Peer Revenue Fully funded

Papers

Fresh from arXiv, typeset properly. Highlighted words trade on the market.

Physics Quantum Physics

quant-ph Watch Quantum Physics (sign in to use)

Monday 21 September

Quantum Physics · Cross-listed from nucl-th

Persistent State Method for Resonances on Classical and Quantum Computers

We introduce a new method for extracting resonance pole positions that does not require non-Hermitian extensions of a Hamiltonian. The complex resonance poles are extracted from unitary time evolution of a persistent state, a compact trial state chosen such that its survival amplitude is governed by a single exponential over an extended time window. We solve several two- and three-body systems interacting via short- and long-range forces on a lattice and show that the pole positions obtained using the persistent state method converge approximately exponentially with the linear size of the system. We also consider a gate-based quantum implementation of our method using the Rodeo algorithm and a Hamiltonian variational ansatz, and outline an extension to two-cluster scattering.
Read the full abstract

All authors Cong-Wu Wang, Lukas Bovermann, Evgeny Epelbaum, Hermann Krebs, Dean Lee, Yu-Gang Ma, Avik Sarkar

Quantum Physics

Pulsed coherent and squeezed driving of a spin-$S$ emitter as a deterministic source of Wigner-negative light

Generating propagating Wigner-negative states of light is an important and difficult task for many quantum technologies. Historically, the proposed methods of creating such states have been intrinsically probabilistic, relying on conditional measurements or photon heralding. More recently, methods have been proposed involving the steady-state driving of two-level emitters, where Wigner-negative temporal modes are present in the outgoing field. We theoretically demonstrate through the simulation of a cascaded-systems model that this approach can be improved significantly with pulsed coherent or squeezed driving of a spin-1/2 emitter. This enables the deterministic generation of strongly Wigner-negative states, using only driving-source states with positive Gaussian Wigner distributions. This method is extended to the driving of a spin-$S$ emitter with $S\geq 1$ to generate still more exotic, highly non-classical states. The array of states demonstrated in this work includes close approximations to displaced N-photon states, squeezed Schrödinger cat states, and finite-energy Gottesman-Kitaev-Preskill (GKP) states.
Read the full abstract

Quantum Physics · Cross-listed from cond-mat.stat-mech

Quantum Mpemba effect from Stark localization

In classical systems, rugged potential energy landscapes provide a transparent mechanism for the celebrated Mpemba effect, in which hotter initial states cool down faster. This picture generally does not survive in quantum systems. Here we show how to design a quantum energy landscape with local dissipation leading to an Mpemba effect with parametrically separated timescales. Our approach uses Stark localization to design an energy landscape and localized incoherent hopping as cooling mechanism. The hops are triggered by rare "detection" events whose rate grows with energy, allowing hotter states to cool faster and producing super-exponentially separated cooling rates for localized initial states. We further show that the effect is dramatically enhanced by collective hopping of bound pairs in the presence of attractive on-site interactions. These findings have clear experimental signatures accessible in present-day setups.
Read the full abstract

Quantum Physics

Tight entropy contraction beyond detailed balance

We establish quantitative entropy contraction bounds for finite-dimensional quantum channels beyond detailed balance. For channels compatible with a faithful conditional expectation, we show that GNS (Gelfand–Naimark–Segal) norm contraction yields relative entropy contraction with only a logarithmic loss in the dimensional constant. For quantum Markov semigroups with a faithful asymptotic conditional expectation, this gives a lower bound on the complete modified logarithmic Sobolev constant in terms of the GNS spectral gap. The bounds allow initial entanglement with an external environment and are independent of its system size. Applications to alternating reservoir pulses and continuously coupled energy ladders give bounds with optimal size dependence.
Read the full abstract

Quantum Physics

Improving the Loss Tolerance of Heralded Photonic GHZ States for Long-Distance Device-Independent Conference Key Agreement

