Quantum Physics
Papers
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Wednesday 11 March
Hybrid quantum computing systems that combine discrete-variable qubits with continuous-variable qumodes offer promising advantages for quantum simulation, error correction, and sensing applications. However, existing quantum software frameworks lack native support for expressing and manipulating hybrid circuits, forcing developers to work with fragmented toolchains or rely on simulation-coupled representations that limit scalability. We present Hybridlane, an open-source software development kit providing a unified frontend for hybrid continuous-discrete variable quantum computing. Hybridlane introduces automatic wire type inference to distinguish qubits from qumodes without manual annotations, enabling compile-time validation of circuit correctness. By decoupling gate semantics from matrix representations, Hybridlane can describe wide and deep circuits with minimal memory consumption and without requiring simulation. The framework implements a comprehensive library of hybrid gates and decompositions following established instruction set architectures, while remaining compatible with PennyLane's extensive qubit algorithm library. Furthermore, it supports multiple backends including classical simulation with Bosonic Qiskit and hardware compilation to Sandia National Laboratories' QSCOUT ion trap. We demonstrate Hybridlane's capabilities through bosonic quantum phase estimation and ion trap calibration workflows.
Quantum Physics
Quantum Hypergraph States: A Review
Quantum hypergraph states extend the well-studied class of graph states by taking into account multi-qubit interactions through hyperedges. They provide a powerful framework to represent a family of quantum states with genuine multipartite entanglement. In this review, we provide a compact overview of the formal structure, entanglement characteristics, and operational relevance of hypergraph states in quantum information theory. We begin by introducing their mathematical foundations and generalizations of the stabilizer formalism. A central focus is placed on their entanglement properties, including the classification under local unitary (LU) and stochastic local operations with classical communication (SLOCC), the quantification of multipartite entanglement, and detection techniques via entanglement witnesses. We also explore other nonclassical features of hypergraph states, such as contextuality and genuine multipartite nonlocality, derived from stabilizer-based Bell-type inequalities. Additional attention is given to the role of hypergraph states in error correction, and as a computational resource in measurement-based quantum computation (MBQC), and to their non-stabilizer character - quantified via resource-theoretic measures of quantum magic. Finally we review their generalization to higher dimensions, i.e. to qudits and continuous variables.
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Quantum Physics
Quantum Telepathy: A Quantum Technology with Near-Term Applications
Quantum telepathy is the concept of using quantum entanglement to solve real-world problems involving decision coordination between parties with restricted communication. One possible reason for this restriction is a latency constraint: some pairs of parties do not have enough time to communicate with each other before they have to produce their outputs. Example scenarios include high frequency trading and distributed systems. Another reason is physical or operational isolation: for some pairs of parties, there is an obstacle to communication. Example scenarios include locating a stray traveler by a rescue team and coordination within a network where nodes are owned by competing firms. In this paper we give a concise overview of the different application areas of quantum telepathy. We find that these real-world problems can be modeled as a nonlocal game or its generalizations. We also discuss possible physical implementations. Quantum telepathy guarantees a quantum advantage via Bell's theorem and can directly solve real-world problems, such as reducing risk in high frequency trading or balancing data loads efficiently in ad hoc networks. Moreover, this quantum advantage can be physically realized with existing or near-term quantum hardware.
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Quantum Physics
Star Topology Optimizes the Charging Power of Quantum Batteries
Quantum batteries are quantum systems that store energy and deliver it on demand, and their practical value hinges on how fast they can be charged. While collective charging protocols and global control are known to enhance charging power, it remains unclear how the battery's internal interaction architecture itself constrains performance. Here we study interacting fermionic batteries whose internal couplings are encoded by a graph adjacency matrix, charged via a simple interaction with an external fermionic device. We prove that the star topology maximises the early time charging power, which proxies the maximal average power - a widely used quantum battery quality metric. We substantiate the result numerically by an exhaustive sweep over all graphs with $N\leq 7$ vertices and by benchmarks against random graph ensembles at larger $N$. Our findings shed light on architecture as a controllable knob for fast charging and motivate hub-and-spoke designs in scalable quantum-battery platforms.
