Statistical Mechanics
In memoriam J. Robert Dorfman
An obituary of J.R. Dorfman. The focus is on his scientific career and on his many important publications.
Papers
Fresh from arXiv, typeset properly. Highlighted words trade on the market.
Friday 16 January
Soft Condensed Matter
Universal wrinkling dynamics of a sheet on viscous liquid
We investigate the wrinkling dynamics of a thin elastic sheet that is indented or compressed while floating on a viscous liquid. We show that the deformation speed controls the dynamics, leading to a wrinkle wavelength significantly smaller than that selected under quasistatic compression. Once active compression ceases, the wrinkles coarsen until their wavelength relaxes toward the equilibrium value. We develop a theoretical model coupling Stokes flow in the liquid to elastic bending of the sheet, which quantitatively predicts both the initial wavelength selection and its subsequent coarsening. We demonstrate that the same mechanism governs two dimensional and axisymmetric geometries, thereby extending classical static wavelength selection laws to dynamic situations. Although developed from controlled laboratory experiments, the model captures a generic viscous-elastic coupling and applies broadly to thin elastic films interacting with viscous environments, including the formation of surface wrinkles in pahoehoe lava flows.
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Statistical Mechanics
100 Glorious Years of the Ising Model
This is an editorial article based on the reseaches on the Ising model over the last 100 years.
Superconductivity
Vacuum-selected timescales in driven Josephson systems
In this work, we demonstrate that the intrinsic timescale of a Josephson junction can be controlled through dynamical vacuum selection. By applying a Kapitza-like high-frequency drive to the system, the effective Josephson potential is reshaped, allowing for the stabilization of inphase or antiphase configuration. As a result, the Josephson plasma frequency, that is, the clock frequency of the junction, becomes a tunable property of the selected vacuum. Our findings establish a vacuum-controlled Josephson clock principle, in which the dynamical vacuum acts as an internal reference that fixes the operational timescale of Josephson oscillations, rather than this scale being imposed externally.
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Strongly Correlated Electrons · Cross-listed from math.OA
On a C*-Diagonal Generated by the Toric Code
Materials Science
Predictive autoencoder-transformer model of Cu oxidation state from EELS and XAS spectra
X-ray absorption spectroscopy (XAS) and electron energy-loss spectroscopy (EELS) produce detailed information about oxidation state, bonding, and coordination, making them essential for quantitative studies of redox and structure in functional materials. However, high-throughput quantitative analysis of these spectra, especially for mixed valence materials, remains challenging as diverse experimental conditions introduce noise, misalignment, broadening of the spectral features. We address this challenge by training a machine learning model consisting of an autoencoder to standardize the spectra and a transformer model to predict both Cu oxidation state and Bader charge directly from L-edge spectra. The model is trained on a large dataset of FEFF-simulated spectra and evaluates model performance on both simulated and experimental data. The results of the machine learning model exhibit highly accurate prediction across the domains of simulated and experimental XAS as well as experimental EELS. These advances enable future quantitative analysis of Cu redox processes under in situ and operando conditions.
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Other Condensed Matter
Broadband Terahertz Time-domain Spectroscopy of Quantum Materials in a Dilution Refrigerator
We have constructed a terahertz time domain spectroscopy system using a Bluefors dilution refrigerator with a 7 T split-coil magnet. Using a gallium arsenide single quantum well sample, terahertz waveforms were measured at 145 mK in a magnetic field range from 0 to 6 Tesla to measure cyclotron resonance. Effective mass is found to be $0.073 m_{e}$, which is larger than the commonly accepted bulk value of $0.068 m_{e}$.
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Strongly Correlated Electrons
Visualization of Tunable Electronic Structure of Monolayer TaIrTe$_4$
Monolayer TaIrTe$_4$ is an ideal platform to explore the tunability of band topology where charge doping converts the quantum spin Hall insulator (QSHI) state into a dual QSHI state. However, experimental visualization of its band structure has been lacking despite its importance in interpreting this topological phase transition. Here we report the band structure of monolayer TaIrTe$_4$ using micro-focused angle-resolved photoemission spectroscopy ($\mu$ARPES). Observed dispersions agree with the Heyd-Scuseria-Ernzerhof (HSE) calculations, establishing the insulating ground state without strong electronic correlations. Furthermore, we show an electron-hole asymmetry in the doping response, where hole doping is readily induced by electrostatic gating, whereas electron doping via gating and alkali-metal deposition yields band renormalization instead of a rigid shift. Fractional-charge calculations demonstrate that added electrons shrink the band gap and drive band renormalization. Thus, our work identifies the microscopic mechanism by which induced charges reshape the band topology of monolayer TaIrTe$_4$, beyond the rigid shift behavior.