Heralded multipartite entanglement distribution is a key requirement for device-independent conference key agreement (DI-CKA) over lossy quantum networks. Although locally equivalent in the absence of loss, different single-rail photon-number encodings of Greenberger–Horne–Zeilinger (GHZ) states respond differently to photon loss. Here, we investigate the critical detection efficiencies for detection-loophole-free parity–CHSH violations of computational-basis GHZ states—a coherent superposition of the vacuum and an $n$-photon component—and of fixed-photon-number GHZ states, deriving exact analytical conditions for both. We show that for states that are not permutation symmetric, such as the latter, the assignment of measurement roles to physical modes affects loss tolerance. We introduce a star-network protocol employing heterogeneous sources to directly herald the loss-tolerant vacuum-$n$-photon GHZ states while retaining the favourable long-distance scaling $O(\eta_{\text{c}}^{n/2})$, where $\eta_{\text{c}}$ is the channel transmittance. For four users, we characterize the heralded state under photon loss and show that tunable source parameters allow genuine multipartite entanglement to persist at any finite channel distance. With ideal Pauli and displacement-based measurements, our protocol achieves positive DI-CKA key rates at lower detection efficiencies than previous schemes, while retaining comparable or greater rates and communication distances at high efficiency. Overall, our work improves the loss tolerance of heralded photonic GHZ states for DI-CKA both by directly heralding a more loss-tolerant encoding and by optimizing existing schemes. These results identify photon-number encoding, source architecture, and measurement-role assignment as key design parameters for loss-resilient multipartite quantum networks, offering a practical route toward near-term DI-CKA.
Read the full abstract

All authors Yazeed K. Alwehaibi, Makoto Ishihara, Shakib Daryanoosh, Ewan Mer, Shang Yu, Wojciech Roga, Ian A. Walmsley, Masahiro Takeoka, Raj B. Patel

Quantum Physics

A thermal microwave bus for neutral atom quantum computing

High-fidelity two-qubit gates in neutral-atom arrays rely on the Rydberg blockade, which is intrinsically short ranged and requires long range connectivity to be achieved through atom shuttling. We propose a four level architecture, where the typical ground state qubit can be leveraged for its long lifetime and the Rydberg states couple to a microwave cavity, allowing for long range cavity mediated gates. We first find the thermal dependence of two established protocols, the dispersive iSWAP native to the Tavis-Cummings model and the Controlled phase gate generated from driving the cavity. We simulate them under the presence of Rydberg decay, thermal photons, finite cavity linewidth and find fidelities which accompany closed form bounds. We then introduce the bichromatic Raman gate, which only virtually populates the Rydberg states and cancels dispersive shifts to mitigate both atomic and cavity decay, achieving a fidelity of $F = 0.997$. Finally, we consider a full optical tweezer array in a microwave cavity, and show that using a cavity mediated gate to close the periodic boundaries of the toric code shortens an error correction round by a factor of 2.3 for realistic array sizes. This was then applied to the wider family of Bivariate bicycle codes, and we find that it shortens a round of the gross code by a factor of 4.8.
Read the full abstract

All authors Matthew J.H. Kendall, Christopher J. Watson, Michael Ben Shem, Jonathan D. Breeze

Quantum Physics · Cross-listed from physics.optics

Fisher-information training of optical sensing front ends from natural fluctuations

Fisher-information-based optimization of programmable optical front ends in situ generally requires a response model or parameter-labeled measurements. We show that natural parameter fluctuations can instead provide the training signal. We construct proxies for the Fisher information (FI) of one parameter and the prior-weighted FI spectrum of multiple parameters from measured covariances after subtracting conditional detection noise, assuming locally affine responses. We use simulated photon counts from two incoherent point sources to train a mode sorter that approaches the quantum limit for separation and the Nagaoka–Hayashi single-copy bound for joint centroid–separation estimation. We demonstrate count-only updates that require no instrument response model and achieve performance comparable to model-based gradients. Our results provide a route to adaptive optical measurements without controlled parameter scans.
Read the full abstract

Quantum Physics

Explanation of the Observed Energy Exchange through the vacuum in Optomechanics

In cavity optomechanics, the standard large-detuning regime is commonly described by retaining only the radiation-pressure interaction, while higher-order mirror–field interactions are assumed to be negligible. This approximation, however, fails to provide a microscopic explanation for the vacuum-mediated heat transfer observed between the mechanical membranes in the experiment of Fong, et.al.,[Nature 576, 243 (2019)], whose physical origin has remained under active debate. Here, using a fully quantum model, we show that the neglected higher-order optomechanical interactions naturally generate phonon-phonon coupling and quantitatively account for the observed energy exchange within the standard optomechanical framework. Building on this microscopic description, we further propose a protocol in which phonon-phonon interaction drives a cyclic process enabling net work extraction. Our results establish the fundamental role of higher-order optomechanical interactions and provide a microscopic framework for describing next-generation optomechanical experiments beyond the linear approximation.
Read the full abstract

