Quantum Physics · Cross-listed from physics.bio-ph
Collective Emission in LH2 Assembly Beyond the Point-Dipole Approximation
Javed Akhtar and Himangshu Prabal Goswami
Collective emission in light-harvesting assemblies is governed by the local transition dipole and finite geometry of emitting units, a fact that point-dipole approximation obscures. To go beyond this picture, we develop a non-Hermitian
Hamiltonian using the
quantum electrodynamic dyadic Green's tensor for a purple bacteria. We construct it for the isolated 24-bacteriochlorophyll conical frustum and its P42$_1$2 crystallographic assembly. The P42$_1$2 unit-
cell symmetry is found to invert the bright-dark ordering of the single ring, placing subradiant states at the low-energy end and revealing the entire
crystal to be the energy-harvesting entity. Tilt-driven switching is activated only in
crystal geometries where the finite dipole-carrier (LH2) lies perpendicular to the growth plane. Vacancy and orientational disorder work only in cooperation to renormalize the switching threshold from higher polar angles to lower values.
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Quantum Physics
Pure State Transformations under Block Coherence
Dipayan Chakraborty, Priyabrata Char, Indrani Chattopadhyay et al. (+1 more)
Block coherence provides a natural generalization of standard
quantum coherence by treating superpositions across different subspaces as a resource. This work studies deterministic pure-state conversion under three free operations: physically block incoherent operations (PBIO), strictly block incoherent operations (SBIO), and block dephasing covariant incoherent operations (BDCO). For PBIO, we prove that, under a natural nondegeneracy condition on the active Kraus branches, any deterministic conversion from one pure state to another must be implemented by a block incoherent
unitary. When the nondegeneracy requirement is removed, the condition becomes more general. It demands that the blockwise action of every active branch reproduce the target block structure with a common proportionality factor across all output blocks. For SBIO and BDCO, we show that deterministic pure-state transformation is completely characterized by the majorization relation between the input and output block probability vectors. The converse proof is constructive, yielding an explicit Kraus representation for every admissible BDCO transformation. In the rank-one limit, these conditions reduce to the known pure-state transformation criteria for physically incoherent operations (PIO), strictly incoherent operations (SIO), and dephasing covariant incoherent operations (DIO) in the standard resource theory of coherence. Using the majorization condition, a maximally block-coherent state with uniform block weights is also identified as a universal pure-state resource under BDCO and SBIO. We have also provided
geometric numerical illustrations comparing the state transformation power of BDCO and DIO for a fixed input state, fixed output state and mutual convertibility scenarios.
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All authors Dipayan Chakraborty, Priyabrata Char, Indrani Chattopadhyay, Debasis Sarkar
Quantum Physics
Mitigating Noise-Induced Barren Plateaus Using a Non-Unitary Ansatz: Application to Molecular Electronic Transport
Sasanka Dowarah, Abeda Sultana Shamma, Yazdan Maghsoud et al. (+2 more)
Variational
quantum algorithms (VQAs) offer a promising route toward simulating many-body
quantum systems on noisy intermediate-scale
quantum (NISQ) hardware. However, their scalability is severely limited by noise-induced barren plateaus (NIBPs), where hardware noise causes the gradients of the cost function to vanish exponentially with
circuit depth, rendering optimization impossible. In this work, we demonstrate that introducing nonunitary elements into the variational ansatz can mitigate NIBPs in open-
quantum systems. Using an analytically tractable infinite-range dissipative Ising model, we show that a nonunitary ansatz restores finite gradients in the presence of depolarizing noise, enabling convergence to the correct
symmetry-broken steady state. We also develop a Floquet-type variational ansatz in which each layer repeats the same parameters, reducing the deep variational
circuit to an effective
quantum channel whose fixed points can be analyzed directly. We then extend these ideas to a realistic
quantum-chemistry system by simulating electron transport through Oligophenylethynylene-sulfurmethyl (OPE-SMe) using
Hamiltonians and jump operators of the model derived from first-principles polarizable QM/MM calculations. Our results show that nonunitary variational ansätze provide a scalable and physically grounded route for simulating open-system steady states on NISQ hardware, offering a pathway to overcoming one of the limitations of current
quantum hardware.