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Materials Science
Halide diffusion in mixed-halide perovskites and heterojunctions
Migration of halide defects guides ion transport in metal halide perovskites and controls the kinetics of halide mixing and phase separation. We study the diffusion of halide vacancies and interstitials in \ce{CsPb(I_{x}Br_{1-x})_{3}} and \ce{CsPbI_{3}}/\ce{CsPbBr_{3}} heterojunctions by molecular dynamics simulations using neural network potentials trained on density functional theory calculations. We observe enhanced diffusion of both vacancies and interstitials in the mixed halide compounds compared to the single halide ones, as well as a difference in mobility between Br and I ions in the mixed compound. Diffusion across heterojunctions is governed by the interface structure, where a Br-rich interface blocks migration of vacancies in particular, but an I-rich interface is permeable.
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Materials Science
Raman scattering fingerprints of the charge density wave state in one-dimensional NbTe$_4$
Charge-density waves (CDWs) are ordered quantum states of conduction electrons accompanied by periodic lattice distortions. Raman scattering (RS) spectroscopy is therefore well suited for probing CDW-induced structural modulations. We investigate the CDW state in quasi-one-dimensional NbTe$_4$ using RS spectroscopy. At $T$=5~K, the resonantly enhanced Raman spectrum exhibits 25 phonon modes. Polarization-dependent measurements reveal a strong coupling between phonon-mode symmetry and crystallographic symmetry, with modes polarized parallel or perpendicular to the crystallographic $c$-axis, along which the one-dimensional structure is elongated. Temperature-dependent RS measurements identify a transition between commensurate and incommensurate CDW phases, accompanied by pronounced thermal hysteresis, with transition temperatures of approximately 45~K upon cooling and 90~K upon warming. The hysteresis width depends on the warming rate, indicating a finite nucleation rate of CDW domains and suggesting potential relevance for memory-device applications.
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Soft Condensed Matter · Cross-listed from math.GT
Entanglement complexity of spanning pairs of lattice polygons
We study the entanglement complexity of a system consisting of two simple-closed curves (self-avoiding polygons) that span a lattice tube, referred to as a 2SAP. 2SAPs are of interest as the first known model of confined ring polymers where the linking probability goes to 1 exponentially with the size of the system. Atapour et al proved this in 2010 by showing that all but exponentially few sufficiently large 2SAPs contain a pattern that guarantees the 2SAP is non-split, provided that the requisite pattern fits in the tube. This result was recently extended to all tubes sizes that admit non-trivial links. Here we develop and apply knot theory results to answer more general questions about the entanglement complexity of 2SAPs. We first extend the 1992 concept of a good measure of knot complexity to a good measure, $F$, of spanning-link complexity for $k$-component links. Using tangle products, we show, for example, that the more complex the prime knot decomposition of any component of a given link type, the greater its $F$-measure. We then prove that all but exponentially few size $m$ 2SAPs have $F$ complexity that grows at least linearly in $m$ as $m\to \infty$. We establish that good measures of knot complexity yield good measures of spanning-link complexity. We also establish conditions whereby more general link invariants can yield good measures. In particular, we establish that measures based on several classical invariants are good measures by our definition, eg bridge number or the splitting number. Finally, we consider how the tube dimensions affect which links are embeddable as 2SAPs as well as geometric restrictions on the entanglement complexity of the embeddings. For example, we establish that there are two-component links that occur as 2SAPs in a given tube size only when one of the components is forced into a non-minimal bridge number conformation.
