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Physics Condensed Matter

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Friday 10 July

Materials Science

The Precursor Genome: A Pairwise Reaction Dataset for Solid-State Synthesis

Solid-state reactions remain the dominant route to inorganic materials, yet no large, machine-readable dataset reports their experimental protocols and outcomes with consistent provenance; this gap obstructs first-principles, data-driven, and machine-learning approaches to synthesis science. Here, we present the Precursor Genome, a dataset of 1,035 pairwise solid-state reactions generated autonomously by the A-Lab self-driving laboratory, spanning 46 precursors and 39 elements. Every reaction is reported together with its full experimental metadata, including measured thermal profiles, precursor and recovered masses, and instrument configuration. Every product mixture is identified from raw X-ray diffraction (1,351 scans) through automated Rietveld refinement with the Dara framework, yielding 1,950 refinement cases that are independently validated by human experts on a three-tier quality scale. Raw pattern files, serialized refinement objects, and reviewer annotations are distributed through a Pydantic-validated JSON ledger, preserving full traceability from each precursor pair to its final phase assignment. The Precursor Genome establishes a FAIR, reusable benchmark for training and evaluating predictive models of solid-state reactivity.
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All authors Lauren N. Walters, Matthew J. McDermott, Bernardus Rendy, Yuxing Fei, Kristin A. Persson, Gerbrand Ceder

Materials Science

Bragg Interferometry of Moiré Superlattices: From Geometric Phase Principles to Atomic Reconstruction

The emergence of moiré superlattices formed by twisting and stacking two-dimensional materials has created a need for characterization techniques capable of mapping sub-angstrom atomic reconstruction across micron-scale fields of view. This review surveys a suite of methodologies developed to extract geometric phases in electron microscopy and X-ray spectroscopy, with a primary focus on the interference of overlapping Bragg reflections in the dark field. We provide a comparative analysis of some established techniques, including geometric phase analysis, converged beam electron diffraction holography, and various ptychographic paradigms, culminating in a discussion of Bragg interferometry for measuring interlayer displacement fields and strain in moiré materials. We demonstrate the utility of Bragg interferometry through case studies of twisted bilayer and trilayer graphene as well as transition metal dichalcogenide moiré systems. Special attention is given to the unique advantages of this dark-field interferometric method for probing buried interfaces and encapsulated heterostructures, as well as the inherent challenges of interpreting incomplete phase information in the presence of dynamical scattering. By examining the physical principles underlying these approaches, this review highlights the conceptual similarities and practical trade-offs involved in high-resolution structural mapping of materials in which the interplay between structural relaxation and electronic behavior defines a scientific frontier at the nexus of modern condensed matter physics, nanomaterials engineering, and interfacial chemistry.
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Materials Science

Approximate explicit formulas for Stoner-Wohlfarth hysteresis loops

Approximate explicit formulas for the hysteresis loops in the Stoner-Wohlfarth model are derived. We consider the hysteresis loops both for a single particle with a fixed easy-axis direction and for an ensemble of particles with randomly oriented anisotropy axes. The physical assumption used to derive the formulas is that the particle magnetic moment lies in the vicinity of the easy axis or the external field direction, at low and high fields, respectively. Surprisingly, the low-field formula is approximately valid even near the Stoner-Wohlfarth astroid, where the reduced magnetic field h0 is not very small. The general piecewise formula is obtained by an appropriate matching of the functions defined on different intervals of the magnetic field, which are chosen to maximize the formula accuracy. For the averaged hysteresis loop, the maximal, but reasonably small, deviation of our formula from numerically calculated magnetization occurs at h0 = 0.5, which corresponds to the sharp change in magnetization slope.
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Superconductivity

Landau-Zener tunneling and quantum interference of Andreev states

With the aid of a microscopic theory we derive an effective Hamiltonian that controls quantum dynamics of Andreev states in superconducting nanojunctions out of equilibrium. Resolving the corresponding Schrödinger-like equation we obtain the "wave functions" for Andreev levels and evaluate electric current across the junction in the presence of an external voltage bias. We demonstrate that quantum interference of Andreev states may yield pronounced coherent oscillations of the supercurrent as a function of the Josephson phase in junctions with barrier transmissions slightly below unity. Further implications of this novel effect are expected for junctions with diffusive barriers.
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Other Condensed Matter · Cross-listed from gr-qc

