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Physics Condensed Matter

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Monday 13 July

Statistical Mechanics

A Fokker-Planck approach to a stochastic multiplicative wealth model with taxation and redistribution

We develop a Fokker-Planck description of the dynamics of wealth distribution in a stochastic multiplicative economic growth model with taxation and redistribution, as introduced by P.M.C. de Oliveira. Extending the original formulation, our theoretical framework includes general redistribution protocols, encompassing a broad class of state-dependent transfer mechanisms. As a particular case, we investigate a two-state protocol designed to emulate conditional cash transfer programs. Analytical expressions for the stationary wealth distributions are derived, revealing how the interplay between multiplicative noise, taxation, and redistribution shapes the emergence of inequality. The theoretical results are corroborated by agent-based simulations. To quantify and compare the impact of the different protocols, we employ the Gini index as a measure of inequality. Our analysis highlights how specific nonuniform redistribution schemes can significantly mitigate wealth disparities.
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Materials Science

Exchange topology and criticality in ferrite and chromium spinels: a unified Monte Carlo analysis

We report a unified analysis of Metropolis Monte Carlo results for two families of magnetic spinels: inverse ferrites Fe$^{3+}_{A}$[M$^{2+}$Fe$^{3+}$]$_{B}$O$_4$ (M = Co, Cu, Fe, Ni), where superexchange couples two chemically distinct sublattices, and chromium spinels $A$Cr$_2X_4$ ($A$ = Zn, Cd, Hg, $X$ = S, Se) together with the breathing-lattice chromates Li$M$Cr$_4$O$_8$ ($M$ = Ga, In), where a single Cr$^{3+}$ species occupies a corner-sharing tetrahedral network. Placing the exchange constants, transition temperatures, critical exponents, hysteresis, and magnetocaloric responses of these systems on a common footing, we introduce two reduced quantities not previously reported: the ratio $\theta_{\mathrm{CW}}/T_C$ for the ferrites and the normalized ordering scale $t^{*}=k_BT_C/[J_1S(S+1)]$ for the chromium compounds. The ferrites cluster in the range $\theta_{\mathrm{CW}}/T_C = 0.94$-$1.19$, close to the mean-field expectation of unity and the signature of dominant, unfrustrated A-B superexchange, and their exponents ($\beta = 0.20$-$0.26$, $\gamma = 1.23$-$1.27$, $\delta = 4.76$-$4.78$) follow the three-dimensional Ising class. The chromium systems split into three regimes: $t^{*} \approx 1.4$-$1.9$ for Ising-treated sulfides, $t^{*} \approx 0.99$ for Heisenberg-treated selenides, and $t^{*} \approx 0.24$-$0.25$ for the antiferromagnetic breathing chromates, quantifying the combined suppression of $T_C$ by continuous spin symmetry and by geometric frustration. Finite-thickness simulations of Fe$_3$O$_4$ resolve a dimensionality crossover between two and four unit cells. We identify the Ising-versus-Heisenberg dependence of the predicted universality class in frustrated chromites as the principal open problem.
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All authors Keltoum Khallouq, Ayoub El Maazouzi, Kamal Boumhara, Rachid Masrour

Mesoscale and Nanoscale Physics

High-field Josephson effect enabled by a moiré Hofstadter spectrum

Magnetic fields generally suppress phase-coherent Josephson transport, limiting superconducting interferometry to relatively low fields. Here we show that moiré-engineered graphene Josephson junctions can overcome this constraint. Using ballistic graphene/hBN junctions, we establish phase-coherent Andreev transport through Fabry-Pérot oscillations and Fraunhofer interference that persist across both the primary Dirac cone and reconstructed moiré minibands. We then demonstrate phase-coherent Josephson interference up to 6 T in the fractal Hofstadter-butterfly regime, well beyond the range expected for conventional ballistic graphene junctions. Comparison with Hofstadter-spectrum calculations reveals that superconductivity survives where the moiré potential transforms Landau levels with quenched group velocity into dispersive magnetic Bloch bands with finite quasiparticle group velocity, enabling extended electron-hole Andreev trajectories across the junction. Our results show that Hofstadter minibands can stabilize phase-coherent superconductivity deep into the parameter domain conventionally associated with the quantum Hall regime, establishing a new platform for high-field superconducting interferometry.
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All authors A. Díez-Carlón, M. Cárdenes Wuttig, N. Wei, D. Ivanov, P. Altpeter, P. Hakonen, K. Watanabe, T. Taniguchi, L. I. Glazman, D. K. Efetov

Materials Science · Cross-listed from cs.LG

CatRetriever: Contrastive Representation Learning for Slab-to-Bulk Retrieval in Generative Catalyst Discovery