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Mesoscale and Nanoscale Physics · Cross-listed from quant-ph
Heat, work, and fluctuations in a driven quantum resonator
A central building block of a heat engine is the working fluid, which mediates the conversion of heat into work. In nanoscale heat engines, the working fluid can be a quantum system whose behavior and dynamics are non-classical. A particularly versatile realization is a quantum resonator, which allows for precise control and coupling to thermal reservoirs, making it an ideal platform for exploring quantum thermodynamic processes. Here, we investigate the thermodynamic properties of a driven quantum resonator whose temperature is controlled by modulating its natural frequency. We evaluate the work performed by the external drive and the resulting heat flow between the resonator and its environment, both within linear response and beyond. To further elucidate these processes, we determine the full distribution of photon exchanges between the resonator and its environment, characterized by its first few cumulants. Our results provide quantitative insights into the interplay between heat, work, and fluctuations, and may help in designing future heat engines.
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Materials Science · Cross-listed from physics.chem-ph
The rise and fall of stretched bond errors: Extending the analysis of Perdew-Zunger self-interaction corrections of reaction barrier heights beyond the LSDA
Incorporating self-interaction corrections (SIC) significantly improves chemical reaction barrier height predictions made using density functional theory methods. We present a detailed, orbital-by-orbital analysis of these corrections for three semi-local density functional approximations (DFAs) situated on the three lowest rungs of the Jacob's Ladder of approximations. The analysis is based on Fermi-Löwdin Orbital Self-Interaction Correction calculations performed at several steps along the reaction pathway from the reactants (R) to the transition state (TS) to the products (P) for four representative reactions selected from the BH76 benchmark set. For all three functionals, the major contribution to self-interaction corrections of the barrier heights can be traced to stretched bond orbitals that develop near the TS configuration. The magnitude of the ratio of the self-exchange-correlation energy to the self-Hartree energy (XC/H) for a given orbital is introduced as an indicator of one-electron self-interaction error. For the exact, but unknown density functional, XC/H = 1.0 for all orbitals, while for the practical DFAs studied here, XC/H spans a range of values. The largest values are obtained for stretched or strongly lobed orbitals. We show that significant differences in XC/H for corresponding orbitals in the R, TS, and P configurations can be used to identify the major contributors to the SIC of barrier heights and reaction energies. Based on such comparisons, we suggest that barrier height predictions made using the SCAN meta-generalized gradient approximation may have attained the best accuracy possible for a semi-local functional using the Perdew-Zunger SIC approach.
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Soft Condensed Matter · Cross-listed from q-bio.BM
Principles of Client Enrichment in Multicomponent Biomolecular Condensates
Biomolecular condensates are commonly organized by a small number of scaffold molecules that drive phase separation together with client molecules that do not condense on their own but become selectively recruited into the dense phase. A central open question is how client recruitment feeds back on scaffold interactions to determine condensate composition. Here we address this problem in a reconstituted focal adhesion system composed of focal adhesion kinase (FAK) and phosphorylated p130Cas (Cas) as scaffolds and the adaptor protein paxillin (PXN) as a client. We show that both FAK phosphorylation and PXN recruitment produce a common compositional response in which FAK becomes enriched while Cas is depleted within the condensate. To interpret these observations, we develop two complementary theoretical descriptions. First, within a two-component Flory-Huggins framework, we show that phosphorylation can be captured by either strengthening heterotypic FAK-Cas interactions or increasing the effective number of interaction-relevant segments on FAK, both of which bias partitioning toward FAK-rich condensates. Second, we introduce a minimal three-component Flory-Huggins theory without an explicit solvent and map it onto an effective two-component description, demonstrating that client recruitment renormalizes homotypic and heterotypic scaffold interactions. Analytical predictions for the location of the critical point are tested in reconstituted multicomponent systems through PXN addition, showing that client recruitment alone tunes proximity to criticality and reshapes condensate composition. Together, our results reveal distinct yet convergent physical routes by which post-translational modification and client recruitment control scaffold composition in multicomponent condensates.
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Quantum Gases
Pathway to Kondo physics in ytterbium atom chains with repulsive spin impurities
The Kondo effect is a paradigmatic model of strongly-correlated physics, where a magnetic impurity forms a many-body singlet with a fermionic environment. Cold gases of ytterbium (Yb) atoms have been proposed to be an ideal platform to study the Kondo effect since different internal states of the atom can be used to create both the impurity and the fermionic environment. In Yb gases, however, the atomic impurity interacts with the fermionic environment both through magnetic and potential scattering. These two scattering mechanisms counteract one another, raising the question of how robust Kondo screening remains. Here, we show that potential scattering can quench the Kondo screening in one-dimensional Yb gases; yet, strikingly, Kondo physics survives this quench in well-defined regimes. Combining analytical renormalization-group theory for a Luttinger liquid with density matrix renormalization group (DMRG) simulations, we identify a transition from a strongly- to a weakly-entangled impurity as potential scattering is increased. The two approaches show excellent agreement concerning the stability of Kondo physics throughout the different parameter regimes considered. Our results provide a quantitative criterion for the emergence of Kondo screening in one-dimensional Yb gases and delineate experimentally accessible regimes for its realization in cold-atom platforms.
