Papers

We develop a localised wavelet formulation of multifractal random walk unwrapping based on the local multiplicative modulation freezing. The framework is motivated by the observation that finite-support wavelet localisation may induce approximate local factorisation of multiplicatively modulated stochastic fields, allowing the modulation component to become effectively frozen within sufficiently localised probing domains. Within this regime, logarithmic wavelet amplitudes admit an approximate additive decomposition linking local wavelet statistics directly to the underlying modulation field. This viewpoint reformulates covariance-based MRW unwrapping as a localised multiscale operator problem in which wavelet coefficients act as finite-support probes of multiplicative organisation. The validity of the approximation depends explicitly on support geometry, scale-dependent overlap, and residual multiscale mixing generated by internal modulation variability. We show that these effects naturally produce finite-scale deviations from ideal logarithmic covariance scaling and lead to structured covariance distortions whose form depends on the interaction between the modulation field and the geometry of the wavelet representation. In the resulting framework, localisation itself becomes the operational mechanism enabling multiscale probing of local stochastic organisation. Numerical investigations using orthonormal wavelet decompositions support the proposed interpretation and demonstrate the emergence of scale-dependent freezing regimes, residual covariance mixing, and finite-support breakdown effects consistent with the theory. The proposed framework suggests a broader connection between wavelet localisation, local regularity organisation, and finite-support multiscale stochastic operators. Wavelet localisation becomes an operational mechanism for probing localised multiscale structure.

Quantum geometry underlies many electronic responses, but its transport signatures have so far been established mainly for pure single-particle Bloch states. Whether collective many-body fluctuations possess a measurable quantum geometry remains largely unexplored. Here we show that superconducting fluctuation transport provides a direct probe of quantum information geometry in collective many-body matter. Starting from a multicomponent time-dependent Ginzburg-Landau theory in the Gaussian fluctuation regime, we identify the equilibrium density matrix of fluctuating Cooper pairs as the static pair propagator, which defines a positive mixed-state manifold in momentum space. The geometry of this manifold is directly measurable through paraconductivity: the longitudinal paraconductivity is governed by the quantum Fisher information of superconducting fluctuation modes, while the fluctuational anomalous Hall effect is governed by the mean Uhlmann curvature, the mixed-state counterpart of Berry curvature. This correspondence further yields geometric bounds between these two transport components, with no direct analogue in normal electronic transport. Applied to chiral superconducting fluctuations in quarter-metal systems motivated by rhombohedral multilayer graphene, a symmetry-allowed Lifshitz invariant generates finite mean Uhlmann curvature and logarithmically enhances the anomalous Hall conductivity above the critical temperature. Our results establish collective superconducting fluctuations as an experimentally accessible transport probe of mixed-state quantum information geometry.

Spin Hall magnetoresistance (SMR) has emerged as a powerful probe for investigating interfacial spin transport and magnetic anisotropy in complex oxide heterostructures. In this work, we investigate the interfacial magnetic anisotropy in Pt/CVO through angle-dependent magnetotransport measurements. Unlike the bulk-sensitive magnetic measurements on both strained CVO and Pt/CVO films, which exhibit a ferrimagnetic transition at $T_{C} \approx 150$ K accompanied by out-of-plane anisotropy that reorients toward in-plane anisotropy below 90 K, SMR reveals a distinct interfacial magnetic anisotropy. The rotational scans of the in-plane transverse SMR at 20 K exhibit substantial hysteresis about [100], while no hysteresis is observed along [110] and [1$\bar{1}$0], indicating a biaxial anisotropy with easy axes along [110] and [1$\bar{1}$0]. Furthermore, the absence of sharp discontinuities in both the in-plane longitudinal and transverse SMR, together with pronounced discontinuities near the in-plane [010] direction during out-of-plane rotation, strongly indicates the presence of in-plane anisotropy. This behavior persists up to 120 K. The discrepancy between the bulk-sensitive magnetic measurements and the SMR response suggests that the Pt/CVO interface retains a magnetic anisotropy distinct from the bulk, highlighting the interfacial sensitivity of SMR. Additionally, the spin mixing conductance is found to be of the order of $10^{14}$ $\Omega^{-1}\mathrm{m}^{-2}$, comparable to other oxide-based spintronic systems. These findings highlight the crucial role of interfacial effects in spin transport and establish Pt/CVO as a promising platform for spintronic applications.

