Strongly Correlated Electrons
Short-range magnetic order and multi-stage phase transitions in the easy-plane van der Waals magnet CrCl$_3$
T. B. Mazitov, M. I. Panin, A. S. Pakhomov et al. (+4 more)
We investigate the
evolution of
spin correlations and the nature of the multi-stage
magnetic transition in the quasi-two-dimensional easy-plane van der Waals magnet $\rm CrCl_3$. By combining broadband
ferromagnetic resonance (FMR) spectroscopy and DC SQUID magnetometry on mechanically exfoliated micro-flakes with non-local dynamical mean-field theory (DFT+DMFT) calculations, we analyze both long- and short range
magnetic order in CrCl$_3$. Experimentally, SQUID and FMR measurements confirm the presence of the crossover to a
spin polarized phase with the subsequent transition into an
antiferromagnetic ground state upon cooling, but show robust short-range correlations at temperatures far above the
magnetic ordering temperatures. Theoretically, we show the existence of highly stable local
magnetic moments at room temperature, with a
giant room temperature lifetime $\tau$ of 130–300 ps due to a wide Mott bandgap. Below room temperature, a rapid growth of the in-plane correlation length $\xi$ signals the formation of strong short range
magnetic order consistent with the experimental observations. We also obtain a temperature-driven crossover of the interlayer exchange interaction, which changes from positive (
ferromagnetic) at high temperatures to negative (
antiferromagnetic) in the low-temperature ordered phase.
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All authors T. B. Mazitov, M. I. Panin, A. S. Pakhomov, M. V. Bakhmetiev, E. O. Chiglintsev, A. I. Chernov, A. A. Katanin
Mesoscale and Nanoscale Physics
Coherent dynamics of individual excitons in a quantum dot embedded in a nanopost
Maxime Gaignard, Karolina Ewa Polczynska, Niels Gregersen et al. (+5 more)
We measured coherent ultrafast dynamics of
exciton complexes in a single strongly-confined InAs
quantum dot embedded in a GaAs nanopost. Such a photonic structure combines a wave guiding with a cavity effect and assures an enhanced light-matter coupling over a broad spectral range of 30 nm. Coherence properties of an
exciton-biexciton system hosted by a
quantum dot are assessed with four-wave mixing microscopy. Our results show that this broad-band photonic structure is an excellent asset to probe coherent couplings in a small set of solid state
quantum systems and to investigate the coherence dynamics within the level structure of their excited states.
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All authors Maxime Gaignard, Karolina Ewa Polczynska, Niels Gregersen, Daniel Wigger, Jean-Philippe Poizat, Jean-Michel Gérard, Julien Claudon, Jacek Kasprzak
Statistical Mechanics
The Statistical physics of unsaturated soil water: kinetic theory and non commutative pore water dynamics
Riccardo Rigon
We develop a statistical-mechanical theory of water in unsaturated soil whose outcome is a continuum field equation for the pore-occupancy g(r,x,t), the fraction of pores of radius r that are water-filled at position x and time t. The theory is built across three scales: microscopic inter-pore transfers set by Hagen-Poiseuille rates and a driving potential (the difference of pore-class chemical potentials, taken in capillary-gravitational form but open to adsorptive, osmotic, or thermal refinement); a mesoscale master equation relaxing the occupancy toward the
equilibrium step g_eq=H(r*-r); and, on contracting the averaging volume to a point, the continuum balance d_t g + div F = C[g] - E - T, of which everything else is a limit, a moment, or a boundary resolution. The kinetic equation is an Onsager gradient flow descending the Gibbs free energy, with an H-
theorem for the isothermal unforced system and mass conservation as its zeroth moment. A single dimensionless group, the pore-resolved Damkohler number Da(r,x), organizes the behavior and unifies phenomenologies long modelled separately. A Chapman-Enskog reduction identifies Richards' equation as the quasi-static (Da->0) limit, with matric potential and hydraulic conductivity K emerging only there and K vanishing below the percolation threshold; capillary-bundle and critical-path models are its diagonal and spectral limits. Hysteresis is the holonomy of a forcing bundle, a
geometric phase rather than per-pore bistability, with a falsifiable loop-area law H ~ I^2. Preferential flow is what the same equation does where Da>1, so the Richards/preferential-flow dichotomy becomes a continuous Da-controlled crossover. Out of the quasi-static limit g(r) is the irreducible state variable. All inputs are
geometric properties of the pore network, measurable from micro-CT and calibrated against no macroscopic data.