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Quantum Physics
Entanglement distillation based on Hamiltonian dynamics
Efficient entanglement distillation is a central task in quantum information science and future quantum networks. At the core of distillation protocols are the quantum error correction and detection schemes which enhance the fidelity of entangled pairs. Conventional protocols focus on digital systems, which typically require complicated compiled circuits, high-fidelity multi-qubit operations and delicate pulse-level control that impose high demands on near-term hardware. Crucially, the leading physical platforms for quantum networks, trapped ions and neutral atoms, are governed by native many-body Hamiltonians inherently suited for analog, continuous-time evolution. Adopting these natural dynamics is simpler than engineering digital logic via delicate pulse-level control. Motivated by this experimental reality, we seek to leverage the intrinsic analog capabilities for efficient entanglement distillation. In this work, we introduce the Hamiltonian entanglement distillation protocol, which exploits the intrinsic information scrambling generated by random time evolution under native Hamiltonians. We establish a quantitative connection between output fidelity and Out-of-Time-Order Correlators, showing that efficient scrambling directly implies good distillation performance. Since generic Hamiltonians are naturally efficient scramblers, the capability for distillation is ubiquitous: almost all Hamiltonians in the Hilbert space suffice for high-fidelity distillation. Numerical simulations of representative Rydberg-atom and trapped-ion systems further confirm that robust performance could be achieved using only short-range interactions and evolution times feasible in current experiments. By avoiding the complexity of digital circuit control, our approach substantially relaxes experimental requirements, providing a scalable route to entanglement engineering on current analog quantum platforms.
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Quantum Physics
Open quantum systems beyond equilibrium: Lindblad equation and path integral molecular dynamics
The Lindblad equation determines the time evolution of the density operator of open quantum systems. While valid for any system size, its use is, in practice, restricted to prototype/surrogate models with the aim of tackling specific aspects of the overall quantum complexity of a multi-atomic system. Path integral molecular dynamics (PIMD) instead provides static and dynamical quantum statistical averages of physical observables for systems in equilibrium composed of up to thousands of atoms over timescales up to nanoseconds, under the condition that short-time quantum coherence is not relevant for the properties of interest. PIMD relies on the well-established technique of molecular dynamics (MD) with its associated classical trajectories. However, it cannot describe a direct time evolution of a system and its convergence to a stationary state in situations out of equilibrium. In this work, we analyze the link between the Lindblad equation and PIMD; specifically, we will discuss how PIMD can actually be used to calculate the time evolution of ensemble-averaged physical observables and their convergence to a stationary state for situations out of equilibrium, bypassing the need of explicitly solving the Lindblad equation. Yet, at the same time, the Lindblad equation and PIMD are linked to one another through a formal relation of equivalence, which provides an argument for the consistency of PIMD results, namely the positivity of the density operator at any time. A numerical study of a prototype system, which is of interest in chemical physics, will be used to showcase the method.
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Quantum Physics · Cross-listed from cond-mat.stat-mech
Dissipation- versus Chaos-Induced Relaxation in Non-Markovian Quantum Many-Body Systems
In interacting quantum many-body systems, relaxation toward equilibrium reflects a competition between internal chaotic dynamics and environmental dissipation. While conventional Markovian baths typically produce exponential decay, non-Markovian dissipation can give rise to more intricate behavior, including algebraic relaxation. We study an open Sachdev-Ye-Kitaev (SYK) model coupled to a pseudogapped fermionic bath, using the Keldysh formalism to compute steady-state correlations in the large-$N$ limit. Our results uncover a rich dynamical phase diagram, with regimes of bath-driven power-law relaxation, chaos-driven exponential decay, and an intermediate pre-relaxation phase where exponential decay crosses over to algebraic decay. These findings demonstrate that non-Markovian environments can qualitatively reshape relaxation mechanisms in strongly correlated quantum many-body systems.