Understanding how energy flows from photoexcited carriers into the lattice is essential for describing nonequilibrium phenomena in low-symmetry quantum materials. Here, we use ultrafast low-energy electron diffraction and diffuse scattering to probe momentum-resolved phonon dynamics at the surface of T$_d$-WTe$_2$, a strongly anisotropic semimetal. Following optical excitation, the Debye–Waller suppression of Bragg peaks exhibits a biexponential increase of the mean-squared atomic displacement, indicating sequential lattice relaxation. Analysis of the diffuse background reveals a preferential intensity build-up parallel to the tungsten-chain axis in the material, attributed to anisotropic electron–phonon coupling during electronic cooling which precedes anharmonic phonon–phonon scattering and subsequent thermalization across the surface Brillouin zone. The results identify a hierarchical relaxation pathway in which energy is first deposited into selected finite-momentum phonons before spreading through the broader lattice bath. Our work highlights the importance of momentum-resolved diffuse scattering for disentangling electron–phonon and phonon–phonon relaxation in anisotropic topological semimetals.

Understanding lattice vibrations in two-dimensional (2D) materials is essential for controlling thermal transport, mechanical response, and energy dissipation in nanoscale devices. However, the intrinsic lifetimes of low-energy phonon modes, particularly those that are optically silent, remain largely unexplored. Here we use helium-3 spin-echo spectroscopy to resolve low-energy phonons at the surface of hexagonal boron nitride (hBN) and measure their intrinsic linewidths. We observe the flexural and Rayleigh wave modes and extract the bending rigidity of a quasi-freestanding hBN monolayer. We further report the simultaneous observation of multiple surface-confined interlayer shear modes whose energies agree closely with linear-chain model predictions. By resolving their intrinsic linewidths, we demonstrate a strong confinement-induced reduction in phonon lifetimes, with a near order of magnitude increase in linewidth between the four- and two-layer modes. The temperature dependence of the linewidths indicates that phonon-phonon scattering dominates between 160-360K, while the systematic broadening with decreasing layer number reveals the impact of confinement on phonon decay. These results reveal how reduced dimensionality affects the decay of interlayer shearing modes in hBN, providing direct insight into the phonon lifetimes, confinement effects, and dissipation pathways that govern the dynamical behaviour of two-dimensional materials.

We show that quantum backflow in spin-$\tfrac{1}{2}$ systems within the Pauli framework can arise from spin-dependent contributions to the probability current. We construct explicit two-mode states in which the orbital current reduces to a uniform drift, so that no interference between longitudinal momentum components is present in this sector. In such configurations, backflow is generated entirely by spinor structure, which induces time-dependent modulations of the local current leading to flux reversal, while the longitudinal momentum distribution remains strictly supported on positive momenta. We derive analytical conditions for backflow in terms of spinor and momentum parameters, allowing direct control of the effect via internal degrees of freedom. We further analyze spatial coarse-graining, showing exponential suppression of interference and a qualitatively different scaling of orbital and spin contributions, with spin-induced backflow remaining robust in regimes where orbital effects are strongly suppressed.

We introduce a machine learning framework for extracting Ising topological order from defect partition functions of the two-dimensional Ising model on a torus. Restricted Boltzmann Machines (RBMs) are trained on Ising model data sampled at criticality across topological sectors. We take a component-wise square-root map of the learned distributions which naturally produces candidate wavefunctions for the (2+1)-dimensional Ising TQFT. As a nontrivial consistency check, we extract the modular S-matrix from overlaps of the resulting states and recover the expected Ising modular data. Our results demonstrate that neural network representations can capture both critical fluctuations and emergent topological structure, providing a data-driven route from lattice statistical mechanics to topological quantum field theory.

