Quantum Physics
Exact efficient simulation of noisy logical magic states using Clifford stabilizers
Yugo Takada, Stephen D. Bartlett and Dominic J. Williamson
The preparation of high-fidelity logical magic states is a crucial subroutine for universal fault-tolerant
quantum computation (FTQC). Predicting the performance of FTQC and developing improved protocols rely on numerical methods to classically simulate logical magic state preparation in the presence of noise. Clifford logic on Pauli-stabilizer codes with
circuit-level Pauli errors can be efficiently simulated using Pauli-stabilizer formalism, but the non-Clifford operations required to prepare logical magic states render generic simulation inefficient. We introduce Clifford-stabilizer simulation, an exact and efficient
algorithm based on updating a Clifford-stabilizer group to simulate noisy preparation protocols for a broad class of logical magic states used to implement non-Clifford gates in the third level of the Clifford hierarchy under
circuit-level Pauli errors. Clifford-stabilizer simulation applies to a range of operations that commonly appear in preparation protocols for such logical magic states, including Pauli-stabilizer measurements, logical Clifford measurements, and transversal non-Clifford gates. Our
algorithm for Clifford-stabilizer simulation maps a non-Clifford
circuit with sampled
circuit-level Pauli errors to a Clifford
circuit that exactly reproduces its measurement outcome distribution, achieving time and space complexities
polynomial in relevant protocol parameters. We perform exact simulation of magic state cultivation up to fault distance 7 by Clifford-stabilizer simulation. Our method provides a route to perform exact benchmarking of large-scale logical magic state preparation protocols required for useful FTQC.
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Quantum Physics
Portable Vector NV-Diamond Magnetometer for Shot-Noise-Limited, Drift-Free Operation in Unshielded Environments
Annirudh K P, Vinayak Rane, Shradha Atakar et al. (+5 more)
Ensemble nitrogen-vacancy (NV) diamond magnetometers combine high sensitivity with vector-field reconstruction, but practical deployment is limited by errors arising from high-frequency
laser noise during short-duration operations and slow-varying gain fluctuations and offset drift during long-term operation. Here, we present an integrated digital architecture for achieving NV magnetometry stability across distinct timescales. A dynamic differential readout continuously balances fluorescence and reference channels to suppress correlated
laser noise. Second-derivative Lorentzian lineshape tracking enables in-situ correction of slope variations arising from slow changes in gain and optical excitation. We further identify temperature-induced bias-magnet fluctuations as a dominant source of long-term drift and introduce a
magnetic eigenvector transformation that uses the intrinsic response of NV resonances to eliminate these variations. We show, under unshielded ambient conditions, that this architecture achieves an off-resonance noise factor of 1.0 $\pm$ 0.1, matching the fundamental limit with ten-fold suppression of long-term drift, enabling stable, field-ready
quantum magnetometry.
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All authors Annirudh K P, Vinayak Rane, Shradha Atakar, Sanika Joshi, Maheshwar Mangat, Jay Gharat, Siddharth Tallur, Kasturi Saha
Quantum Physics
Understanding the spin coherence of molecular photoexcited triplet states from first principles
Ecaterina Păunică and Sam L. Bayliss
Optically readable molecular
spins are attractive as
quantum sensors due to their nanoscale modularity, synthetic tunability, and scope for sensitive readout. In particular, photoexcited
spin-triplet states in organic molecules are appealing in supporting high optical-
spin contrast at room temperature. Their utility is underpinned by their coherence, which warrants a detailed understanding of it. Here, from first principles, we systematically explore the Hahn-echo decoherence of the
benchmark molecular system for room-temperature optically detected
spin coherence—pentacene guest molecules coupled to a para-terphenyl host. Using generalized cluster-correlation expansion methods, we investigate the mechanisms of nuclear-
spin-induced decoherence from zero to high
magnetic field, exploring the role of guest vs host molecules, specific
nuclei, zero-field splitting interactions, and hyperfine parameters. We describe how zero-field decoherence is driven by ~6
nuclei on the guest, while high-field decoherence is driven by ~600
nuclei in the host; how the longitudinal zero-field splitting parameter, $D$, can prolong $T_2$; and the
magnetic-field-dependent processes which drive decoherence. These results advance our understanding of decoherence in optically readable molecular
spins, providing insight for their synthetic enhancement and deployment as
quantum probes.