Quantum Physics · Cross-listed from physics.atom-ph

Anomalously enhanced lifetimes of low angular momentum Rydberg states in singly charged alkaline-earth metal ions

Trapped ions excited to high-lying electronic states, so-called Rydberg states, open new opportunities for quantum simulation and quantum computing. Generally, the fidelity of quantum coherent operations critically depends on the longevity of Rydberg states. However, scaling laws predict that the lifetimes of Rydberg states in singly charged alkaline-earth metal ions are 16 times shorter, compared to their neutral atom counterparts. Here, we show that this is not generally the case. We report an anomalous lifetime enhancement of certain low angular momentum ionic Rydberg series by factors larger than eight. The anomaly is present at both zero and finite temperature, although it is caused by different mechanisms. At zero temperature, the anomalously enhanced lifetimes are caused by accidental cancellations of the relevant dipole transition matrix elements, while at room temperature the anomaly originates from the enlarged energetic separation of ionic Rydberg levels with respect to neutral-atom levels.
Read the full abstract

Quantum Physics · Cross-listed from hep-th

Measuring correlations using local and nonlocal quenches

We present a theoretical proposal for measuring correlation functions in a quantum field system based on the use of quantum quenches. Using the examples of massive and massless scalar field theories, we show that a short-term perturbation of the system leads to a dependence of the further evolution of the average field on the initial state's correlation functions. Considering two types of perturbations, namely local and nonlocal quenches, we show which correlation functions can be measured in each of these cases. The proposed procedure can be applied to study non-Gaussian correlations.
Read the full abstract

Quantum Physics

Overcoming the Hong-Ou-Mandel interference limitation for the second photon from a two-photon cascade

Quantum emitters such as semiconductor quantum dots can provide entangled photon pairs emitting from a system of cascaded states. However, the resulting temporal correlation between the two photons from the three-level ladder system has been shown to set a limit on the achievable two-photon interference. In this work, we show that such limitation, for photons emitted by the second transition, is only due to reduced temporal overlap at the interference beam splitter. We investigate this theoretically and experimentally by determining time-resolved four-photon coincidences between two successively emitted photon pairs. Post-emission synchronization shows the recovery of maximum interference visibility; in prospective quantum networks this could be achieved via deterministic quantum memories.
Read the full abstract

All authors Raphael Joos, Michal Vyvlecka, Tim Strobel, Benjamin Breiholz, Furkan Aglarci, Ponraj Vijayan, Hans-Georg Babin, Arne Ludwig, Michael Jetter, Simone L. Portalupi, Peter Michler

Quantum Physics

Trade-offs and experimental feasibility of nonlocal polygamy with two-outcome Bell inequalities

Entanglement and Bell nonlocality have different sharing constraints across subsystems of a multipartite quantum system. We examine simultaneous violations of Bell inequalities with two-outcome observables and two or three measurement settings per party. We identify configurations whose simultaneous violations can be demonstrated on IBM Quantum hardware, and derive bounds and trade-off relations for several polygamous configurations. The results connect experimental capabilities of quantum computers with mathematical methods for studying the limits of quantum correlations.
Read the full abstract

All authors Josep Batle, Tomasz Rybotycki, Tomasz Białecki, Piotr Gawron, Adam Bednorz

Quantum Physics

Stabilizing temporal quantum-enhanced sensitivity via sub-optimal measurements

In non-equilibrium probes, quantum-enhanced sensitivity is quantified through super-linear scaling of precision with respect to time, as a central metrology resource. However, this requires optimal measurements, which are often complex and time-dependent, making it challenging in practice. Sub-optimal measurements typically fail to retain robust super-linear scaling and show oscillations. Here, we begin by establishing a universal temporal scaling law in a general multi-parameter non-equilibrium quantum sensing framework. Within this setting, we identify the universal behavior of the sensing precision with sub-optimal measurements which shows quadratic scaling modulated by an additional bounded oscillatory function. To remove the oscillatory part, we propose a protocol in which measurements are partitioned into different groups, each performed at different times. The collective precision obtained from this protocol stabilizes a robust quadratic scaling even for sub-optimal measurements in the multi-parameter regime. We validate our protocol through three distinct examples as well as Bayesian estimation. Our protocol is applicable to every informative measurement and takes a key step towards practical realization of quantum-enhanced sensitivity.
Read the full abstract