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Quantum Physics
High fidelity photon-photon gates by scattering off a two-level quantum emitter
We present a scheme for implementing a high-fidelity non-linear phase shift on a photonic state. The scheme is based on repeated scattering off a two-level quantum emitter embedded in a chiral or one-sided waveguide. The waveguide is equipped with elements inducing second-order dispersion and temporal phase shifts, which effectively form a harmonic trap and confine the photon pulses to a Gaussian shape. The same quantum emitter can be used for each scattering, and thus, only one quantum emitter is needed in this scheme. To illustrate the application of our scheme for photonic quantum computing and quantum communication, we analyze the implementation of a control-Z gate and a deterministic Bell-state analyzer for photonic qubits. Through numerical optimization, we show that we can reach a control-Z gate fidelity of $\mathcal{F} \sim 99.2\%$ ($\mathcal{F} \sim 96\%$) and a success probability of $P_s \sim 99.6 \%$ ($P_s\sim 98 \%$) for a Bell-state measurement with $N=17$ ($N=5$) scatterings.
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Quantum Physics
Quantum Limits of Passive Optical Surface Metrology and Defect Detection
We develop a quantum statistical framework for passive optical surface metrology. Modelling a surface as an incoherent ensemble of point emitters imaged through a diffraction-limited system, we employ techniques from quantum parameter estimation and hypothesis testing to derive ultimate bounds for jointly estimating geometrical features and for deciding the presence or absence of surface defects, and we identify optimal measurements from the geometry of the point-spread-function manifold. As a representative application, we analyse a minimal surface crack model based on three point sources and show that spatial mode sorting can simultaneously enable near-quantum-limited estimation of crack width and depth and markedly enhanced detectability of the crack, compared with direct imaging. Our results pave the way towards enhanced optical inspection and characterisation of sub-diffraction surface features by probing a limited number of spatial modes without any illumination control.
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Quantum Physics
Universal purification dynamics in real non-unitary quantum processes
We study purification dynamics in monitored quantum processes governed by ensembles of quantum circuits in different random-matrix symmetry classes. We analyze the universal aspects that emerge away from the measurement induced phase transition and inside the volume/weak measurement phase and in the scaling limit of large time and Hilbert space dimension. We present two toy models that reveal two complementary visions and provide quantitative access to universal scaling: i) a discrete-time dynamic in which each time step corresponds to multiplication by a Gaussian random matrix; ii) weak continuous-time monitoring that induces a Dyson brownian motion of the eigenvalues of the density matrix. The first approach provides an algebraic characterization based on rotational invariance emerging in Kraus's operator space, focusing in particular on the unitary and orthogonal cases, respectively $\beta=2$ and $\beta=1$, with $\beta$ the Dyson random-matrix index. The second approach, on the other hand, allows for a unified treatment for any $\beta$, thanks to the mapping of the Fokker-Planck evolution of eigenvalues onto the Calogero-Sutherland integrable Hamiltonian diagonalized in terms of Jack polynomials. We provide explicit expressions for the universal decrease of Rényi entropies. We show that, approaching the universal scaling limit, numerical simulations of different models agree with each other and with our theoretical predictions. Our results clarify the existence of different classes of universality for the purification process in hybrid quantum systems, accessible in random circuit architectures and weak measurement protocols.
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Quantum Physics · Cross-listed from physics.atom-ph
Zero crossings of the differential scalar polarizability of Ba$^+$ clock transition
The differential scalar polarizability $\Delta\alpha_0(\omega)$ of the Ba$^+$ S$_{1/2}$-to-D$_{5/2}$ clock transition has a zero crossing near 481nm, which is measured to be 623.603\,13(17)\,THz. From this measurement, we infer a ratio of reduced matrix elements $\langle P_{3/2}\|r\|S_{1/2}\rangle/\langle P_{1/2}\|r\|S_{1/2}\rangle=1.411\,81(13)$, which provides a stringent test of atomic structure calculations and experimental determination of matrix elements. Additionally, it enables the construction of an accurate approximation to $\Delta\alpha_0(\omega)$, valid for frequencies up to 450\,THz, with only one reduced matrix element, $\langle P_{1/2}\|r\|S_{1/2}\rangle$, appearing in the model's parameterization. We discuss the achievable accuracy of the model, the application to the assessment of blackbody radiation (BBR) shifts in ion-based clocks, and the applicability of the approach to other alkaline-earth ions.
