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Physics Condensed Matter

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Tuesday 24 March

Other Condensed Matter · Cross-listed from physics.optics

GHz control of THz QCL band structure and gain by standing acoustic strain

Active frequency comb generation and waveform control are central challenges in the terahertz (THz) domain. In THz quantum cascade lasers (QCLs), these functions have typically been achieved through active bias modulation, which alters the operating point of the device and imposes severe limitations on its flexibility. To address these challenges, we propose an approach based on the direct modulation of the QCL bandstructure using GHz-frequency standing bulk acoustic waves (BAWs), promising direct and localized control of the optical gain and chromatic dispersion. To this end, we fabricated a bulk acoustic transducer on top of a THz QCL in order to excite GHz standing BAWs within its active region. We demonstrate that radio-frequency driving of the transducer leads to the tunable generation of standing BAWs in 5-12 GHz frequency range with wavelengths commensurate to the QCL period length. The effect of the BAW on the QCL bandstructure is revealed by measuring photoluminescence (PL) of the active region, where the BAW strain leads to a considerable modulation of the PL energy up to a few meV around its non-modulated value. We also develop a model and perform bandstructure simulations to predict the effect of the BAW on the QCL subband structure and gain. These results mark the first demonstration of dynamic bandstructure modulation in a THz QCL using GHz acoustic strain, introducing a fundamentally new paradigm that establishes a powerful synergy between QCLs and BAWs towards coherent control and frequency comb engineering in the THz domain.
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All authors Alexander S. Kuznetsov, Valentino Pistore, Lutz Schrottke, Klaus Biermann, Xiang Lü

Strongly Correlated Electrons

Chemical and optical control of chiral-domain dynamics in 1T-TaS$_2$

Optical control of symmetry-breaking quantum phases is often constrained when one domain is strongly favored in equilibrium. This limitation is exemplified by the chiral charge-density-wave (CDW) order in 1T-TaS$_2$, where pristine samples predominantly select a single chirality. Here we show that free-energy landscape engineering through Ti substitution enables a distinct nonthermal pathway for ultrafast chiral-domain redistribution. Ti doping stabilizes coexisting chiral domains and tunes their relative stability, allowing femtosecond excitation to drive an asymmetric and anisotropic redistribution from the dominant toward the minority chirality. The subpicosecond response follows a $\sim2$ THz amplitude mode and is consistent with a phonon-assisted pathway involving transient domain-wall configurations. Our results establish free-energy landscape engineering as a strategy for selecting nonequilibrium transition pathways.
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All authors Qingzheng Qiu, Mengxian Zhao, Roman Mankowsky, Henrik Till Lemke, Serhane Zerdane, Mathias Sander, Zihao Tao, Qizhi Li, Xiquan Zheng, Shilong Zhang, Qian Xiao, Xinyi Jiang, Xin Liu, Shih-Wen Huang, Yang Yang, Sheng Meng, Yingying Peng

Strongly Correlated Electrons

Non-Hermitian skin effect in periodic, random, and quasiperiodic systems

The non-Hermitian skin effect (NHSE), which drives bulk states toward system boundaries, modifies bulk-boundary correspondence and complicates the identification of topological edge modes. Although breaking translational symmetry is known to influence this behavior, a systematic comparison of different structural classes remains limited. Here we investigate periodic, random, and quasiperiodic (Fibonacci) systems using a one-dimensional non-Hermitian quantum walk model. By matching the local scattering parameters in a topologically nontrivial regime, we isolate the role of spatial structure in the presence of the NHSE. We find that periodic systems exhibit pronounced boundary accumulation of bulk states. Random systems suppress this accumulation through Anderson localization, but the topological gap becomes partially filled with localized in-gap states. In contrast, the Fibonacci quasiperiodic system suppresses large-scale boundary accumulation while maintaining a well-defined topological gap. Analysis of the wave functions suggests that the hierarchical quasiperiodic structure fragments bulk states across multiple length scales, thereby mitigating the NHSE. These results identify deterministic quasiperiodicity as a distinct structural regime for controlling non-Hermitian skin dynamics and isolating topological boundary modes.
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Mesoscale and Nanoscale Physics