Quantum Physics · Cross-listed from physics.optics

Collective cavity quantum electrodynamics in solid-state optical clocks

Solid-state frequency standards are generally limited by strong decoherence, rendering conventional interrogation schemes inefficient. The $^{229}$Th nuclear clock provides a unique and timely platform for solid-state optical metrology and nuclear cavity quantum electrodynamics (QED), featuring a coherence time many orders of magnitude shorter than the radiative lifetime in current experiments. Here, we propose and analyze three cavity QED-enhanced clock interrogation schemes that turn this timescale mismatch into an advantage, leveraging collective coupling of thorium nuclei to nanophotonic modes to enable fast interrogation and detection despite the long population lifetime. We reveal the central role of collective cooperativity in determining the clock frequency instability, and derive the optimal conditions (power, working-point detuning, thorium density) for clock operation.
Read the full abstract

All authors Karen Mamian, Georgy A. Kazakov, Thorsten Schumm, Charles Roques-Carmes

Quantum Physics

Observable-targeted variational quantum simulation of Hamiltonian dynamics

Standard variational quantum simulation seeks to reproduce the evolution of the full quantum state, although many applications require only the expectation values of a few observables. We study a variational method for pure-state Hamiltonian dynamics that updates circuit parameters to reproduce the evolution of selected expectation values. An exact error identity guides the choice of observables, motivating a construction based on repeated commutators of the target with the Hamiltonian. For Pauli observables and Pauli-rotation circuits, the update can be estimated without ancillary qubits or controlled operations for overlap estimation. Across six-qubit spin, fermionic, and molecular benchmarks, the targeted update extends the median time within the target-error tolerance by up to a factor of $4.2$ relative to standard variational quantum simulation at equal shot budgets. These results show that directing the variational update toward the target observable can extend accurate simulation without increasing the measurement cost per time step.
Read the full abstract

Quantum Physics

Superconducting qubit based on altermagnets

Altermagnets, characterized by vanishing net magnetization and momentum-dependent spin splitting, provide a promising platform for next-generation Josephson devices. Here, we exploit the Josephson effect in superconductor-altermagnet-superconductor junctions and show how to engineer prescribed current-phase relations by device design. Based on these programmable Josephson potentials utilizing altermagnetism, we propose a new class of superconducting qubits that combine large anharmonicity with enhanced robustness against decoherence via coherent two-Cooper-pair tunneling. We show that in the $2\phi$-junction regime, this kind of qubit is intrinsically protected against both charge and flux noise due to parity protection. Magnetic flux can be used to precisely control the qubit and, under appropriate bias, this architecture further suppresses charge and flux noise. Our results establish altermagnets as a versatile platform for Josephson-potential engineering and open a new route toward high-performance superconducting qubits combining high coherence, large anharmonicity, and broad tunability.
Read the full abstract

All authors Xue-Feng Pan, Xin-Lei Hei, Franco Nori, Peng-Bo Li

Quantum Physics · Cross-listed from physics.app-ph

Pendellösung length-scale neutron and X-ray interferometry

Neutron and X-ray perfect-crystal interferometers (PCIs) are powerful platforms for studies of fundamental physics and phase-contrast imaging. Further enhancing several PCI capabilities requires reducing crystal blade thickness to the micron scale, which minimizes dynamical-diffraction image blur, permits operation in the pendellösung regime where blade thickness controls beam splitting, and reduces absorption for simultaneous neutron and X-ray operation. However, fabricating multiple crystal blades with identical micrometer-scale thicknesses over centimeter-scale areas remains a major challenge. Here, using a non-etching sub-micron fabrication technique, we demonstrate silicon triple-Laue interferometers with equal-blade-thicknesses of 110 $\mu$m and 350 $\mu$m, operated with both neutrons and X-rays. These devices are the thinnest PCIs realized to date, enabling a factor-of-six reduction in dynamical-diffraction beam spreading for improved phase-contrast imaging, while reaching the single pendellösung length regime in which crystal thickness provides an experimentally accessible control parameter for engineered quantum-optical beam splitting of plane-wave inputs. These results motivate multi-blade PCI designs utilizing identical half-pendellösung crystal lamellae that are proposed for neutron spin–orbit and electric dipole moment measurements.
Read the full abstract