Perturbative aspects of analogue FLRW spacetime Jellium models

We study electro-acoustic perturbative modes in homogeneous, isotropic and expanding – dubbed as Friedmann-Lemaitre-Robertson-Walker (FLRW) – Jellium models, thereby mimicking density perturbations in analogous Newtonian cosmological expansions. We present both novel analytic solutions for linear perturbations in specific analogue cosmological expansions and full numerical evaluations that characterize the temporal evolution of the electro-acoustic modes capturing their full dynamical behavior across the linear and the nonlinear regimes. For both the case of pressure supported evolution or modes sourced by nonadiabatic contributions, we also characterize the temporal evolution of such perturbations by introducing their scale dependent particle number fluctuation power spectrum which can act as a tool to connect theory and experiments. The dependence of the latter on the physical parameters of the model is demonstrated in detail.
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All authors Matheus E. Pereira, Hermano Velten, Francisco B. Lustosa, Alexandre G. M. Schmidt

Mesoscale and Nanoscale Physics

Silicon-Germanium Heterostructures with Enhanced Valley Splitting for Spin Qubits

Achieving valley splittings well in excess of the thermal energy of electrons and avoiding valley excitations is essential for the consistent initialization, operation and readout of gate-defined Si spin qubits. In this work, we present a device-level optimization strategy for pushing valley splittings to between 1 and 5 meV, well beyond values reported in nearly all previous theoretical studies. Using device-scale simulations that incorporate atomistic alloy disorder through a 1D tight-binding theory, we demonstrate that our proposed approach yields large valley splittings with a tight distribution across disorder realizations, a key requirement for reproducible qubit performance at scale. The approach rests on an unorthodox Si/SiGe heterostructure design combining a narrow quantum well, a small Ge spike, and a pure-Ge cap. We corroborate these predictions with targeted atomistic density functional theory calculations. These results offer a clear path forward for scalable Si/SiGe spin qubit devices and, if realized experimentally, effectively eliminate valley splitting as an existential problem for large scale SiGe-based quantum processors.
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All authors David W. Kanaar, Efrain Martinez, Peihong Zhang, Mark F. Gyure

Mesoscale and Nanoscale Physics · Cross-listed from quant-ph

Complete measurement of tunnel- and valley-coupling parameters in a silicon double quantum dot

Tunneling is essential in the initialization, measurement, and control of quantum dot qubits. In silicon, such tunneling connects not only the qubit states but also valley minima in the conduction band on opposite sides of the Brillouin zone, with large consequences for the quantum dot behavior. Here we present a full characterization of the intravalley and intervalley tunnel couplings, including their complex phases – the valley phases. These phases are shown to control measurable parameters, including the ratios of the gaps at anticrossings between quantum states of a double quantum dot. The valley phases themselves evolve as a function of the quantum dot gate voltages and depend on the underlying atomic structure of the quantum well. Knowledge of the valley phases completes the picture and fills a key gap in our understanding of sample-wide variations of valley couplings and the physical parameters that depend on them, including spin-orbit coupling, valley-orbit mixing, and Landé $g$-factors.
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All authors Daniel J. King, Minyoung Kim, J. Reily, Jonathan C. Marcks, Mark Friesen, Benjamin D. Woods, M. A. Eriksson

Disordered Systems and Neural Networks · Cross-listed from econ.TH

Non-Equilibrium Economics: A Physicist's Point of View

Financial and economic history is strewn with bubbles and crashes, booms and busts, crises and upheavals of all sorts. Understanding the origin of these events is arguably one of the most important problems in economic theory: are economies intrinsically unstable, and can one “stabilize unstable economies”? In this review I argue, from a physicist's vantage point, that the concept of equilibrium – so central to mainstream economic thinking – is likely to be the exception rather than the rule in large, complex, interacting systems. Drawing on a series of stylized “toy” models, I show how excess volatility, endogenous crises and crashes, inflation swells and persistent inequalities can all emerge naturally from genuinely out-of-equilibrium dynamics, without invoking large exogenous shocks. Three generic mechanisms recur throughout: trapping in a multiplicity of history-dependent equilibria; the impossibility of dynamically reaching equilibrium, leading to oscillations and chaos; and the spontaneous evolution towards fragile, marginally stable states – the self-organized criticality paradigm. I stress that these are phenomenological scenarios rather than calibrated theories: there is, at this stage, no “smoking gun”. But the burden of proof, I contend, should be on the equilibrium camp.
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Statistical Mechanics

