings based on overlapping windows and multi-scale aggregation. The pipeline combines semantic projections (e.g., EigAngle), circuit-inspired feature mappings, and optional teacher-student distillation, together with a fingerprinting mechanism for reproducibility and controlled evaluation. We introduce a set of diagnostic tools for hybrid retrieval, including static and dynamic interpolation between BM25 and embedding-based scores, candidate union strategies, and a conceptual alpha-oracle that provides an upper bound for score-level fusion. Experiments on controlled corpora of Italian and English documents across technical, narrative, and legal domains, using synthetic queries, show that BM25 remains a strong baseline, teacher embeddings provide stable semantic structure, and standalone quantum-inspired embeddings exhibit weak and unstable ranking signals. Distillation yields mixed effects, improving alignment in some cases but not consistently enhancing retrieval performance, while hybrid retrieval can recover competitive results when lexical and embedding-based signals are combined. Overall, the results highlight structural limitations in the geometry of quantum-inspired embeddings, including distance compression and ranking instability, and clarify their role as auxiliary components rather than standalone retrieval representations.
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Quantum Physics · Cross-listed from math-ph

Periodicity in Ergodic Quantum Processes

We study the periodic properties of sequences of quantum channels sampled from an ergodic stochastic process satisfying a natural irreducibility condition. We relate these periodic properties to certain global spectral data defined by the sequence of quantum channels, proving a general Perron-Frobenius-type theorem that in particular constitutes a full generalization of the work of Evans and Høegh-Krohn to the disordered setting.
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Quantum Physics

Symmetry-driven thermalization via finite de Finetti theorems

Thermal behavior in subsystems of closed quantum systems is commonly attributed to dynamical chaos, quantum ergodicity, canonical typicality, or the eigenstate thermalization hypothesis, suggesting a fundamentally statistical origin of thermalization. Here, we propose a potential alternative mechanism in which thermal structures emerge deterministically from symmetry considerations alone, without recourse to statistical arguments. We prove a finite de Finetti-type theorem for quantum states invariant under energy-preserving unitaries, establishing that the reduced marginals of any such invariant $N$-qudit state are close (both in trace distance and relative entropy) to convex mixtures of thermal product states, with explicit error bounds vanishing as $N \to \infty$. We further present an example of energy-conserving Lindblad dynamics whose long-time limit is invariant under energy-preserving unitaries, providing a dynamical realization of the desired symmetry class. These results imply that invariance under energy-preserving unitaries suffices as a sole fundamental, deterministic principle to enforce thermal structures.
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Quantum Physics

Quantum Uncertainty and Entropy

We review the plethora of uncertainty relations that appear in quantum mechanics and their nuances. We present both foundational applications, e.g. in understanding and defining complementarity, and practical applications, e.g. in quantum metrology and cryptography. Both variance- and entropy-based uncertainties are covered here.
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Quantum Physics

Variational Quantum Physics-Informed Neural Networks for Hydrological PDE-Constrained Learning with Inherent Uncertainty Quantification

We propose a Hybrid Quantum-Classical Physics-Informed Neural Network (HQC-PINN) that integrates parameterized variational quantum circuits into the PINN framework for hydrological PDE-constrained learning. Our architecture encodes multi-source remote sensing features into quantum states via trainable angle encoding, processes them through a hardware-efficient variational ansatz with entangling layers, and constrains the output using the Saint-Venant shallow water equations and Manning's flow equation as differentiable physics loss terms. The inherent stochasticity of quantum measurement provides a natural mechanism for uncertainty quantification without requiring explicit Bayesian inference machinery. We further introduce a quantum transfer learning protocol that pre-trains on multi-hazard disaster data before fine-tuning on flood-specific events. Numerical simulations on multi-modal satellite and meteorological data from the Kalu River basin, Sri Lanka, show that the HQC-PINN achieves convergence in ~3x fewer training epochs and uses ~44% fewer trainable parameters compared to an equivalent classical PINN, while maintaining competitive classification accuracy. Theoretical analysis indicates that hydrological physics constraints narrow the effective optimization landscape, providing a natural mitigation against barren plateaus in variational quantum circuits. This work establishes the first application of quantum-enhanced physics-informed learning to hydrological prediction and demonstrates a viable path toward quantum advantage in environmental science.
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Quantum Physics

Discrete-time quantum walks in synthetic dimensions

In this work we introduce discrete-time quantum walks in state space, more precisely on Fock-state lattices. Fock-state lattices provide a natural and clean setting for implementing lattice models, particularly in quantum optical systems. Thus, contrary to the common setting where the walker resides in real space or phase space, here the walk takes place in a synthetic space. We present a general formalism based on Lie algebras and their properties. For each Lie algebra one can associate both a phase space and a Fock-state lattice, and by understanding how these spaces are related, together with the action of generalized displacement operators, we construct the discrete unitary operator that generates the walk. In this framework the displacement operators replace the usual nearest-neighbor shifts and lead to state-dependent tunneling on the lattice. By considering several examples we demonstrate ballistic spreading and other characteristic features of discrete-time quantum walks, such as coin-walker entanglement and symmetry-induced interference patterns. We also show that different algebraic structures can give rise to qualitatively different dynamics, including anomalous behavior such as super-ballistic spreading as well as localization effects.
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Quantum Physics