All authors Owen Lailey, Alexandre Boutot, David G. Cory, Joseph P. Cotter, Vishal Dhamgaye, Tao Hong, Michael G. Huber, Young-June Kim, Winfried Kockelmann, Jeremy W. Paster, Dusan Sarenac, Kawal Sawhney, Naume Shentevski, Ivar Taminiau, Dmitry A. Pushin

Quantum Physics

Unified spatiotemporal quantum states and spatiotemporal entanglement from Kirkwood-Dirac phase space

The notion of a spatiotemporal quantum state extends the conventional concept of a spatial quantum state to the spatiotemporal domain. Such states are represented by unit-trace operators that encode correlations among quantum events distributed across space and time. In this work, we use the spatiotemporal Kirkwood-Dirac phase space to provide a unified characterization of spatiotemporal quantum states. Spatiotemporal states obtained from Kirkwood-Dirac distributions are generally non-Hermitian and nonnormal; whereas those constructed from Margenau-Hill distributions are Hermitian. We provide a unification via (quasi)probabilistic mixture of Kirkwwod-Dirac spatiotemporal states which encompasses almost all existing formulations of spatiotemporal quantum states. We derive recursive expressions for spatiotemporal states and elucidate the relation between Kirkwood-Dirac nonclassicality and the temporality of spatiotemporal states. We further extend the construction to many-fold correlation functions and establish its connection with out-of-time-ordered correlators (OTOCs). We also develop a more general unifying framework based on (quasi)probabilistic mixture of $s$-parametrized spatiotemporal states and establish their Petz time reversal and application in studying Kubo-Martin-Schwinger (KMS) condition in two-time setting. Finally, we apply this framework to characterize quantum entanglement in spacetime and analyze spatiotemporal entanglement using several complementary entropy measures.
Read the full abstract

Quantum Physics

Wigner-positive quantum states can have lower entropy than the vacuum

The Wigner entropy conjecture posits that pure Gaussian states minimize the Shannon entropy of non-negative Wigner functions, known as the Wigner entropy. We show that mixing a specific pure Wigner-negative state with another suitably chosen quantum state can restore Wigner positivity while retaining a Wigner entropy that is slightly - but strictly - below the vacuum entropy. As a consequence, we disprove the Wigner entropy conjecture, as well as the stronger Wigner majorization conjecture, by deriving simple analytical counterexamples with violations of the entropy bound no larger than $10^{-3}$. Such states with sub-vacuum Wigner entropy can be found arbitrarily close to the vacuum and can also exhibit sub-vacuum Wigner-Rényi $\alpha$-entropy for $0<\alpha<2$. We identify the physical mechanism behind the existence of such states, which arises from a subtle interplay between the uncertainty principle and non-Gaussianity. The key idea of this paper was developed with the help of AI tools, building on the characterization of extreme non-negative Wigner functions.
Read the full abstract

Quantum Physics

Experimental evidence of generalization in quantum machine learning in small-data regime

Quantum machine learning is a promising paradigm for learning from limited data, a central bottleneck in domains such as medical imaging, clinical trials, and rare diseases. Quantum convolutional neural networks (QCNNs) are particularly attractive in this setting, combining a hierarchical architecture with strong inductive bias and a parameter count that grows only logarithmically with system size. Their appeal rests on the generalization bounds of Caro et al. (2022), which show that the generalization error of a quantum model scales with the number of trainable parameters rather than with the Hilbert-space dimension, placing QCNNs in a potentially sample-efficient regime. We develop a hardware-compatible QCNN with mid-circuit measurement and classical feed-forward, and show on a binary handwritten-digit task that strong test performance is achievable from as few as 10 training samples, with the generalization error decreasing as the training set grows. At a matched 45-parameter budget the QCNN learns where an equally small classical convolutional network stays at chance, although an unconstrained classical baseline with roughly 25,000 parameters remains strongest when data are plentiful. Transpiling amplitude and angle encoded circuits across image resolutions from 2x2 to 512x512 pixels then exposes the dominant scaling bottleneck: amplitude encoding stays qubit-efficient but grows extremely deep, whereas angle encoding stays shallow but becomes qubit-prohibitive. On the medically motivated BreastMNIST benchmark the QCNN does not surpass the unconstrained classical network, yet it learns consistently above chance using orders of magnitude fewer parameters. Our results indicate that for QCNNs, learning from few samples is attainable in practice, whereas scaling to realistic image data is constrained less by optimization than by data encoding and hardware execution.
Read the full abstract