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Soft Condensed Matter
Confinement-induced motion of ciliates
The time dynamics of flagellar and ciliary beating is often neglected in theories of microswimmers, with the most common models prescribing a time-constant actuation of the surrounding fluid. By explicitly introducing a metachronal wave, coarse-grained to a sinusoidal surface slip velocity, we show that a spatial resonance between the metachronal wave and the corrugation of a confining cylindrical channel enables a ciliate to swim even when it cannot move forward in a bulk fluid. Using lubrication theory, we reduce the problem to the Adler equation that reveals an oscillatory and ballistic swimming regime. Interestingly, a ciliate can even reverse its swimming direction in a corrugated channel compared to the bulk fluid.
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Soft Condensed Matter
NAVIS: A LAMMPS-Python framework for efficient computation of nanochannel velocity and thermal interfacial slip
We present NAVIS (NAnochannel Velocity and thermal Interfacial Slip), a LAMMPS-Python scripted toolkit for computing the Navier (hydrodynamic) friction coefficient and Kapitza (thermal) resistance at arbitrary solid-fluid interfaces. NAVIS is based on equilibrium molecular dynamics (EMD) methods for calculating the linear response friction and thermal resistance at the interface, as well as the corresponding velocity and temperature slips. The methodology is based on our previous studies (Hansen, et al., Phys. Rev. E 84, 016313 (2011); Varghese et al., J. Chem. Phys. 154, 184707 (2021); Alosious, et al., J. Chem. Phys. 151, 194502 (2019); Alosious, et al., Langmuir 37, 2355-2361 (2021)), and in this work we provide a pedagogical framework for the implementation of this toolkit on two systems: (i) a water-graphene system (for hydrodynamic slip) and (ii) a water-CNT system (for thermal slip). We provide detailed instructions for performing the EMD simulations using the LAMMPS package and processing the simulation outputs using Python modules to obtain the desired quantities of interest. We expect the toolkit to be useful for computational researchers studying interfacial friction and thermal transport, key factors for efficient and practical applications of nanofluidic systems.
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Materials Science
An exciting approach to theoretical spectroscopy
Theoretical spectroscopy, and more generally, electronic-structure theory, are powerful concepts for describing the complex many-body interactions in materials. They comprise a variety of methods that can capture all aspects, from ground-state properties to lattice excitations to different types of light-matter interaction, including time-resolved variants. Modern electronic-structure codes implement either a few or several of these methods. Among them, exciting is an all-electron full-potential package that has a very rich portfolio of all levels of theory, with a particular focus on excitations. It implements the linearized augmented planewave plus local orbital (LAPW+LO) basis, which is known as the gold standard for solving the Kohn-Sham equations of density-functional theory (DFT). Based on this, it also offers benchmark-quality results for a wide range of excited-state methods. In this review, we provide a comprehensive overview of the features implemented in exciting in recent years, accompanied by short summaries on the state of the art of the underlying methodologies. They comprise DFT and time-dependent DFT (TDDFT), density-functional perturbation theory (DFPT) for phonons and electron-phonon coupling, and many-body perturbation theory in terms of the $GW$ approach and the Bethe-Salpeter equation (BSE). Moreover, exciting can handle resonant inelastic x-ray scattering (RIXS), pump-probe spectroscopy as well as exciton-phonon coupling (EXPC). Finally, we cover workflows and a view on data and machine learning (ML). All aspects are demonstrated with examples for scientifically relevant materials.