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Quantum Physics
Hybrid Photonic Quantum Reservoir Computing for High-Dimensional Financial Surface Prediction
We propose a hybrid photonic quantum reservoir computing (QRC) framework for swaption surface prediction. The pipeline compresses 224-dimensional surfaces to a 20-dimensional latent space via a sparse denoising autoencoder, extracts 1,215 Fock-basis features from an ensemble of three fixed photonic reservoirs, concatenates them with a 120-dimensional classical context, and maps the resulting 1,335-dimensional feature vector to predictions with Ridge regression. We benchmark against 10 classical and quantum baselines on six held-out trading days. Our approach achieves the lowest surface RMSE of~$0.0425$ while maintaining sub-millisecond inference. The quantum layer has zero trainable parameters, sidestepping barren plateaus entirely. Variational quantum methods (VQC, Quantum LSTM) yield negative $R^{2}$ on test data, confirming that fixed quantum feature extractors paired with regularised readouts are more viable for low-data financial applications.
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Quantum Physics
Two-qubit-gate operation in a high-connectivity transmon lattice utilizing a tunable coupling to a shared mode
Increasing connectivity and decreasing qubit-state delocalization without compromising the speed and accuracy of elementary gate operations are topical challenges in the development of large-scale superconducting quantum computers. In this theoretical work, we study a special honeycomb qubit lattice where each qubit inside a unit cell is coupled to every other one via two dedicated tunable couplers and a common central element. This results in an effective multi-mode interaction enabling tunable, on-demand, all-to-all connectivity between each qubit pair within the unit cell. We provide a thorough analysis of the unit cell, including a proposal for a novel and efficient conditional-Z gate scheme which takes advantage of the effective multi-mode coupling. We develop an experimentally viable pulse protocol for a single-step gate implementation which considerably improves the gate speed compared to the previous two-qubit-gate realizations suggested for architectures utilizing a center mode. We also show numerical results on how the presence of spectator qubits affects the average two-qubit-gate fidelity, and analyse how the multi-mode coupling structure mitigates the delocalization-induced crosstalk during simultaneous single-qubit gates within the unit cell. We also provide analytical estimates for the errors caused by relaxation and dephasing during a two-qubit-gate operation, including noise terms for the multi-mode coupling structure. Our multi-mode coupling architecture results in a good balance between increased connectivity and available parallelism, especially when several interacting unit cells form a quantum processing unit. We anticipate that the obtained results pave the way towards high-connectivity quantum processors with efficient and low-overhead quantum algorithms.
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Quantum Physics
Probing the ergodicity breaking transition via violations of random matrix theoretic predictions for local observables
Quantum many-body systems can exhibit distinct regimes where dynamics is either ergodic, dynamically exploring an extensive region of available state-space, or non-ergodic, where the dynamics may be restricted. An example is the many-body localization (MBL) transition, where disorder induces non-ergodic behaviour. Most measures of ergodicity notably rely on global quantities, such as level spacing statistics. We explore the ability for a subsystem to probe the ergodicity of dynamics via measurement of local observables, and use expected results from random matrix theory (RMT) as a benchmark for the ergodic regime. We exploit two predictions from RMT as ergodicity is broken: the time evolution of the quantum Fisher information, and a fluctuation-dissipation relation. These are investigated in three different ergodicity breaking mechanisms, namely, as a consequence of transition to integrability, MBL, and Quantum Many-Body Scars (QMBS). We show that the predicted behaviour from RMT can be used as a potential witness for transition to non-ergodic behaviour from the measurement of local observables alone.
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Quantum Physics
Dressed-State Optomechanics in the Few-Photon Regime
Efficient optomechanical cooling typically requires high photon occupancy to maximize cooling power, a constraint that generally limits the degree of coherent quantum control available in the few-photon regime. Here, we investigate this trade-off by considering a strongly nonlinear cavity operated as a discrete quantum system. In the weak-coupling limit, we derive a general connection between the optomechanical damping rate and the cavity's dressed-state manifold. This framework reveals that the damping rate (determined by the population imbalance across dressed states) is directly tunable via the coherent manipulation tools which are standard in circuit quantum electrodynamics. We illustrate this framework using a Josephson photonics architecture, where a dc-biased junction induces a photon blockade that truncates the cavity to an $N$-level system. By sacrificing raw cooling (or heating) power, this platform enables full quantum mechanical control over optomechanical properties, offering a versatile avenue for the quantum manipulation of mechanical modes.