All authors Leena Anthony, Artemiy Burov, Nicolas Piro, Matteo Dal Peraro, Clément Javerzac

Quantum Physics

Circuit Hypernetworks for Quantum-Augmented Diffusion Language Models

Language models can be adapted by changing the computations applied to individual tokens. Quantum circuits offer one such approach, but evaluating wider circuits inside a large model can be computationally demanding. Here we introduce HyperQ, which adds token-conditioned quantum residual branches to a frozen masked-diffusion language model. A quantum residual branch is a module in each transformer block that reads a token's hidden state, emits the coordinates of that token's circuit, executes it, and adds the measured values back through a residual connection. The backbone remains frozen, and only the added branches are trained. Within each branch, a lightweight circuit hypernetwork emits token-specific rotation angles, coupling strengths, and measurement axes in a shared sparse circuit structure. The required expectation values have an exact classical expression whose evaluation cost grows linearly with the qubit count, enabling circuits from 16 to 64 qubits to be trained within a 1.1-billion-parameter backbone. Across downstream benchmarks, increasing circuit width raises the average score from 47.65 to 54.30. At 64 qubits, HyperQ exceeds the backbone and its low-rank-adapted counterpart by 4.71 and 3.67 points, respectively. HyperQ is fine-tuned on 20,000 prompt-response pairs, compared with 200,000 for the classical baselines. These findings support token-conditioned circuit emission as a tractable architectural approach to quantum-augmented language modelling.
Read the full abstract

All authors Xiaoqiang Wang, Mengyang Xiong, Jun Dai, Bang Liu

Quantum Physics

Phase space anatomy of dynamical quantum phase transitions

Dynamical quantum phase transitions (DQPT) are commonly defined either by the behavior of a late-time order parameter or by nonanalyticities in a quantum state's return rate. We show that discrete phase space fundamentally separates these two notions by the scale of information they require. An order parameter transition is determined by a local reduced state, requiring no quasiprobability negativity. In contrast, general global returns can contain information absent from every proper reduced state. For stabilizer returns, we derive an exact decomposition of the rate into distinct costs from loss of support and destructive quantum interference. Dynamics of a qutrit Potts chain show that selective cancellation can reverse the ranking of competing block returns and delay their exchange. An exact control also exhibits a thermodynamic return cusp with zero negativity at the crossing. The existence of a return singularity and the role of interference in selecting its branches are therefore distinct physical questions.
Read the full abstract

Quantum Physics

Explicit closed-form propagators for time-dependent gain-loss master equations

Time ordering is a central obstacle in driven open-system dynamics governed by master equations with time-dependent rates. We derive explicit closed-form factorizations of the chronological and antichronological propagators for a time-dependent generator of the form $\mathcal{L}(t)=\alpha(t)A+\beta(t)B$, when the commutator $[A,B]$ is a simultaneous eigenoperator of the adjoint actions of $A$ and $B$, namely $[A,[A,B]]=\lambda_{A}[A,B]$ and $[B,[A,B]]=\lambda_{B}[A,B]$. In contrast to the disentangling procedure known as the Wei-Norman decomposition, our construction determines the factorization coefficients directly, without solving a coupled system of nonlinear differential equations. Applying this result to the bosonic gain-loss Lindblad equation, we obtain the exact dynamical map for arbitrary time-dependent gain and loss rates. The gain-loss master equation provides a canonical description of a driven harmonic oscillator coupled to a thermal bath. We benchmark the construction by deriving the time evolution of the Wigner function of an initial Fock state and comparing it with independent phase-space results. We further apply the resulting dynamical map to evaluate the code-space survival probability of a binomial bosonic code under driven gain-loss dynamics.
Read the full abstract

Quantum Physics · Cross-listed from physics.chem-ph

Benchmarking higher-ranking multipoles and polarizability tensors for small molecular systems