Inverse design is an emerging data-driven paradigm for efficiently navigating vast chemical spaces to discover new materials with targeted properties, and in the context of heterogeneous catalysis, surface generative models have recently advanced this goal by directly generating catalyst surface-adsorbate structures. However, these models typically operate at the slab level and do not provide the corresponding parent bulk structure, making it difficult to assess bulk-dependent properties such as formation energy, surface energy, crystallographic symmetry, and synthesizability. Here, we address this missing slab-to-bulk connection as a retrieval problem and introduce CatRetriever, a contrastive representation learning model that aligns slab and bulk crystal representations in a shared latent space. From a slab query, CatRetriever accurately retrieves plausible parent bulk candidates with R@1 > 91% and R@3 > 98% on both the in-distribution and holdout evaluation sets. We further extend the CatRetriever framework into an adsorption energy targeted bulk discovery pipeline that combines bulk retrieval, generative search space expansion, and adsorption energy distribution analysis. This workflow evaluates candidates by both structural compatibility with the query slab and their ability to access the target adsorption energy range across diverse surface environments. CatRetriever therefore provides a scalable route for connecting catalyst generative models with physically plausible and adsorption energy compatible bulk catalyst discovery.
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All authors Jungho Oh, Woosung Kim, Dong Hyeon Mok, Jonggeol Na, Seoin Back

Materials Science · Cross-listed from physics.chem-ph

Correlation-consistent Gaussian basis sets for copper solids from material-constrained atomic optimization

Correlation-consistent Gaussian basis sets are central to systematic molecular quantum chemistry, but their direct use in periodic solids is often limited by severe linear dependence from diffuse atomically optimized primitives. This problem is particularly acute for metallic and metal-containing systems, where reliable complete-basis-set (CBS) extrapolation is needed for correlated-wavefunction benchmarks. We introduce material-constrained atomic optimization (MCAO), a basis-set optimization framework that preserves the atomic and correlation-consistent character of Gaussian basis sets while penalizing large overlap-matrix condition numbers in representative solids. As a proof of concept, we generate Dunning-style MCAO-cc-pVXZ basis sets (X = D, T, Q) for Cu with all-electron, scalar-relativistic all-electron, effective core potential (ECP), and pseudopotential treatments. The resulting basis sets remain numerically stable for Cu solids and surfaces while reproducing molecular Cu dimer energetics and plane-wave reference properties of bulk Cu. CBS-extrapolated random-phase approximation calculations further enable a controlled assessment of pseudopotential, relativistic, and basis-set errors in bulk Cu and CO adsorption on Cu(111), providing scalar-relativistic all-electron Gaussian-basis benchmarks for the CO adsorption puzzle.
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All authors Jincheng Yu, Xiaoyu Zhang, Min-Ye Zhang, Yu Cao, Qiming Sun, Hong-Zhou Ye

Mesoscale and Nanoscale Physics

Thermodynamic bound on the Fano factor of a coherent thermoelectric heat engine

We show that for fermionic coherent thermoelectric transport, selecting heat-engine operation yields a thermodynamic uncertainty relation for the charge current that imposes a universal lower limit of $F > 1/2$ on the corresponding Fano factor. We find that violations of the thermodynamic uncertainty relation for classical Markov processes, typically associated with a quantum advantage, are far more restricted for heat engines than what is allowed by a generic thermodynamic process. For bosonic and classical carriers, the minimum Fano factor increases to $F > 1$, and the thermodynamic uncertainty relation for classical Markov processes is never violated. We provide numerical evidence that all the obtained bounds are tight and can be saturated by properly designed transmissions.
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Strongly Correlated Electrons

Electronic tuning of the soft-phonon transport anomaly in Ta$_2$Ni(S$_x$Se$_{1-x}$)$_5$

Ta$_2$NiSe$_5$ continues to be investigated for its phase transition at $T_\textrm{c}$ = 326 K, where it develops both an electronic gap and a distortion of its Ta/Ni chains. One intriguing feature at $T_\textrm{c}$ seen in thermal transport is the giant anisotropic scattering of phonons moving perpendicular to the chains, which is apparently associated with the softening of a transverse acoustic phonon, but whose microscopic origin and significance demand clarification. By tuning the normal-state band overlap/gap with S substitution, we uncover a close connection between this soft-phonon transport anomaly and underlying electronic instabilities: When Ta$_2$Ni(S$_x$Se$_{1-x}$)$_5$ approaches a band insulator at high $x$, and signatures of the electronic transition are suppressed, the soft-phonon transport anomaly concomitantly vanishes. Our results establish the following picture for the Ta$_2$Ni(S$_x$Se$_{1-x}$)$_5$ family: Near the S end, a sole lattice instability gives rise to a weak structural transition with $T_\textrm{c}$ approaching 130 K. Near the Se end, additional electronic instabilities boost $T_\textrm{c}$ up to 326 K and amplify experimental signatures of the transition. The strong interaction between electrons, holes, and the lattice is manifested as a soft-phonon transport anomaly accompanied by electronic fluctuations, which include excitonic and hybridization-gap fluctuations.
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All authors Yuan-Shan Zhang, Masahiko Isobe, Hidenori Takagi, Dennis Huang

Statistical Mechanics

Still life in a classic Blume-Capel model: pseudo-transitions in a spin-1 diamond chain