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Quantum Physics
Self-testing with untrusted random number generators
Self-testing–the attractive possibility to infer the underlying physics of a quantum device in a black-box scenario–has gained increased traction in recent years, with applications to device-independent quantum information processing. Thus far, self-testing has been done under the assumption that the settings for the requisite Bell test are chosen freely and independently of the device tested in the experiment. That is, the random number generator used to generate the settings has been assumed to have no correlations with the device tested. Here, we extend self-testing protocols beyond the independence assumption. Surprisingly, we show that all pure bipartite partially entangled states can be self-tested provided that the random number generator obeys a residual randomness constraint strictly weaker than the independence assumption. This in itself provides a semi-device-independent certification of independence between the randomness source and the device.
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Quantum Physics
Graph Symmetry Organizes Exceptional Dynamics in Open Quantum Systems
Exceptional points (EPs), indicative of parity-time (PT) symmetry breaking, play a central role in non-Hermitian physics, yet most studies begin from deliberately engineered effective Hamiltonians whose parameters are tuned to exhibit exceptional behavior. In realistic open quantum systems, however, dynamics are governed by Lindblad superoperators whose spectral structure is high-dimensional, symmetry-constrained, and not obviously reducible to minimal non-Hermitian models. A general framework for discovering exceptional dynamics directly from microscopic dissipative models has been lacking. Here we introduce a symmetry-resolved approach for identifying and characterizing exceptional points directly from the full Liouvillian generator. Correlated dissipation induces graph symmetries that decompose Liouville space into low-dimensional invariant sectors, within which minimal non-Hermitian blocks govern the onset of EPs and PT-breaking behavior. We further introduce a numerical diagnostic - the exceptional-point strength $\mathcal{E}$ - based on eigenvector conditioning, which quantifies proximity to defective dynamics without requiring analytic reduction. Applied to tight-binding models with correlated dephasing and relaxation, the method reproduces analytically predicted exceptional seams and reveals universal scaling of $\mathcal{E}$ near EP manifolds. More broadly, the framework enables systematic discovery of hidden exceptional structure in complex or high-dimensional open systems and is naturally compatible with matrix-free and tensor-network implementations for scalable many-body applications.
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Quantum Physics
Experimental simulation of non-equilibrium quantum piston on a programmable photonic quantum computer
Quantum fluctuation relations provide a microscopic formulation of thermodynamics beyond equilibrium, but experimentally accessing many-body quantum work statistics remains an outstanding challenge. The quantum piston constitutes a canonical model of boundary-driven nonequilibrium dynamics, where finite-time deformation of a confining potential generates non-adiabatic transitions, dissipation and irreversibility. Here we experimentally simulate the nonequilibrium dynamics of a two-boson quantum piston on a programmable photonic quantum computer. Using two indistinguishable photons, we encode a truncated piston propagator through a quasi-unitary embedding, with an ancilla mode representing leakage into higher-energy states outside the resolved manifold. This architecture enables direct reconstruction of thermodynamic transition statistics for both expansion and compression protocols as functions of driving speed and final trap length. We observe the crossover from quasi-adiabatic to strongly non-adiabatic evolution and show that bosonic interference restructures the resulting two-particle Fock-state populations and work distributions. The measured statistics are in close agreement with theoretical predictions and satisfy the Jarzynski equality across expansion and compression protocols for cyclic driving we further quantify irreversibility through dissipated work and state overlap. Our work identifies programmable photonic quantum hardware as a powerful platform for simulating nonequilibrium quantum thermodynamics and for experimentally resolving how indistinguishability and many-body interference shape quantum work, dissipation and entropy production.
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Quantum Physics
Topological robustness of orbital angular momentum entanglement in stochastic channels
Orbital angular momentum (OAM) entanglement gives access to multiple qubit and high dimensional Hilbert spaces, but is unfortunately susceptible to disturbance, decaying in real-world noisy channels. Here, we show there is an underlying topology arising from OAM entanglement that is robust to such channels, which we demonstrate using atmospheric turbulence – exemplary of stochastic or chaotic media. Using a quantum channel with various turbulence strengths, we find the OAM topological observable preserved even though the OAM itself is shown to be highly sensitive to the turbulence. We show this is true for mixed states too, with the OAM topology intact even as the purity of the state decreases due to decoherence. Our work offers a new perspective on OAM entanglement preservation, and may easily be extended to other spatial bases, degrees of freedom, as well as complex channels, whether static or dynamic.