Molecular properties govern how molecules interact with one another or external fields. Accurate molecular properties are essential for constructing intermolecular interaction models, and to achieve high accuracy we need to go beyond leading-order (dipolar) terms. This work presents CCSD(T) references for 73 small non-spin-polarized molecules for molecular dipole and quadrupole moments, and dipole-dipole and quadrupole-quadrupole polarizabilities. Using these results, we provide a holistic performance analysis of molecular properties computed with HF, MP2, CCSD, and a wide range of density-functional methods. Additionally, we investigate in detail what levels of basis sets are required to simultaneously describe all properties in the data set. The best-performing density functionals for all four properties are the asymptotically cor- rected hybrid GGAs B97-3-AC, closely followed by PBE0-AC. Surprisingly, modern meta- GGAs and range-separated functionals perform inconsistently, with large errors in the quadrupo- lar properties. These results have direct implications for methods for intermolecular interac- tions, such as symmetry-adapted perturbation theory based on density functional theory, or for the quality of properties and interactions in machine-learning datasets. Finally, for DFT methods, the Jensen aug-pcseg-2 basis set is a computationally efficient alternative to more established basis sets, but for generating correlated references, third-row elements benefit from core polarization, and double augmentation is strictly necessary for quadrupole-quadrupole polarizabilities.
Read the full abstract

Quantum Physics

An Exact Operator Formulation of Statistical Quasiparticle Theory for Nonlinear System-Bath Coupling

We develop an operator formulation of statistical quasiparticle theory for open quantum systems with nonlinear system-bath coupling, extending beyond the linear coupling setting of the standard Gaussian influence functional formulation. For Gaussian baths, the statistical quasiparticles, termed dissipatons, are explicitly constructed as collective operators in the thermofield bath space. Our construction provides a microscopic operator basis for the dissipaton algebra and generates hierarchical equations of motion directly from the Liouville equation. Nonlinear interactions are incorporated through a recursive generalized Wick's theorem, enabling automatic generation of hierarchical equations for polynomial couplings. The resulting framework connects explicit bath operator representations to nonperturbative, non-Markovian dynamics and unifies the treatment of linear and nonlinear system-bath interactions.
Read the full abstract

Quantum Physics · Cross-listed from cond-mat.stat-mech

Random-matrix and transport frequencies in eigenstate spectral functions

The fact that generic isolated many-body quantum systems thermalize is understood using the eigenstate thermalization hypothesis (ETH). In recent years, there has been much interest in the behavior of the ETH spectral functions, which characterize the smooth dependence of the variance of the off-diagonal matrix elements of observables on the associated energy and frequency, and whose low-frequency part contains information about the long-time dynamics. In finite systems described by the ETH, the spectral functions are expected to exhibit plateaus below a characteristic frequency $\omega^{}_{\mathrm{ETH}}$. In this regime, the statistics of the matrix elements of observables are expected to be described by random matrix theory. Related frequencies that have been studied in the literature are $\omega^{}_{\mathrm{SFF}}$, which controls the onset of random-matrix behavior in the spectral form factor, and the transport frequencies $\omega^{}_{\mathrm{tr}}$, which are derived from transport coefficients. However, a direct quantitative comparison of these frequencies is lacking. Using exact diagonalization, we conduct such a comparison for the spectral functions of current operators in clean and disordered quantum spin ladders with diffusive energy and spin transport. We find clear evidence for the expected low-frequency plateaus in the ETH spectral functions. For the accessible system sizes, $\omega^{}_{\mathrm{SFF}}$ is consistent with the extent of the plateaus, while the transport frequencies are systematically larger and lie in the nonuniversal regime of the spectral functions. Our findings highlight the need to better understand the origin of these quantitative differences.
Read the full abstract

All authors Kadir Çeven, Rohit Patil, Marcos Rigol, Fabian Heidrich-Meisner

Quantum Physics · Cross-listed from cond-mat.mes-hall

The Superconducting Talbot Effect in Phased-Array Josephson Junctions

We introduce the superconducting Talbot effect—a macroscopic quantum self-imaging phenomenon occurring when proximitized Cooper pairs propagate through a ballistic two-dimensional electron gas. By configuring periodic superconducting leads into a phased-array Josephson junction with programmable phase differences, we demonstrate active steering of the resulting superconducting Talbot carpet. To overcome transport resolution limits, we design a Vernier-scale collector array that performs sub-wavelength sampling of the fractional Talbot pattern. This approach maps real-space quantum interference with high robustness to disorder, enabling direct extraction of Fermi wavelengths across helical, spin-degenerate, and spin-orbit-split Fermi surfaces. Tight-binding numerical calculations on a square lattice validate the real-space interference patterns. Our results establish a versatile framework for coherent wavefront engineering and quantum materials diagnostics in superconducting optics.
Read the full abstract