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Materials Science
Unlocking ultrafast spin dynamics in a rare-earth magnet
Paul Herrgen, Christian Holzmann, Torben Manzke et al. (+5 more)
The speed of optically driven magnetization dynamics is fundamentally determined by how efficiently angular momentum can be transferred between electronic,
spin and
lattice degrees of freedom. In rare-earth magnets, this process is typically slow because optical excitation primarily addresses itinerant electrons, whereas the
magnetic moment resides in localized 4f states. Here we show that selective optical excitation of localized
magnetic states can overcome this limitation. Using femtosecond pump-probe magneto-optical spectroscopy of ferrimagnetic gadolinium iron garnet, we resonantly excite an intra-4f transition of Gd3+ at 4.65 eV and resolve the ensuing dynamics of the antiferromagnetically coupled Gd and Fe sublattices. Direct excitation of the 4f
manifold induces an ultrafast demagnetization of the Gd sublattice with a characteristic time of 38 fs, more than two orders of magnitude faster than in elemental gadolinium and even faster than the response of the Fe sublattice in the same material. By contrast, off-resonant excitation strongly suppresses the acceleration of the Gd dynamics while leaving the Fe response largely unchanged. These results demonstrate that the ultrafast
magnetic response of rare-earth systems is governed not only by intrinsic material properties but also by the optical excitation pathway. Selective access to localized
magnetic states therefore provides a powerful photonic handle for engineering angular-momentum flow and controlling magnetism far from
equilibrium.
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All authors Paul Herrgen, Christian Holzmann, Torben Manzke, Ulrich Nowak, Peter M. Oppeneer, Manfred Albrecht, Benjamin Stadtmüller, Martin Aeschlimann
Statistical Mechanics
Local-dynamics accessibility of the stripe phase in the triangular-lattice $J_1$-$J_2$ Ising antiferromagnet
Tom Poisblaud
The interplay between energetic relaxation and global stripe-sector selection is investigated by analyzing the finite-rate cooling dynamics of the triangular-
lattice $J_1-J_2$ Ising antiferromagnet under local single-
spin Metropolis updates. A protocol-dependent stripe-accessibility time, $n^*(L,J_2/J_1)$, was established as an operational diagnostic to determine the threshold at which half of the trajectories achieve global stripe order. Real-space morphology diagnostics and fixed-temperature holds were subsequently employed to assess late-stage domain wall elimination and to characterize the finite-time coarsening behavior across varying system sizes and $J_2/J_1$ coupling ratios. The system quickly forms local stripe patterns before aligning them globally. Final
alignment is slowed by domain-wall elimination, taking longer in larger systems but speeding up with a higher $J_2/J_1$ ratio.
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Mesoscale and Nanoscale Physics · Cross-listed from physics.chem-ph
Quantum phases in endofullerene zigzag chains
Tobias Serwatka, Muhammad Shaeer Moeed, Roger G. Melko et al. (+1 more)
We employ large-scale density
matrix renormalization group calculations to study the
quantum phases of dipolar molecules confined in bent (zigzag) endofullerene chains, as a function of the chain angle $\gamma$. For LiF, ferroelectric order persists across the full range $60^\circ < \gamma 180^\circ$, with the critical effective dipole moment increasing as the chain bends and parallel
alignment becomes less favorable. Near the equilateral configuration ($\gamma = 60^\circ$),
geometric frustration drives a transition to an antiferroelectric Néel-ordered phase in which neighboring dipoles anti-align along the chain axis. We show that capturing this reorientation requires including dipolar couplings beyond the nearest-neighbor approximation, since next-nearest-neighbor interactions become equally strong at $\gamma = 60^\circ$. For confined water, o-D$_2$O reproduces both ordered phases, whereas p-H$_2$O – owing to its large rotational constants – develops no order at any chain angle despite the enhanced coordination of the bent geometry. Because a zigzag chain is the narrowest stripe of a two-dimensional
lattice, these results suggest that engineered endofullerene layers could host a rich variety of dipole-ordered
quantum phases beyond the ferroelectric ordering observed in previous work.
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All authors Tobias Serwatka, Muhammad Shaeer Moeed, Roger G. Melko, Pierre-Nicholas Roy
Strongly Correlated Electrons
Sixteenfold Classification of Many-Body Multipoles from Rotation-Compatible Canonical Symmetries
Shingo Kuniyoshi, Rikuto Oiwa and Satoru Hayami
The conventional multipole framework provides a standard
symmetry-based
language for one-body electronic degrees of freedom, but fails to distinguish physically distinct sectors in many-body operator space. We show that canonical
symmetries compatible with rotations provide this structure through two additional 2 labels associated with the particle-number gauge transformation G{\pi}/2 and the particle-hole transformation CA. These labels separate operators with different body numbers and particle-number changes, leading to a sixteenfold classification that organizes selection rules for nonzero expectation values, induced multipoles, and
symmetry-allowed couplings in many-body multipole space.