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Quantum Physics
Fundamental Limits of Non-Hermitian Sensing from Quantum Fisher Information
Exceptional points (EPs) exhibit strongly enhanced spectral responses and are therefore promising candidates for sensing applications. Whether these non-Hermitian degeneracies provide a genuine advantage in the quantum regime has been the subject of ongoing debate. Here, we address this issue within a scattering-matrix formalism for sensing with coherent light, which allows the quantum Fisher information (QFI) to be evaluated directly from experimentally accessible scattering data without introducing additional noise channels beyond those inherent to the scattering process. We analyze both nondegenerate and degenerate scattering-matrix poles, including EPs of arbitrary order, and show that the QFI per incoming photon flux is governed by three key factors: the decay rate of the resonant mode, the strength of the spectral response associated with non-normality, and the adjustment between the scattering states and the information source. For spatially localized perturbations, this implies that the Fisher information is fully determined by the local density of states at the perturbation site. Within this framework, we demonstrate that EPs can enhance the QFI compared to isolated modes or diabolic points with identical decay rates, and that the QFI can be further increased by moving away from the EP toward parameter regimes where non-Hermitian linewidth splitting reduces the decay rate of one mode. We further show that sufficiently small additional internal losses do not alter this overall picture, thereby providing a unified and experimentally relevant perspective on the design of quantum-limited non-Hermitian sensors.
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Quantum Physics
Is the existence of unbounded operators a problem for quantum mechanics? In response to Carcassi, Calderon, and Aidala
In this paper I argue against Carcassi, Calderon, and Aidala's recent claim that the Hilbert spaces are unphysical and should be replaced with the Schwartz spaces in quantum mechanics, since Hilbert spaces include states with infinite expectation values for certain observables. I also review and discuss issues regarding unbounded operators in quantum mechanics raised by Streater and Wightman, Heathcote, and Lemos. I argue that the existence of infinite expectation values does not cause problems in quantum mechanics. On the other hand, replacing the Hilbert spaces with the Schwartz spaces would cause more issues, as it would exclude a class of meaningful Hamiltonian evolutions. I also discuss the question in literature whether reformulating quantum mechanics with essentially self-adjoint operators instead of self-adjoint operators may cause problems. I further analyse the hierarchies of the notions of "physicality" and possibility in fundamental physics, and suggest that "physicality" is a vague concept. Finally, I connect the problem raised by Carcassi, Calderon, and Aidala with the problem of the Hadamard condition in quantum field theory.
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Quantum Physics
Optical quantum teleportation with known amplitude distorting factors of teleported qubits
We develop a quantum teleportation protocol of an unknown optical single rail qubit using a hybrid quantum channel composed of continuous variable (CV) states of certain parity. The quantum channel is characterized by two parameters: a squeezing parameter of single-mode squeezed vacuum (SMSV) state and the beam splitter (BS) parameter used to implement it. The CV part of the hybrid state belongs to Alice, while discrete variable (DV) half is controlled by Bob. The third parameter of the protocol is a parameter of the beam splitter, used to mix the CV components of the hybrid quantum state with unknown optical single-rail qubit. Even though the number of measurement results Alice sends may increase, Bob can obtain the original qubit half the time with an appropriate choice of parameter values. In almost half the remaining cases, Bob obtains the original qubit with distorted amplitudes, and both participants know the value of the distortion factors. This means that as the amount of classical information transmitted by Alice increases, they both gain greater access to partial information about the unitary transformations that the teleported qubits undergo, allowing Bob to continue using them or attempt to recover them to improve the protocol's efficiency. The proposed method is a generalization of quantum teleportation with a nonlocal photon used as a quantum channel and unknown single-rail optical qubit.