Quantum Physics

A Reconfigurable Multilayer Quantum Key Distribution Network over Existing Metropolitan Fibre

Scaling quantum networks requires architectures extending end-to-end service reachability despite constrained fibre and equipment. Critically, in brownfield deployments, the quantum network must be engineered around classical telecommunications infrastructure and the operating capabilities of quantum key distribution (QKD) technology. To address this, we demonstrate a seven-node, multilayer QKD network deployed over existing metropolitan fibre. The implementation compares spectral management techniques to accommodate inherited constraints across its layers. It combines a trusted-node ring with a three-node subnetwork interconnected through reconfigurable optical switching, extending physical connectivity and service reachability without an additional transmitter. A meshed key management layer maps endpoint requests onto trusted-relay paths and supplies Layer 1, Layer 3, and one-time-pad applications. Over 73 days, eight link configurations generated 119.4 Gbit of secret key material with 99.1% link availability. Randomised end-to-end requests revealed indirect cross-layer coupling between key consumption, stored-key state and quantum-layer reconfiguration, demonstrating resource sharing through reconfigurability, spectral multiplexing and logical key-management abstraction.
Read the full abstract

All authors Mariella Minder, Andreas Siakolas, Elizabeth Pasatembou, Stylianos Mavrikos, Stephanos Yerolatsitis, Konstantinos Katzis, Kyriacos Kalli

Quantum Physics

Collective advantage from a minimal record in a quantum information engine

For a single particle, a quantum information engine can turn measurement fluctuations into transport by raising a barrier behind the particle each time its position is measured. When many particles are present, the barrier still depends on just one number, the position of the leftmost particle, so we let the demon measure that order statistic and nothing else. A demon that resolves every position instead pays a record entropy that grows with particle number, even though the extra distinctions never change where the barrier is placed. We show that the coarser measurement supplies an energy that is bounded independently of particle number, and that this bound yields a ceiling on the record entropy that falls as the filling increases. At the same tilt, the collective engine then delivers $44\%$ more work per recorded nat than independent single-particle engines, each with its own optimized cycle time and each running at equal or greater power per particle. Pauli blocking ends this advantage once the accessible region just above the wall fills. We also evaluate the coherence that the coarse measurement leaves behind, and the cost of placing the barrier imprecisely.
Read the full abstract

Quantum Physics

Statistical mechanics of multipartite entanglement in hypergraph states

We investigate multipartite entanglement in a particular family of pure $n$-qubit hypergraph states through a statistical-mechanics framework, where the average bipartite purity maps onto an effective Hamiltonian of $2^n$ classical binary spins. In this correspondence, each hypergraph state uniquely corresponds to a classical spin configuration, while temperature serves as a control parameter that continuously interpolates between a uniform ensemble of random hypergraph states at high temperature and maximally multipartite entangled states (MMES) at zero temperature. Remarkably, the exponential of the zero-temperature entropy directly gives the number of MMES within the set of hypergraph states. For small system sizes ($n \leq 5$), we perform an exact enumeration, fully characterizing the energy landscape and associated thermodynamic observables, and validating known MMES counts. For larger systems ($n = 6$ and $7$), where exact methods become computationally infeasible, we employ simulated annealing and parallel tempering algorithms to efficiently sample the exponentially large state space. Our analysis yields quantitative predictions of the number of MMES and reveals how entanglement is statistically distributed across the sets of hypergraph states. These results establish hypergraph states as an ideal platform for investigating multipartite entanglement through thermodynamic methods, offering both computational advances and physical insights into the structure of quantum entanglement in restricted families of quantum states.
Read the full abstract

All authors Paolo Scarafile, Giorgia Trotta, Paolo Facchi, Giuseppe Magnifico, Giorgio Parisi, Saverio Pascazio, Karol Życzkowski