Fluctuation theorems for thermally isolated driven quantum systems: nonadiabaticity, excess work and strong inequalities

We expand on the ideas developed by C. Jarzynski in Physica A 552, 122077 (2020), where an integral fluctuation theorem was derived with the aim of obtaining thermodynamic inequalities stronger than those implied by the Jarzynski equality. Restricting ourselves to the quantum setting, we derive the corresponding detailed fluctuation theorem and additional detailed and integral fluctuation theorems; we also provide a clear physical interpretation of the stochastic quantities defined in the previous reference. Furthermore, we show that their averages are given by the nonadiabaticity parameter (i.e., the relative entropy between the final state after a finite-time driving protocol and the corresponding adiabatically evolved state) and the excess work (also known as inner friction). We elaborate on the inequalities derived from the fluctuation theorems and discuss their connection to irreversibility and formulations of the Second Law.
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Quantum Gases · Cross-listed from nlin.PS

Stabilization of two-dimensional optical continuous-wave states by a potential trough

We consider quasi-one-dimensional (Q1D) continuous waves (CWs) in the two-dimensional (2D) optical system with the cubic-quintic nonlinearity and a Q1D potential trough. In the case of a smooth trough profile, we confirm the known modulational instability (MI) of Q1D CWs with the transverse structure corresponding to the 1D ground state (GS) in the potential trough, and demonstrate the MI of CWs with the dipole-mode (DM) transverse structure, corresponding to the lowest 1D excited state in the potential trough. The CWs of both GS and DM types remain nearly stable close to the edges of their existence regions. Stable stationary states in the form of periodic chains of 2D solitons, trapped in the potential trough, are produced in a numerical form. The dynamics of the soliton chains excited by a localized kick is studied too. For the potential trough with the singular delta-functional profile, we find two species of exact analytical solutions for CWs, one of which is completely stable.
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Strongly Correlated Electrons

Thermalization in a Height-Conserving Quantum Dimer Model

Strongly constrained quantum systems, in which local rules forbid most configurations, play a central role in condensed matter and lattice gauge theory. Their thermalization is often thought to be delicate: extensive conservation laws and dynamically frozen states can shatter the Hilbert space into many disconnected sectors. A natural question is whether, once the frozen states are removed, the dynamics within a single sector still thermalizes. We address this in the height-conserving quantum dimer model on the square lattice, whose local plaquette flips conserve an emergent height field. Resolving the winding numbers, the four sublattice heights, and lattice momentum , we isolate the dominant connected Krylov component of each fragmented sector and analyze its spectral spectral statistics, entanglement, and connectivity. The two standard chaos diagnostics then show different behavior:across momentum sectors the level-spacing statistics range from near-Poisoon to Wigner-Dyson, yet in every sector the eigenstate entanglement entropy collapses onto a narrow, dome-shaped curve characteristic of eigenstate thermalization. Only a handful of low-entanglement outliers interrupt this thermal pattern, in selected sectors. Thus, strong kinematic constraints can lead to a situation where spectral correlations and eigenstate thermalization need not follow the same universal signatures – a manifestation of constrained quantum chaos.
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Superconductivity

A Cloud-Accessible Open-Source Framework for the Electromagnetic Modelling of Applied Superconductors

We present the H-cloud formalism, a cloud-accessible and open-source finite-element framework for electromagnetic modelling of applied superconductors. The proposed method expresses the nonlinear electromagnetic response of type-II superconductors in a curl-conforming discretisation based on Nédélec finite elements, where the tangential applied-field boundary condition, nonlinear E-J power law, and fully implicit time-discrete residual are stated explicitly at the variational level, all within a scripted Python finite-element workflow. The weak form is used as the basis for forward simulation and for extension to adjoint differentiation and PDE-constrained optimisation, while keeping the governing assumptions, boundary conditions, and solver structure fully visible to the user. The implementation is realised in Firedrake with UFL and PETSc-backed nonlinear solvers, allowing the identical script to run on local machines and in browser-accessible environments such as Google Colab without reformulating the problem. The method is verified on the canonical magnetisation benchmark of a cylindrical superconductor under Bean-like penetration conditions and then benchmarked against an independently constructed COMSOL model for a practical high temperature superconducting Bi2212 wire. Across matched mesh studies, the open-source workflow reproduces the commercial-reference magnetisation loops to within approximately \(1\%\) , with relative peak errors below 1.5%, while cloud execution preserves the same numerical solution at rather modest additional runtime considering the use of (freely available) reduced hardware resources. The proposed framework provides a rigorous, reproducible, and portable route for superconducting simulation, benchmarking, and future optimisation-led modelling of applied and functional superconductors, shareable and executable into open cloud environments.
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Mesoscale and Nanoscale Physics