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Quantum Physics · Cross-listed from physics.atom-ph
Orbital-angular-momentum partition in hydrogen photoionization by a monochromatic vortex beam
Zhongchen Xing, Chengyin Wu, Zheng Li et al. (+1 more)
Understanding how optical orbital angular momentum (OAM) is transferred to matter requires treating recoil and translational motion alongside the internal electronic dynamics. We develop a center-of-mass-resolved theory of one-
photon ionization of hydrogen by a monochromatic Laguerre–Gaussian beam and show that the Bessel-
vortex photoelectron predicted in fixed-target models is a preparation-dependent limit. For a sharply defined atomic center-of-mass momentum, the recoil records the
photon-cone azimuth, and tracing over it generally destroys the coherence required for a pure electron
vortex. In the small-transverse-retardation regime, the optical OAM is transferred predominantly to the center-of-mass motion and hence, in the laboratory frame, to the
proton. Finite-retardation corrections redistribute angular momentum between center-of-mass and relative motion, while an additional correlation contribution to the electron and
proton angular momenta can be tuned through the spatial uncertainty of the atomic center of mass. These results reveal atomic recoil as a key element of OAM transfer in photoionization.
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All authors Zhongchen Xing, Chengyin Wu, Zheng Li, Marcelo F. Ciappina
Quantum Physics · Cross-listed from cond-mat.mes-hall
Generation of pure spin currents via nonadiabatic quantum pumping in an antiferromagnetic chain
Leila Eslami, Fatemeh Bourbour, Somaieh Ahmadi et al. (+1 more)
In this study,
quantum spin pumping in an antiferromagnetic chain driven by time-dependent potential is investigated. The aim is to explore the possibility of generating and controlling
spin currents in the absence of external bias and to examine the role of exchange field and periodic driving in the separation of
spin-up and
spin-down currents. The system is described using a tight-binding model, and
spin-resolved currents are calculated employing the Keldysh non-
equilibrium Green's function formalism. Two time-dependent potentials with a specific phase difference are applied to the two ends of the chain, while the chemical potentials of both electrodes are set equal. The results demonstrate that in the adiabatic regime (low frequencies), the response of the two
spin channels is nearly identical. However, as the driving frequency increases and the system enters the nonadiabatic regime, absorption and emission processes of energy quanta become activated, leading to significant differences between
spin-up and
spin-down currents. The pumped current exhibits strong dependence on the chemical potential, allowing for the control of both magnitude and direction of the
spin current through its adjustment. With increasing frequency, the
spin current enhances, and parameters can be tuned such that the charge current nearly vanishes while a considerable
spin current persists. This finding indicates the feasibility of achieving nearly pure
spin pumping without net charge transfer in the antiferromagnetic chain. The results provide a promising perspective for designing
spin-pumping devices based on antiferromagnetic systems.
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All authors Leila Eslami, Fatemeh Bourbour, Somaieh Ahmadi, Santanu K. Maiti
Quantum Physics
TSS Graphs for Hadamard Matrices: Real vs Complex
Wesley Lewis, Darsh Pareek and Ravi Janjam
We have observed that Hadamard
matrices whether real or complex lead to a dense output of identical probabilities for any given single input state. Complex Hadamard
matrices have unusual orders and introduce phase which prove useful when controlled phase transformation gates are used. By taking a superposed combinations of input states, we discovered that the Hadamards generate non-uniform probabilities which is practically significant towards amplitude amplification without the need for manual parameterization like Grover's operator~\cite{grover1996}. A variety of graph theoretic properties are applied to TSS graphs and their trends were explored. Additionally, graphs turn out to be nearly isomorphic for the same set of input states which has potential applications for developing
Quantum Algorithms. Keywords:
Quantum Algorithms, Hadamard
Matrices,
Unitary Matrix Approach, Topological Structure of Superpositions (TSS), Graph Theory
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Quantum Physics
Initial-Slip Dynamics Enables the Quantum Mpemba Effect
M. Crotti, F. Cavaliere, D. Ferraro et al. (+2 more)
We investigate the
quantum Mpemba effect, whereby a system initially farther from
equilibrium relaxes faster than one initially closer to
equilibrium, emerging in a
quantum harmonic oscillator linearly coupled to a bosonic environment. Starting from factorized thermal states at different temperatures, we derive exact analytical criteria for the occurrence of the
quantum Mpemba effect valid also beyond the typically considered weak-coupling and Markovian approximations. Most importantly, we show that the effect is enabled by the initial-slip dynamics generated by the sudden switch-on of the system-bath interaction. Neglecting this contribution completely suppresses the anomalous relaxation, identifying transient system-bath correlations as the key ingredient underlying the
quantum Mpemba effect.
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All authors M. Crotti, F. Cavaliere, D. Ferraro, G. Benenti, M. Sassetti
Quantum Physics
Experimental Private Quantum Networked Sensing
Nicolas Laurent-Puig, Laura dos Santos Martins, Luis Bugalho et al. (+5 more)
Entangling distant
quantum sensors is a key application of future
quantum networks, allowing for the estimation of global functions of local parameters, with precision that is not possible with stand-alone, individual,
quantum sensors. However, with this advantage comes the risk of information leakage over the network via possible malicious parties. It is often particularly important that local parameters remain unknown and that only the global function is shared across the network. Recently, the notion of
privacy has been introduced in this context, which ensures that only the agreed function of parameters is shared over the network, even when malicious parties control the network itself, whilst maintaining the estimation advantage. In this work, we introduce a noise-robust protocol for private
quantum networked sensing, which we realise using a high-fidelity Greenberger-Horne-Zeilinger (GHZ) state source. We further run a comparative analysis and simulate attacks using three different
quantum states, a four-
qubit GHZ state, two Bell pairs, and a fully separable state. Our results highlight the clear advantage of GHZ states in maintaining high precision, accuracy, and
privacy for the distributed estimation task.