Algebraic structure of Fock-state lattices

We analyze Fock-state lattices (FSLs) from an algebraic viewpoint. Starting from a Lie algebra, we associate a FSL constructed from the action of its generators: diagonal (Cartan) generators define the lattice sites, while off-diagonal (root) generators determine the lattice bonds. This construction reveals that identifying an underlying algebraic structure provides direct physical insight into FSLs, including their dimensionality, connectivity, symmetry constraints, and possible transport and revival phenomena. By examining several common Lie algebras, we identify not only their associated FSLs but also the corresponding Lie phase spaces, thereby establishing a systematic connection between FSL dynamics and phase-space geometry. In many cases, both the phase space and the FSL exhibit nontrivial curvature, opening possibilities for exploring quantum dynamics in curved synthetic spaces. We further address whether every integrable Hamiltonian admits an underlying Lie algebra that reproduces the same FSL structure. We show that this is not generally the case, particularly for Hamiltonians that are nonlinear in the generators, and that for systems combining different types of degrees of freedom the appropriate underlying structure may instead be a Lie superalgebra.
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Quantum Physics

Tailoring tensor network techniques to the quantics representation for highly inhomogeneous problems and few body problems

Tensor network techniques are becoming increasingly popular tools to solve partial differential equations within the so-called quantics representation. Their popularity stems from the fact that their spatial resolution depends only logarithmically on the number of grid points, making them very tempting approaches in situations where two or more characteristic length scales are vastly different. A first generation of technique used “out-of-the-box” algorithms of the tensor network toolkit (e.g. the celebrated Density Matrix Product State (DMRG) algorithm) to solve these problems. These techniques were designed for situations (e.g. quantum magnetism) where the different degrees of freedom (e.g. spins) play equivalent roles. In the quantics representation, however, the different degrees of freedom correspond to the physics at different scales and therefore play inequivalent role. Here we show that by tailoring the tensor network algorithms to this particular case, in the spirit of the multigrid approach, we obtain faster and more robust convergence of the algorithms. We showcase the approach on linear (Poisson equation) and eigenvalue (Schrödinger equation) problems in two, three and four dimensions. Our simulations involve up to $2^{80}$ grid points and would represent, we argue, a very strong challenge for conventional approaches.
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Quantum Physics

Convergence to semiclassicality in the quantum Rabi model

We investigate the emergence of semiclassical dynamics in the quantum Rabi model using a recently developed limiting procedure that formally establishes correspondence with the semiclassical Rabi Hamiltonian [E. K. Twyeffort Irish and A. D. Armour, Phys. Rev. Lett. 129, 183603 (2022)]. While the limit itself is defined at the Hamiltonian level, how it is reached depends on the choice of quantum states. Defining a set of quantitative measures that capture the differences between quantum and semiclassical dynamics, we examine convergence to the semiclassical limit when the field is prepared in a displaced number state. These states, which interpolate to Fock states for zero displacement, are more general than the set of coherent states usually employed when considering the emergence of semiclassical behavior. Numerical computations of these measures consistently demonstrate the progressive emergence of semiclassical behavior as the joint limit of vanishing coupling and infinite displacement is approached. Complementing the numerical results, analytical approximations are developed that reproduce the behavior in the vicinity of the semiclassical limit with a high degree of fidelity and allow scaling relations to be derived. Although any initial displaced number state will eventually converge to the corresponding semiclassical dynamics as the limit is taken, the rate of convergence depends on the Fock number $n$ of the state. States with larger values of $n$, which behave less classically than coherent states, converge more slowly to the limit.
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All authors H. F. A. Coleman, R. A. Morrison, A. D. Armour, E. K. Twyeffort

Quantum Physics · Cross-listed from physics.optics

Cascade Brilloiun scattering on short-lived phonons for frequency comb generation

We consider Brillouin scattering on short-lived phonon modes, such that the relative Brillouin shift between propagating and scattered waves is smaller than the relative width of phonon modes. In this case one phonon mode facilitates scattering between many pairs of optical modes. We show that in this limit two phonon modes are sufficient for cascade Brillouin scattering (one forward propagating wave and one counter propagating wave), and that the cascade behavior is qualitatively different from the cascade in conventional Brillouin systems with distinct phonon modes for each optical mode pair. In particular, our results show that there is a pump threshold above which many optical modes become excited simultaneously, as opposed to a cascade gradually building up. The resulting cascade scattering can be exploited for frequency comb generation with uniform amplitudes and without the need for anomalous dispersion in the medium.
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All authors Egor R. Verevkin, Ilya V. Doronin, Alexander A. Zyablovsky, Evgeny S. Andrianov