Confinement drives valley splitting above 4K in buried silicon quantum wells

Controlling the energy scales of a quantum system is essential for defining robust qubits. In silicon spin qubits, the nearly degenerate conduction-band valleys create a leakage channel from the single-spin computational basis, posing a challenge to scaling and to shuttling-based architectures. Here, we measure the relevant energy scales of single-electron spin qubits in buried silicon quantum wells co-designed for low disorder and high valley splitting. Across a linear array of four quantum dots with an average orbital energy of 2.4(2) meV, we report an average single-electron valley splitting of 0.40(6) meV and an average two-electron singlet-triplet splitting of 0.24(7) meV. In three dots, we observe a strong correlation between valley splitting and orbital energy, with an average linear coefficient of $\approx 0.22$ (meV/meV), demonstrating that electrostatic confinement can increase the valley splitting by several hundred microelectronvolts. In contrast, the remaining dot exhibits the highest valley splitting of 0.76(2) meV and low correlation, suggesting excellent characteristics for spin-qubit operation. Our findings demonstrate that strong confinement can be exploited in buried quantum wells to effectively enhance the valley splitting, thereby establishing a viable path toward the realization of shuttling and sparse-occupation-based architectures in low-disorder heterostructures.
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All authors Davide Degli Esposti, Emma Catherine Brann, Asser Elsayed, Davide Costa, Mark Friesen, Giordano Scappucci

Soft Condensed Matter

Delayed Arm Retraction Controls the Nonlinear Oscillatory Response of Long-Chain-Branched Polymer Melts

Long-chain branching profoundly modifies the nonlinear oscillatory response of entangled polymer melts by introducing arm-retraction pathways absent in linear polymers. We present a molecular tube theory that explains the characteristic maximum of the Nonlinearity Index (NLI) observed experimentally in long-chain-branched polymers. The theory extends the recently developed nonlinear tube-orientation description of linear polymers by incorporating branch-point force transmission and delayed arm retraction. The backbone initially develops nonlinear orientation as in the corresponding linear polymer, whereas long-arm retraction subsequently relaxes the stored branch-point tension and progressively erases backbone orientational memory. This competition produces a characteristic NLI maximum followed by a post-peak decay. The theory predicts two distinct nonlinear regimes corresponding to sparse and dense long-chain branching and introduces an architecture parameter governing the height and width of the nonlinear peak. The resulting framework provides a molecular interpretation of nonlinear Fourier rheology and directly links the nonlinear harmonic response to polymer architecture.
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Soft Condensed Matter

A Boosted Energy Extraction from the CapMix Process by Grafting with Titratable Polymers

Salinity gradient energy offers a sustainable route to convert ionic chemical potential differences into usable power. Capacitive mixing enables this conversion without membranes, but suffers from limited ion regulation at electrode interfaces. Here we show that by grafting electrode surfaces with titrating polymers, the performance can be substantially improved. Using Grand Canonical Monte Carlo simulations with exact image-charge Ewald summations, we demonstrate how the coupled effects of ion adsorption and charge regulation in response to an external potential can be harnessed. Grafted electrodes are shown to deliver substantially more energy relative to bare surfaces, driven by charge regulation effects that exploit the pH difference that typically exists between rivers and the ocean. While the effect is in principle maximized at high grafting densities and moderate chain lengths, the performance is fairly robust to variations of these parameters, within reasonable bounds. Complementary classical polymer Density Functional Theory calculations confirm these trends, validating the mechanistic framework. This work also establishes a practical approach to harvest electrical energy during wastewater neutralization, where acidic (or alkaline) effluents serve as complementary reservoirs, and offers a promising strategy to couple environmental remediation with renewable energy recovery.
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Strongly Correlated Electrons