We exactly investigate the ground-state, magnetic, and thermodynamic properties of a spin-1 Blume-Capel diamond chain in a magnetic field by means of the transfer-matrix method. After establishing the complete ground-state phase diagram and characterizing each ground-state spin configuration, we examine the finite-temperature behavior in the vicinity of selected phase boundaries and triple points. It is demonstrated that an extremely small energy gap between a nondegenerate ground state and competing macroscopically degenerate low-lying excited states gives rise to entropically-driven pseudo-transitions. These pseudo-transitions manifest themselves through abrupt but continuous changes in the magnetization and entropy resembling discontinuous jumps, while the magnetic susceptibility and specific heat exhibit exceptionally sharp yet finite peaks resembling divergences. Our results provide the exact evidence that pseudo-transitions can also emerge in the classical spin-1 Blume-Capel model and thereby extend the class of one-dimensional spin systems known to display pseudo-transitions.
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Disordered Systems and Neural Networks

Emergent quantum chaos from correlations on a random graph

This work demonstrates that sparse long-range random bonds on a one-dimensional lattice alone can generate quantum-chaotic spectral correlations and also drive a localization transition in a noninteracting single-particle Hamiltonian. The model is a one-dimensional ring in which each pair of sites is connected independently with a probability $p_{ij}= d_{ij}^{-(1+\sigma)}$. Each bond carries identical unit hopping and on-site disorder is absent. Despite the absence of on-site disorder and interaction, the model displays quantum chaotic spectra with Gaussian orthogonal ensemble (GOE) level statistics at small $\sigma$ and localized eigenstates with Poisson statistics at larger $\sigma$. The transition occurs in the range $ 0.80 \lesssim \sigma_c \lesssim 0.85$, far above the summability threshold of the mean hopping profile ($\sigma=0$). A Gaussian field theory retaining only the mean and variance of the Bernoulli bonds instead predicts a threshold at $\sigma=1$, suggesting that higher cumulants are infrared-relevant. Our findings hint towards a universality class that is distinct from both the power-law random banded matrix model and the standard Anderson transition.
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All authors Mrinal Sarkar, Valerio Pagni, Tilman Enss, Nicolò Defenu

Statistical Mechanics

Thermal phase transitions in a mixed-spin Ising model on the Lieb lattice: Exact results beyond zero magnetic field

We investigate the ground-state and finite-temperature properties of a mixed spin-1/2 and spin-1 Ising model on a decorated square (Lieb) lattice incorporating a uniaxial single-ion anisotropy and magnetic field. By employing the generalized decoration-iteration transformation, the model is mapped exactly onto an effective spin-1/2 Ising model on the square lattice characterized by an effective nearest-neighbor interaction and an effective field. The studied model consequently becomes exactly solvable even for finite values of the applied magnetic field whenever the effective field vanishes. The ground-state analysis reveals three distinct phases: ferrimagnetic phase (FRI), disordered phase (DP), and ferromagnetic (FM) phase. The ground-state boundary between FRI and DP phases gives rise to a dome-shaped surface of discontinuous thermal phase transitions, which is terminated by a line of Ising-type critical points associated with continuous thermal phase transitions. Both continuous and discontinuous thermal phase transitions belong to the exactly solvable parameter regime defined by a vanishing effective field in spite of the fact that the applied magnetic field is finite. Two consecutive discontinuous thermally-induced reentrant phase transitions DP-FRI-DP are identified in a narrow parameter region. The exact analytical predictions including reentrance, field- and thermally-driven phase transitions are independently verified by classical Monte Carlo simulations.
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Soft Condensed Matter

How do 3M Command strips work? A fracture mechanics approach

Removable adhesive systems such as 3M Command strips are designed to support substantial loads while allowing clean, damage-free removal from the substrate. These systems rely on a highly extensible adhesive strip that bonds strongly during use but releases when stretched, causing the adhesive layer to elongate and progressively debond from the surfaces. A central challenge in the design of stretch-release adhesives is therefore to maximize load-bearing capacity while minimizing the force required for removal. This study investigates the finite-deformation mechanics governing both load support and tape release in a hyperelastic stretch-release adhesive system, with particular focus on the 3M Command tape geometry. Explicit analytical expressions are derived for the energy release rate of interfacial cracks under both load-bearing and release conditions and are validated against $J$-integral evaluations from finite element simulations. The results show that the ratio of maximum supported load to release force scales linearly with the ratio of bonded length to adhesive thickness, which is typically very large. We also investigate geometry-driven alternating crack propagation between the backing and substrate interfaces, governing tape removal, by analytical solutions and simulations. Parametric studies of competing interfacial fracture toughnesses produce failure envelopes that provide a predictive framework for estimating release forces and unstable crack propagation in multilayer stretch-release adhesive systems.
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Mesoscale and Nanoscale Physics