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Quantum Physics
Entanglement distribution among distinct mechanical nodes in a quantum network
We propose two schemes to achieve remote entanglement distribution between two mechanical nodes with a significant frequency mismatch, based on optomechanical systems. The first scheme utilizes the physical mechanism to redistribute the quantum entanglement initially established in a dispersively-coupled optomechanical system with a megahertz mechanical resonance to a distant optomechanical system which embodies the tripleresonant interaction induced by the scattering of gigahertz mechanical phonon. We also provide a fast optical pulse protocol to realize the long-distance entanglement distribution from the optomechanical system supporting the gigahertz mechanical mode to the megahertz mechanical mode included in a distant optomechanical system. Specifically, these two schemes respectively demonstrate the megahertz-to-gigahertz and gigahertz-tomegahertz entanglement distribution in the quantum network of optical photons and phonons. This work may facilitate the application of various mechanical systems in hybrid quantum network-based quantum technologies and fundamental physical research.
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Quantum Physics · Cross-listed from physics.atom-ph
Quantum-logic spectroscopy of forbidden vibrational transitions in single nitrogen molecular ions
Electric-dipole forbidden spectroscopic transitions in atoms form the basis of many advanced implementations of quantum computers, atomic clocks and quantum sensors. Coherently addressing such transitions in molecules which are among the most ubiquitous and versatile quantum objects has remained a long-standing challenge owing to their complex energy-level structure. Here, we report the search, observation and coherent manipulation of electric-quadrupole rotational-vibrational transitions in single trapped molecules using a quantum-logic-spectroscopy protocol. We identified individual hyperfine-Zeeman-rotational components of the fundamental vibrational transition of the nitrogen molecular ion, N$_2^+$, and performed coherent population transfer between energy levels. Our work opens up new perspectives for precision molecular spectroscopy, for high-fidelity qubits encoded in the rotational-vibrational motion of molecules, for precise infrared molecular clocks and for searches for new physics
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Quantum Physics · Cross-listed from cond-mat.mtrl-sci
First-Principles Electronegativity Scale from the Atomic Mean Inner Potential
Electronegativity is a cornerstone of chemical intuition, essential for rationalizing bonding, reactivity, and material properties. However, prevailing scales remain empirically derived, often relying on parameterized models or composite physical quantities. In this work, we introduce a universal electronegativity scale founded on the atomic mean inner potential (AMIP), also known as the average Coulomb potential, a fundamental, quantum-mechanical property accessible through both first-principles computation and electron-scattering experiments. Our scale, denoted $\chi_{\mathrm{AMIP},p}$, is an analytic function of just three ground-state atomic descriptors and carries explicit physical units. It demonstrates excellent agreement with established scales and successfully classifies bonding types across 358 compounds, including adherence to the metalloid “Si rule". Beyond replicating known trends, $\chi_{\mathrm{AMIP,1/2}}$ proves to be a powerful predictive tool, accurately determining Lewis acid strengths for over 14,000 coordination environments ($R^2=0.93$) and $\gamma$-ray annihilation spectral widths for 36 elements ($R^2=0.97$), outperforming previous methods. By linking electronegativity directly to a measurable quantum property, this work provides a unified and predictive descriptor for electronic structure and chemical behavior across the periodic table.
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Quantum Physics
Airfoil shape optimization via coherent Ising machine
Airfoil shape optimization presents a challenge where classical solvers frequently struggle with computational efficiency and local minima. In the promising paradigm of quantum computing, the coherent Ising machine (CIM), a specialized physical solver, offers acceleration capabilities. However, its native discrete binary architecture restricts the application in aerodynamic design. To bridge this gap, we propose a comprehensive framework that translates airfoil shape optimization into hardware-compliant quadratic unconstrained binary optimization formulations. We integrate high-order response surface models via the Rosenberg order reduction, enabling the CIM to capture strong nonlinearities in the aerodynamic performance response. Furthermore, we introduce a block-diagonal scalarization strategy that compose trade-off scenarios into a single optimization. Validated on the NACA 4-digit airfoil series using CIM hardware with 615 spins, the framework successfully locates the global optimum with a computational speedup of three orders of magnitude compared to the classical simulated annealing. The parallel embedding capacity allows for the extraction of an entire optimal Pareto front in a single hardware execution. This work demonstrates a viable, quantum-enhanced paradigm for engineering optimization.