A nonstandard statistics for strongly correlated systems: Two simple examples

We discuss two different cases of strongly correlated fermions statistics. The first of them is the non-Fermi liquid (NFL) case, $i.e.$, that of fermions with exclusion of doubly occupancy of quasimomentum states $\{\bf k\}$ with opposite spins ($\uparrow\downarrow$). The second is that of statistical spin liquid (SSL) case, in which the fermion spins hop around and mix with the holes (unoccupied) states. For both cases we calculate the system entropy and the corresponding statistical distribution function, analyzed for a two-dimensional square-lattice filling $n\in [0,1]$ and relative temperature $k_B T/|t|$, where $t<0$ is the nearest neighbor hopping integral. We are particularly interested in the situation when the system of itinerant fermions reduce to the Mott-insulator state for the half-filled band ($n\to1$). This limiting situation signals a qualitative difference between the present SSL statistics and that of uncorrelated fermions representing normal Fermi-liquid state.
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All authors Józef Spałek, Piotr Kuterba, Mateusz Wójcik, Danuta Goc-Jagło, Maciej Fidrysiak, Leszek Spałek, Włodzimierz Wójcik

Disordered Systems and Neural Networks

A multi-ensemble mean-field reduction method for networks of globally coupled phase oscillators with arbitrary parameter distributions

Understanding the dynamical properties of coupled phase oscillator systems with heterogeneous oscillator frequencies has been a long-standing challenge of complex systems theory. While the seminal work of Ott and Antonsen dramatically improved our theoretical understanding of coupled phase oscillators for a small family of oscillator frequency distributions, we here present a mean-field reduction method for arbitrary frequency distributions. Our method leverages the drastic dimensionality reduction obtained for Lorentzian frequency distributions, and combines it with a data-driven multi-ensemble approach. As such, the method renders the Ott-Antonsen equations directly applicable to empirical distributions of phase oscillator frequencies, often achieving a drastic dimensionality reduction and allowing to study real-world physical and biological systems by means of stability, sensitivity, and bifurcation analyses.
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All authors Richard Gast, Shotaro Takasu, Helmut Schmidt, Ann Kennedy

Mesoscale and Nanoscale Physics

Majorana parity qubit in coupled minimal Kitaev chains

Majorana zero modes provide a route to fault-tolerant qubits by encoding information non-locally in fermion parity. Their sensitivity to noise is expected to decrease exponentially with increasing separation between the Majoranas, a suppression known as topological protection. Kitaev chains engineered in quantum dot-superconductor arrays provide a tunable platform in which separated Majorana zero modes can emerge at the ends of the chain, even in two-site chains. These minimal-chain modes are known as poor man's Majoranas and retain characteristic Majorana properties, including near-zero energy and equal electron-hole character, but have only limited protection. A key outstanding challenge is to move beyond identifying such modes in electrical transport measurements and achieve coherent qubit control in the time domain. Here, we demonstrate a Majorana parity qubit by realizing coherent coupling between two-site Kitaev chains. Since total fermion parity is conserved, the system separates into global even and odd parity manifolds. We observe coherent parity oscillations in both manifolds with equal oscillation frequencies at the Majorana sweet spot, as predicted for isolated Majorana zero modes. We further show that the oscillation frequency and coherence depend systematically on inter-chain coupling and quantum-dot detunings, in close agreement with our model for short, partially protected chains. Our results establish the first coherent control of a Majorana qubit, encoded in the fermion parity of Majorana zero modes in minimal Kitaev chains.
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All authors Francesco Zatelli, Bart Roovers, Nick van Loo, Antonio Lombardi, Juan D. Torres Luna, Sebastian Miles, Vincent P.M. Sietses, Florian J. Bennebroek Evertsz', Pablo Cova Fariña, Alberto Bordin, Ghada Badawy, Erik P.A.M. Bakkers, Michael Wimmer, Leo P. Kouwenhoven