Random non-hermitian matrix ensembles with double-sided rotation invariance obey, in the limit of large matrix size, the Single Ring Theorem, which states that the support of the mean eigenvalue distribution in the complex plane is either a disk or an annulus. In contrast, rotational-invariant random normal matrix ensembles can have mean eigenvalue densities supported over any number of concentric annuli in the complex plane. In this paper we introduce and investigate, both analytically and numerically, a non-hermitian matrix model which flows from a generic matrix distribution obeying the Single Ring Theorem to a distribution of normal matrices by tuning a parameter which penalizes non-normality. We observe numerically breakdown of the Single Ring Theorem as the model flows towards normality, and determine the critical value of the parameter at which the transition occurs. We also study in detail the behavior of the singular values of these matrices under the flow. These singular values form a Fermi gas confined to the positive half-line. In particular, we find that at small values of the flow parameter, the interparticle spacings in the gas exhibit Wigner-Dyson repulsion, whereas for asymptotically large values of the flow parameter, at the normal matrix endpoint of the flow, the spacing statistics is Poissonian. The flow interpolates continuously between these two types of statistics. However, this change in statistics is not related directly to breaking of the Single Ring Theorem, which occurs very early-on along the flow, in the regime of Wigner-Dyson statistics. Finally, we introduce a certain ensemble of random permutations associated with the gas, and make a conjecture on how to use it in order to reconstruct approximately the average density of complex eigenvalues from that of the singular values in the large-$N$ limit.

We study spin-dependent transport in a hybrid magnetic system, where a non-magnetic (NM) wire is coupled to a side-attached antiferromagnetic (AFM) mesoscopic ring, placed between two non-magnetic electrodes subject to an in-plane electric field oriented perpendicular to the NM wire. The system is described within a tight-binding (TB) framework, and transport properties are computed using the non-equilibrium Green's function (NEGF) formalism. We consider two junction configurations distinguished by the ring-wire coupling: a single-coupled junction and a double-coupled junction. In the single-coupled configuration, the coupling geometry alone breaks the spin symmetry, yielding a finite spin polarization (SP) even without any external field. The in-plane electric field further enhances the symmetry breaking in both configurations, serving as an efficient tuning parameter that drives the SP nearly $100\%$ in the low-bias region. In the double-coupled configuration, spin symmetry is preserved in the absence of the external field, and the electric field acts as a sole source of symmetry breaking, producing a large SP. Finite temperature effects and different system sizes are examined, confirming the robustness of the observed features. To validate the findings over a wide parameter space, we considered different sets of parameters and found that the key signatures remain unchanged. Our results demonstrate that such hybrid structures are promising candidates for realizing an externally controllable spintronic device in low-dimensional systems.

Kagome oxides provide a fertile platform for exploring exotic electronic states arising from geometrical frustration and characteristic band topology. Here, we report the synthesis of a 5d transition-metal kagome oxide, Nd4Os3ZnO14, obtained via high-temperature, high-pressure hydrothermal synthesis. Single-crystal X-ray diffraction reveals a two-dimensional kagome network formed by corner-sharing OsO6 octahedra, with a nominal osmium valence of +4.67. In-plane resistivity and hard X-ray photoelectron spectroscopy measurements indicate that the semimetallic electronic structure at room temperature evolves into a semiconducting ground state upon cooling, accompanied by a pronounced enhancement of hole mobility. Magnetic susceptibility measurements demonstrate localized Nd3+ moments without long-range magnetic order down to 2 K. The coexistence of a metallic kagome plane, strong spin-orbit coupling inherent to 5d electrons, and rare-earth magnetism establishes Nd4Os3ZnO14 as a promising platform for investigating correlated electron phenomena in kagome oxides within the itinerant regime.

Self-organized critical systems often exhibit three macroscopic features simultaneously: nonextensive thermodynamics (quantified by the Tsallis index $q$), structural fractality (measured by the Hausdorff dimension $D$), and non-Markovian dynamics (characterized by the memory exponent $\alpha$). Historically, these parameters have been treated as independent, to be empirically fitted case by case. Here we demonstrate that phase-space self-consistency imposes a unique algebraic closure: $\alpha=D/(2D-1)$. This relation, together with $q=1+1/D$ derived from the extensivity of Tsallis entropy on fractal supports, yields the known result $\alpha=1/(3-q)$ as a consequence, not as an independent assumption. The closure contains no free parameters and satisfies the physical boundary conditions $\alpha(1)=1$ (ballistic transport in Euclidean spaces) and $\alpha\to1/2$ as $D\to\infty$ (maximally subdiffusive regime). We validate the Troika relation across eight independent experimental systems, including seismicity, electromagnetic precursors, EEG, urban networks, botanical architectures, and space plasma. All measured values fall within error bars of the theoretical prediction, establishing the universality of the closure.