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All authors Nicolas Laurent-Puig, Laura dos Santos Martins, Luis Bugalho, Santiago Scheiner, Majid Hassani, Sean William Moore, Damian Markham, Eleni Diamanti
Quantum Physics
Improved Separations between Quantum and Classical Communication Complexity of Total Functions
François Le Gall
We refine Gavinsky's framework (arXiv:2608.18784) for exponential separations between
quantum and randomized communication complexity of total functions and obtain larger separations: polylogarithmic
quantum communication versus $\tilde\Omega(\sqrt n)$ randomized communication with two
quantum messages, and versus $\Omega(n^{1-\varepsilon})$ for every fixed $0<\varepsilon<1$ with more
quantum messages.
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Quantum Physics · Cross-listed from physics.flu-dyn
Rotation Collision based Quantum Lattice Boltzmann Methods
Kangyang Zeng, Changshen Huang, Xi Liu et al. (+2 more)
In the existing
quantum algorithms for the
lattice Boltzmann method, resolving the unitarity problem of the BGK collision operator from first principles remains a fundamental challenge, and a systematically constructed
unitary alternative that reproduces the BGK relaxation structure to leading order has not yet been established in the literature. In this work, we propose a novel
quantum lattice Boltzmann method (QLBM) based on the rotation collision operator, in which the non-
unitary BGK relaxation is replaced by a
unitary rotation in the amplitude space of the distribution function, and the corresponding gate-level
quantum circuits are also constructed. Specifically, the rotation collision operator is developed for both the D2Q5 model of the convection-
diffusion equation and the D2Q9 model of the incompressible Navier–Stokes equations. It is worth noting that, for the D2Q5 model, the
equilibrium-state preparation
circuit can be precompiled and reused, and the resulting
unitary blocks can be sequentially composed once the state-dependent collision parameters are specified. Finally, some numerical experiments are performed to validate the developed QLBM, demonstrating its accuracy and effectiveness.
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All authors Kangyang Zeng, Changshen Huang, Xi Liu, Xiaodong Niu, Zhenhua Chai
Quantum Physics
Phase Transition in Binary Compressed Sensing via Annealing with Adaptive Regularization
Xiaoxin Huang and Masayuki Ohzeki
Regularization choice changes the recovery phase diagrams of annealing-based binary compressed sensing. We develop a regularization-selection method that combines systematic parameter search with random forest regression. Under noiseless Gaussian measurements with known sparsity, reference parameters are selected from a candidate grid by minimizing mean squared reconstruction error over repeated simulated annealing (SA) trials. The fitted model predicts these reference values from signal dimension, sampling ratio, and sparsity. With predicted regularization, the SA recovery transition broadly follows the asymptotic reference boundary for box-constrained $\ell_1$ recovery at the larger signal dimensions examined. Without retraining, the same predictor supplies identical regularization values to SA and a
quantum–classical hybrid solver. On matched problem instances, the hybrid solver yields smaller mean squared reconstruction errors than SA in parts of the evaluated parameter space. The resulting rule reuses the searched information for subsequent reconstruction without repeating candidate searches at each setting. The results quantify empirical performance under the stated finite candidate grid and solver settings; they do not constitute a solver-independent recovery guarantee or a time-to-solution comparison.
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Quantum Physics · Cross-listed from physics.optics
In-Situ Quantum Optical Measurement for Colloidal Quantum Dots Confined in an Optical Trap
Zhi-Bo Ni, Jiong-Zhao Li, Jia-Wang Yu et al. (+7 more)
While optical manipulation of atomic arrays has reached a high degree of precision and scalability, the stable optical confinement of solution-based artificial atoms like colloidal
quantum dots (CQDs) remains hindered by weak trapping forces and thermal fluctuations. High-intensity trapping often compromises the
quantum properties of these emitters, creating a significant trade-off between mechanical stability and optical integrity. To overcome this, we propose encapsulating CQDs within a transparent
polymer matrix, thereby increasing the effective interaction volume and optical restoring force without altering the emitters themselves. This strategy allows for stable spatial confinement under standard experimental conditions, as evidenced by the direct resolution of positional fluctuations through photoluminescence imaging and trajectory tracking. With averaged position fluctuations below 20 nm, the intrinsic emission spectra and photoluminescence decay dynamics remain largely unaffected, and
photon-correlation measurements confirm the full preservation of single-
photon emission. These findings establish a robust method for the controlled confinement of colloidal
quantum emitters and in-situ
quantum-optical measurements for future advancements in
quantum-optical manipulation of artificial atoms.