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All authors Sasanka Dowarah, Abeda Sultana Shamma, Yazdan Maghsoud, G. Andrés Cisneros, Michael Kolodrubetz
Quantum Physics · Cross-listed from hep-th
Ambiguity problem of the Bootstrap Method in Quantum Mechanics
Takeshi Morita, Worapat Piensuk and Pushkar Soni
The bootstrap method for
quantum mechanics is a powerful tool for computing the energy
eigenvalues of a
Hamiltonian. However, we point out that this method suffers from an ambiguity problem: it fails to yield the correct spectrum when the potential contains different types of functions, such as
polynomial and exponential terms. Similarly, the bootstrap method may break down when evaluating the expectation values of operators of different types. This issue can arise in a wide range of systems, including statistical models and
matrix models. We propose three possible resolutions to this problem.
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Quantum Physics · Cross-listed from physics.optics
Metasurfaces for neutral-atom trapping
Chengyu Fang, Minjeong Kim, Mark Saffman et al. (+2 more)
Trapped neutral atoms are one of the leading platforms for
quantum information technologies, in particular for
quantum computing, but scaling them to array sizes needed for utility-scale
quantum computing is a major engineering challenge. Here we review optical metasurfaces as an enabling technology that provides fine control over the phase, amplitude, and polarization of light, with pixel counts far exceeding what is available with spatial light modulators (SLMs) and other active devices. The large pixel counts have recently led to demonstrations of arrays of optical tweezers with hundreds of thousands of sites and arrays of optical bottle-beams with complex three-dimensional trapping profiles. The flexibility and scalability of optical metasurfaces provides a route towards miniaturized, integrated, and highly scalable atomic experiments and instruments.
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All authors Chengyu Fang, Minjeong Kim, Mark Saffman, Jennifer T. Choy, Mikhail Kats
Quantum Physics
Rydberg state engineering of trapped ions
Robin Thomm, Vinay Shankar, Natalia Kuk et al. (+3 more)
Microwave dressing of Rydberg ions creates tunable eigenstates with controllable polarizability and interaction strength, but coherent
navigation between these states has remained elusive. Here, we report on the first demonstration of coherent population transfer between different Rydberg states of a trapped ion. We investigate both microwave-mediated Rabi oscillations between Rydberg S and P states and adiabatic transfer between microwave-dressed Rydberg states. Between Rydberg S and P states we achieve a population transfer efficiency of 91.5(5)% in a single microwave ${\pi}$-pulse. Microwave dressing hybridizes the S and P Rydberg states into new eigenstates with tunable polarizability, enabling both noise-resilient zero-polarizability states and maximally interacting states. We demonstrate adiabatic transfer between these zero-polarizability and maximally dressed states, enabling experiments that combine noise-resilient excitation with strong dipole-dipole interactions and Förster resonance control within a single measurement sequence.
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All authors Robin Thomm, Vinay Shankar, Natalia Kuk, Marion Mallweger, Ivo Straka, Markus Hennrich
Quantum Physics
A Denser Planar Surface Code
Guang Hao Low, William J. Huggins, Dominic W. Berry et al. (+4 more)
We present a
quantum code implementable on a regular $2$D hex grid with an estimated encoding rate up to $4.5\times$ of that of a rotated surface code patch using
circuit-level noise in a one- and two-
qubit $10^{-3}$ error uniform depolarizing model. Our approach is based on yoking a dense packing of surface code twist defects, enabled by new stabilizer measurement cycles with an optimal four layers of nearest-neighbor two-
qubit gates, almost no distance-reducing hook errors, and efficient decoding. We demonstrate a space-efficient architecture for computing on densely packed logical
qubits, including new padding-free
lattice surgery protocols in an optimal bounding box of $2d^2$ data and measurement
qubits per patch. Assuming a $1\mu$s surface code cycle time and a $10\mu$s reaction time, these developments enable chemically accurate ground state phase estimation of a broad class of `utility-scale' electronic structure simulation problems such as the $108$
spin-orbital FeMoco-based nitrogen fixation catalyst in under a month with $89$k noisy superconducting
qubits. We elucidate a Pareto frontier of space-time trade-offs and find a minimum physical
quantum volume of $1.3$ mega-
qubit-hours. These correspond to a $36\times$ space and $6.6\times$ spacetime improvement, respectively, over our previous state-of-the-art minimum-Toffoli resource estimates (Phys. Rev. X 15, 041016).