Combining effective field theory and numerical renormalization-group (NRG), we study the ground-state phase diagram and single-particle excitations of a spin-$\tfrac{1}{2}$ impurity in a superconducting system with a tunneling density of states behaving as $\rho(\epsilon) \sim |\epsilon|^{r}$, for $|\epsilon|\gg \Delta$ ($\Delta$ being the $s$-wave pairing potential). We focus on the properties of the doublet-singlet transition at large Kondo coupling. The effective field theory for the singlet phase is inferred from a strong coupling expansion in the Kondo coupling. For $\Delta \neq 0$, it contains a local pairing term which drives the system into a spin-singlet phase with enhanced paring correlations. We study how the singet-doublet phase boundary is affected by particle-hole symmetry breaking perturbations such as a scattering potential and/or the chemical potential. Results for the $T$-matrix spectral function are also reported near the transition both at particle-hole symmetry and away from it. It is shown that the singlet-doublet transition can be induced by the chemical potential rather than the Kondo coupling strength. At particle-hole symmetry, a resonance-like feature is observed for $r= 1$ and related to a two-quasiparticle excitation using a single-site model which is derived from effective field theory.

Superconducting spin qubits, realized as Yu-Shiba-Rusinov spin-doublet states in quantum-dot-superconductor systems, represent a cornerstone of current research in quantum technologies. We analyze these ground states of quantum impurities in superconducting pseudogap systems, namely systems with a pseudogap tunneling density of states $\rho(\epsilon) \sim |\epsilon|^r$ for energies $|\epsilon|\gg \Delta$ ($\Delta$ being a $s$-wave pairing potential). For $r=1$, these hosts are realized as Dirac materials (graphene or 3D topological insulator surfaces) in proximity to conventional superconductors, or as $d+i s$ superconductors. Using effective field theory and numerical renormalization group, we map the phase diagram against the pseudogap exponent $r > 0$ and particle-hole symmetry-breaking perturbations. At particle-hole symmetry, increasing $r$ also increases the critical value, $J_c$, of the Kondo coupling that triggers the transition from spin doublet to singlet. Unlike the gapless pseudogap Kondo systems, numerical and analytical evidence suggest that Andreev reflection stabilizes a singlet ground state at $J$ for all $r > 0$. Breaking particle-hole symmetry – by potential scattering or chemical potential – eventually restores the transition at lower $J_c$. Our results indicate that coupling to superconducting hosts with large pseudogap exponents enhances the stability of spin qubits at large Kondo coupling.

In correlated insulators, the interplay among coexisting charge, spin, orbital, and lattice degrees of freedom gives rise to rich quantum phenomena, while unraveling the interplay is not straightforward. In the family of cubic $5d^2$ double perovskites, the ground spin-orbit coupled electronic states of $5d$ metal sites are degenerate and couple to the Jahn-Teller active vibrations, whereas no experimental evidence of the symmetry-lowering in the low-temperature ordered phases has been reported. To quantitatively unravel the nature of $5d^2$ centers, we apply equation-of-motion coupled cluster (EOM-CC) theory to analyze the vibronic and magnetic properties of $5d^2$ W sites of Cs$_2$WCl$_6$. We derive the electronic and vibronic model Hamiltonians, calculate the W $L_3$ edge resonant inelastic x-ray scattering (RIXS) spectra, and determine the effective magnetic moment. The simulated RIXS spectra show that vibronic coupling makes several peaks asymmetric. The effective magnetic moments exhibit a temperature dependence similar to that observed experimentally, confirming the validity of the calculated distribution of low-energy levels. Our calculations indicate that the Jahn-Teller effect in Cs$_2$WCl$_6$ is in a weak regime, and noticeable deformation would not occur, whereas the dynamic Jahn-Teller effect modulates the shapes of the RIXS spectra and affects the magnetic moment. This work demonstrates the usefulness of the EOM-CC method for predicting physical phenomena on metal sites in correlated insulating materials.