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All authors Zhi-Bo Ni, Jiong-Zhao Li, Jia-Wang Yu, Xiao-Tian Cheng, Yun-Ran Wang, Dai-Bao Hou, Yan-Hua Liu, Wei Fang, Xing Lin, Chao-Yuan Jin
Quantum Physics · Cross-listed from cond-mat.mes-hall
1/f frequency noise in mechanical resonators scales inversely with volume, not with quality factor
M.L. Roukes
Mechanical frequency-shift sensors have never reached their fundamental thermomechanical or
quantum limits. Every material, size, and transduction scheme yet examined yields a $1/f$ floor 1-3 orders higher, with a flicker-noise coefficient $h_{-1} \propto 1/V_{\varepsilon}$. Surveying the published record, I find the invariant $h_{-1}\,V_{\varepsilon} \equiv \sigma_A ^2\, V_{\varepsilon}/(2\ln 2)$ independent of device size across 13 decades; volume-independent noise is excluded by 9$\sigma$, site-averaging by 3.8$\sigma$. No $Q$ dependence appears: reported $Q^{-n}$ laws scale equivalently when $Q$ and volume co-vary; only volume scaling survives when they do not. Mass resolution follows as $|\delta m| \propto \sqrt{h_{-1}\,V_{\varepsilon} \cdot V}$.
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Quantum Physics
Approximate synthesis of general single-qubit unitaries over the Clifford+$\sqrt{T}$ gate set
Mathias Weiden, Jae Won Kim, Justin Kalloor et al. (+2 more)
For the standard Clifford+$T$ gate set, deterministic, ancilla-free synthesis now attains the minimal $T$-count for general single-
qubit unitaries (Morisaki et al., arXiv:2510.05816). The $\sqrt{T}$ gate rotates by half the angle of $T$, generating a finer
lattice of implementable operations. It was assumed that access to this magic state lowers the cost of deterministic and ancilla-free synthesis of general single-
qubit unitaries, but no direct Clifford+$\sqrt{T}$
algorithm existed for this case. We provide one by extending the integer
lattice-point enumeration method of Morisaki et al. We adopt a resource state cost model based on the magic-state catalysis approach of Gidney and Fowler (arXiv:1812.01238). On Haar-random targets synthesized to precisions ranging from $\varepsilon=10^{-3}$ to $10^{-8}$, the cost of Clifford+$\sqrt{T}$
circuits scales as $2.4\log_2(1/\varepsilon)$ compared to $3.0\log_2(1/\varepsilon)$ for the provably $T$-count-optimal Clifford+$T$
circuits. Once a one-time catalyst state is amortized, the Clifford+$\sqrt{T}$
circuits are never costlier than their Clifford+$T$ counterparts.
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All authors Mathias Weiden, Jae Won Kim, Justin Kalloor, John Kubiatowicz, Costin Iancu
Quantum Physics · Cross-listed from cond-mat.mes-hall
Accurate noise spectroscopy using quantum sensing ensembles
Dhilan T Vallury, Nikolai Dontschuk, Alexander M Jakob et al. (+2 more)
Noise spectroscopy with
quantum sensors is a powerful tool for characterising the properties of the sensor environment and detecting critical
magnetic phenomena. While replacing single sensors with large ensembles promises substantial gains in measurement sensitivity and field of view, the output becomes difficult to interpret when there is a variable coupling to targets across the sensing ensemble. In this work we present an analysis procedure for accessing the true source noise spectrum using ensemble coherence from dynamical decoupling measurements. We show that sequence timing plays a dual role in ensemble noise spectroscopy, setting both the frequency selectivity and the weighted collection of signal across the ensemble, and demonstrate how incorporation of the coupling distribution allows accurate parameter extraction of the noise. We apply this procedure to a model system, shallow nitrogen-vacancy centres in diamond, and show that consistent information about the spectral character of MHz-range surface noise can be obtained from two sensing ensembles featuring distinct depth distributions. Our results pave the way for using large
quantum sensor ensembles for quantitative, broadband noise spectroscopy, with straightforward extension to other solid-state and molecular sensing platforms.