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All authors Guang Hao Low, William J. Huggins, Dominic W. Berry, Tanuj Khattar, Alec F. White, Nicholas C. Rubin, Ryan Babbush
Quantum Physics
Shreya Banerjee, Vinodh Raj Rajagopal Muthu, Charlie Nation et al. (+5 more)
Finding
symmetries is crucial for understanding physical models. In this work, we present an optimization framework that searches Pauli
symmetries of
Hamiltonians, merging the fields of machine learning with automated
symmetry finding. Built on a Set-
Transformer architecture, our framework uses self-
attention to encode the pairwise and higher-order correlations among the Pauli-Strings. The relations are then decoded as a candidate, which is further optimized with a custom commutation-based objective, and mapped to a
symmetry of the input
Hamiltonian. We apply our method to random Pauli
Hamiltonians, periodic one and two dimensional transverse-field Ising model and the Toric code. We show that for physical
Hamiltonians (Ising and Toric), our framework succeeds with near-deterministic probability while providing substantial advantage compared to state-of-the-art strategies. For random Pauli
Hamiltonians, we estimate the required computational resources, specifically the number of parallel starts and the number of GPUs, to find a
symmetry with high success probability under fixed design specifications.
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All authors Shreya Banerjee, Vinodh Raj Rajagopal Muthu, Charlie Nation, Rick P.A. Simon, Francesco Martini, Alessandro Ricottone, Federico Cerisola, Luca Dellantonio
Quantum Physics
Graph automorphisms to obtain Clifford symmetries in open and closed qudit models
Charlie Nation, Rick P. A. Simon, Shreya Banerjee et al. (+4 more)
In the recent article [arXiv:2605.18966], we demonstrated that finding Clifford
symmetries can be mapped to a Graph
Automorphism (GA) problem. Here, we provide an
algorithm to obtain such
symmetries on general qudit systems, that works on the principle of encoding Clifford invariants of a
Hamiltonian onto properties of a graph. Labelling
Hamiltonian terms as vertices, a permutation of such vertices that respects the Clifford invariants (a GA) is both a valid Clifford, and a
symmetry up to phase correction checks. We test this on multiple physical models and discuss the scaling with respect to the number of qudits and Pauli strings, as well as various strategies for optimisation in different regimes. We further show that the graph
automorphism representation of Clifford
symmetries can be expanded to open
quantum systems.
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All authors Charlie Nation, Rick P. A. Simon, Shreya Banerjee, Francesco Martini, Alessandro Ricottone, Federico Cerisola, Luca Dellantonio
Quantum Physics
Detecting bipartite entanglement with PnCP maps and non-negative polynomials
Gaël Massé, Mounir Rezig, Paul Catala et al. (+4 more)
Positive non-Completely Positive (PnCP) maps are an essential tool to detect
entanglement since their characterization is a dual aspect of the separability problem. A recent
algorithm proposed by Kelp et al. explains how to generate PnCP maps based on the construction of certain positive non-Sum-of-Squares
polynomials. We implement this
algorithm in a numerically robust way and propose a working version on GitHub. We theoretically demonstrate that the maps produced by the
algorithm are indecomposable, localized on the boundary of the positive cone and show that they are inequivalent with most other known PnCP maps. We numerically investigate their
entanglement power, demonstrating notably that they are capable of detecting PPT entangled states that most criteria fail to detect.