To achieve a robust valley splitting in transition metal dichalcogenides (TMDs) at zero magnetic field is a challenging and elusive goal for valleytronic and spintronic devices. Therefore, in the current study, using the first principles calculations, we introduce an oxide-driven valleytronic platform by employing a two-dimensional ferromagnetic oxide (V2O3) as a magnetic proximity partner for WSe2. We found that the intrinsic ferromagnetism of V2O3 induces a prominent and spontaneous valley splitting of ~ 10.41 meV in WSe2. This pronounced valley polarization mainly originates from the strong interfacial exchange coupling interaction and charge redistribution mediated by V 3d electrons, coupled with the intrinsic spin-orbit coupling of WSe2. Interestingly, this value is significantly greater than the previously reported value for CrI3/WSe2, which corresponds to an effective magnetic field of ~ 10 T. Besides, we also have a high Curie temperature of 500 K, and an out-of-plane magnetic anisotropy energy (MAE) of 0.31 meV, indicating that this oxide-based heterostructure can also be used for near-room temperature operation. Importantly, under the external electric field with a step of 0.1 eV/Å, the ferromagnetism is preserved and an enhancement in Curie temperature and MAE makes this oxide-based heterostructure more valuable for the next generation valleytronic devices. Therefore, these findings establish a new paradigm for realizing tunable, robust, and magnetic field-free valleytronic and spintronic devices for this oxide-based heterostructure. Moreover, this concept can be generalized to other correlated oxide-based TMD systems, providing a versatile strategy for next-generation quantum and functional materials.

Addressing the critical trade-off between initial Coulombic efficiency (ICE) and reversible capacity in hard carbon anodes for Na-ion batteries (NIBs), we introduce a novel coupling strategy that combines carbon layer orientation reconstruction with closed-pore construction to produce hard carbon with an ultra-low specific surface area. We demonstrate that the nanographite domains within the hard carbon precursor undergo entropy-driven orientation reconstruction through the synergistic regulation of heteroatom doping and medium-temperature carbonization. This process not only increases interlayer spacing and promotes structural disorder but also enables the formation of dense, closed pores and ultramicropores at domain boundaries via confined atomic migration, while simultaneously encapsulating surface open pores within internal closed ones. Due to this unique pore architecture, our hard carbon exhibits an ultra-low specific surface area of 1.89 m2 g-1 with a markedly higher proportion of closed pores. As a result, our hard carbon achieves a remarkable reversible capacity of 342.3 mAh g-1 at 20 mA g-1, with an exceptional ICE of 90.4% and a dominant plateau capacity of 262.3 mAh g-1 (76.6%) for NIBs. We believe this coupling strategy provides a new paradigm for the structural engineering of high-ICE anode materials in advanced NIBs.

The observation of extremely large magnetoresistance in WTe2 has attracted considerable attention towards understanding its underlying origin. With its layered van der Waals structure, the question that remains largely unexplored is whether the three-dimensional anisotropic transport characteristics of WTe2 persists under chemical substitution. Here, we present a systematic angle-dependent magneto-transport study of single-crystalline TaxW1-xTe2 (x = 0, 0.05, 0.1). The results are analysed within a mass anisotropy scaling framework to extract the mass anisotropy parameter {\gamma} as a function of temperature and doping. It is observed that Ta substitution leads to monotonic increase of {\gamma} across all temperatures, indicating a progressive deepening of quasi-two-dimensional Fermi surface character. Ta doping also leads to a substantial improvement in crystalline quality, reflected in a pronounced increase in the residual resistivity ratio. Despite weakening electron-hole compensation, the magnetoresistance rises sharply to ~58,211% at x = 0.1, which is assigned to a substantial enhancement in carrier mobility. Rietveld refinement confirms a systematic c-axis contraction with Ta content, identifying the structural origin of the enhanced anisotropy. The mass anisotropy scaling that holds for x = 0 and x = 0.05 breaks down for x = 0.1, where the angular magneto-resistance anisotropy substantially exceeds single-ellipsoid predictions, pointing to a multi-pocket Fermi surface with distinct anisotropies. Nonlinear Hall resistivity provides independent evidence for the underlying multiband character of transport in this system. These findings demonstrate that Fermi surface anisotropy, carrier compensation, and mobility are independent parameters that can lead to tuneable control of large magnetoresistance in topological semimetal WTe2.