Solitary waves in a phononic integrated circuit

Solitons are universal nonlinear excitations that appear in settings as varied as optics, water waves, and quantum gases [1-5]. While reduced models of soliton dynamics are well established, their validity and dynamical behaviour in strongly nonlinear regimes with frequent interactions remain largely unexplored experimentally. Progress has been constrained by the difficulty of simultaneously achieving precise control of dispersion and nonlinearity, together with the temporal and spatial resolution required for dynamical observations. Here we overcome these difficulties by producing acoustic solitons in integrated phononic waveguides. We exploit the interplay between waveguide dispersion and mechanical Kerr nonlinearity to generate 'dark' solitons that persist over metre-scale propagation distances. The slow phonon velocity allows direct imaging of hundreds of dark soliton collisions – two orders of magnitude more than have previously been accessible [6, 7] – as well as soliton fission and the melting of a soliton Wigner crystal. Furthermore, the unprecedented dynamical resolution allows us to verify two long-predicted aspects of dark soliton behaviour: the existence of a collisional phase shift and two depth-dependent collision regimes [8, 9]. These results not only illuminate fundamental nonlinear energy transport processes, but also show a path towards acoustic versions of soliton-enabled technologies such as frequency combs and mode-locked lasers [1, 2, 10].
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All authors Timothy M.F. Hirsch, Xiaoya Jin, Nicolas P. Mauranyapin, Nishta Arora, Erick Romero, Matthew Reeves, Glen I. Harris, Warwick P. Bowen, Christopher G. Baker

Mesoscale and Nanoscale Physics

Electron scattering by a magnetic monopole in solid-state experiments

The scheme of experiment for studying electron scattering in the field of a magnetic monopole in two dimensional electron gas is proposed. The differential scattering cross section is obtained in the eikonal approximation. For unpolarized initial electron, the differential cross section coincides with that in the field of an infinitely long solenoid, up to redefinition of a magnetic flux. It is shown that the scattered electron becomes polarized even for unpolarized initial electron. Besides, in an experimental setup similar to the Hall experiment, the spin polarization arises in the direction perpendicular to the electron current.
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All authors P. S. Sidorov, N. A. Vlasov, I. S. Terekhov, A. I. Milstein

Materials Science

Mechanical Origin of High-Temperature Thermal Stability in Platinum Oxides

Platinum oxides are vital catalysts, but their limited thermal stability hinders applications. Recent studies have uncovered a structural transition in two-dimensional platinum oxides that significantly enhances their thermal resilience by several hundred Kelvin. Herein, we demonstrate that this enhanced stability stems from the mechanical robustness of the elastic network at the atomic scale. Prior to the transition, an over-constrained lattice generates localized states of self-stress through an incommensurate Moiré pattern with the platinum substrate, reducing thermal endurance. After the transition, the oxide shifts to a mechanically flexible structure with balanced degrees of freedom and constraints. The isostatic network, together with the platinum substrate, forms a commensurate Moiré superlattice that relaxes elastic energy and enhances stability. These findings highlight the fundamental role of network connectivity in governing thermal stability, and provide a design principle for catalysts in extreme environments.
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All authors Fangyuan Ma, Mengzhao Sun, Xuejian Gong, Jun Cai, Zhujun Wang, Di Zhou

Materials Science

Ultrafast optical route to coupled ferroelectric and altermagnetic switching

Exploring novel magnetoelectric coupling mechanisms to achieve control of ferroelectric polarization and magnetism is highly significant for both fundamental science and electronic device applications. Although extensive studies have been conducted on electrical switching of magnetism in multiferroic materials, simultaneous ultrafast laser switching of ferroelectric polarization and altermagnetism remains unexplored. In this letter, we propose that the ultrafast laser can be used to switch ferroelectric polarization and altermagnetism concurrently in charge-order-induced altermagnetic ferroelectrics. Building on this idea, we further demonstrate that such dual switching can be realized in charge-order-induced altermagnetic ferroelectric LiV$_2$F$_6$ by symmetry analysis and time-dependent density functional theory (TDDFT) calculation. Given that LiV$_2$F$_6$ has already been experimentally synthesized, our work not only provides an ideal material platform for experimentally realizing simultaneous switching of ferroelectric polarization and altermagnetism but also holds potential application value in future ultrafast spintronic devices.
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All authors Yuhao Gu, Yu-Hui Song, Peng-Jie Guo, Yihao Wang, Zhe Li, Ze-Feng Gao, Huan-Cheng Yang, Zhong-Yi Lu