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Materials Science
Chemical Origin of Exciton Self-trapping in Cs$_3$Cu$_2$X$_5$ Cesium Copper Halides
Copper halides Cs3Cu2X5 (X=Cl, Br, I) are promising materials for optoelectronic applications due to their high photoluminescence efficiency, stability, and large Stokes shifts. In this work, we uncover the chemical bonding origin of the Stokes shift in these materials using density functional theory calculations. Upon excitation, one [Cu2X5]3- anion undergoes sizeable local distortions, driven by Cu-X and Cu-Cu bond formation. These structural changes coincide with the formation of a self-trapped exciton, where particularly the hole is strongly localized on one anion. Analysis of the electronic structure and bonding reveals reduced antibonding interactions and enhanced bonding character in the excited state, stabilizing the distorted geometry. Our results establish a direct link between orbital-specific hole localization and bond formation. It provides a fundamental understanding of the excitation mechanism in Cs3Cu2X5 and offers design principles to tune optical properties in 0D copper halides.
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Materials Science
Thermalization of Optically Excited Fermi Systems: Electron-Electron Collisions in Solid Metals
Ultrafast optical excitation of metals induces a non-equilibrium energy distribution in the electronic system, with a characteristic step-structure determined by Pauli blocking. On a femtosecond timescale, electron-electron scattering drives the electrons towards a hot Fermi distribution. In this work, we present a derivation of the full electron-electron Boltzmann collision integral within the random-k approximation. Building on this approach, we trace the temporal evolution of the electron energy distribution towards equilibrium, for an excited but strongly degenerate Fermi system. Furthermore, we examine to which extent the resulting dynamics can be captured by the numerically simpler relaxation time approach, applying a constant and an energy-dependent relaxation time derived from Fermi-liquid theory. We find a better agreement with the latter, while specific features caused by the balance of scattering and reoccupation can only be captured with a full collision integral.
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Mesoscale and Nanoscale Physics
Conductance Oscillations in a Topological Insulator-Disordered Superconductor Hybrid Interface
We report on the observation on proximity-induced superconductivity in the topological insulator BiSbTeSe2 coupled to a disordered superconductor, amorphous indium oxide (a-InO). Resistance temperature measurements reveal superconducting signatures at low temperatures, even when InO is in an insulating state, indicating the persistence of superconducting correlations. Differential conductance spectra reveal nearly periodic oscillations at higher bias, together with a pronounced zero-bias conductance peak. Both effect disappears at high temperature, marking the critical temperature (T*) of the superconducting islands in InO. These results underscore the influence of topological surface states on proximity-induced superconductivity and highlight the role of superconducting fluctuations in disordered superconductor/topological-insulator hybrid interfaces.
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Materials Science
Unexpected Anisotropic Mn-Sb Anti-site Distribution and Van der Waals Epitaxy of MnSb2Te4
Mn-Sb site mixing directly impacts both the magnetic and topological properties of MnSb2Te4. This study reveals, unlike previously believed, that these anti-sites can be unevenly distributed within the crystal. To that end, a polycrystalline sample was created with a two-step synthesis using MnTe and Sb2Te3 as precursors. DC-SQUID magnetometry was used to confirm its magnetic properties. In addition, the use of High-Resolution Scanning Transmission Electron Microscopy combined with Energy-Dispersive X-ray Spectroscopy allowed us to identify the presence of an inversion-breaking asymmetry in the anti-site distribution. This reduced-symmetry structure bears resemblance to the recently proposed class of Janus materials and thus warrants further exploration due to its potential for combining topology and magnetism with other effects, such as non-linear optics and piezoelectricity. Finally, to further elucidate the interplay between site mixing, doping, topology, and magnetism, a method for growing MnSb2Te4 thin films over amorphous SiOx using Sb2Te3 seeds is introduced. The successful Van der Waals epitaxy of MnSb2Te4 over Sb2Te3 seeds using Pulsed Laser Deposition is confirmed using Scanning Transmission Electron Microscopy. This represents a crucial step in incorporating these materials into a Si-based architecture, which offers the possibility of controlling the Fermi lever via gating.