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Quantum Physics
Temporal-Mode Engineering for Multiplexed Microwave Photons and Mode-Selective Quantum State Transfer
Quantum communication between distant superconducting qubits on separate chips using itinerant microwave photons has been studied to realize distributed quantum information processing. To enhance information capacity and fault tolerance in quantum networks, it is beneficial to encode a large quantity of quantum information using auxiliary degrees of freedom of these photons. In this work, we experimentally investigate the use of temporal modes of photon wave packets. Through the photon-shaping technique with a fixed-frequency transmon qubit, we generate single microwave photons in four orthogonal temporal modes propagating along a waveguide. We demonstrate mode-selective absorption across orthogonal modes via the time-reversed process of emission, achieving absorption efficiencies exceeding 0.89 for mode-matched cases, while remaining below 0.13 for orthogonal modes. Photons rejected by a given receiver mode can remain mutually orthogonal, enabling selective absorption at subsequent receivers in future multi-node architectures. These results highlight the feasibility of temporal-mode engineering for constructing a higher-dimensional orthogonal basis for multiplexed quantum networks.
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Quantum Physics
Remote engineering of particle-like topologies to visualise entanglement dynamics
Skyrmions are a particle-like topology with a quantised skyrmion number, realised across condensed matter and photonic platforms alike. In quantum photonics, they constitute an emerging resource, promising robust quantum information encoding, so far realised as single photon and bi-photon entangled states. Here we report the first visualisation of tripartite entanglement dynamics through topological structure using spin-skyrmion entangled states, where the topology of a single photon is remotely controlled through the spin of its entangled partner. We visualise our tripartite state theoretically by introducing the notion of a topological Bloch sphere that completely captures the entanglement and topolological features of the state. By leveraging this state, we realise the first quantum multiskyrmions, comprising multiple localised skyrmions within a single structure, that emulate signatures of their magnetic counterparts. We verify this experimentally and show that traversing our topological sphere reveals entanglement-driven particle-like motion of the localised topological structures. These dynamics unveil a physical manifestation of tripartite entanglement correlations which we illustrate by example of GHZ-like states, enabling a visualisation of multiple Bell states encoded within our system. Our work opens exciting possibilities for quantum sensing by mapping complex quantum channel features onto topological observables of multipartite states and offers a promising avenue for harnessing quantum topologies for multi-level encoding quantum communication schemes.
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Quantum Physics
Practical Methods for Distance-Adaptive Continuous-Variable Quantum Key Distribution
Continuous-variable quantum key distribution (CV-QKD) is a promising quantum-safe alternative to classical asymmetric cryptography that enables two authenticated parties to establish a shared secret over a potentially eavesdropped quantum channel. A key step in CV-QKD post-processing is information reconciliation, which leverages forward error correction (FEC) techniques to extract identical bit strings from noisy correlated data. In this work, we analyze the strict limitations on operating distance that are imposed by constant-rate FEC, severely limiting the practicability of CV-QKD systems in deployed optical networks. To overcome the distance limitations, we evaluate three strategies: (i) tuning modulation variance, (ii) adding controlled amounts of trusted detector loss, and (iii) the use of rate-adaptive FEC. All approaches are validated experimentally, compared in terms of performance, and we discuss implementation aspects. Our results show that while methods (i) and (ii) extend the operational distance of constant-rate FEC without the need for additional hardware components, they incur a significant penalty in secret key rate (SKR). In contrast, rate-adaptive FEC enables CV-QKD operation with performance close to the asymptotic SKR over a wide range of distances, provided that the reconciliation efficiency is chosen appropriately.
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Quantum Physics · Cross-listed from cond-mat.mes-hall
Do single-shot projective readouts necessarily estimate the $T_1$ lifetime ?
When single-shot qubit readout protocols are adapted for multilevel systems, theoretical $T_1$ lifetime calculations often fall short of capturing the experimental lifetime trends. We identify extrinsic population dynamics as the fundamental origin of this disparity, establishing that the lifetime estimates can, in certain operating regions, be distinct from the intrinsic $T_1$ time. We clarify these aspects with an integrated theory to address recent measurements [Nat. Nano, 20, 494, (2025)] on spin-valley states in bilayer graphene. While confirming that phonon and Johnson noise are the dominant intrinsic sources, we show that the inclusion of extrinsic factors provide the critical match to the experimental estimates. The extrinsic factors also effectuate violations of generalized Mathiessen's rules. With an improved handle on the design space, a revised readout protocol to estimate the $T_1$ lifetime of the valley qubit is proposed.