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All authors Gaël Massé, Mounir Rezig, Paul Catala, Santiago Scheiner, Laia Serradesanferm Córdoba, Enky Oudot, Damian Markham
Quantum Physics
Dually tunable YBCO coplanar waveguide resonators based on helium-ion-generated Josephson inductances
Kenny Fohmann, Timo J. Glebe-Märklin, Benedikt Wilde et al. (+5 more)
Superconducting microwave
circuits with and without Josephson inductances are the Swiss Army knife for many experiments and technologies from
quantum information science to astrophysical particle detectors. Despite a large variety of existing
circuit types, thin film materials and Josephson junction technologies, a flexible and reliable platform for high-
magnetic-field and high-temperature applications is yet to be found. In this manuscript, we investigate coplanar waveguide cavities made of the high-temperature cuprate
superconductor YBa$_2$Cu$_3$O$_7$ (YBCO), integrated with Josephson inductances and
quantum interferometers that are generated by the controlled local irradiation of the YBCO with a focused helium ion beam. We obtain strongly flux-tunable microwave resonators, which not only display periodic interferometer oscillations of resonance frequency and decay rate, but also a superimposed Fraunhofer-like modulation pattern. The latter originates from the
magnetic field tuning of the individual Josephson junction critical currents due to the out-of-plane junction barriers. It allows adjusting resonance frequency and flux responsivity independently of each other, potentially enabling tunable microwave
circuits with low sensitivity to external
magnetic-field noise over a broad range of frequencies. Finally, we investigate the temperature dependence of the cavities, show that they have promising characteristics up to 14$\,$K, and present a model for the junction-induced cavity losses.
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All authors Kenny Fohmann, Timo J. Glebe-Märklin, Benedikt Wilde, Mohamad Kazouini, Christoph Schmid, Dieter Koelle, Reinhold Kleiner, Daniel Bothner
Quantum Physics · Cross-listed from hep-ph
Aaditya Datar, Arun M. Thalapillil and Palak Thareja
In this work, we broach a
quantum information-theoretic treatment of
axion–
photon mixing. Motivated by an emerging class of
quantum-enhanced
axion searches, we analyse the two-level single-excitation sector of
axion–
photon oscillations, demonstrating how the coupled dynamics naturally generate bipartite
axion–
photon mode
entanglement. We study in detail the ensuing aspects of
entanglement entropy, concurrence, negativity,
quantum mutual information and discord, and capacity of
entanglement, and the corresponding
neutrino analogues wherever novel and previously unaddressed. In particular, we highlight the characteristic features that connect maximal
axion–
photon entanglement to resonant or strong-mixing conversion, and the distinct thresholds for the extremal values attained by the
quantum information measures. We study aspects of the Mandelstam–Tamm and Margolus–Levitin
quantum speed limits for both the
axion–
photon and
neutrino systems. While orthogonalisation occurs only at
axion–
photon resonance, or at maximal
neutrino mixing, where the two bounds coincide, away from these limits, the Margolus–Levitin bound is saturated at maximal conversion, while the Mandelstam–Tamm bound is generally weaker. We also study an
entanglement quantum speed limit for
axion–
photon conversion, that separates into detuning-dominated and
magnetic-mixing-dominated regimes, and find that it is saturated for a period and then the bound becomes weak. The results in this work identify the
quantum resources and limiting timescales intrinsic to
axion–
photon conversion, and connect
axion phenomenology,
neutrino oscillations and
quantum information theory.
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Quantum Physics · Cross-listed from gr-qc
Toward a Phenomenologically Acceptable Quantum Cyclic Universe
Sean M. Carroll, Nadiia Diachenko and Saakshi Dulani
We put forward a
quantum model of cosmology that is exactly periodic but avoids the Boltzmann
Brain problem. If the universe is described by a
quantum state evolving unitarily in a finite-dimensional
Hilbert space, its
evolution will be recurrent: given enough time, the state will return arbitrarily close to its initial state. There is a worry that such a scenario cannot be phenomenologically acceptable, because the state will spend most of its time in a high-
entropy equilibrium macrostate, with rare fluctuations downward in
entropy, and the vast majority of observers will be minimal fluctuations away from
equilibrium, or “Boltzmann
Brains." Here we show that this is not necessarily true. If the differences in energy
eigenvalues are commensurable, the
evolution is not simple recurrent, but exactly periodic. Moreover, if the state starts at minimum thermodynamic
entropy, its
evolution can feature a distinguished
entropy excursion that is much more pronounced than one would expect from the conventional expression $P(\Delta S) \propto \exp(-\Delta S)$. This excursion could represent our Big Bang, with relatively few Boltzmann fluctuations occurring in the subsequent
equilibrium phase before a Big Crunch occurs and the cycle begins again. We speculate on the spacetime interpretation of this kind of
quantum universe.