Materials Science

Profound impacts of interlayer interactions in bilayer altermagnetic V2S2O

Two-dimensional altermagnets exhibit exceptional potential for low-power spintronics via nonrelativistic spin splitting and zero net magnetization. Here, we systematically investigate the influence of interlayer interactions on the electronic, magnetic and quantum transport properties of bilayer vanadium oxysulfide (V2S2O), a prototypical layered altermagnet, using DFT and NEGF calculations. Our results reveal that interlayer interactions predominantly modulate the p-orbital derived top valence bands, inducing a profound competitive valence band maximum position between Gamma-point pz and X/Y-point pxy orbitals, with an energy difference as small as 9 meV. Furthermore, interlayer interactions suppress the piezomagnetic effect and impose additional requirements on the type of strain for the bilayer system, compared to its monolayer counterpart. Out-of-plane external electric fields effectively weaken interlayer coupling by enlarging the energy difference of Gamma/X-Y top valence bands to 170 meV. Quantum transport simulations on a bilayer Au/V2S2O/Au two-probe device demonstrate the presence of pronounced spin current. Interlayer interactions reduce the transmission spin polarization from nearly 100% (monolayer) to 60% (bilayer) for energies above the Fermi level. Notably, gate-voltage modulation exhibits significant asymmetry in controlling charge-to-spin current conversion efficiency, originating from the out-of-plane symmetry breaking induced by the electrode geometry. Specifically, a positive gate voltage markedly enhances the contribution of the bottom layer to the overall spin polarization, while a negative gate voltage induces a marginal reduction of transmission spin polarization, attributed to the inherently weak polarization contribution of the bottom layer. These findings provide essential insights for the design and optimization of multilayer altermagnetic spintronics.
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All authors Siqi Xu, Qilong Cui, Shaowen Xu, Xianbo Chenwei, Jiahao Zhang, Ruixue Li, Yuan Li, Gaofeng Xu, Fanhao Jia

Materials Science

Experimental investigation of magnetic properties of MnFeCo$_{4}$Si$_{2}$ discovered by GNoME

AI-driven inorganic materials research has garnered significant attention due to its ability to reduce the time, labor, and cost associated with experiments. An AI model known as GNoME, recently developed by Google DeepMind, is particularly fascinating because it is integrated with the Materials Project open database. The experimental verification of compounds identified by GNoME is a crucial process for advancing AI-driven materials research. Here, we focus on the magnetic compound MnFeCo$_{4}$Si$_{2}$ (Materials ID: mp-3203253), which possesses a layered-like structure. Consistent with the GNoME prediction, MnFeCo$_{4}$Si$_{2}$ crystallizes in a rhombohedral structure with a single-phase nature. We have characterized its magnetic properties and determined that MnFeCo$_{4}$Si$_{2}$ is a soft ferromagnet with a Curie temperature of 1039 K.
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Quantum Gases · Cross-listed from quant-ph

Boundary-sensitive non-Hermiticity of Floquet Hamiltonian: spectral transition and scale-free localization

We report a novel mechanism of boundary-sensitive PT symmetry breaking in one-dimensional Floquet systems. By designing a time-periodic driving protocol, we realize a Floquet Hamiltonian that is Hermitian under periodic boundary conditions yet acquires non-Hermitian boundary terms under open boundary conditions due to the non-commutativity of driving Hamiltonians. We establish that a PT symmetry breaking transition occurs when the quasienergy bandwidth expands to cover the entire frequency Brillouin zone. This condition highlights a crucial difference from static non-Hermitian systems, where such transitions typically require band touching. Furthermore, we demonstrate that in the PT-broken phase, the eigenstates exhibit scale-free localization, a phenomenon arising from the specific system-size scaling of non-Hermitian terms. Finally, we provide a general framework for constructing multi-band models that exhibit this boundary-induced phase transition.
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Materials Science

Hydrogenation-induced gigantic resistance decrease of palladium films deposited by high pressure magnetron sputtering

We demonstrate a pronounced decrease in the electrical resistance of highly disordered palladium (Pd) films deposited under a high working Ar pressure using a compact film coating system. The resulting resistance change ratio of up to $1/335$ is predominant among those reported previously. Film characterization suggests two primary mechanisms responsible for this significant resistance reduction: atomic force microscopy observation indicates improved electrical contacts among Pd grains, and X-ray diffraction measurement demonstrates hydrogenation-induced crystallization of Pd. These findings offer a simple scheme to enhance hydrogen sensor performance and can contribute to a more comprehensive understanding of the hydrogenation process in Pd.
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Strongly Correlated Electrons

Symmetric Mass Generation Transition and its Nonequilibrium Critical Dynamics in a Bilayer Honeycomb Lattice Model