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Soft Condensed Matter
Dispersion Polymerization in an Elastomeric Solvent
Senthilkumar Duraivel, Reagan J Dreiling, Tyler E Ball et al. (+5 more)
Polymerization-induced phase separation (PIPS) provides a powerful route to generate structured polymeric materials by coupling chemical conversion with thermodynamic demixing. PIPS in
liquid-state systems underlies dispersion polymerization, serving as a cornerstone technique for microparticle production, yet is constrained by solvent compatibility and limited range of morphologies. Here, we establish an elastically mediated PIPS regime that bridges these two limits by conducting controlled polymerization within a deformable elastomeric network. This approach, termed Dispersion Polymerization in an Elastomeric Solvent (DiPolES), serves as a solid-state analogue of dispersion polymerization in which an elastomeric network simultaneously serves as solvent and physical stabilizer. Using photoiniferter-mediated polymerization of methyl methacrylate (MMA) within poly(dimethyl siloxane) (PDMS) elastomeric solvent, DiPolES enables robust fabrication of elastomeric composites containing uniform PMMA microparticles with tunable size (0.85 to 3 {\mu}m) and shape (spheroidal and ellipsoidal). The strategy is generalizable beyond the PDMS/MMA system and is applicable to diverse monomers, such as acrylonitrile and 2-vinyl pyridine, which can be extracted from the elastomeric solvent, enabling high-yield production of microparticles. Real-time imaging and compositional analysis reveal that particle formation proceeds through rapid nucleation at low monomer conversion, followed by growth accompanied by cavitation of the surrounding network. Monomer loading governs the particle size, while solvent elasticity modulates the transition from isolated uniform spheroids to heterogeneous clusters. Interestingly, applying uniaxial strain during DiPolES enables production of ellipsoidal particles without any post-processing.
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All authors Senthilkumar Duraivel, Reagan J Dreiling, Tyler E Ball, Harsha Koganti, Jay Fu, Ethan E. O'Banion, Brett P. Fors, Eric R. Dufresne
Soft Condensed Matter
Quantifying nanoparticle size effect on the photoacoustic generation efficiency
Arthur Billon, Sarah Boumati, Lorenzo Mancini et al. (+9 more)
Photoacoustic (PA) signal generation in colloidal suspensions of optically absorbing nanoparticles is dominated by the thermal expansion of water for gold nanoparticles, but remains mostly unexplored for organic nanoparticles. Here, we derive a model where the PA generation efficiency scales with particle size and thermoelastic contrast with water. The model is validated using solid lipid nanoparticles labeled with several BODIPY dyes. This experimental validation paves the way for quantitative PA characterization of nanomaterials and rational design of PA contrast
agents.
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All authors Arthur Billon, Sarah Boumati, Lorenzo Mancini, Charaf Eddine Benaddi, Elise Michel, Clément Linger, Colin Schotté, Rachel Méallet, Frédéric Gobeaux, Gilles Clavier, Nicolas Tsapis, Jérôme Gateau
Statistical Mechanics
Is the Eyring Plot Misleading? A Case for Arrhenius Analysis of Activation Parameters
Titus S. van Erp
A common view in physical chemistry literature is that the Eyring representation, in which a linear fit of $\ln(k/T)$ versus $1/T$ is attempted, is more fundamental than the Arrhenius representation, $\ln(k)$ versus $1/T$. This perception is typically motivated by its derivation from statistical mechanics and
quantum mechanics, and by the interpretation of the intercept in terms of the activation
entropy $\Delta S^\ddagger$, whereas the Arrhenius equation and its prefactor are often regarded as purely phenomenological. However, harmonic approximation models yield exact linearity in Arrhenius plots but not in Eyring plots, although for real experimental data both generally appear equally linear within typical experimental accuracy. Furthermore, the impression that the Eyring formulation is inherently
quantum mechanical arises from the presence of the Planck constant in the prefactor, whereas this term results from normalization conventions in the partition function. This also highlights an interpretational issue in $\Delta G^\ddagger$, which is based on partition functions of different dimensionality between reactant and transition state. This dimensional mismatch can be reformulated in an alternative representation that improves interpretability and reduces to an Arrhenius-type expression in which the prefactor is directly related to an
entropy of activation. In this framework, both activation enthalpy and
entropy obtained from an Arrhenius fit are arguably more physically relevant than the corresponding Eyring fit values.
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Materials Science
Semi-Empirical Kinetic Model for Phase Selection in Rapidly Solidified Multicomponent Concentrated Alloys
O.I. Kushnerov, S.I. Ryabtsev and V.F. Bashev
A semi-empirical kinetic framework is formulated for predicting phase selection in multicomponent concentrated
alloys under rapid solidification. The approach is based on the critical cooling rate required to suppress competing crystalline pathways and combines
topology-dependent ranking of BCC-, FCC-, and HCP-like crystallization pathways with a correction for glass-forming ability. The formulation includes a
topology-dependent viscosity correction with a smoothed BCC multiplier and a continuous correction factor for glass-forming ability based on mixing enthalpy, excess
entropy, and atomic-size dispersion. Comparison with experimental and computational data shows that the kinetic criterion captures changes in the
lattice type expected from the valence electron concentration criterion, describes kinetic suppression of phase separation, and identifies competitive multiphase crystallization. The model also distinguishes
alloys with high and low glass-forming ability. The proposed framework provides a practical approach for preliminary evaluation of kinetic phase competition in rapidly solidified multicomponent melts.