We use density functional theory to investigate the shift-current response in zincblende III–V (AlP, AlAs, AlSb, GaP, GaAs, InP, InAs, and InSb) and II–VI (ZnS, ZnSe, ZnTe, CdS, CdSe, and CdTe) semiconductors. Our main goal is to identify which material generates the largest shift-current under illumination and to examine the factors influencing this response. We find that aluminum-containing semiconductors, particularly AlSb, exhibit the highest shift-current responses, while CdSe shows the lowest. We analyze the contributions of specific band-to-band transitions to the shift-current in AlSb by selectively summing valence and conduction bands. Additionally, we calculate delocalization indices to investigate the electron delocalization, which correlates with the shift current. Hydrostatic pressure does not enhance the shift current in these materials. These findings have potential applications in optoelectronics and identify the most promising zincblende semiconductors for efficient shift-current generation under visible-light illumination

We show that a symmetry-protected Floquet nullspace can host anomalous many-body eigenstates that are obtained by projecting structured parent states onto an exact zero-quasienergy sector. We demonstrate this in a periodically driven PXP chain with an exponentially large (in system size) protected nullspace. Over the accessible system sizes, special parent states show an exponentially increasing enhancement of their nullspace weight relative to the typical value, even as their absolute overlaps decrease. The resulting Floquet scars can therefore become globally orthogonal to their parents while retaining anomalous correlations inherited from them. We demonstrate this mechanism for two contrasting parents: a locally rotated volume-entangled Ivanov-Motrunich scar and the unentangled Rydberg vacuum. Floquet perturbation theory captures the weak-dressing regime, while exact diagonalization shows persistence into nonperturbative regimes where the Floquet Hamiltonian generically contains increasingly nonlocal terms. Our results identify projection into a protected zero-quasienergy sector as a route to Floquet quantum many-body scars.

Quantum critical points can host symmetry-protected topological edge modes even when the bulk is gapless, giving rise to symmetry-enriched universality classes beyond the conventional Landau–Ginzburg–Wilson paradigm. Here we show that the tricritical Ising (TCI) critical point—described by a paradigmatic conformal field theory (CFT) with emergent supersymmetry—admits a topologically nontrivial, symmetry-enriched realization, which we term the topological TCI. We construct this critical point in the cluster O'Brien–Fendley spin chain by applying a symmetry-protected topological entangler to the original O'Brien–Fendley model. The two realizations therefore share the same bulk TCI CFT. Under open boundary conditions, however, the original model exhibits the free conformal boundary condition, whereas the cluster model exhibits a spontaneously fixed boundary condition: an infinitesimal boundary field can select one of the fixed boundary states, yielding spontaneous boundary magnetization. We further show that symmetry enrichment and boundary renormalization-group flow provide two physically distinct routes to the spontaneously fixed boundary condition. Whereas the free and spontaneously fixed boundary conditions of the original model can be interconverted by tuning a symmetry-preserving boundary term, no such conversion occurs for the cluster model along the boundary deformations studied here, even in the strong-deformation limit. Although they share the same conventional boundary CFT data, including the boundary operator content and boundary $g$-function, the two realizations of the spontaneously fixed boundary condition are distinguished by different time-reversal charges of the disorder field....

Block copolymers self-assemble into ordered nanostructures whose geometry is governed by a competition between interfacial energy and chain conformational entropy. While this competition produces a rich sequence of morphologies, topologically complex “frustrated” phases, such as the primitive cubic network and single networks, incur severe packing penalties and are difficult to access in neutral systems. Here we show that ions functionalized at the termini of one block in an AB diblock copolymer melt introduce a qualitatively new stabilization mechanism. Strong ion correlations drive chain-end association and generate a curvature preference toward the charged domain; the resulting tendency of end-localized ion clusters to adopt compact, curved geometries selectively favors the highly frustrated single-primitive-cubic network ($Pm\bar{3}m$) and single-gyroid network ($I$4$_1$32) over the classical phases, in a region of parameter space with a segregation strength lying below the order-disorder transition of the neutral system. Free energy decomposition reveals that the electrostatic energy, arising almost entirely from beyond-mean-field ion correlations, becomes increasingly negative with increasing interfacial curvature. In the primitive cubic network, pronounced local segregation of ions into the cylindrical struts generates compact curved clusters whose correlation energy gain more than offsets the enhanced packing frustration, so the very geometry that is the source of packing frustration in neutral systems becomes the source of its stability here. Increasing ion size weakens correlations and suppresses the network phases, consistent with experimental observations. Our results establish curvature-selective end-group association as a general principle for accessing frustrated topologies in block copolymer systems.