Symmetric mass generation (SMG) transitions defy the conventional Landau-Ginzburg-Wilson paradigm by opening a many-body gap without spontaneous symmetry breaking or topological order, attracting intense interest across particle physics and condensed matter physics. Here, we utilize unbiased quantum Monte Carlo simulations to investigate the equilibrium and nonequilibrium critical dynamics of the SMG transition in a bilayer honeycomb lattice model. We unambiguously confirm the existence of an SMG transition at $J_{\text{c}}=2.584(8)$ that separates the Dirac semimetal phase from a symmetry-preserving SMG phase. High-precision extraction of the critical exponents reveals a novel universality class that profoundly departs from mean-field theory. We then extend our study to the nonequilibrium regime, exploring the driven dynamics of the SMG transition. Notably, despite the breakdown of the prerequisites for the celebrated Kibble-Zurek mechanism, the nonequilibrium SMG transition still follows the generalized finite-time scaling. By bridging equilibrium criticality and nonequilibrium dynamics, our work uncovers the universal critical properties of SMG transitions, providing a solid theoretical basis for future experimental studies of SMG physics.
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All authors Zhi-Xuan Li, Yin-Kai Yu, Zi-Xiang Li, Shuai Yin

Materials Science · Cross-listed from physics.app-ph

Simultaneous measurement of pressure-dependent bulk and interfacial thermal properties in thermal interface materials using square-pulsed source thermoreflectance

Thermal interface materials (TIMs) critically regulate heat dissipation from electronic chips to heat spreaders, yet their thermal conductivity (k), volumetric heat capacity (C), and interfacial thermal resistance (ITR) evolve with mechanical pressure and cannot be determined simultaneously using existing steady-state or transient techniques. As a result, the coupled roles of bulk compaction and interfacial contact in governing heat transport in TIM assemblies remain poorly resolved. Here, we present a square-pulsed source (SPS) thermoreflectance method that enables simultaneous determination of k, C, and ITR in TIM stacks under controlled mechanical loading. By spanning square-wave modulation frequencies from 1 Hz to 10 MHz, SPS probes a broad range of thermal penetration depths, enabling distinction between heat diffusion in the TIM bulk and interfacial heat transfer at the Al/TIM contact. Measurements on a thermally conductive gel, a thermal pad, and a high-vacuum grease during compression-unloading cycles reveal distinct pressure-dependent thermal transport mechanisms. The gel and pad exhibit increases in k and C, reduced ITR, and pronounced hysteresis, indicating coupled bulk densification and persistent interfacial conformity during loading cycles. In contrast, the grease shows nearly pressure-independent bulk properties but a strong pressure dependence of ITR, consistent with an interface-dominated response. These results resolve the long-standing challenge of simultaneously quantifying bulk and interfacial thermal transport in mechanically loaded TIM assemblies, enabling experimentally constrained thermal management and reliability analysis in electronic packaging.
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All authors Tao Chen, Bingjia Xiao, Xin Qian, Puqing Jiang

Materials Science

First-Principles Analysis of Chirality-Induced Spin Selectivity at Molecule-Metal Interfaces in Photoemission

Spin-resolved photoelectron spectroscopy (PES) probes chirality-induced spin selectivity (CISS), yet it remains unclear whether the measured spin polarization reflects molecular chirality itself or the broader electronic structure of the hybrid interface. We present a first-principles analysis of PES spin polarization at chiral molecule-metal interfaces, treating the interface holistically rather than as a metal substrate plus a separate molecular spin filter/polarizer. Using density functional theory within a three-step photoemission framework, we compute the spin polarization generated in the optical-excitation step for ($M$)- and ($P$)-heptahelicene adsorbed on Au(111) and Cu(111), and for coronene/Au(111) as a non-chiral control. We find that adsorption strongly reshapes the PES spin polarization relative to the clean metal surface, but opposite enantiomers yield symmetry-related responses. These results indicate that changes in the PES spin polarization are more naturally attributed to the electronic structure of the hybrid interface than to molecular chirality alone.
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Materials Science

Weak Coupling of Diffusional and Phonon-like Modes in Liquids Revealed by Dynamic Kapitza Length

Understanding heat transfer across solid-liquid interfaces is central to thermal management and energy technologies, yet whether the interfacial thermal conductance (ITC) depends on the timescale of heating remains unclear. Here we use square-pulsed source thermoreflectance, which combines time-resolved detection with broadband modulation, to probe Al-water and Al-octane interfaces. We observe a reproducible increase of the apparent ITC with modulation frequency. A control Al-silica interface shows no measurable frequency dependence, indicating that the effect is specific to liquids rather than a generic feature shared by all amorphous materials. We explain the data with a two-channel liquid picture in which diffusional and phonon-like modes exchange energy weakly over a finite nonequilibrium length. From the relative magnitude of the thermal penetration depth and the nonequilibrium length, we identify three transport regimes. These findings challenge the common assumption of fully equilibrated liquid modes and provide experimental constraints for modeling dynamic energy exchange at liquid interfaces.
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Mesoscale and Nanoscale Physics