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Mesoscale and Nanoscale Physics · Cross-listed from quant-ph
Skyrmion Quantum Diode Prototype: Bridging Micromagnetic Simulations and Quantum Models
Magnetic skyrmions are topologically protected spin textures known for their robustness against perturbations. Their topological stability makes them robust information carriers, ideal for tackling a key challenge in quantum computing: creating reliable, one-way links between different types of qubits. In this proof-of-concept study, we introduce a novel device - the skyrmion quantum diode - based on skyrmion qubits. Our approach combines classical micromagnetic simulations, achieving skyrmion diameters as small as 3 nm, with quantum circuit models inspired by superconducting qubits. In this work, we demonstrate: (i) unidirectional skyrmion transport via the skyrmion Hall effect in asymmetric junctions, spanning length scales from 20 nm down to 3 nm; (ii) potential compatibility with flux-tunable quantum architectures; and (iii) preliminary insights into anharmonicity in skyrmion-based qubit systems. These results establish both the operational feasibility and the scaling behavior necessary for a hybrid skyrmion-quantum platform. Our work outlines a path toward integrating skyrmion based quantum components into practical device architectures, enabling low-dissipation, unidirectional quantum information transport. This capability is crucial for scalable quantum computing, spintronic logic, and hybrid quantum systems, and opens opportunities for chipscale, pump-free isolators and directional quantum links that enhance readout fidelity, reduce cryogenic load, and support modular skyrmion-superconducting processors
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Strongly Correlated Electrons
Three-dimensional topological insulator feature of ternary chalcogenide Ge2Bi2Te5
The exploration of novel topological insulators (TIs) beyond binary chalcogenides has been accelerated in pursuit of exotic quantum states and device applications. Here, the layered ternary chalcogenide Ge2Bi2Te5 is identified as a three-dimensional TI. The bulk electronic structure of Ge2Bi2Te5 features a hole-type Fermi surface at Fermi level EF, which dominates the transport properties. Moreover, an unoccupied topological surface state with a Dirac point located at 290 meV above EF has been observed. Theoretical calculations confirm a bulk bandgap and a nontrivial Z2 topological invariant (000;1). The present study demonstrates that the material family of layered tetradymite-like ternary compounds is an important platform to explore exotic topological phenomena.
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Mesoscale and Nanoscale Physics
Nanoscale wireframe SQUID on a cantilever by corner lithography
We present the fabrication of nanoscale superconducting quantum interference devices (SQUIDs) at the apex of wireframe tips on self-aligned superconducting cantilever probes. The probes are made on silicon wafers using molding techniques in combination with corner lithography, which results in a nanowire frame tip with a tuneable apex structure. A shadow effect deposition using magnetron sputtering of Nb creates self-aligned superconducting wireframes on cantilevers with accompanying device circuitry. Superconducting weak links are realized at the apex of the wireframes with the use of focused ion beam nanopatterning. The realized SQUIDs have effective diameters ranging from several micrometers down to 100 nm and can be operated in magnetic fields up to 1 T. Furthermore, the nanowires in the wireframe can be used to flux modulate the SQUID locally. This fabrication process enables the production of wafer-scale templates for probes based on on-tip superconducting devices.
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Soft Condensed Matter
Non-equilibrium geometric forces steer spiral waves on folded surfaces
Spiral waves are ubiquitous signatures of non equilibrium dynamics, appearing across chemical, biological, and active systems. Yet, in many living systems these waves unfold on curved and folded surfaces whose geometry has rarely been treated as a dynamical factor. Here we show that surface curvature fundamentally shapes spiral wave behavior and can contribute to the organization of neural activity in the brain. Via analytical theory and simulations of the complex Ginzburg Landau equation (CGLE) on curved surfaces, we demonstrate that curvature enters through the Laplace Beltrami operator as a spatial modulation of effective diffusion. Gradients of this effective diffusion generate a geometric force on spiral defects, and the complex nature of the CGLE produces a complex mobility that leads to non central and non reciprocal responses. Applied to realistic cortical surfaces of the human brain, the model predicts that the pattern of cortical folding stabilizes and localizes spiral waves, while progressive smoothing of the surface erases these non equilibrium structures. This reveals that brain geometry is not a passive scaffold but an active physical constraint that shapes neural dynamics. More broadly, the same geometric mechanism provides a universal route by which curvature and topology control pattern formation across oscillatory, chemical, and active matter systems.