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Materials Science
Learning to Converge: Warm-Starting DFTB Self-Consistent Charges with Machine Learning
Maximilian L. Ach, Karsten Reuter and Chiara Panosetti
Semiempirical electronic structure methods such as Density-Functional Tight-Binding (DFTB) offer a computationally efficient approach to molecular and materials simulations, bridging the gap between first-principles accuracy and classical force field speed while retaining full access to electronic properties. However, DFTB calculations based on self-consistent charge (SCC) schemes can still suffer from slow convergence, particularly for complex molecular and materials systems, making the iterative procedure a significant bottleneck in large-scale simulations and high-throughput workflows. We present a machine learning approach that accelerates DFTB simulations by predicting optimal initial atomic charges. Using element-specific models based on the Smooth Overlap of Atomic Positions descriptor and kernel ridge regression, we train charge models on reference calculations and demonstrate that ML-predicted initial charges consistently and significantly improve SCC convergence across diverse chemical systems including organic molecules, biomolecules, water clusters, transition metal
oxides and solid electrolytes.
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Materials Science
Kinetic Cellular Model of Corrosion
Orkan Sezer and Andrew Horsfield
Aqueous corrosion of metals involves multiple interconnected processes. Thus, computer simulation of corrosion as a whole needs to be able to describe the individual processes and how they influence each other. Atomistic simulations are designed to obtain detailed information for small regions of space over short times. Thus there are limits to the understanding that can be obtained by atomistic simulations alone. Here is presented a method that uses generalised rate equations to extend the length and time scales that can be accessed. It is shown to reduce to either the phase field or cellular automata methods in certain limits. The generalised kinetic equations can reproduce the behaviour described by both the Nernst-Planck and Butler-Volmer equations, which are frequently used to describe corrosion. In addition, the method can describe local rearrangements of atoms such as chemical reactions. Example results are shown for illustrative 1D and 2D problems, with good agreement being found with other methods.
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Disordered Systems and Neural Networks
Transient Reserves, Sink Dampers, and the Failure of Eigenvalue Reasoning in the Attention Propagator
Li Hengyu
The
attention matrix of a causal
transformer is row-
stochastic, iterated over depth, and non-normal by construction. For non-normal operators,
eigenvalues control only asymptotic behavior; finite-depth behavior is controlled by resolvent quantities such as pseudospectra and Kreiss constants. We test, under pre-registered criteria, whether this resolvent view predicts anything about trained
transformers that
eigenvalues miss. Two structural facts organize the analysis: the mask pins the Kreiss constant of every causal
stochastic matrix at $\sqrt{n}$, and deflating the mask-forced Perron projector factorizes the depth deviation dynamics exactly into a product of deflated operators. Across GPT-2, Pythia-410m, and Llama-3-8B, learned non-normality proves to be signed. A routing minority carries excess transient reserve that tracks previous-
token function and doubles when induction heads engage, while the sink majority is suppressed below matched shuffle nulls, so that
attention sinks act as transient dampers. On depth products,
eigenvalue predictions of surviving deviations err by seven to eleven orders of magnitude, an error absent in matched nulls. Checkpoint censuses date this organization to a consolidation phase after
circuit formation, and a clamping intervention on Llama-3-8B establishes a causal chain from three massive activation dimensions through sink
attention to transient damping; LayerNorm models implement the same functions elsewhere. A cross-validated contest concludes that resolvent features are required for depth-transient persistence and routing-head identity, and that no single-operator summary of any kind predicts per-head causal criticality.
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Statistical Mechanics
The scales of disorder in perfect quasicrystals
Alan Rodrigo Mendoza Sosa, Atahualpa S. Kraemer, Michael Schmiedeberg et al. (+1 more)
The classical dichotomy between crystalline order and amorphous disorder is increasingly challenged by novel states that lack conventional crystalline
symmetries while retaining
crystal-like properties. Quasicrystals occupy a distinctive position within this expanding framework by possessing long-range order without translational periodicity, thereby permitting arbitrary $N$-fold rotational
symmetry. Paradoxically, far from their unique
symmetry center, high-
symmetry quasicrystals closely resemble disordered patterns, raising the question of how deterministic order can be detected. Here we show that increasing rotational
symmetry progressively suppresses local statistical signatures of quasiperiodicity, while preserving its underlying exact long-range order. This order is thus concealed below an emergent crossover length that grows linearly with $N$. Therefore, as $N \rightarrow \infty$, the disorder-like regime expands without bound, defining a
symmetry-controlled
geometric critical point at which deterministic order and randomness become statistically indistinguishable over any finite observation window. For finite $N$, however, quasiperiodic order becomes detectable beyond this crossover, revealing a second emergent length scale that we identify as the size of a statistical unit
cell – finite patches over which statistical properties recur despite the absence of conventional translational periodicity. In one dimension, the statistical-unit-
cell size coincides with the crossover length, whereas in two dimensions it grows as $N^2$, remaining smaller than the size of typical approximants and establishing a hierarchy of emergent length scales. Together, the disorder-to-order crossover and statistical unit
cells provide a quantitative framework connecting
crystals, quasicrystals, and amorphous matter, showing how apparent disorder can emerge from purely deterministic geometry.