Anomalous Dissipation in Current Biased Josephson Systems

A new phase diffusive regime in a current biased Josephson junction is theoretically explored which originates from embedding the junction in a circuit environment with anomalous dissipation. This is realized by placing parallel to the junction a resistor in series with a capacitor such that electromagnetic fluctuations effectively couple also to the charge of the junction. This leads to rich Josephson dynamics, in particular for the switching of the junction out of a zero voltage state. Modelled as the escape process of a fictitious phase-particle out of a metastable well, a detailed study reveals that anomalous dissipation has a strong impact at low temperatures when quantum tunneling dominates against thermal activation. As a manifestation, a regime is found, where for realistic circuit parameters the quantum escape process is substantially enhanced, followed by a short voltage pulse and re-trapping with high probability. This class of circuits may be leveraged for detecting microwave photons or dissipative quantum annealing processes. In addition, the analysis provides a general framework for engineering dissipative dynamics in nonlinear systems using anomalous environments.
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All authors Johannes Hauff, Niklas Gaiser, Joachim Ankerhold, Dominik Maile

Soft Condensed Matter

Photoconductive nonpolar liquids based on azobenzene

The weakly conductive properties of mixtures of organic surfactants in nonpolar liquids are fundamental to many electrohydrodynamic phenomena and underpin several cutting-edge technologies, particularly the development of electrophoretic displays. To date, tuning the electrical properties of these systems has involved modifying their composition, including surfactant type and concentration, water content, and the carrier liquid, all of which influence their behavior. Here, we use photoresponsive molecules to control electric phenomena in nonpolar liquids externally with light irradiation, thereby rendering them photoconductive. In particular, we examine azobenzene solutions in toluene, whose conductivity can be adjusted by two colors of light: UV induces trans to cis isomerization, leading to an increase in conductivity, while blue light triggers cis to trans back-isomerization, decreasing conductivity. The findings of this study suggest new ways to expand the applications of weakly conductive organic fluids, such as in self-regulating devices that respond to sunlight or in externally programmable displays.
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All authors Carlo Rigoni, Promeet K. Saha, Jinyu Sheng, Rafal Klajn

Soft Condensed Matter

Hygroscopic hysteresis drives intermittent salt creeping

Salt creeping – the precipitation of salt crystals away from an evaporating liquid interface along surrounding surfaces – occurs across settings from geology and cultural-heritage weathering to inkjet printing and carbon sequestration. Yet why its dynamics are sometimes smooth and sometimes violently intermittent has remained unexplained. Here we investigate the confined evaporation of salt solutions from a capillary with unidirectional water loss and show that salt creeping is an intrinsically intermittent, out-of-equilibrium process. By systematically varying the initial salt concentration and the ambient relative humidity, we identify regimes in which crystal deposition on the outer capillary surface goes hand in hand with non-monotonic, intermittent dynamics. Time-resolved measurements reveal that these intermittent dynamics are sustained by episodic water imbibition into the growing salt structures on the outer surface of the capillary, which sets up a self-amplifying feedback between evaporation and crystallization. Combining experiments with a minimal theoretical model, we demonstrate that hysteresis between deliquescence and efflorescence concentrations is sufficient to generate oscillatory salt accumulation and intermittent dynamics. Hygroscopic hysteresis, in other words, is the switch that turns steady evaporation into intermittent creeping. Our results recast salt creeping as a relaxation oscillator, and point to the hysteretic phase change as a generic route to intermittency in evaporating multicomponent fluids.
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All authors Javier Rodríguez-Rodríguez, Manikuntala Mukhopadhyay, Lijun Thayyil Raju, Detlef Lohse, Jasper van der Gucht, Uddalok Sen

Statistical Mechanics · Cross-listed from quant-ph

Classical probabilistic realisation of quantum double-slit interference

We demonstrate how the interference effects for a quantum particle in the double-slit experiment can be described by classical probabilities. We investigate a classical field theory for a complex scalar field with probabilistic initial conditions. A central element are conserved charges leading to the concept of particles. These are statistical observables which describe properties of the probability distribution for field configurations. The conserved charges define subsystems for particle excitations of a vacuum state. The classical probability distribution for the one-particle subsystem can be expressed in terms of a complex wave function. The Liouville equation for the classical probability distribution implies that the time evolution of this wave function obeys the Schrödinger equation for a quantum particle in a potential. The potential arises from space-dependent external fields in the otherwise relativistic classical field theory. It can be chosen arbitrarily, realizing the typical quantum effects of interference, tunneling or discrete energy spectra.
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Mesoscale and Nanoscale Physics