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All authors Dhilan T Vallury, Nikolai Dontschuk, Alexander M Jakob, Alexander J Healey, David A Simpson
Quantum Physics · Cross-listed from q-bio.PE
Graph construction in QUBO-based recursive phylogenetic tree reconstruction
Yoshiki Kanazawa and Takahiko Koyama
Molecular sequence data are used to reconstruct evolutionary relationships among taxa, but reconstruction accuracy depends not only on the tree-building method but also on how pairwise sequence relationships are represented. We evaluated sequence-to-affinity representations in a recursive normalized-cut (Ncut) framework whose graph-partitioning subproblems were formulated as quadratic unconstrained binary optimization (QUBO) models and solved using Simulated Bifurcation. Using simulated amino-acid and nucleotide
datasets spanning multiple tree-generation settings and evolutionary divergence, we compared normalized bit-score affinities with representations derived from transformed sequence similarities and evolutionary distances, examined post-swap refinement, and used neighbor joining (NJ) as a distance-based comparator. Affinity representation substantially affected internal split recovery, particularly for nucleotide data. JC69-based local affinities maintained comparatively high accuracy as divergence increased, whereas normalized bit-score and BLAST-derived kernel representations declined more markedly. Post-swap refinement generally improved recovery, but not consistently across individual reconstructions. NJ achieved higher mean split recovery than corresponding recursive Ncut reconstructions for WAG and JC69 distances across all evaluated conditions, whereas recursive Ncut outperformed NJ for BLAST-derived logarithmic distances under some conditions. These results show that graph construction is an important determinant of recursive Ncut-based phylogenetic reconstruction. A representation that performs well within Ncut does not necessarily provide the most accurate use of the underlying pairwise distances. Pairwise representation, affinity transformation, optimization, and recursive tree construction should therefore be evaluated jointly.
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Quantum Physics
Two-qubit gates for the soft 0-{\pi} qubit
Zhenxing Liu, Eli Weissler and Joshua Combes
The 0-{\pi}
qubit promises longer lifetimes than the transmon, making it a strong candidate for a next-generation, lower-error
qubit. Gyenis et al. experimentally demonstrated an unprotected single-
qubit gate in the soft 0-{\pi} regime [1], but no corresponding two-
qubit gate has yet been proposed. We propose an unprotected CZ gate for capacitively coupled soft 0-{\pi}
qubits. The gate uses a direct transition between a computational state and a higher non-computational state. Assuming negligible device disorder and a phenomenological noise model, the simulated CZ gate achieves a fidelity of approximately 99.9% at a gate time of approximately 160 ns.
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Quantum Physics
Quantum Simulation of Two-Dimensional Free Dirac Hamiltonian in Multimode Circuit QED
Jiwon Kang, Jiuk Lee, Eliya Blumenthal et al. (+2 more)
Two-dimensional massive Dirac systems feature a gapped Dirac-cone dispersion central to a broad range of phenomena in condensed-matter and topological physics. While
quantum simulations have demonstrated one-dimensional Dirac dynamics and two-dimensional massless Weyl dynamics, programmable simulation of massive two-dimensional Dirac dynamics remains experimentally unexplored. Here, we realize a programmable two-dimensional free Dirac
Hamiltonian in
circuit QED, with independently tunable
spin-momentum couplings and mass, using a single Rabi-driven
qubit coupled to two modes of a multimode cavity. Using this
Hamiltonian, we observe rotational Zitterbewegung of a two-dimensional massive Dirac particle and its dependence on the effective mass. Time-dependent master-equation simulations incorporating measured decoherence, corrections beyond the rotating-wave approximation (RWA), and anharmonicity of the transmon reproduce the observed dynamics. Our results establish multimode
circuit QED as a compact, programmable platform for higher-dimensional relativistic
quantum dynamics and provide a foundation for exploring dynamical and topological phenomena in gapped Dirac systems.
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All authors Jiwon Kang, Jiuk Lee, Eliya Blumenthal, Shay Hacohen-Gourgy, Eunseong Kim
Quantum Physics
Floquet Dressing and Bath Spectral Effects on the Geometric Phase of a Driven Dissipative Qubit
Chirag Arora
The
geometric phase (GP) of a periodically driven symmetricspin-
boson model (SBM) is investigated using the process-tensor time-evolving
matrix product operator (PT-TEMPO) method. A longitudinal monochromatic field drives the
qubit along the same coordinate that couples to an Ohmic bosonic environment. The gauge-invariant kinematic GP is evaluated from the reduced-statetrajectory, and a circular non-additivity measure quantifies the combined effects of driving and dissipation relative to driven-
unitary and undriven-dissipative references. Amplitude, frequency, coupling-strength, and bath-cutoff sweeps reveal regimes in which periodic driving reduces or enhances environmental phase deformation relative to the
unitary counterpart. The one-cycle GP exhibits pronounced nonmonotonic drive frequency dependence, while its bath-induced shift depends sensitively on both coupling strength and cutoff. These trends are interpreted qualitatively in terms of Floquet dressing and bath spectral structure. A two-cycle echo provides a complementary reversibility diagnostic, whose persistence signal does not generally measure the Tong GP. The results characterize the non-additive influence of driving and dissipation on
geometric-phase dynamics and identify parameter regimes of reduced bath-induced deformation.