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All authors Alan Rodrigo Mendoza Sosa, Atahualpa S. Kraemer, Michael Schmiedeberg, Erdal C. Oğuz
Mesoscale and Nanoscale Physics
Terahertz field-driven nonlinear Hall effect and other second order transport phenomena in two-dimensional tellurene
M. D. Moldavskaya, L. E. Golub, E. Mönch et al. (+4 more)
We study terahertz field-driven second-order nonlinear electron transport phenomena, including the nonlinear
Hall effect (NLHE), in two-dimensional tellurene flakes. The dc current excited by linearly polarized terahertz (THz) radiation in
Hall bar samples is investigated in directions both along and perpendicular to the $c$-axis of tellurene. As expected for second-order transport phenomena, the current scales as the square of the in-plane electric field of the radiation $\bf E$, and depends on its orientation. The current results from a combination of three contributions, including the NLHE, the Nonlinear Longitudinal (NLL) and Nonlinear Diagonal (NLD) currents. We established the equivalence between NLH, NLL, and NLD transport currents and Linear photogalvanic effect (LPGE) contributions induced by the absorption of linearly polarized and unpolarized THz radiation. All contributions can be controlled by a gate voltage and have opposite signs for electron and hole conductivity. The magnitude of the current increases drastically when the samples are cooled from room temperature to 4.2 K. It also increases with decreasing radiation frequency. These results are well described by the developed phenomenological and microscopic theories. We show that the THz radiation-induced electric current originates from microscopic mechanisms such as skew scattering, side jump, and the Berry
curvature dipole.
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All authors M. D. Moldavskaya, L. E. Golub, E. Mönch, Chang Niu, Peide D. Ye, J. Wunderlich, S. D. Ganichev
Quantum Gases
Observation of a Rydberg-atom time crystal with an ultralong lifetime
Qi-Feng Wang, Tian-Yu Han, Ya-Jun Wang et al. (+9 more)
Continuous time
crystals (CTCs) represent a nonequilibrium
quantum phase that spontaneously breaks time-translation
symmetry without periodic external driving, manifesting as persistent, long-lived oscillations under steady pumping. The lifetime is constrained by the instability of the limit cycle phase, balanced between nonlinear feedback and energy dissipation, which have rarely been studied in experiments before. Here, we report an observation of an ultralong-lived Rydberg-atom CTC in a driven-dissipative many-body atomic system. By harnessing long-range interactions and engineering a dissipative environment that stabilizes the limit-cycle dynamics, we suppress heating and decay effects that typically destroy time-crystalline order. The key factor underlying the ultralong-lived CTC is the closing of the Liouvillian gap and the near-zero real part of the system's Liouvillian eigenspectrum. Through systematic optimization, we achieve an oscillatory lifetime exceeding 16.95 hours-orders of magnitude longer than previous CTC realizations. Our work establishes a robust platform for exploring long-lived autonomous nonequilibrium phases and paves the way for applications in
quantum sensing and continuous-time
quantum information processing.
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All authors Qi-Feng Wang, Tian-Yu Han, Ya-Jun Wang, Dong-Yang Zhu, Chao Yu, Yu Ma, Yi-Ming Yin, Guang-Can Guo, Bang Liu, Li-Hua Zhang, Dong-Sheng Ding, Bao-Sen Shi
Mesoscale and Nanoscale Physics
Screening-controlled dynamical criticality in the quantum Hall regime
Tanima Chanda, Simrandeep Kaur, Anantbir Virk et al. (+5 more)
At continuous electronic phase transitions, Coulomb interactions can modify the relation between length, energy, and temperature, but experimentally disentangling their effects on spatial versus dynamical criticality has remained difficult, since finite-temperature scaling alone measures only the combined exponent $\kappa = 1/(z\gamma)$. Here, we introduce two advances that resolve this limitation. First, by combining temperature scaling with independent current scaling, we separately extract the dynamical exponent $z$ and the localization-length exponent $\gamma$ at the
quantum Hall plateau transition – rather than inferring one from an assumed value of the other. Second, using dual-graphite-gated
graphene devices in which the effective Coulomb interaction range is tuned geometrically by the ratio of the
magnetic length $l_B$ to the graphite-gate distance $d$, we track this separation across both screened and unscreened interaction regimes within the same device platform. Temperature scaling gives $\kappa \simeq 0.21$ in the screened regime and $\kappa \simeq 0.41$ in the unscreened regime; combining this with current scaling reveals that screening changes $z$ from $\simeq 1$ in the unscreened regime to $\simeq 2$ in the screened regime. In contrast, $\gamma$ remains close to $2.4$ throughout. Our results establish that gate-controlled screening selectively modifies the interaction-dependent dynamical sector of the
quantum Hall transition, leaving the localization-length exponent $\gamma$ unchanged within experimental uncertainty. More broadly, this work establishes
geometric screening as a versatile tool for controlling interactions and disentangling interaction and disorder effects in correlated two-dimensional systems, including fractional
quantum Hall states, moiré materials, and other strongly localized electronic phases.