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Quantum Physics · Cross-listed from hep-ph
Leptonic CP Phase Determination from Fisher Information in NO$\nu$A and T2K
Neetu Raj Singh Chundawat, Luis A. Delgadillo and Yu-Feng Li
The precise determination of the leptonic CP phase $\delta_{\rm CP}$ remains one of the central objectives of current and future long-baseline (LBL)
neutrino oscillation experiments.
Quantum estimation theory provides a natural framework to quantify the ultimate precision limits for estimating physical parameters encoded in
quantum states. In this work, we employ the
quantum Fisher information to investigate how much information about $\delta_{\rm CP}$ is intrinsically encoded in
neutrino states and how efficiently it is extracted in present LBL experiments such as T2K and NO$\nu$A. We first analyze the intrinsic
quantum sensitivity of
neutrino and antineutrino states and demonstrate how matter effects generate a
neutrino mass-ordering dependent information structure. To compare the intrinsic information content of the
quantum state with the information experimentally accessible through
flavor measurements, we compute the event-level Fisher information from reconstructed event spectra using Poisson statistics. We find that both experiments extract only a small fraction of the total information available in the underlying
quantum state. This extraction efficiency becomes particularly suppressed near maximally CP-violating regions, where the reconstructed event spectra exhibit reduced sensitivity to small variations in $\delta_{\rm CP}$. Our analysis provides a complementary information-theoretic perspective on precise estimation of oscillation parameters in LBL
neutrino experiments.
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Quantum Physics · Cross-listed from math-ph
A Boundary–Residue Incidence Coalgebra for Associahedral Scattering Forms
Ioannis P. Zois
We introduce a boundary–residue incidence coalgebra associated with the face poset of a positive geometry and apply it to associahedral scattering forms. The construction is motivated by the analogy between the Connes–Kreimer coproduct on Feynman graphs and the recursive residue structure of canonical forms. For the Stasheff associahedron \(K_n\), whose faces are indexed by non-crossing dissections of an \((n+1)\)-gon, we prove that the incidence coproduct records all intermediate nested planar factorisation channels of the corresponding tree-level scalar amplitude. The residue of the canonical form on a face labelled by a dissection factorises as the exterior product of canonical forms on the lower associahedra associated with the resulting subpolygons. We illustrate the construction explicitly for the pentagon associahedron \(K_4\), corresponding to the five-point planar scalar amplitude. We then formulate a loop-level extension: whenever a planar loop integrand is represented by a positive geometry, the associahedral face poset is replaced by the boundary poset of the corresponding loop geometry. The one-loop halohedron gives a concrete scalar example, while in the non-planar case we define the associated incidence coalgebra at the level of logarithmic singularity strata. Finally, we compare the boundary–residue coalgebra with the cellular incidence coalgebra of a triangulated or regular CW spacetime. The face poset of a finite regular CW complex reconstructs its barycentric subdivision, and hence its underlying polyhedron, while in positive geometry the same incidence mechanism organises canonical-form residues. This yields an incidence-first bridge between cellular spacetime
topology and positive-
geometric amplitude factorisation, without assuming that metric or causal data are determined by
topology.
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Quantum Physics · Cross-listed from cs.IT
Majorization precursors to supermodularity and subadditivity on the majorization lattice
Alexander Stévins, Michael G. Jabbour, Serge Deside et al. (+1 more)
We establish two structural majorization relations, which we call precursors, underlying the properties of supermodularity and subadditivity on the
lattice induced by majorization. These are precursors in that they immediately imply that all sums of concave functions, which we dub sum-concave functions, are supermodular and subadditive on the majorization
lattice. Using these majorization relations, we then show the supermodularity and subadditivity (in the
lattice-theoretic sense) of Tsallis
entropies (for all $\alpha$) and Rényi
entropies (for all $\alpha > 1$), also recovering these properties for the Shannon
entropy in the process. We further strengthen these inequalities, showing that: (i) all these entropic functionals are strictly subadditive on the majorization
lattice; (ii) Tsallis
entropies (and therefore the Shannon
entropy as well) are strictly supermodular on the majorization
lattice.