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Quantum Physics
Strong converse for the quantum capacity of the pure-loss bosonic channel
Mark M. Wilde
This paper reports the proof of a strong converse for the unconstrained
quantum capacity of the pure-loss bosonic channel. At every fixed rate above capacity, the
entanglement-generation fidelity of every code is bounded by a constant times the reciprocal of the number of channel uses. The bound holds without an energy constraint and for arbitrary encoded states, including states correlated across all input modes, and arbitrary joint decoders. The proof combines
quantum Chebyshev and hockey-stick testing inequalities with a uniform relative-
entropy-variance bound for the balanced pure-loss channel, corresponding to transmissivity $\eta=1/2$. The variance bound follows by expressing the balanced beam splitter in bright and dark modes: the dark modes are exactly in
vacuum, and any state orthogonal to that
vacuum contains at least one dark
photon. For general transmissivity, dilating the degrading attenuator reduces the problem to this balanced-channel setting and bounds the decoder test by precisely the factor that produces the known
quantum-capacity threshold. The resulting argument establishes the strong converse at the unconstrained
quantum capacity for every pure-loss bosonic channel.
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Quantum Physics · Cross-listed from cond-mat.stat-mech
Diffusivity in Dissipative Quantum Transport from an Exactly Solvable Krylov Chain
Zhi-Li Zhou and Jorge Noronha
The computation of transport coefficients in interacting
quantum many-body systems is rarely analytically accessible. Here, we develop a new Krylov-space mechanism that makes the leading density dependent correction to Green-Kubo diffusivity exactly calculable in the strong-dissipation regime of a one-dimensional noisy
spin-$\frac{1}{2}$ XXZ chain. This is done by showing that the density-polarization-dressed bond coherence generates a Krylov subspace where repeated action of the dissipator closes exactly on an explicitly identifiable operator family. Within this subspace, the dissipative dynamics is then mapped onto a self-similar semi-infinite chain with a boundary defect. Surprisingly, all Lanczos coefficients of the Krylov chain and its boundary Green's function can be determined exactly. The latter then determines the exact leading density-dependent correction to the diffusivity. Finally, we calculate analytically the full boundary-to-bulk Green's function and find that it decays exponentially along the emergent Krylov chain.
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Quantum Physics · Cross-listed from physics.chem-ph
Tailored coupled cluster method with sample-based quantum diagonalization: Application to titanium-based metallocene catalytic reactions for 1-hexene production
Tzu-Wei Lin, Hirotoshi Hirai, Kuan-Chieh Huang et al. (+3 more)
Sample-based
quantum diagonalization (SQD) is a hybrid
quantum-classical method for electronic-structure calculations. We applied SQD to a titanium-based metallocene catalyst system for 1-hexene production, where free-energy differences must be predicted within 1 kcal/mol to accurately determine product selectivity. However, currently accessible active spaces on
quantum computers are limited in size, leaving significant dynamical correlation effects outside the active space. To address this challenge, we combined SQD with Tailored Coupled Cluster (TCC) theory. In this SQD-TCC framework, static correlation is treated by SQD, while dynamical correlation is incorporated through CCSD and its perturbative triples extension, TCC(T). We calculated the relative energies of two transition states governing 1-hexene selectivity. While SQD alone did not yield converged relative energies within practically accessible active spaces, SQD-TCC and SQD-TCC(T) provided reasonably converged results. Importantly, the relative energy obtained from SQD-TCC(T) differed by more than 1 kcal/mol from the corresponding CCSD(T) result, demonstrating the significance of static correlation in this system and its impact on predicted selectivity. Although TCC(T) calculations based on CASCI are feasible for small active spaces, the present system requires substantially larger active spaces that are beyond the reach of CASCI. By using SQD, we were able to access active spaces impractical for classical CASCI calculations. These results demonstrate that both static and dynamical electron correlation are essential for a reliable description of this chemistry and highlight the importance of incorporating dynamical correlation into
quantum-computing approaches targeting chemically accurate simulations.
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All authors Tzu-Wei Lin, Hirotoshi Hirai, Kuan-Chieh Huang, Zih-Chao Hong, Hui-Zhong Zhuang, Tsung-Hui Li
Quantum Physics
Pretty good quantum state transfer via transcendental edge weights
Addison Ballif, Mark Kempton, James B. Larsen et al. (+3 more)
We prove that if we take a rooted product of a circulant graph with universal perfect state transfer with a path of fixed length whose end edge is weighted with a transcendental number, then there is pretty good state transfer between any pair of endpoints of these paths. As a consequence, in a path with an even number of vertices with transcendental weights on the two edges incident to the endpoints, there is pretty good state transfer.