Two-dimensional bound excitons in real space and Landau quantization space: A comparative study

The Landau quantization space is based on the respective motion of the electron and hole in a magnetic field and can provide a new route to understand the bound exciton behaviors observed in the experiments. In this paper, we study the two-dimensional exciton properties of monolayer WSe$_2$ in both real space and Landau quantization space. Focusing on the excitons of zero center-of-mass momentum, we calculate its energy spectrum in both spaces, with the results agreeing well with each other. We then obtain the diamagnetic coefficients and root-mean-square radius, which are consistent with the available $s$ state data in the experiment. More importantly, in the exciton state $nl$, we find that the dominant electron-hole pair component may shift with the magnetic field and the Coulomb interactions, and reveal that the magnetic field will drive the dominant component to be the free electron-hole pair $\{n_e=n+l-1,n_h=n-1\}$, whereas the Coulomb interactions drives it to be the pair of the lower index.
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Materials Science

Distinct memory properties in spin-wave reservoir computing based on synthetic antiferromagnet

Spin-wave-based physical reservoir computing (RC) is a promising candidate for energy-efficient physical implementations of artificial intelligence because of its potential for nanoscale integration with low power consumption. Most of the previous studies on spin-wave RC have utilized spin waves excited in a single-layer ferromagnet. In this study, we focused on spin waves in a synthetic antiferromagnet (SAF), consisting of two ferromagnetic layers coupled antiferromagnetically, and investigated additional memory properties of spin-wave RC. We theoretically and numerically demonstrate the emergence of two distinct memory properties in the SAF device due to the distinct spin-wave characteristics of the acoustic and optical modes inherent in SAFs.
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All authors Takumu Shinkai, Satoshi Iihama, Kensuke Hayashi, Takahiro Moriyama, Shigemi Mizukami, Natsuhiko Yoshinaga

Strongly Correlated Electrons

Dimensionality-Dependent Exciton Dispersion in a Single-Band Mott Insulator

Excitonic band structure is critical for investigating exciton dynamics. Theoretically, quantum effects from exchange scattering between electron-hole pairs significantly modulate exciton dispersion. Here, we report the direct observation of dimensionality-dependent exciton dispersion in a single-band Mott insulator Nb3Cl8 through high-resolution electron energy loss spectroscopy. In the high-temperature phase, the exciton in Nb3Cl8 hosts an exceptionally large binding energy, and exhibits clear quasi-two-dimensional massless linear dispersion. In contrast, in the low-temperature phase, the exciton splits into two bands, both displaying three-dimensional parabolic dispersion. These dramatic changes in the exciton dispersion stem from the dimensional mutation driven by a substantial enhancement of interlayer coupling across the phase transition. This Letter provides a clear and typical example of how exciton behavior evolves with dimensionality.
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All authors Zhibin Su, Junjian Mi, Shaohua Yan, Jiade Li, Siwei Xue, Zhiyu Tao, Enling Wang, Xiongfei Shi, Hechang Lei, Zhuan Xu, Jiandong Guo, Xuetao Zhu

Soft Condensed Matter

Finite compressibility and strain hardening in elasto-plastic models of amorphous matter

We study a mesoscopic elasto-plastic model of amorphous matter with varying dimensionless compression modulus, $K/\mu$, where $K$ and $\mu$ are the compression and shear moduli. We study both cyclic shear with amplitude $\Gamma$ and forward steady shear. In cyclic shear, the terminal behavior is, in order of increasing $\Gamma$: i) trivially elastic, ii) hysteretic but with microscopically reversible limit cycles, iii) diffusive with no return to previously visited configurations. We show that the transition between i) and ii) at the onset point $\Gamma_0$ is determined by the Eshelby back stress, $\sigma_0$, which depends on the Poisson ratio. Systems with smaller $K/\mu$ (more compressible) are effectively harder with a higher $\Gamma_0$ and a correspondingly larger purely elastic regime in cyclic loading. In forward shear, $\sigma_0$ plays a similar role where lower $K/\mu$ results in a higher steady state flow stress, $\sigma_y$. We show that increasing $K/\mu$ increases the amplitude of stress redistribution after a local yielding event without changing the net stress relaxation and relate this to the assumptions in mean-field descriptions of amorphous solids. A striking feature of the model is the emergence of a complex hardening behavior in the absence of any ad-hoc hardening parameters: a transition between a kinematic and an isotropic hardening behavior precisely at $\Gamma_0$ associated with the hysteresis transition. The enhanced plastic response for incompressible systems is also seen in amorphous alloys where it is usually attributed to excess free volume, while in the present model, it arises from the dependence of the Eshelby backstress on the Poisson ratio. Our results should have important implications for amorphous metallic alloys or other glassy systems where $K/\mu$ can vary with composition, age, quench procedure, or mechanical processing history.
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Disordered Systems and Neural Networks