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All authors Alexander Stévins, Michael G. Jabbour, Serge Deside, Nicolas J. Cerf
Quantum Physics
Analytical model for structured light propagation through a turbulent atmosphere
Konstantin Kravtsov
We develop a straightforward analytical framework for the propagation of spatial light modes through a turbulent atmosphere. Built upon the split-step approach with the mode-based optical field representation, it directly assesses how
turbulence-induced phase fluctuations deplete the optical power in the original mode and re-distribute it into neighboring spatial modes. Importantly, this power transfer scales linearly with the propagation distance in a uniform channel, yielding a simple solution for arbitrary distances in the form of a
matrix exponential. The transfer rate is determined by the spatial spectral overlap between the
turbulence spectrum and the acceptance spectrum for a pair of interacting spatial modes. The model predicts the average power in each spatial mode and is exact when a single mode strongly dominates all others. Our predictions show reasonably good agreement with simulations up to medium-to-strong
turbulence levels. The model also confirms the scalings with mode order previously known as empirical observations.
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Quantum Physics
Quantum Desynchronization of Limit Cycles
Hans Christiansen and Jens Paaske
It is well known from classical physics that weakly coupled self-sustained oscillators may spontaneously lock their phases. Just like classical synchronization is known to break down due to noise induced phase slips, we show here how the synchronization of continuous variable
quantum systems breaks down by proliferation of
quantum phase slips. Within a Keldysh path integral formulation of limit cycles, we analyze the phase dynamics and show how, in spite of strong phase correlations,
quantum phase slips degrade the actual phase locking. This approach also allows us to address non-Markovian effects on the synchronization of limit cycles, which we illustrate explicitly for superconducting resonators coupled via a voltage biased double
quantum dot.
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Quantum Physics
Improved sample complexity bound for sample-based Lindbladian simulation
Siheon Park, Youngjin Seo, Byeongseon Go et al. (+3 more)
We establish improved sample-complexity bounds for sample-based Lindbladian simulation based on the Wave
Matrix Lindbladization (WML)
algorithm. For a jump operator $L$ with dimension $d$, we derive an explicit non-asymptotic sample complexity bound $n_d^*(t,\varepsilon) \le \left( \frac{2d+3}{8} \right) \|L\|_\infty^2 \left( \frac{t^2}{\varepsilon} \right)$, holding for simulation time $t$ and error $\varepsilon$. This refines the dimension dependence of the best previously known bound, $O(d^2 t^2/\varepsilon)$, from [Go et al.,
Quantum Sci. Tech. 10, 045058 (2025)]. Remarkably, we show that this dimensional overhead can be entirely avoided when $\| L\|_\infty^2 = O(1/d)$, a condition satisfied with high probability for random Lindblad operators, yielding a typical-case sample complexity of $O(t^2/\varepsilon)$. On the other hand, in the worst case, we show that WML necessarily requires $\Omega(dt^2/\varepsilon)$ samples by constructing an explicit example with a rank-one Lindblad operator. Our results reveal a sharp dichotomy between typical and
adversarial sample complexities in Lindbladian simulation, thereby strengthening the theoretical foundations of sample-based
quantum algorithms.
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All authors Siheon Park, Youngjin Seo, Byeongseon Go, Dhrumil Patel, Mark M. Wilde, Hyukjoon Kwon
Quantum Physics
Quantum Synchronization of Fock States
Fabian Hassler, David Scheer, Samah Saquaque et al. (+1 more)
Synchronization, a ubiquitous phenomenon in classical systems, has recently been extended to the
quantum domain. Here, we show
quantum synchronization of a bosonic mode exhibiting a Fock state-like limit cycle, manifesting as a steady state with a negative Wigner function. We demonstrate that this non-classical state can be phase-locked to an external drive, achieving synchronization within an Arnold tongue regime. We argue that synchronization is a dynamical property and fundamentally tied to the suppression of phase slips, which we show to occur with exponentially decreasing probability. We introduce a novel method to extract the phase slip rate from the Lindblad time
evolution of the system. This work opens new avenues for understanding and manipulating non-classical synchronization dynamics.