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All authors Addison Ballif, Mark Kempton, James B. Larsen, Kellon Sandall, Christino Tamon, Trevor Wai
Quantum Physics
Partial projected ensembles reveal slow tilt-constrained information spreading
Yi-Rui Zhang, Yu-Jun Zhao, Han-Ze Li et al. (+1 more)
Projected ensembles reveal information about
quantum many-body dynamics beyond the reduced density
matrix. Here we investigate how spatial constraints affect the emergence of this information in a kicked Ising chain with a spatially varying longitudinal field. We consider partial projected ensembles, obtained by measuring a remote region while leaving an intervening buffer unobserved. Our numerical results reveal a pronounced contrast between nearly ballistic correlation onset in the ergodic regime and strongly delayed onset in the tilt-constrained regime, corroborated by
quantum mutual information. Despite these different onset scales, the conditional-state fluctuations decrease approximately exponentially with buffer length in both regimes. Full projected ensembles additionally exhibit slow relaxation and persistent measurement-basis dependence in their higher moments. We establish an information-theoretic characterization of the connected second moment and use a solvable dephasing model with effective-basis measurements to illustrate the separation of phase accumulation and coherence loss. Within this model, a factorially suppressed coupling envelope yields sublogarithmic spreading consistent with the finite-distance onset trends. Our results identify partial projected ensembles as probes of the distinction between the time required for correlations to develop and the information that remains accessible under partial observation.
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All authors Yi-Rui Zhang, Yu-Jun Zhao, Han-Ze Li, Jian-Xin Zhong
Quantum Physics
Phantom Codes: Hardness, Rate Optimal qLDPC Constructions, and Distance Limits
Rui Mao, Weixiao Sun and Shengyu Zhang
An $[[n,k,d]]$ stabilizer code is phantom if every in-block logical CNOT gate can be realized by a permutation of its physical
qubits. This eliminates the large and complicated physical overhead normally required for logical entangling gates. Yet this
symmetry is highly restrictive: phantom codes are rare, the number of logical
qubits is limited to $k=O(\log n)$, and no phantom qLDPC family with growing logical dimension was previously known. We make three contributions. 1. We prove that recognizing phantomness of a given stabilizer code is at least as hard as Graph Isomorphism, even for CSS codes encoding only $k=2$ logical
qubits. 2. We propose the first rate optimal phantom qLDPC families: for every fixed $D$, our CSS families achieve the maximal logical scaling $k=\Theta(\log n)$ and distance $d\geq D$. 3. We prove a distance no-go
theorem: every phantom code family with $k=\omega(\sqrt{\log n})$ and check weight $w=O(1)$ satisfies $d\leq w$ for sufficiently large $n$. Thus our fixed-distance qLDPC families are distance-scaling optimal at the maximal logical scaling $k=\Theta(\log n)$.
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Quantum Physics
Truncated hybrid tensor networks for distributed quantum simulation
Yong Liu, Guangyao Huang, Weixu Shi et al. (+4 more)
Simulation of
quantum many-body systems is a principal application of
quantum computing, but available devices remain limited by the number of
qubits and cannot accommodate systems of the desired size. One approach is to host a large
evolution across several modest distributed systems that exchange classical information alone. Current protocols such as
circuit knitting incur a quasi-probability sampling cost that grows exponentially with the number of remote gates across the cut, even when physical correlations across the cut are actually bounded. In this work, we present a truncated hybrid tensor network (THTN) framework in which a remote two-body gate is applied as a sum of local
unitaries on the subsystems, linked by a classical connecting tensor, and an interface truncation retains Schmidt modes across the cut. Remote gates between the same subsystems can be merged on one connector, so non-one-dimensional models, such as layered partitions with strong intra-layer and weaker interlayer couplings, may be cast onto a one-dimensional cut. The retained non-negative Schmidt coefficients also define a sampling rule for local observables. We validate this distributed protocol by classical simulation against time-evolving block decimation (TEBD) at the same bond dimension. The truncated dynamics track the TEBD references on chains and ladders, with the clearest gain on a layered model.
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All authors Yong Liu, Guangyao Huang, Weixu Shi, Yizhi Wang, Jiandong Ouyang, Zeqian Chen, Junjie Wu
Quantum Physics
Exact Ionization Amplitudes for a Delta-Function Well in an Arbitrary-Strength DC Electric Field
Ilki Kim and Gerald J. Iafrate
We investigate finite-time field-induced ionization from a one-dimensional attractive delta-function well in a uniform dc electric field of arbitrary strength. Our aim is to determine the physical bound-state survival amplitude \(a_b(t)\) at any observation time without constructing the complete time-dependent propagator or wavefunction. In the gauge-equivalent Kramers–Henneberger representation, the field appears as motion of the contact point, and the resulting dynamics reduces to a closed Volterra equation. Exact endpoint-phase factorization organizes the full chronological rescattering history into a relative-time convolution hierarchy and an exact resolvent. By introducing the accumulated bound-state amplitude and reorganizing its two-time domain in relative and complementary center times, the final contact contribution becomes an explicit boundary integral. All spatial integrations are carried out analytically. The field-driven contact-free term is obtained in closed form using the Faddeeva function, while the direct and repeated-rescattering terms are expressed as explicitly evaluable time integrals. The result applies at arbitrary dc-field strength and finite time, with no weak-field expansion, rescattering truncation, or asymptotic-time approximation. It is verified through the exact field-free limit and an independent numerical solution of the original physical Volterra equation. The formulation gives an exact nonperturbative solution of a fundamental ionization model and reveals otherwise hidden analytical structure in driven
quantum dynamics.