Non-Hermitian Mosaic Maryland model

We introduce the non-Hermitian mosaic Maryland model, where a discrete modulation period and a non-Hermitian phase are incorporated into the potential, rendering the originally exactly solvable system generally non-integrable. This model provides a unique platform to investigate how structural modulation governs localization in complex quasiperiodic potentials. Using Avila's global theory, we analytically derive the exact Lyapunov exponent and obtain explicit formulas for the complex mobility edges. Remarkably, for modulation periods kappa >= 2, the system intrinsically hosts kappa-1 robust extended bands that persist independently of the potential strength and non-Hermiticity. We further characterize the topological nature of these phases via the spectral winding number. Unlike the standard Maryland model, the mosaic modulation induces mobility edges, and the resulting phase transitions are continuous, reflecting the non-integrable nature of the system. Numerical calculations of the inverse participation ratio and fractal dimension confirm the analytical predictions for the asymptotic form of the mobility edges in the large non-Hermiticity limit. This work establishes structural design as a powerful degree of freedom for engineering wave transport and enhancing the robustness of extended states in non-Hermitian systems.
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All authors Zhenning Wang, Ni Lu, Dan Liu, Xiaosen Yang, Xianqi Tong

Superconductivity

A mechanism for nonmonotonic $T_{c,max}(n)$ in multilayer cuprates

We propose an explanation of the observed dependence of the maximal critical temperature $T_{c,max}$ on the number of conducting layers $n$ in layered copper-oxide superconductors within the preformed pair mechanism. Copper-oxygen planes fine-tune the lattice anisotropy and regulate the balance between the attractive and kinetic energies of carrier holes. To maximize the Bose-Einstein condensation temperature, real-space pairs must be compact and light at the same time. Generally, $T_{c,max}$ increases between $n = 1$ and $n = 3$ because pairs become lighter. For $n > 3$, the rising kinetic energy weakens the pairs, leading to inflated pair volumes and reduced $T_{c,max}$. By varying model parameters, the peak of $T_{c,max}(n)$ can be tuned to $n = 2$, $n = 3$, or $n > 3$. We also discuss strategies for using this knowledge to boost $T_{c,max}$ beyond the current record of 138 K.
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Monday 23 March

Materials Science · Cross-listed from cs.RO

Functionalization of Situated Robots via Vapour

Tight matching with the environment is key to effective robot operation in complex settings. Situated robots that build their bodies in situ (e.g. by spinning) are uniquely positioned to exploit their surroundings, yet functionalization of these structures remains an integration challenge - multimaterial spinning requires complex spinneret multiplexing, and mixture doping is limited by additive availability and chemical stability. We propose instead using materials available in the environment to functionalize in situ spun webs, reducing payload and uniquely matching the structure to its surroundings. As a demonstration, we transform an optically scattering PVDF fiber web into an optically absorbing, polypyrrole-grafted structure via pyrrole vapour exposure. Two activator-delivery strategies are shown: liquid infusion into a prefabricated web, and activator pre-embedding in the spinning mixture. Beyond this proof-of-concept, we foresee broader applications including biohybrid robots that exploit bacterial genomes for specific biomolecule synthesis in situ.
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All authors Kadri-Ann Pankratov, Leonid Zinatullin, Adele Metsniit, Marie Vihmar, Indrek Must

Soft Condensed Matter · Cross-listed from physics.flu-dyn

Self-organised structures in mixed active-passive suspensions due to hydrodynamic interactions