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All authors Fabian Hassler, David Scheer, Samah Saquaque, Steven Kim
Quantum Physics · Cross-listed from nucl-th
Chandan Sarma and Paul Stevenson
In this work, we compare three
qubit-mapping strategies to study the structure of the
nuclear ground state within the shell model description employing the Variational
Quantum Eigensolver (VQE) approach. Although the initial point for different mappings is a
Hamiltonian matrix in many-body particle basis or Slater determinant (SD) basis, the structure of the trial wavefunction and resource counts are different for each mapping. These three mappings are tested for a mid $p$-shell
nucleus $^{10}$B and compared the
quantum resources required to find the ground state for each mapping. Further, we extend the
qubit-efficient mapping to study the ground state of one more mid $p$-shell
nucleus $^{12}$C. We run
circuits up to 26-
qubits representing their ground states on a noisy simulator (IBM's FakeFez backend) and
quantum hardware ($ibm\_fez$). The best post-error mitigated results from the hardware for $^{10}$B ground state is obtained following SD to
qubit mapping with a percent error of 0.21 %. The percent errors for the same state following cSD and pnSD mapping are 3.37 and 8.88 %, respectively. On the other hand, following the cSD mapping, the post-error mitigated ground state energy of $^{12}$C is 6.82 % away from the exact result. We further evaluate the fidelity of the VQE wavefunctions obtained from hardware with respect to the shell model wavefunctions for the cSD mapping. This cSD mapping can be useful for scaling the VQE
algorithm for complex
nuclei across different mass regions in terms of
qubit efficiency.
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Quantum Physics
Quantum optimization beyond QUBO for industrial logistics and scheduling
Juan F. R. Hernandez, Pavle Nikacevic, Enrique Solano et al. (+4 more)
The increasing complexity of industrial scheduling and transport routing problems motivates the study of alternative optimization formulations and computational paradigms. In this work, we study how higher-order unconstrained binary optimization (HUBO) formulations of such problems map onto
quantum optimization workflows in both noisy and fault-tolerant regimes. We consider three representative logistics and manufacturing use cases and formulate each as a HUBO problem. This captures process intricacies, such as highly correlated assembly-line scheduling rules, which are difficult to express faithfully with the standard quadratic (QUBO) form, while at the same time reducing the number of binary variables required in the
quantum mapping, thus lowering
qubit demand. We compare the HUBO formulations with corresponding QUBO encodings, highlighting a key trade-off: while HUBO reduces
qubit requirements through compact binary encoding, it introduces higher-order interaction terms that increase
circuit depth, limiting feasibility on current
quantum hardware. The proposed formulations are validated using classical solvers across several problem instances and
benchmark small routing problem instances using bias-field digitized counterdiabatic
quantum optimization in classical simulation. We complement these results with a resource and scalability analysis, focusing on the capacitated vehicle routing problem as a representative large-scale industrial use case. Our analysis indicates that while HUBO formulations offer advantages in
qubit scaling compared to QUBO encodings, their practical implementation is constrained by gate fidelity, coherence, and
circuit depth, making hybrid
quantum-classical workflows and early fault-tolerant
quantum hardware the most plausible settings for their practical use.
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All authors Juan F. R. Hernandez, Pavle Nikacevic, Enrique Solano, Chinonso Onah, Agneev Guin, Arne-Christian Voigt, Archismita Dalal
Quantum Physics
Indefinite Causal Order Reverses the Real-Complex Hierarchy
Jacopo Surace, Shintaro Minagawa and Ravi Kunjwal
[Note added after submission. After posting the first version of this preprint and corresponding with Ved Kunte and Kuntal Sengupta, we identified an issue with the claimed separation between real
quantum theory and ordinary complex
quantum theory in the process-
matrix framework. This version imposes normalization only for local CPTP maps acting on the parties' process input-output systems, which we call N1. A stronger compositional requirement is to impose normalization also after arbitrary shared ancillary systems are introduced and each party acts jointly on its process system and local share of the ancilla, which we call N2. Under N2, the process
matrix used in this version to separate RQT from QT is not valid, and the claimed RQT/QT separation is therefore not established. We are preparing a revised version that clarifies this distinction and revises the affected claims. This temporary update is intended to alert readers to this issue while we work on revising the manuscript.]