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Materials Science
Growth of Large Crystals of Janus Phase RhSeCl Using Self-Selecting Vapour Growth
In recent years, interest in 2D Janus materials has grown exponentially, particularly with regard to their applications in spintronics and optoelectronic devices. The defining feature of Janus materials is the ordered arrangement of different layer terminations - creating chemically distinct surfaces and an inherent out-of-plane polarity. Among the few known Janus materials, RhSeCl is particularly intriguing as a rare example of an intrinsic Janus compound. Owing to its exceptional chemical stability, RhSeCl offers a promising platform for exploring the physics related to the Janus-structure. However, synthesising large, high-quality crystals of this compound remains a significant challenge. Here, we report a novel synthetic pathway for growing crystals up to 6 mm in lateral size via a two-step self-selecting vapour growth reaction. We further present a comprehensive comparison of newly developed synthesis routes with all previously reported methods for RhSeCl. During these investigations, we identified a previously unreported impurity that forms in specific growth pathways and demonstrate how it can be avoided to obtain phase-pure few- and monolayer flakes. We showcase the reproducibility of the process to obtain high-quality, large single-crystals and flakes.
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Materials Science
Cavity-Mediated Radiative Energy Transfer Enables Stable, Low-Threshold Lasing in Hybrid Quantum Dot-Nanoplatelet Supraparticles
Colloidal semiconductor nanocrystals are promising building blocks for optoelectronics due to their solution processability, spectral tunability, and ability to self-assemble into complex architectures. However, their use in lasing application remains limited by high working thresholds, rapid nonradiative losses from Auger recombination, and sensitivity to environmental conditions. Here, we report hybrid microscale supraparticles composed of core/shell CdSe/ZnS quantum dots (QDs) and CdSe/CdxZn1-xS nanoplatelets (NPLs), which overcome these limitations through efficient, cavity-mediated energy funneling and coupling. Broadband absorbing QDs rapidly transfer excitation to narrow emitting NPLs, enabling stable whispering gallery mode lasing with a low threshold of 0.35 mJ/cm2. These supraparticles retain optical performance after prolonged exposure to air, water, and continuous irradiation, offering practical advantages for optoelectronic devices and advanced pigment technologies. Ultimately, our approach provides a versatile, programmable platform for optical amplification and tunable emission control within colloidal photonic architectures. Keywords
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Materials Science
Controlled epitaxy of room-temperature quantum emitters in gallium nitride
The ability to generate quantum light at room temperature on a mature semiconductor platform opens up new possibilities for quantum technologies. Heteroepitaxial growth of gallium nitride on silicon substrates offers the opportunity to leverage existing expertise and wafer-scale manufacturing to integrate bright quantum emitters in this material within cavities, diodes, and photonic circuits. Until now, it has only been possible to grow GaN QEs at uncontrolled depths on sapphire substrates, which is disadvantageous for potential device architectures. Here, we report a method to produce GaN QEs by metal-organic vapor phase epitaxy at a controlled depth in the crystal through the application of silane treatment and subsequent growth of 3D islands. We demonstrate this process on highly technologically relevant silicon substrates, producing room-temperature QEs with a high Debye Waller factor and strongly anti-bunched emission.
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Mesoscale and Nanoscale Physics · Cross-listed from quant-ph
Controlled Parity of Cooper Pair Tunneling in a Hybrid Superconducting Qubit
Superconducting quantum circuits derive their nonlinearity from the Josephson energy-phase relation. Besides the fundamental $\cos\phi$ term, this relation can also contain higher Fourier harmonics $\cos(k\phi)$ corresponding to correlated tunneling of $k$ Cooper pairs. The parity of the dominant tunneling process, i.e.~whether an odd or even number of Cooper pairs tunnel, results in qualitatively different properties, and controlling this opens up a wide range of applications in superconducting technology. However, access to even-dominated regimes has remained challenging and has so far relied on complex multi-junction or all-hybrid architectures. Here, we demonstrate a simple "harmonic parity qubit" (HPQ); an element that combines two aluminum-oxide tunnel junctions in parallel to a gate-tunable InAs/Al nanowire junction forming a SQUID, and use spectroscopy versus flux to reconstruct its energy-phase relation at 85 gate voltage points. At half flux quantum, the odd harmonics of the Josephson potential can be suppressed by up to two orders of magnitude relative to the even harmonics, producing a double-well potential dominated by even harmonics with minima near $\pm\pi/2$. The ability to control harmonic parity enables supercurrent carried by pairs of Cooper pairs and provides a new building block for Fourier engineering in superconducting circuits.