Microswimmers in suspension exhibit collective swimming behaviour, forming various self-organised structures including ordered, aggregated, and turbulent-like structures. When mixed with passive particles phase-separation is known to occur, but due to the difficulty of accurately handling many-body hydrodynamic interactions, the formation of self-organised structures in mixed suspensions has remained unexplored so far. In this study, we investigate the dynamics of mixed dense suspensions of spherical bottom-heavy squirmers and obstacle spheres using Stokesian dynamics in three dimensions, taking hydrodynamic interactions into account. The results show that without an external orientating mechanism the formation of orientational order is in general disturbed by the presence of passive spheres. An initially phase-separated state is metastable for neutral or puller squirmers at high packing densities. When the squirmers are bottom-heavy, phase-separation can occur dynamically in some cases, notably a fibrillar kind of separation for neutral squirmers and pullers at medium densities. We also observed a novel form of lamellar phase-separation for pullers at high densities with strong bottom-heaviness, with a sandwich-like structure consisting of a layer of passive particles pushed by a layer of swimmers, followed by a gap. These results indicate that microstructure and particle transport undergo significant changes depending on the type of swimmer, highlighting the importance of hydrodynamic interactions. These insights allow for a deeper understanding of the behaviour of active particles in complex fluids and to control them using external torques.
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Materials Science · Cross-listed from physics.ins-det

Methods for an Electron Emission Digital Twin

The effective design and operation of electron emitters is the core of critical technologies such as high-resolution electron imaging and spectroscopy or X-ray production for medical imaging. Despite 100 years of theoretical development in thermo- and field-electron emission models, the analysis of experimental data and design of electron emitters remains an art more than a science. This is due to the many processes that are involved in electron emission, which result in an extremely complex phenomenon. Here we describe and develop the Methods for an Electron Emission Digital Twin (MEEDiT), which integrates state-of-the-art thermo-field electron emission models and experimental data characterisation. By applying MEEDiT to silicon electron emitters, we demonstrate an approach that bridges the gap between simple experimental measurements and 'hidden' physical quantities like temperature and field enhancement. MEEDiT provides the physical consistency of a 3D simulation with the speed of a neural network, enabling resource-effective, real-time characterization and the extraction of critical data that is otherwise inaccessible during operation.
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All authors Salvador Barranco Carceles, Veronika Zadin, Steve Wells, Aquila Mavalankar, Ian Underwood, Anthony Ayari

Strongly Correlated Electrons · Cross-listed from physics.chem-ph

Radial Gausslets

Gausslets are one of the few examples of basis sets for electronic structure which allow for two-index/diagonal electron-electron interaction terms. A weakness of gausslets is that, because of their 1D origin, they have been tied to Cartesian coordinates. Here we generalize the gausslet construction for the radial coordinate in three dimensions for atomic basis sets. These radial gausslets make a very compact radial basis with a relatively modest number of functions, with diagonal interaction terms. We illustrate the accuracy of this construction with Hartree–Fock and exact diagonalization on atomic systems.
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Superconductivity

Triplet superconductivity supported by an X$_9$ high-order Van Hove singularity

We study a four-fold symmetric dispersion relation of a quantum material, which exhibits a single high-order Van Hove singularity of X$_9$ type at the Fermi energy. First, we analyze in detail its form, type and density of states when the energy dispersion is in its canonical form. Subsequently, we study the possibility of a superconducting state when Hubbard repulsive interactions are taken into account. By solving the gap equation, it is shown that triplet state superconductivity with power-law dependence of the critical temperature T$_c$ on the interaction strength can be formed when a single singularity is present in the Brillouin zone. We discuss the effects of fluctuations and provide an upper bound of a possible superconducting critical temperature for the ruthenate Sr$_3$Ru$_2$O$_7$ which has been shown to exhibit this type of singularity.
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Statistical Mechanics

Pseudospectral phenomena and the origin of the non-Hermitian skin effect

The non-Hermitian skin effect (NHSE), characterized by a macroscopic accumulation of eigenstates at the edge of a system with open boundaries, is often ascribed to a non-trivial point-gap topology of the Bloch Hamiltonian. We revisit this connection and separate the question of the NHSE as a spectral reconstruction effect in clean systems from the question of stable topological protection. For a Hatano-Nelson ladder, where point-gap winding and non-normality can be varied independently, we demonstrate that, in a clean translationally invariant multiband setting, the NHSE can occur without point-gap winding and, conversely, that point-gap winding can persist without the NHSE. These results establish that in the clean case the connection between point-gap winding and the NHSE only holds in the scalar one-band case but, in general, not in the multiband case. Even more importantly, the eigenspectrum of non-normal operators is generically highly sensitive to boundary conditions and perturbations, and therefore does not constitute a stable object encoding topological information. Instead, topological properties are reflected in the splitting of the singular-value spectrum for finite systems and, in the semi-infinite limit, correspond to boundary-localized kernel modes implied by the index of the corresponding Toeplitz operator.
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Superconductivity