The dramatic slowdown of dynamics in supercooled liquids is accompanied by a sequence of dynamical crossovers, most notably the transition from high-temperature collision-dominated transport to low-temperature activated structural relaxation. A particularly striking manifestation of this change is the crossover from Rosenfeld excess-entropy scaling to the Adam–Gibbs relation. In this work we develop a theoretical framework based on a configuration-space extension of Zwanzig's entropic-neck picture and combine it with a Mori–Zwanzig memory-function formalism to address anomalies of supercooled liquids. The central idea is that structural relaxation is controlled by the narrowing of configurational pathways connecting metastable basins of the inherent-structure landscape. Starting from coupled slow variables describing intrabasin motion and neck fluctuations, we derive a reduced generalized Langevin description in which elimination of the neck coordinate generates a long-lived memory kernel and naturally leads to entropy-controlled activated dynamics. At high temperatures the neck is broad and readily accessible, yielding Rosenfeld-type transport governed primarily by local structural entropy. Upon cooling, progressive neck constriction produces an increasing entropy deficit, leading to Adam–Gibbs behavior and activated relaxation. Within this picture, fragility acquires a simple geometric interpretation: fragile liquids are characterized by a rapid collapse of the effective configurational neck with decreasing temperature, whereas strong liquids exhibit a much slower evolution of accessible pathways. The framework does not by itself compute the configurational entropy, mismatch penalty, or cooperative length from microscopic interactions; its aim is to provide a dynamical and geometrical interpretation.

Switching the bulk Chern number in topological materials is of central importance for the design of topological electronic devices. Motivated by recent observations of integer and fractional quantum anomalous Hall effects in twisted transition metal dichalcogenides (tTMDs), we realize the switching of valley Chern number through sliding and gating in alternately twisted tetralayer (ATT) MoTe$_{2}$. Using large-scale density functional theory (DFT) calculations, we show that the Chern number of the first $K$-valley moiré band evolves from $+1$ to $-1$ under the interlayer sliding. Furthermore, an applied electric field can switch the valley Chern number from $-1$ to $+1$. Based on the developed continuum model, we reveal that these switching behaviors are caused by the sliding- and gate-dependent intralayer moiré potential distributions across the layers. Our results establish ATT MoTe$_{2}$ as a promising platform for engineering moiré band topologies through the design of moiré potentials with sliding in multilayer moiré systems.

Self-driving laboratories (SDLs), where artificial intelligence proposes subsequent experiments and robotic systems execute them, are rapidly becoming the vanguard of materials discovery. A critical bottleneck, however, lies in seamlessly bridging diverse AI algorithms tailored for specific exploration goals with the heterogeneous robotic hardware found across different laboratories. Here, we present NIMO, an open-source software platform designed to dissolve this barrier through three core paradigms: a modular AI-robot decoupling mediated via simple CSV file exchange, a discrete candidate-pool architecture that seamlessly absorbs domain knowledge, and a unified Python interface pre-loaded with twelve distinct AI algorithms. In this Perspective, we review the operational principles of each algorithm alongside six diverse SDL implementations driven by NIMO, covering electrolyte discovery, organic synthesis, thin-film exploration, fuel-cell process informatics, coffee-ring phase exploration, and legacy liquid-handling automation. One of these also demonstrates NIMO's seamless interoperability with the IvoryOS orchestration framework. To democratize autonomous science, we also introduce a no-code desktop application that enables intuitive, human-in-the-loop exploration for non-programmers. NIMO is freely available at https://github.com/NIMS-DA/nimo, offering a versatile, plug-and-play foundation to accelerate autonomous materials exploration across diverse experimental landscapes.

Trapped-ion quantum simulators realize programmable spin models through phonon-mediated interactions. For Hamiltonians with noncommuting terms, however, the same phonon bus generates intrinsic spin-phonon errors that strongly distort the target dynamics. Because these errors are governed by the full time history of the spin-dependent phonon motion, they survive standard loop-closing control and limit simulation accuracy. Using a sequence of frame transformations, we isolate the residual error dynamics and show that this intrinsic error can be strongly suppressed while preserving programmable Ising couplings. Full spin-boson simulations of multi-ion chains demonstrate orders-of-magnitude lower error than both constant-drive and conventional loop-closing protocols. These results remove a central precision barrier in trapped-ion analog quantum simulation and enable accurate programmable simulation of noncommuting many-body Hamiltonians and dynamical protocols.