Discovery of a symmetry-driven electronic cascade in a $d$-wave altermagnet

Altermagnets host magnetic compensation together with non-relativistic spin-split bands, a coexistence enabled by crystal symmetry. Yet whether and how crystal symmetry organizes collective electronic order remains largely unexplored. Here we uncover a symmetry-driven cascade of finite-$q$ charge order in a $d$-wave altermagnet Rb$_{1-{\delta}}$V$_2$Te$_2$O, using phase-resolved scanning tunneling microscopy. A primary density-wave instability drives an initial electronic reconstruction, followed by the emergence of a nematic component and an off-axis modulation with wave vectors geometrically tied to the preceding orders. Phase-resolved spectroscopy distinguishes these components through separate contrast-inversion energies and maps out branch-selective spectral-weight redistribution within the off-axis mode. Together with doping and temperature evolution, these observations establish a highly coordinated hierarchy of coupled density-wave instabilities, consistent with successive symmetry lowering. This multi-component hierarchy can be well described in the Landau framework through sequential softening of the charge orders, where bilinear coupling to their compatible octupolar partners at the lower-symmetry stages enables mutual stabilization within an intertwined charge-multipole state. Such a transparent realization of a charge-order cascade shows how altermagnetic symmetry can extend beyond band formation to organize collective electronic order, offering a new perspective on emergent many-body states in correlated quantum materials.
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All authors Zhouyi Yin, Zheng Shi, Shuxuan Zhang, Changchao Liu, Xingkai Cheng, Fayuan Zhang, Han-Bin Deng, Jia-Xin Yin, Chaoyu Chen, Guang-Han Cao, Junwei Liu, Yue Zhao

Mesoscale and Nanoscale Physics

Robust Spin Qubit Coupler via Minimal Kitaev Chain

While a minimal Kitaev chain is promised to host unprotected Majorana zero modes, its role for spin qubits is relatively underappreciated. Following recent breakthroughs in the fine control of transport behaviors, we propose to use minimal Kitaev chain as a robust coupling module between spin qubits. Long-distance, anisotropic exchange coupling can be mediated by the Andreev bound states (ABSs) in the hybrid segment. The chemical potential of ABS gives a simple way to selectively control the coupling strength and its response to local perturbations. Moreover, this additional control degree of freedom creates a unique sweet spot, allowing both strong coupling and first-order immunity against charge noise. The protected qubit encoded on the minimal Kitaev chain at the sweet spot is shown to boast over 200 fold improvement in decoherence time.
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Materials Science

Synthesis of Ti2B2Clx MBenes in molten salts from theoretical and experimental perspectives

The unique properties and application possibilities of two-dimensional (2D) materials motivates the exploration of different nanolaminated compounds. Here, by using a molten salt approach, we selectively etch Ti2InB2 with ZnCl2 to produce a multilayer (ml) Ti2B2Clx MBene. Scanning transmission electron microscopy, in combination with energy dispersive X-ray, and electron energy loss spectroscopies show that In atoms are completely removed from the precursor upon etching, being replaced by chlorine surface terminations with a coverage 1.1 < x < 1.4. Further, in situ X-ray diffraction indicates a direct biphasic transformation from Ti2InB2 to ml-MBene, with no signs of intermediate phase formation. A computational framework based on density functional theory further corroborates these experimental observations by showing a negative reaction free energy for the formation of ml-MBene, favourable over all competing processes. In addition, A-element substitution into to the 3D Ti2ZnB2 phase is predicted to be endergonic, consistent with the absence of experimental evidence for its formation. Initial Li-ion battery performance evaluation showed a stable discharge capacity similar or better than MAX phases and other borides. Altogether, the theoretical framework combined with materials synthesis and characterization provides a general approach for 2D materials development, for further expansion of the family of 2D materials.
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All authors Rodrigo M. Ronchi, Emile Defoy, Andrejs Petruhins, Justinas Palisaitis, Lianghao Yu, Lan Tang, Solenn Reguer, Dominique Thiaudière, Ningjun Chen, Durga Sankar Vavilapalli, David Portehault, Jonas Björk, Per O. Å. Persson, Johanna Rosen

Strongly Correlated Electrons

Stripe-Ordered Altermagnetism Emerging from Correlation-Driven Spin-Density-Wave Instability

Altermagnetism is conventionally identified within the paradigm of collinear antiferromagnets. Its potential realization within other spin instabilities, such as a spin-density wave (SDW), remains a fundamentally compelling open question. Here, we combine Hartree-Fock mean-field and unbiased determinant quantum Monte Carlo methods to investigate a minimal Hubbard model relevant to iron pnictides. We reveal a novel $d_{xy}$-wave stripe-ordered altermagnetic (SOAM) insulating phase driven fundamentally by the correlation-induced $(\pi,0)$ SDW instability. Within this phase, an introduced uniaxial staggered electric potential alters the underlying symmetry: it breaks the original combined time-reversal and spatial translation symmetry ($T_{d}\mathcal{T}$) and retains a combined time-reversal and mirror invariance ($M\mathcal{T}$), thereby unlocking the pronounced nonrelativistic spin splitting. Crucially, the exact finite-size scaling from our determinant quantum Monte Carlo simulations confirms that this correlation-driven SOAM phase stably survives at accessible finite temperatures. Our study pushes the frontier of altermagnetism beyond the conventional antiferromagnetic paradigm into the realm of SDW instability, advancing the fundamental understanding of altermagnetism in strongly correlated electron systems.
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Statistical Mechanics