Mesoscale and Nanoscale Physics · Cross-listed from quant-ph

Superconducting singlet-triplet qubits

Hybrid devices integrating quantum dots with Josephson junctions are gaining interest because they combine spin-based quantum computing with circuit quantum electrodynamics (circuit QED) methods. In particular, Andreev spin qubits have shown significant experimental progress including strong two-qubit coupling, and are predicted to exhibit all-to-all connectivity. Here we propose superconducting singlet-triplet (SST) qubits that rely on parallel-aligned double quantum dots in Josephson junctions. While Andreev spin qubits require spin-orbit interaction to unlock the spin degree-of-freedom, SST qubits do not require spin-orbit interaction, making the advantages of hybrid devices available to a wider range of materials. Similar to Andreev spin qubits, the qubit states couple to the superconducting phase across the junction, which allows for control and readout using circuit QED, and supports all-to-all connectivity. Only $N$ flux lines are required to perform any single- and two-qubit gate among $N$ qubits, and thus the overhead of control lines is small. Finally, linear protection from charge or flux noise makes these qubits interesting candidates for a future quantum processor.
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Strongly Correlated Electrons

Macroscopic Zero-Mode Manifold Isolated by Quantum Chaos

Chaotic many-body spectra are expected to densely fill their energy window. We show that constrained spin chains with chiral symmetry evade this expectation by hosting an exponentially large manifold of symmetry-protected exact zero modes separated from the surrounding spectrum by a sharp gap at zero energy. The gap is generated by chaotic level repulsion, with width set by the number of zero modes times the mean level spacing. We verify this mechanism in an East-West kinetically constrained chain, develop a minimal random-matrix description, and show how the gap can be detected through linear-response spectroscopy.
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All authors Cheryne Jonay, Kun W. Kim, Frank Pollmann, Alexander Altland

Strongly Correlated Electrons

Symmetry-Protected Pinch Curves in Classical Spin Liquids

Classical spin liquids are correlated paramagnets in which local constraints generate extensive degeneracy and emergent gauge structures, often observable as pinch-point singularities in spin structure factors. Here we introduce pinch-curve spin liquids, in which the pinch singularities form one-dimensional algebraic curves in momentum space. Inversion symmetry protects these curves by reducing the singularity condition to two real algebraic constraints in three dimensions, and the geometry of the pinch locus is algebraically programmable. We identify elementary mechanisms for generating straight and curved pinch loci, construct lattice spin models that realize them, and test the predicted structure factors using Monte Carlo simulations. We further show that pinch curves can host an infrared Gauss-law transition: the leading local constraint and the associated anisotropic scaling of the structure factor change, even though the singular locus remains one-dimensional.
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Superconductivity · Cross-listed from astro-ph.HE

Neutron contribution to the force on a proton vortex in superconducting neutron-star matter

We investigate the forces acting on a proton vortex in superconducting neutron-star matter composed of neutrons, protons, and electrons, accounting for Fermi-liquid interactions in the neutron-proton subsystem. While the force arising from electron scattering by the vortex magnetic field is well known, we demonstrate that normal neutrons also exert a force on proton vortices due to Fermi-liquid coupling with superconducting protons. Using a kinetic approach based on Landau Fermi-liquid theory, we show that neutron quasiparticles scatter off a proton vortex through the spatially varying condensate momentum, giving rise to a longitudinal force proportional to the relative neutron-vortex velocity. In contrast to the electron contribution, this force has no transverse component and vanishes in the absence of neutron-proton Fermi-liquid interaction. Within a simple model, we analyze the main properties of this force and provide physically motivated estimates of its magnitude.
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Materials Science

Unraveling atomic-resolution valence electron energy-loss spectroscopic imaging in a single-crystal CaNb2O6

Despite advancements in electron optics and spectrometer design over the past twenty years, atomic-resolution valence-electron energy-loss spectroscopy imaging remains challenging due to the delocalization of inelastic electron scattering. In this study, we used an energy-filtered spectrometer equipped with a hybrid-pixel direct electron detector and spherical aberration-corrected scanning transmission electron microscopy to analyze many-electron excitations and interband transitions in a single-crystal calcium niobate, CaNb2O6, with spatial resolution ranging from the nanometers to the atomic scale. In the low-loss region above the bandgap at about 3.8 eV, we observed volume plasmons, around 6 eV and 15 eV energy loss, as well as a mix of strongly correlated plasmons and excitons, known as plexcitons, at approximately 7.3 eV energy loss. Additionally, we employed an on-axis EELS setup for atomic-resolution zero-loss peak (ZLP) imaging and visualized energy- and atom-resolved images of plexcitons and VPs, which showed contrast reversal relative to high-angle annular dark-field images. To investigate elastic contrast preservation, we also analyzed the effect of the collection angle and minimized its influence to produce delocalized VP images. In fact, the ZLP and VEELS images obtained using the weak-beam setup demonstrate that, in both cases, the contrast resembles Z-contrast. Moreover, we found that [NbO6] octahedra directly contributed to the lateral maps of interband transitions in the range from 3.2 eV to 3.5 eV energy loss. These findings demonstrate that Cs-STEM-EELS, which examines atomic-scale contrast associated with low-energy losses, can be a powerful tool for visualizing the structure, bonding, and electronic properties of complex crystalline nanostructures, including individual atomic sites, interstitial sites, and point defects.
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All authors Sz-Chian Liou, Xiang-Lin Huang, Vladimir P. Oleshko, I-Ching Lin, Yin-Ping Lan, Hsin-An Chen, Guo-Jiun Shu