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All authors Tanima Chanda, Simrandeep Kaur, Anantbir Virk, Kenji Watanabe, Takashi Taniguchi, G. J. Sreejith, Yuval Gefen, Aveek Bid
Quantum Gases · Cross-listed from hep-th
Quantum field nucleating and Wigner functions
Joonas Hirvonen
We present a novel real-time framework for the decay of metastable states in
quantum field theories using Wigner functions. The framework introduces a nonperturbative nucleation rate formula that captures both
quantum tunneling and over-the-barrier nucleation, alongside steps to evaluate it perturbatively. We apply it to a simple thermal example with direct relevance to current analog experiments. Our derived one-loop nucleation rate fundamentally differs from the widely cited high-temperature result by Linde: The prefactor contains
quantum effects and also asymptotes to a differing form at high temperatures, where the
quantum effects become negligible. Rather, the result is a generalization of Affleck's rate formula to
quantum field theories, asymptoting to the effective field theory approach, and Langer's rate, at high temperatures. The example also reveals that the high-temperature side of the “
quantum-to-classical” transition of thermal
vacuum decay is still inherently
quantum mechanical, even though the bounce background possesses the classical, $\mathrm{O}(d)\times S^1$,
symmetry.
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Materials Science · Cross-listed from cs.AI
Toward Auditable AI Scientists: A Hypothesis Evolution Protocol for LLM Agents
Izumi Takahara and Teruyasu Mizoguchi
Large
language model (LLM)
agents are increasingly expected to play a central role in AI-driven scientific discovery. Equipped with broad knowledge, flexible
reasoning, and tool use, they have the potential to autonomously explore and solve scientific problems by repeatedly proposing hypotheses, testing them, and revising their beliefs in the light of the evidence. In current
agents, however, these hypotheses, tests, and belief updates are buried in unstructured logs, and no mechanism lets the
agent or the human researcher audit that process. Here we propose the Hypothesis
Evolution Protocol (HEP), an
agent harness that provides hypothesis generation, evaluation, and
evolution as explicit, auditable operations. On materials-science research tasks, a HEP-equipped
agent operates the hypothesis–test–evidence–belief cycle that planning-style
agents lack, generalizes across research questions, and exploits the protocol more fully as the base LLM becomes more capable. These results mark a step toward auditable AI scientists, whose scientific
reasoning can be inspected, verified, and built upon.
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Strongly Correlated Electrons
Topological phase transition driven by Hatsugai-Kohmoto interaction on the Kagome lattice
Zhuo-Xuan Yang and Jiangfan Wang
The interplay between band
topology and strong correlations is central to modern condensed matter physics, but exact solutions are rare. Here, we present an exactly solvable model on the Kagome
lattice by combining a Kane-Mele-type
spin-orbit coupling with the Hatsugai-Kohmoto interaction. At 1/3 filling, we uncover a continuous topological
quantum phase transition driven by electron interaction. A weakly correlated $\mathbb{Z}_2$ topological
insulator gives way to a strongly correlated
insulator that, while $\mathbb{Z}_2$-trivial, hosts a nontrivial
spin Chern number $C_s=2$. The transition exhibits critical scaling consistent with the universality class of two-dimensional Dirac
fermions. At half-filling, the same model yields a non-
Fermi-
liquid to Mott-
insulator transition, demonstrating that correlation-driven topological and Mott transitions can be unified within a single solvable framework. Our results establish the Kagome Hatsugai-Kohmoto model as a valuable
benchmark for interacting topological systems.
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Superconductivity
Tunable responsivity and bandwidth in microwave kinetic inductance detectors via readout current nonlinearity
Maclean Rouble, Peter Day, Matt Dobbs et al. (+3 more)
Microwave kinetic inductance detectors (MKIDs) are generally read out with microwave readout tones of high enough amplitude to adequately suppress the noise contribution of the first-stage amplifier. At high readout power, the detector's resonant frequency is altered as a result of the dependence of the kinetic inductance on the internally circulating microwave current. With the tone placed below the resonant frequency, the nonlinear frequency shift results in a positive feedback effect that can significantly enhance the responsivity of the detector, to both optical and microwave power. We report a factor of 10 enhancement in optical response by tuning the readout power and frequency to close to the resonator's bifurcation point. A corresponding decrease in the bandwidth of the resonator is observed under these conditions. We show that the strength of the feedback effect can be easily selected by adjusting the excitation, and provide a map of possible operational states to do so. Operation of MKIDs in this mode could be used to improve sensitivity when non-intrinsic noise sources are significant.