Harnessing finite-size effects to gauge aging in the $2D$ Ising model

The relaxation behavior towards equilibrium of the $2D$ Ising model with nearest-neighbor interactions has been studied with focus on the two-time autocorrelator $C(t,s)$. Finite-size effects affecting the growing magnetic domains lead to the saturation of $C(t,s)$ with a distinct plateau of height $C_{\infty}^{(2)}(s,L)$ scaling algebraically with waiting time $s$ and lattice size $L$. These scaling relations are used to produce precise estimates for the autocorrelation exponent $\lambda$ and dynamical exponent $z$ with deliberately small lattices. Treating smooth domain walls in a similar manner to the lattice boundaries, their effect on $C(t,s)$ can be understood as premature finite-size phenomenon, extending our ansatz to systems not yet in equilibrium.
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Mesoscale and Nanoscale Physics · Cross-listed from physics.optics

NaBiF$_4$: Er$^{3+}$, Yb$^{3+}$ upconversion particle as a multi-functional bio-marker

Lanthanide-doped upconversion particles (UCPs) have revolutionized optical bioimaging platforms because of their excellent photostability, non-toxicity, and utilization of near-infrared excitation, which facilitates deep tissue penetration with negligible autofluorescence. However, it remains a challenge to achieve high-contrast and sub-diffraction imaging in noisy biological media, without using a high-power laser. Here, we report various protocols applied to bismuth-doped UCPs address some of these challenges. Compared to the photoluminescence (PL) emission of the regular Yttrium doped UCPs, we observe a three-fold increment in the quantum yield of the overall emission of bismuth-UCPs, and a four-fold increment, specifically, in red emission. Leveraging this advantage, we devise a protocol employing two infrared wavelengths, 975 nm and 1064 nm, to selectively control the PL emission. Interestingly, our results reveal two distinct regimes in which PL can be systematically quenched or enhanced, by adjusting the 975 nm laser power. We model the overall dynamics as a simplified stimulated emission depletion process involving three energy levels. In addition, the particle has a thickness under sub-diffraction, shows optical trapping ability, and potential of surface functionalization to enable specific conjugation with diverse biospecimens. These studies establish bismuth doped UCPs as an excellent candidate in accomplishing advanced biomarker operating with enhanced signal-to-noise ratio and sub-diffraction imaging capabilities.
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All authors Atanu Ghosh, Krishna Kumari Swain, Agniva Das, Mrutyunjaya Rath, Snigdhadev Chakraborty, Bipeen Kumar, Yamini Selvam, Siddharth Dhomkar, Basudev Roy

Materials Science

Capturing the calendering U-shape in lithium-ion electrode thermal conductivity

Calendering is a key manufacturing step in lithium-ion electrode production, increasing volumetric energy density by reducing electrode porosity. Its effect on through-plane effective thermal conductivity, however, can be non-monotonic: measurements of graphite-based anodes show an initial decrease in thermal conductivity during early calendering followed by recovery at higher compaction. Conventional porosity-based effective-medium closures cannot reproduce this U-shaped behaviour. We develop a calendering-aware extension of the Zehner–Bauer–Schlünder model that combines a Knudsen-corrected porous-medium baseline with a compression-indexed contact contribution. For graphite electrodes, the model represents the competing effects of increasing particle contact and calendering-induced reorientation of anisotropic graphite particles, which initially reduces favourable through-plane heat-transport pathways. For quasi-isotropic NMC cathodes, the observed response is instead captured through process-dependent contact-network evolution. Across 27 calendering states spanning thin and thick graphite anodes and NMC622 and NMC811 cathodes, the proposed closure reduces the mean absolute percentage error from 31.1% for the zero-fit reference model to 4.5%. The result shows that incorporating process-dependent microstructural evolution is necessary to capture the measured conductivity minimum. Validation across additional electrode formulations, thicknesses, and chemistries remains necessary to assess transferability.
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Superconductivity

Microscopic equivalence of the vortex-entry current and the depairing current in a superconducting thin-film strip

The vortex-entry current density $J_{\rm v}$ of a superconducting strip is usually defined, within phenomenological Pearl–London theory, as the current density at which the edge barrier for vortex entry disappears. In that approach, $J_{\rm v}$ depends on a short-distance core cutoff introduced by hand, and its temperature dependence cannot be determined within the same framework. To remove this cutoff ambiguity and determine the temperature dependence, one needs a microscopic calculation of the vortex-entry current. Nevertheless, such a microscopic calculation has never been carried out. Here, we formulate and solve this problem for an ideal homogeneous dirty-limit superconducting thin-film strip at zero applied field, with self-field effects neglected. Vortex entry is treated as the loss of local stability of the vortex-free current-carrying state. The calculation uses the fixed-current Gibbs functional of Usadel theory, which is valid over the full temperature range $0<T<T_c$, and examines both spatially uniform and nonuniform perturbations. The microscopic calculation shows that the condition for disappearance of the vortex-entry barrier is identical to the depairing condition. The central result is not merely that two current densities have the same value. The criterion for disappearance of the vortex-entry barrier and the depairing criterion are not independent conditions. Both identify the same loss of local stability of the vortex-free current-carrying state, namely, the same spinodal. Consequently, $J_{\rm v}(T)=J_{\rm dp}(T)$ for all $0<T<T_c$. This result determines the temperature dependence of $J_{\rm v}$, removes the Pearl–London core-cutoff ambiguity, and establishes the microscopic equivalence of the vortex-entry and depairing current criteria.
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Disordered Systems and Neural Networks · Cross-listed from quant-ph