Strongly Correlated Electrons

Strongly correlated quantum matter: t–J model, real-space pairing, spin-dependent masses, and atomicity in chemical bond and nanosystems

I critically overview my research on strongly correlated fermion systems for almost five decades. It concentrated on: (i) the first derivation of what is now called the t–J model, comprising both the limit of Anderson kinetic exchange of spin–spin interaction in the Mott–Hubbard insulator and taking into account real-space pairing, subsequently applied to high-temperature superconductivity; (ii) the concept of spin-dependent heavy mass of quasiparticles in heavy-fermion systems, and (iii) the first nontrivial model of statistical thermodynamics of the Mott–Hubbard transition. Those three features, together with the specific quantum critical phenomena provide, in my view, fundamental components of the theory of strongly correlated fermions established in the 1960s. Some related questions such as introduction of atomicity in the chemical bonding (iv), and specific properties of correlated nanosystems within the rigorous EDABI (v) approach are also briefly elaborated at the end.
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Disordered Systems and Neural Networks

Level statistics in the fractal phase of generalized Rosenzweig–Porter models

The Rosenzweig–Porter (RP) random matrix ensemble has emerged as a minimal model for the integrability-to-chaos crossover in quantum many-body systems. Its phase diagram features a region with fractal eigenstates, exhibiting intermediate spectral and localization properties between the fully localized and fully delocalized regimes. In this work, we explore several generalizations of the RP model and determine their level statistics at the scale of the Thouless energy $E_T$, which characterizes the crossover. Using tools from free probability theory and the replica method, we compute the full counting statistics in the limit of large system size, and show that it takes a simple, universal scaling form around $E_T$, shared across all variations of the model. We validate our analytical predictions using exact numerical diagonalization of large samples, and large-deviation algorithms that resolve the full counting statistics down to probabilities as low as $10^{-40}$. We also contrast our predictions with measurements on the quantum random energy model, which is the simplest model displaying many-body localization.
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All authors Victor Delapalme, Leticia F. Cugliandolo, Alexander K. Hartmann, Marco Tarzia, Davide Venturelli

Superconductivity

Anisotropic Superconductivity with Enhanced Critical Field in Strained RuO2

The superconductivity in RuO2 emerges under strain. RuO2 is also an altermagnet candidate. The nature of superconductivity and its relation with neighboring orders, however, are not understood. To address this problem, we grew epitaxial RuO2 films on TiO2(100) and TiO2(110) single crystal substrates and studied the electronic transport and emergent superconductivity along various crystallographic directions. We show that the superconducting transition strongly depends on the growth orientation and the crystallographic direction of the transport in the RuO2 films. We also observe a strong violation of Pauli paramagnetic limit with in-plane applied magnetic field which we attribute to strong spin-orbit scattering. These results offer opportunities for epitaxially engineered superconductors.
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All authors Younes Ghorbani, Samuel Poage, Xuehsi Gao, Luka Mitrovic, Neha Wadehra, Benjamin Gregory, Suchismita Sarker, Betul Pamuk, Andrej Singer, Darrell G. Schlom, Chun Ning Lau, Kaveh Ahadi

Soft Condensed Matter

Universal scaling of conformations of tangentially driven ring polymers

The interplay of tangential activity and excluded-volume interactions in ring polymers adsorbed to a surface, consistently results in the overall swelling of the ring configurations. This is in strong contrast to the case for three dimensional linear and ring polymers, where activity induces frequently collapsed structures. By means of Brownian Dynamic simulations, we investigate how the scaling properties of such active rings can be universally characterized by an activity-dependent Flory exponent, as a generalization of the equilibrium behavior. At high activity, an effective persistence length characterizes the conformations of active flexible rings.
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Strongly Correlated Electrons