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All authors Maclean Rouble, Peter Day, Matt Dobbs, Joshua Montgomery, Sofiia Savchyn, Graeme Smecher
Soft Condensed Matter
Shear Unfreezing Explains Yielding, Plasticity and Neck Initiation of Glassy Polymers
Peihan Lyu, Zhaoyu Ding, Masao Doi et al. (+1 more)
Yielding, plasticity, and necking are central to the mechanical performance of materials, yet a concise unified physical picture of how these nonlinear responses arise remains lacking. We develop a minimal theory for glassy
polymers based on a classical volume-dependent relaxation time following the Doolittle equation, and derive the constitutive relation using the Onsager variational principle. Surprisingly, this simple theory explains yielding, plasticity, and neck initiation under constant strain rate loading via a shear unfreezing mechanism: as the sample is stretched, volume-increasing activated molecular mobility drives shear deformation from an initially frozen state to an unfrozen state. The theory yields an analytical expression for the yielding stress as a function of strain rate and temperature. It also predicts a phase diagram for necking initiation in the same parameter space, providing a mechanism beyond the classical Considère criterion. Our results establish a unified framework for nonlinear tensile behavior in glassy materials.
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All authors Peihan Lyu, Zhaoyu Ding, Masao Doi, Xingkun Man
Mesoscale and Nanoscale Physics
Quantum Hopfion rings in the cluster mean-field approximation
Vladyslav M. Kuchkin and Thomas L. Schmidt
We study the
quantum properties of two- and three-dimensional
spin textures – $k\pi$-skyrmions and hopfion rings – within the cluster mean-field approximation (CMFA). By combining the CMFA with a symmetrization procedure, we achieve two key advances: the accurate computation of
quantum fluctuations in large
spin textures and reliable access to metastable states. These challenges are generally insurmountable using standard methods, which are severely limited by the curse of dimensionality and typically restricted to ground-state properties. Exploiting the cylindrical
symmetry of the studied
magnetic configurations, we construct one-dimensional chain-like clusters that can be efficiently simulated using the density
matrix renormalization group method, while inter-cluster interactions are treated at the mean-field level. The resulting spatial profiles of
quantum features such as the local variation of the magnetization length in hopfion rings reveal limitations of the classical micromagnetic model and indicate the necessity of its extension. We demonstrate that the recently proposed regularized micromagnetic equation provides a suitable framework for this purpose.
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Mesoscale and Nanoscale Physics · Cross-listed from physics.app-ph
Symmetry-constrained low-energy effective Hamiltonian for topological RuC and OsC monolayers
A. Baradaran and O. Sedaghatfar
We derive a low-energy $\mathbf{k}\cdot\mathbf{p}$ effective
Hamiltonian for monolayer osmium carbide (OsC) and ruthenium carbide (RuC) in a planar hexagonal configuration. First-principles calculations indicate that both monolayers are dynamically stable and exhibit features of a two-dimensional
quantum spin Hall (QSH) phase, characterized by a nontrivial $\mathbb{Z}_2$ topological invariant. Using
symmetry analysis at the $\Gamma$ point, we construct a multiband $\mathbf{k}\cdot\mathbf{p}$
Hamiltonian including
spin-orbit coupling and reduce it to a four-band low-energy model through Löwdin partitioning. The effective
Hamiltonian has a block-diagonal form, with two blocks related by time-reversal
symmetry, analogous to the Bernevig–Hughes–Zhang (BHZ) model. In contrast to the standard BHZ form, the
symmetry-allowed off-diagonal coupling contains quadratic momentum-dependent terms, which modify the low-energy dispersion near the $\Gamma$ point. The fitted parameters reproduce the ab initio band structures in the low-energy region, yielding a compact model for analyzing the electronic and topological properties of monolayer OsC and RuC.
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Statistical Mechanics
Predictive Renormalization-Group Theory of Universality Classes in Nonlinear Systems
Ko Okumura
Universal scaling behavior appears across a wide range of nonlinear systems despite substantial differences in their governing equations and physical mechanisms. We develop a renormalization-group (RG) framework that identifies two complementary RG mechanisms underlying such universality. First, scale invariance generates RG fixed points corresponding to asymptotic self-similar solutions. Second, repeated RG transformations eliminate non-scale-invariant irrelevant structures, causing broad classes of equations to flow toward the same fixed points and thereby form universality classes. The framework applies to finite-time singularities, long-time intermediate asymptotics,
stochastic Edwards–Wilkinson growth, nonlinear
diffusion, density-dependent biological
diffusion, and fluid-interface dynamics. In each case, it reproduces known scaling behavior and identifies the associated universality class through explicit irrelevance criteria. A central feature of the framework is its predictive character. Once a scale-invariant fixed point is identified, the theory predicts entire families of nonlinear equations sharing the same asymptotic self-similar solution. While the
diffusion class is partially supported by existing mathematically rigorous results, most universality classes identified here have not previously been established and therefore constitute testable predictions. These results provide a unified RG perspective on universality in nonlinear systems and show that universality emerges from the same fundamental RG principles that underlie critical phenomena.