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Quantum Physics
A complete classification of the existence of finite-dimensional quantum solutions to inconsistent linear constraint systems
Markus Frembs
Linear constraint systems (LCS) provide a compact algebraic
language for nonlocal games and state-independent contextuality. In the binary case the Mermin–Peres square shows that inconsistent LCS can be solved by promoting variables to local Pauli operators, whereas a series of no-go results excludes analogous Pauli-, Clifford- and monomial
unitary-based constructions at odd
prime modulus. We first isolate the reason for this difference: for tensor-product
quantum solutions, the obstruction to a classical solution of a LCS over $\mathbb{Z}_n$ decomposes into obstruction classes carried by the individual factors. As a consequence, a genuinely global obstruction cannot arise solely by tensoring locally unobstructed systems. The argument is specific to odd modulus; at even modulus the reordering phase need not vanish, as in Pauli-based examples. Given this distinction, we instead associate LCS to finite arrangements of rank-one projectors and resolutions of the identity in finite-dimensional vector spaces.
Quantum solvability for such LCS is automatic and the search for a
quantum-classical gap rests entirely on proving classical unsatisfiability of the underlying modular incidence problem of the arrangement. By relating such LCS with group-valued frame functions, we identify a family of examples in the work of [Harding, Jager, and Smith, Int. J. Theor. Phys. 44, 539 (2005)]. To establish the (non)existence of classically unsatisfiable LCS over $\mathbb{Z}_n$ with
quantum solutions in all dimensions $d$ and for all $n\in\mathbb{N}$, we further construct explicit examples for the cases $d=n$
prime. Our main result thus positively resolves the existence problem of such LCS beyond the binary case: such systems exist if and only if $d\geq 3$ and $\gcd(n,d)>1$. Moreover, we establish the existence of LCS with a
quantum-classical gap over finite fields if and only if $d\geq 3$ and $p\mid d$.
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Quantum Physics
Error-Bounded Fixed-Point Design of Super-Sample-Rate IIR Filters for Real-Time Superconducting Qubit Flux Predistortion
Matt Huszabianlou, Angelos Ioannou, Nirmalendu Bikash Patra et al. (+3 more)
Flux-activated two-
qubit gates in superconducting processors require correction of line distortion, which otherwise produces residual detuning, conditional-phase error, and leakage. Prior demonstrations of cryoscope-based distortion calibration have generally used commercial solutions that specify the filter models but not their FPGA implementation. These details matter for custom and open-source systems, where the fixed-point coefficient and datapath formats set how accurately the correction is realized, and the IIR feedback loop in its standard form does not meet timing at the required clock rate. We derive the coefficient formats of the correction filters from a step response error tolerance, using bounds on the quantization-induced displacement of the poles and zeros over the physical parameter range of each distortion, and the accumulator format from the smallest input change that must remain resolvable at the output. The same analysis gives the conditions under which quantization preserves filter stability. We implement the resulting FIR/IIR cascade on the QubiC platform at a fabric clock rate of \SI{500}{MHz}, using a super-sample-rate structure with scattered look-ahead pipelining, which removes the feedback recursion from the critical path without changing the target transfer function. A representative cascade for our \SI{1}{GS/s} flux lines, comprising an integrator, a second-order section, and a 20-tap FIR, consumes 88 DSP slices and adds \SI{162}{ns} of latency. We confirm the hardware implementation by correcting characteristic bias-tee distortion, an intermediate step toward full cryoscope-based calibration.
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All authors Matt Huszabianlou, Angelos Ioannou, Nirmalendu Bikash Patra, Anastasiia Butko, Gang Huang, Irfan Siddiqi
Quantum Physics
Environmental records unlock universal quantum computation from thermal decoherence
Chenfeng Cao and Qi Zhao
At a fixed thermal exposure, the same stabilizer processor can be classically simulable or
quantum universal, depending on which environmental records its controller retains. We give an exact computational classification of energy-counting thermal-idle instruments in a
quantum processor with ideal stabilizer control and independent local Markov baths. The relaxation time $T_1$, homogeneous coherence time $T_2$, and
equilibrium excited-state population $p_e$ determine an exact computational boundary at $(1-p_e)T_2/T_1=1$. If every location lies at or below it, branchwise nonnegative stabilizer decompositions give an explicit efficient classical sampler for the adaptive
circuit and its full time-resolved exchange record. Above it at a single repeatedly accessible location, a suitable idle duration and no-exchange conditioning supply distillable ancillas and enable universal
quantum computation with
polynomial overhead. At finite temperature on the resource side, erasing the record at a sufficiently long, unsplit exposure makes the averaged channel stabilizer measure-and-prepare, and even a terminal parity check then yields only simulable branches. Yet at that same exposure, retaining only the bit recording whether any exchange occurred still heralds distillable ancillas, because a thermal round trip restores the parity after its first exchange has already removed the coherence.
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