Quantum Simulation of Strongly Correlated Fermion-Phonon Models in Circuit QED

Gate-based digital quantum simulations offer an exciting new paradigm for studying the many-body physics of strongly correlated systems. In this context, electron-phonon models are challenging for qubit-only quantum simulators, as bosonic degrees of freedom require costly finite-dimensional encodings. Here, we elaborate on an alternative approach based on a digital-analog circuit QED architecture, where fermions are encoded in transmon qubits while bosons are represented directly by microwave resonators. The central building block of this framework is a qubit-resonator Rabi gate that emulates strong electron-phonon coupling and can be implemented through a sequence of resonant Jaynes-Cummings gates interleaved with layers of single-qubit rotations. Using this Rabi gate as the fundamental unitary operation, we construct quantum circuits for the Hubbard-Holstein and Yukawa-Sachdev-Ye-Kitaev models, which describe, respectively, strongly correlated electrons coupled to phonons and phonon-mediated interactions among Majorana fermions. We further demonstrate how nonclassical phonon physics and signatures of quantum chaos in these models can be probed through circuit simulations, and develop measurement and variational protocols tailored to near-term superconducting quantum hardware.
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All authors Tim Bode, Riccardo Roma, Stefan Schmitz, Alessandro Ciani, Dmitriy S. Shapiro, Dmitry Bagrets, Frank K. Wilhelm

Superconductivity · Cross-listed from quant-ph

States dressing analysis in a transmon-transmon-bus system

The multi-qubit gates fidelity of superconducting quantum processors can be limited due to the dressing of computational states by noncomputational ones. Here, we experimentally and analytically investigate a transmon-transmon-bus system where the computational states dressing is tunable over a broad range. We estimate the dressing using three methods: a full three-element model, an effective mode approach, and an unperturbed mode approach. The obtained results highlight the importance of the accurate estimation and control of the computational states dressing in order to optimize gates on superconducting platform.
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All authors P.A. Gladilovich, R.A. Migdisov, A.V. Sabluk, P.S. Burtsev, N.N. Abramov, N.Y. Rudenko, V.I. Chichkov, N.A. Maleeva

Mesoscale and Nanoscale Physics

Purcell enhanced and blinking free single photons from InAs/GaAs quantum dots in deterministically placed circular Bragg gratings

The development of efficient, deterministic, and tunable single-photon sources is a cornerstone for the realization of long-distance quantum communication, quantum repeaters, and photonic quantum computing technologies. In this study, we demonstrate a bright, charge-tunable single-photon source in the 900 nm wavelength range based on InAs quantum dots (QDs) embedded in a p-i-n doped GaAs membrane, which shows blinking free emission. We use a modified circular Bragg grating (CBG) as a micro-resonator. By adding fourfold symmetric bridges in a labyrinth-like geometry, we provide a conductive pathway to the central disk, thereby enabling electrical contact to the QD while maintaining high Purcell enhancement and photon extraction efficiency (PEE). For the negative trion (X-), we demonstrate a lifetime of $44.3 \pm 0.2$ ps - corresponding to a Purcell factor of $18.0 \pm 0.7$ and a PEE of $68.1% \pm 3.1$ %. Furthermore, the device is blinking-free with very low multi-photon contribution, evidenced by a second-order autocorrelation value $g(2)(0) < 0.017 \pm 0.015$. By applying a vertical diode bias, we demonstrate precise charge-state control, resolving distinct emission plateaus ranging from the single negatively charged trion ($X^-$) to triply negatively charged excitons ($X^{3-}$). These results showcase a robust architecture that simultaneously provides high efficiency, high repetition rates, and deterministic charge control, fulfilling key requirements for the next generation of quantum network hardware.
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All authors Peter Gschwandtner, Quirin Buchinger, Krishna Chand Maurya, Mohamed Helal, Barbara Souza Damasceno, Ravindra Kumar, Hyemin Kim, Ievgen Brytavskyi, Silke Kuhn, Arne Ludwig, Dirk Reuter, Yong-Hoon Cho, Tobias Huber-Loyola, Sven Höfling