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Quantum Gases
Superheavy dark-bright soliton as a signature of spatial symmetry breaking transition in harmonically trapped Bose mixtures
Zheng Gao, Ling-Zheng Meng, Jie Liu et al. (+1 more)
We investigate the dynamics of a dark-bright
soliton in harmonically trapped two-component Bose-Einstein condensates and reveal an interesting spontaneous spatial
symmetry breaking driven by nonlinear interactions. When the interaction parameter crosses a threshold value, we find that the dark-bright
soliton's motion demonstrates a transition from symmetric periodic oscillation about the origin to asymmetric oscillations offset from the origin. In particular, at the transition point, the effective
soliton mass, determined by the ratio of inertial mass to physical mass, diverges. The underlying mechanism is uncovered by constructing trial wave functions and employing the Lagrangian variational method to obtain an effective potential in the quasiparticle picture, which changes from a single well to a double well. The anomalous “superheavy
soliton” phenomenon is a direct consequence of the dark-bright
soliton's physical mass vanishing at the transition point. We obtain the phase diagram of this spatial
symmetry-breaking transition. Possible implications of our finding for
quantum metrology are discussed.
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All authors Zheng Gao, Ling-Zheng Meng, Jie Liu, Li-Chen Zhao
Mesoscale and Nanoscale Physics
Negligible current-induced torque from the bulk and interface of Al
Taiyang Zhang, Lujun Zhu, Zhihao Yan et al. (+1 more)
The light metal Al was predicted to have strong orbital
Hall and Rashba effects from its bulk and interface, respectively. In this letter, we report experimental evidence that neither the bulk nor the interface of the Al contributed a detectable torque on adjacent Co and FePt layers with significant
spin Hall effect,
spin-orbit coupling, and resistivity mismatch with Al. These results suggest minimal orbital-
spin conversion in Al and negligible orbital transport and
spin-vorticity torque in Co/Al, Al/Co, and Al/FePt
bilayers. Our findings suggest poor generality and/or effectiveness of torque contributions by the orbital
Hall effect, the interfacial orbital Rashba effect, and the
spin-vorticity coupling.
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All authors Taiyang Zhang, Lujun Zhu, Zhihao Yan, Lijun Zhu
Mesoscale and Nanoscale Physics
A new perspective on the anomalous Hall effect
Jason G. Kattan, Matthew Albert and J. E. Sipe
We revisit the anomalous
Hall effect in
magnetic conductors, and its generalization to finite frequencies, using a formalism based on microscopic notions of polarization, magnetization, and free charges and currents. The electronic degrees of freedom are treated within second-quantized field theory, where the
Hamiltonian features a static and
cell-periodic
magnetic field that encodes the
magnetic order in the
crystal and breaks time-reversal
symmetry. We study the dynamics of bound and free charge carriers at the microscopic level as they respond to a spatially uniform electric field at finite frequency. The conductivity tensor describing the long-wavelength response is a sum of three terms, including a Kubo term associated with the polarization response, along with the metallic Drude term and the anomalous
Hall conductivity that are associated with the longitudinal and transverse parts of the free current response, respectively. We also present numerical calculations of these contributions for the
ferromagnetic body-centered cubic phase of iron.
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Strongly Correlated Electrons
Magnetic devil's staircase in UAgBi$_{2}$
G. S. Freitas, K. Kirchner, C. Girod et al. (+10 more)
Materials characterized by competing interactions often exhibit a large number of nearly degenerate periodic states. Here we show that layered UAgBi$_2$ hosts a cascade of field- and temperature-induced
magnetic transitions. Based on specific heat, thermal expansion, and
neutron diffraction, we construct a phase diagram that reveals at least seven nearly degenerate
magnetic states in UAgBi$_2$. The observed multi-step magnetization process can be understood by square-wave structures with distinct propagation vectors $\mathbf{k}$=(0, 0, k) in the presence of strong easy-axis anisotropy that confines the moments along the c axis. Our findings are consistent with a
magnetic devil's staircase described by the axial next-nearest neighbor Ising (ANNNI) model and place UAgBi$_2$ as a rare realization of the devil's staircase in a 5f-electron system.
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All authors G. S. Freitas, K. Kirchner, C. Girod, D. R. Yahne, W. Simeth, C. S. T. Kengle, F. B. Carneiro, P. G. Pagliuso, J.D. Thompson, M. Janoschek, O. Zaharko, S.M. Thomas, P. F. S. Rosa