Probing Electromigration of Oxygen Vacancies in YBa$_2$Cu$_3$O$_{7-\delta}$ Devices by Multimodal X-ray Techniques

Control of oxygen vacancies by electrical currents in complex oxides such as YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) has attracted considerable interest due to the relative simplicity of its implementation and its potential for both fundamental studies and the tuning of superconducting device properties. However, the structural evolution and depth-dependent effects associated with current-based techniques remain largely unexplored, particularly with respect to the connection between optical signatures and the spatial distribution of oxygen vacancies. Here, we combine nanoprobe X-ray Diffraction (NanoXRD), Cu K-edge X-ray Absorption Near-Edge Structure (XANES), X-ray Photoelectron Spectroscopy (XPS), electrical transport, and optical measurements to reveal modifications induced in YBCO microbridges by pulsed electromigration. We observe a c-axis expansion correlated with spectroscopic features of oxygen depletion in the Cu-O chains, and we confirm that oxygen redistribution, crystallographic changes, and copper coordination evolve consistently across techniques. Notably, the spatial profile of unit-cell expansion closely follows the optical contrast observed after electromigration, demonstrating that the different signatures capture the same underlying oxygen reordering. We further show that optical microscopy cannot reliably capture bipolar electromigration involving strong resistance modifications, as surface deoxygenation appears largely irreversible. Taken together, our findings provide a significant step toward a microscopic understanding of current-assisted oxygen migration in YBCO and establish a framework for effectively exploiting vacancy control in high-temperature superconducting devices.
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All authors Caio C. Quaglio-Gomes, Stefan Marinković, Elijah A. Abbey, Davi A. D. Chaves, Anna Palau, Alejandro V. Silhanek, Pedro Schio, Maycon Motta

Materials Science

Generalized thermodynamic closure in ultrafast phonon dynamics

Driven-dissipative dynamics underlie a wide range of nonequilibrium phenomena in quantum materials, yet reduced descriptions beyond the quasi-equilibrium picture remain difficult to establish. Here, we experimentally demonstrate that a resonantly driven phonon mode admits a generalized thermodynamic description in which coherence and energy jointly organize the nonequilibrium evolution. Beyond a threshold driving field strength, we observe a delayed ultrafast response of a coherently driven phonon mode. Combined with experimentally constrained Lindblad dynamics, we show that this delay reflects the finite-time spreading of excitations across many phonon levels. At the same time, the full density-matrix trajectories for three driving conditions collapse onto a common surface defined by energy and coherence. Our results establish a coherence-extended thermodynamic regime for driven phonons and provide a framework for broader state engineering in driven-dissipative bosonic excitations.
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All authors Sheng Qu, Jiyong Kim, Jaco J. Geuchies, Sergey Kovalev, Jan-Christoph Deinert, Thales de Oliveira, Alexey Ponomaryov, Min Chen, Nilesh Awari, Igor Ilyakov, Mischa Bonn, Heejae Kim

Materials Science

Dynamical Simulation of On-axis Transmission Kikuchi and Spot Diffraction Patterns, Based on Accurate Diffraction Geometry Calibration

Transmission Kikuchi diffraction in the scanning electron microscope has gained popularity as a materials characterization technique for its high throughput and nanometer-level spatial resolution. While conventional diffraction pattern analysis routines focus on Kikuchi bands on the diffraction patterns, the full physical picture of electron scattering and diffraction pattern formation is more complex. Analysis that accounts for additional diffraction features such as diffraction spots and excess-deficiency effects should provide more robust and accurate indexing, if they can be incorporated in pattern indexing or simulation routines. A more accurate understanding of their physics of formation and geometry is required to enable this change. In this work, we demonstrate geometric and full contrast dynamical simulation of on-axis transmission Kikuchi patterns, based on experimental patterns captured using a modular, direct electron detector-based set-up in the scanning electron microscope. First, a diffraction geometry calibration routine is proposed based on the electron channeling pattern of the direct electron detector. This allows us to accurately account for the position of diffraction spots in both geometric and dynamical simulations with good agreement with experimental patterns. Further, by introducing appropriate weight factors, simulation of incoherent diffuse intensity, and calculation of the energy spectra of diffracted electrons, simulated patterns can be obtained which accurately capture the many diffraction features on experimental patterns. Workflows and findings of this work can be used to improve pattern indexing routines, as well as the understanding of the physical processes in the formation of on-axis transmission Kikuchi patterns.
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All authors Tianbi Zhang, Raynald Gauvin, Aimo Winkelmann, T. Ben Britton