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Quantum Physics
Non-Abelian Mixer for QAOA on Hybrid Oscillator-Qubit Quantum Processors
Thinh Le, Hansika Weerasena and Jianqing Liu
The realization of universal control in hybrid oscillator-
qubit quantum processors enables the systematic design and implementation of
quantum algorithms. However, the algorithmic development for such platforms remains at an early stage. While the
Quantum Approximate Optimization
Algorithm (QAOA) has been extensively studied in both continuous-variable (CV) and discrete-variable (DV)
quantum systems, its development in the hybrid CV-DV setting remains limited. In this paper, we propose a hardware-native non-Abelian mixer for QAOA on hybrid CV-DV
quantum processors and develop a corresponding hybrid ansatz for the Max-Cut problem. We evaluate the proposed ansatz on unweighted Erdős-Rényi graphs and
benchmark it against the standard transverse-field mixer using the approximation ratio and optimal-solution probability. Across all graph sizes and Fock cutoffs in our simulations, the proposed non-Abelian mixer consistently improves both expected solution quality and the probability of sampling an optimal solution relative to the transverse-field mixer. These results indicate that the proposed non-Abelian mixer is a promising building block for QAOA on hybrid oscillator-
qubit platforms.
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Quantum Physics
Heralded ultrafast generation of macroscopic quantum states in matter with bright squeezed vacuum light
Shohei Imai
We show that bright squeezed
vacuum light, combined with a single-shot quadrature measurement of the post-interaction light, enables the ultrafast generation of macroscopic
quantum states in matter. Although in the weak-coupling regime multiphoton
quantum light leaves the unconditional matter state as a classical mixture due to light–matter
entanglement, quadrature-based heralding prepares the matter in a Gaussian-weighted
quantum superposition of
laser-driven matter states. For an ensemble of resonantly electric-dipole-coupled two-level systems, this heralding dynamics acts as a Gaussian filter with respect to the electric polarization, with brighter squeezed-
vacuum light accelerating the preparation of the zero-
eigenvalue Dicke state. Counter-rotating terms further drive a stroboscopic transition from this Dicke state to a cat-like state. Our results open a route to ultrafast engineering of macroscopic
quantum matter with strong-field
quantum light.
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Quantum Physics
Programmable Dissipation via Partial Quantum Error Correction
Sameer Dambal, Michael AD Taylor and Yu Zhang
Noise is typically treated as the adversary of
quantum information processing. For open
quantum dynamics, however, dissipation is part of the target physics, creating a tension with fault-tolerant architectures designed to suppress decoherence. Here we show that logical noise can instead be turned into a calibrated resource. We treat the error-correction cycle as a programmable primitive: one fault-tolerant round induces a logical completely positive trace-preserving map, and decoder/recovery randomization generates a controllable family of logical channels whose convex mixtures realize Kraus-channel mixing. This enables direct compilation of target dissipators into effective logical dynamics without explicit ancilla
qubits for encoding the bath degree of freedoms. We derive an accuracy criterion for multi-step simulation in which the code distance is chosen so that uncontrolled logical errors remain a small fraction of the intended dissipation per step, rather than being driven below an arbitrarily small closed-system tolerance. Partial
quantum error correction thus repurposes fault-tolerant structure to sculpt dissipation, offering a resource-efficient route to
quantum simulation of open
quantum systems.
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Quantum Physics
Tunneling phase diagram: A machine-learning framework for multidimensional kinetic isotope effects
Xinrui Yang and Zhigang Wang
The kinetic isotope effect (KIE) is the conventional probe for
quantum tunneling, yet its composite nature conflates tunneling with zero-point energy and classical kinetics. Here, we introduce the tunneling phase diagram, a machine-learning framework that decouples true tunneling strength by decoding the nonlinear relationship between KIE and the tunneling factor (ąppa}). With exceptional fidelity (R^2 > 0.98, RMSE = 0.21), this framework reveals an anomalous high KIE-low ąppa} spanning 300-600 K, thereby defining a paradigm for the quantitative assessment of
quantum tunneling.
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