Strongly Correlated Electrons

Fractionalized metals from doped anyons: Application to tMoTe2

A fluid of mobile anyons may arise naturally when a Fractional Quantum Anomalous Hall (FQAH) state is doped. Motivated by recent experiments on twisted $MoTe_2$, we study metallic phases obtained by doping the $\sigma_{xy} = 2e^2/3h$ state. We propose that the high-resistivity metal observed adjacent to this FQAH state is a $Z_3$ Orthogonal Metal: a non-Fermi liquid with sharp charge $1/3$ fermionic quasiparticles coupled to a discrete $Z_3$ gauge field but with no sharp electronic quasiparticle. For a dilute gas of three species of charge-$1/3$ anyons with $\pi/3$ statistics, we construct two $U(3)$ symmetric $Z_3$ Orthogonal Metals, distinguished by whether the gapless fermions transform as $SU(3)$ triplets or singlets. We show that these states naturally yield large electrical resistivities even when the fractionalized quasiparticles are in a good metallic regime. Pairing of the charge-$1/3$ fermions produces an ordinary charge-$2e$ superconductor, smoothly connected to a BCS state but obtained through an intrinsically fractionalized normal state. We discuss experimental signatures of the idea that the normal metallic state in the lightly doped $2/3$ state may have fractionalized charge carriers.
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Mesoscale and Nanoscale Physics

Theory of phonon-induced spin relaxation in a structured phononic reservoir

By combining Markovian and non-Markovian open quantum system theory with finite-element simulations, we develop a theory of electron spin relaxation in a structured phononic reservoir. This problem is crucial for understanding spin dynamics in hybrid systems involving mechanical modes, as well as for the design of devices combining spin degrees of freedom with photonic and phononic architectures, where the phonon density of states is modulated in the relevant spectral range corresponding to moderate magnetic fields. Taking a QD in a phononic waveguide as a representative and technologically relevant example, we show that spin relaxation in such environments is much more complex than in bulk. While the relaxation rates are several times to an order of magnitude higher than in bulk, there are parameter windows where the relaxation is suppressed by many orders of magnitude due to gaps in mode dispersion and selection rules imposed by mode symmetry. At the border between these two sectors, van Hove singularities in phonon dispersion lead to singularities in relaxation rates, for which we develop power-law scaling and develop a non-Markovian description of the dynamics, revealing polaronic dressing of the spin into slow acoustic modes.
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Soft Condensed Matter

Colloid recovery from porous structures under ambient flow: enhanced extraction via phoretic and osmotic mechanisms

Chemical gradients are widely employed to enhance particle transport in porous media, such as laundry detergency and enhanced oil recovery. Diffusiophoresis and diffusioosmosis refer to the movement of colloid and movement of near-surface fluid in response to electrolyte gradients, respectively. These mechanisms play a crucial role in colloid and drug transport in constricted regions where bulk transport is infeasible. Our earlier work [Tiwari et al., Langmuir 41, 18583 (2025)] has shown that phoretic and osmotic transport in dead-end micro-pores can be controlled by orienting salt gradients into or out of the pores; however, the extent to which this orientation influences large-scale spatiotemporal patterns and colloid extraction is not thoroughly explored. In this work, we study the phoretic and osmotic colloidal extraction from porous structure exposed to an ambient flow. We characterize the impact of solute gradient orientation, such as solute-out (i.e., solute-emitting porous media) and solute-in (i.e., solute-consuming media) modes. The two-dimensional porous structure is made of a number of pillars/fibers arranged in a lattice ordered hexagonal packing with equal spacing. The results from finite-element simulations show that phoretic colloidal extraction exhibits a qualitatively distinct behavior in the two modes: in the solute-out mode, colloids are extracted from the peripheral region of the porous structure, whereas in the solute-in mode, extraction predominantly occurs from the stagnant core. Diffusioosmotic slip on the internal surface of pillars/fibres further amplifies extraction in both modes, with a relatively larger enhancement in the solute-in mode due to internal spatiotemporal flow patterns. Beyond demonstrating the sensitivity of osmotic transport in porous media, these insights can guide enhanced membrane filtration, laundry detergency, and enhanced oil recovery.
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Mesoscale and Nanoscale Physics · Cross-listed from quant-ph

Tunable non-Hermitian skin effect and topological phases in ladders with staggered nonreciprocal inter-leg hopping

We investigate the non-Hermitian skin effect (NHSE) and topological phases in a ladder model with staggered nonreciprocal inter-leg hopping, consisting of an Su-Schrieffer-Heeger (SSH) chain coupled to a normal tight-binding chain. By tuning the system parameters, we show that the direction of the NHSE under open boundary conditions can be reversed and can even become energy dependent. The NHSE is further characterized by the spectral winding number under periodic boundary conditions. We further demonstrate that the inter-leg coupling significantly enlarges the topologically nontrivial parameter regime. Remarkably, the zero-energy topological edge modes reside on different legs of the ladder and are characterized by real-space winding numbers $W=\pm1$. Furthermore, increasing the nonreciprocity of the inter-leg hopping modifies the topological phase boundaries and eventually drives the system into a topologically trivial phase. Our results establish staggered nonreciprocal inter-leg hopping as an effective mechanism for engineering both the non-Hermitian skin effect and topological phases in ladder systems.
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