SDE-based generative models, including diffusion models and the Schrödinger bridge, have found broad applications in signal processing tasks such as speech enhancement, image restoration, and time-series generation. This note presents a modeling framework for such models within the context of stochastic thermodynamics. The main results of this note are trajectory-level definitions of work, heat, and entropy production, along with a generalized Jarzynski identity and a second-law-like inequality. The proposed framework extends the original Jarzynski setup to accommodate time-dependent bath temperature and nonconservative driving forces. This thermodynamic perspective may deepen our understanding of diffusion models and the Schrödinger bridge from a nonequilibrium statistical mechanics viewpoint.

Discovering the governing equations of a physical system from data is a central goal across the sciences, yet in most experiments only a few states are accessible while the rest stay hidden. Existing approaches treat this partial observability as an obstacle to be removed by first reconstructing the hidden state—a step that is ill-posed under noise and that discards the physical constraints, such as energy conservation, that the true dynamics obey. We show that for conservative (Hamiltonian) systems no reconstruction is needed: projecting the dynamics onto the measured coordinates yields a memory kernel that we prove to be a lossless positive-real rational matrix, whose poles are the hidden natural frequencies and whose positive-semidefinite residues encode the couplings. From this kernel we recover a closed, interpretable governing equation for the observed dynamics—identified from output data alone, passive by construction, and validated by out-of-sample forecasting. Under stronger conditions—an equipartitioned measure with position coupling, or a forced input–output experiment—the bare hidden frequencies and couplings of the underlying Hamiltonian are additionally recoverable. We test the method on linear, nonlinear, and chaotic systems under realistic noise. Because it returns energy-conserving equations of motion from partial measurements, it offers a common tool for problems spanning mechanics, fluid and plasma physics, and beyond.

We propose a heuristic model of underscreening phenomenon in high density Coulomb systems, such as concentrated electrolytes and electron hole conglomerates under ultra high dose rate (UHDR) radiation in biological tissues. It explains the data on screening length $L$ increasing with charge particle concentration and offers additional insights in understanding the conductivity and reduction potential of concentrated electrolytes. Also, it validates our current understanding of the FLASH radiation treatment of tumors (FLASH-RT) perceived as an analogous system. The underlying physics is that mutual binding creates diffusion barriers which suppress the concentration of mobile particles thus increasing the screening length. Also, they slow down the rates of chemical reactions responsible for generation of biologically active radicals which explains the sparing effect observed under UHDR.

Generically a quantum system initialized in an unentangled state will, under unitary dynamics, rapidly become entangled, a process closely related to information transport and to thermalization. Disorder can suppress the growth of entanglement and result in memory of initial conditions. In non-interacting systems this arises from localization of single-particle states, the occupancy of which is fixed by the initial condition. In interacting systems similar localized conserved quantities persist, but with the added feature that they are coupled, resulting in entanglement growth which is distinct from both non-interacting localized systems and from generic ergodic systems. The Fermi-Hubbard model has two degrees of freedom per site – charge and spin – and disorder may be present in both of these. We study the growth of entanglement in two scenarios – disorder in charge equal and unequal to that in spin, and determine the distinct contributions of charge and spin degrees of freedom by expanding the Hamiltonian in terms of a set of optimally localized conserved quantities with separate charge and spin character. We find that coupling between charge and spin is significantly weaker than charge-charge and spin-spin coupling. While this decoupling is present in all our results, it is only apparent when the strength of the disorder in the two sectors is different such that there is a separation between the characteristic timescales of the contributions to entanglement made by charge and by spin.

Linker-mediated aggregation plays an important role in modern nanoscience. We demonstrate that it departs sharply from classical Smoluchowski kinetics because cluster reactivity evolves during growth. Combining theory with DNA-linked gold-nanoparticle experiments, we establish kinetic critical point controlled by linker abundance. Below threshold, active linkers are depleted and growth arrests; above threshold, clusters accumulate reactive sites, self-accelerate, and cross over to diffusion-limited coarsening. Experiments verify the predicted arrest, accelerated growth, and scaling collapse.