Effective theories for many-body systems with nonuniform symmetries

The low-energy dynamics of many-body systems is governed by gapless modes whose properties are dictated by symmetry. Their existence follows from Goldstone's theorem, while their effective description at zero temperature is determined by the pattern of symmetry breaking. At finite temperature, an analogous role is played by hydrodynamics, which describes the universal behavior of many-body systems over long times and large distances. These principles are well understood for uniform symmetries, which act homogeneously in spacetime and lead to a correspondence between massless Goldstone modes and broken generators, as well as gapless hydrodynamic modes and conserved charges. However, this simple picture changes in the presence of nonuniform symmetries, whose generators do not commute with spacetime translations. The low-energy implications of these symmetries remain less understood, as they do not introduce additional gapless modes but instead constrain the dynamics of the existing degrees of freedom. In this thesis, we develop a unified framework for many-body systems with nonuniform symmetries and show that their effects can be understood in terms of additional fields that are not independent at low energies and can be eliminated, leading to kinematic constraints that reshape the infrared dynamics. In systems with spontaneous symmetry breaking, this mechanism modifies the effective theory and often softens the dispersion relations of the remaining modes. At finite temperature, it manifests in hydrodynamics as constraints on macroscopic currents. As a result, nonuniform symmetries give rise to qualitatively new physical phenomena, including modified spectra of collective excitations, exemplified by transverse Tkachenko oscillations in quantum vortex crystals, and unconventional transport phenomena, such as anomalously slow diffusion and softened sound modes in dipole-conserving systems.
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Materials Science

Electronic manipulation of polar order in electron crystal

When interaction among atoms or ions is strong enough, they often arrange periodically, forming a crystal. The arrangement patterns of atoms or ions can encode information, a concept that has enabled devices such as ferroelectric memories. It has been found that not only atoms or ions but also electrons in condensed matter can crystallize when Coulomb interaction is strong enough. Typical examples are charge-ordered states in solids, where different valences, or different electron numbers, of an ion spontaneously form a spatial pattern on the lattice. In such electron crystals, information is expected to be encoded into the electron-ordering patterns. Here, we demonstrate electronic manipulation and readout of charge-ordering directions in a paramagnetic semiconductor LuFe$_2$O$_4$. By applying current pulses at room temperature, we observed that the non-reciprocal resistivity of LuFe$_2$O$_4$ is modulated along with a sign reversal, which disappears above the charge-ordering temperature. A numerical calculation incorporating inter-band Berry curvature affected by the charge ordering is consistent with the experimental results. By applying the observed phenomenon, we also demonstrate a non-reciprocal resistance memory operation in the charge-ordered LuFe$_2$O$_4$. This result opens the door to realizing charge-ordering electronics.
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All authors Takashi Kikkawa, Ziyan Chen, Yuto Fujimoto, Takahiro Morimoto, Yuya Hirata, Hiroki Arisawa, Alexey A. Kaverzin, Satoshi Okamoto, Yoichi Okimoto, Naoshi Ikeda, Eiji Saitoh

Mesoscale and Nanoscale Physics · Cross-listed from cs.LG

Action-Factored Multi-Agent Reinforcement Learning for Scalable Quantum Device Tuning

Cooperative multi-agent reinforcement learning is well suited to problems with large parameter spaces and exploitable local structure, such as the tuning of electrostatically-defined quantum-dot arrays. However, if parameter cross-talk is strong, a non-stationary environment from the perspective of any individual agent can destabilize learning - the same effect that plagues manual tuning of such systems. We propose using a factored representation of the action space, learned online, to decouple agents and minimize their interference. Our framework, QADAPT, uses this factorization to efficiently learn shared policies based on local measurements and rewards. With this modular strategy, we achieve zero-shot generalization to unseen quantum device sizes and maintain an approximately constant number of convergence steps to reach target regimes. This work provides a scalable route toward the rapid calibration of large-scale quantum processors.
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All authors Edwin De Nicolo, Rahul Marchand, Cornelius Carlsson, Pranav Vaidhyanathan, Natalia Ares