Chemical Physics
Papers
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Friday 25 September
Optimizing atmospheric pressure interfaces requires balancing efficient ion transport with unwanted collision activation. The complex environment at the inlet region, including rapid pressure drops, RF/DC electric fields, ion-gas collisions, and space charge effects, makes simulation of this system challenging. In this work, we introduce MuCITE (Multiphysics simulation for Continuous Ion Transport and Energetics), which combines continuous ion injection, precomputed electric and gas flow fields, and particle-in-cell space charge updates. Furthermore, by employing improved impulsive collision theory, it can not only predict transport but also analyze the loss position of ions and the evolution of their kinetic energy, internal energy, and dissociation probability during transport. Transport predictions with ion currents and activation trends of in-source fragmentation were compared with experimental measurements using a custom-built source and a Q-Exactive HF source. The results show that the simulation predictions agree well with the experimental results and can serve as a reference before experiments. MuCITE allows users to derive ion transport, output beam characteristics, and ion energy through the configurable interface geometry and operating conditions. It supports simulation-guided design and tunable parameters to achieve predicted efficient ion transport or in source activation.
Chemical Physics
A General Non-Markovian Electronic Friction and Langevin Dynamics Framework for Nonequilibrium Systems
We present a general framework for simulating the nonequilibrium vibronic dynamics of molecules interacting with metal surfaces, which utilizes non-Markovian electronic friction and the corresponding generalized Langevin equation. The method employs a Markovian embedding scheme to sample coordinate-dependent quantum colored noise, with the underlying memory kernels represented systematically by exponential decompositions obtained directly from the electronic forces. In doing so, the approach extends the widely used electronic friction and Langevin dynamics formalism beyond the conventional Markovian approximation while retaining the coordinate dependence of the electronic back-action. We demonstrate the method for nonequilibrium charge transport through a vibrationally coupled molecular junction, where comparisons with numerically exact hierarchical equations of motion simulations show that the non-Markovian formulation is both more accurate and more robust than its Markovian counterpart. In particular, we find that non-Markovian electronic forces play a decisive role in the nonequilibrium vibrational dynamics, stabilizing regimes in which the conventional Markovian approximation fails.
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Geophysics
Structure-dependent failure modes of neural priors in acoustic full-waveform inversion
Frequency continuation does not improve every neural representation, and better velocity recovery need not imply better prediction of unseen waveforms. We compare a velocity grid with total-variation regularization, an adapted sinusoidal coordinate network (SIREN), and a frozen image generator with a full-grid residual in two-dimensional acoustic full-waveform inversion. All methods use the same frozen SWEEP discretization, acquisition, observations, background, and budget of 1,500 shot–model gradient evaluations. Three exposed synthetic targets represent inclined layering, curved layering, and a high-contrast curved interface drawn from a fault-labelled family. With 2-to-10 Hz continuation, the generative-residual model attains velocity RMSEs of 218.7, 108.0, and 341.9 m/s, compared with 232.5, 100.3, and 412.9 m/s for Grid+TV. Thus the latter wins on curved layering, while the former improves model RMSE by 5.9% and 17.2% on the other targets. Grid+TV nevertheless predicts held-out 10 Hz shots better on all three. SIREN is worse than the common background in every cell; continuation worsens two targets but improves one. A five-weight TV sensitivity study preserves the CurveFault model-error ranking. An equal-budget variational extension fails both recovery and interval coverage. These results establish conditional rankings, not universal superiority or an isolated spectral-bias mechanism. Full-grid residuals also prevent attributing gains uniquely to the generator. We advocate joint reporting of model recovery, unseen-shot prediction, optimization cost, and negative outcomes when auditing neural FWI.
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Earth and Planetary Astrophysics
N-Body Dynamics as a Mechanism for Mean Motion Resonance Formation in the Post-Gas Era
Mean motion resonances (MMRs) are traditionally thought to form during the gas-rich phase of protoplanetary disks via disk-driven migration. Whether MMRs can form solely through collisional damping after disk dispersal has not been systematically investigated. To study MMR formation in the post-gas-disk era, we perform a large suite of N-body simulations, each containing 10,000 planetesimals around an M-dwarf star and evolving over 10 Myr. We compare two groups of simulations that differ only in their initial mass distributions. Each group consists of 10 runs with statistically identical initial planetesimal orbital distributions, generated using different random seeds. One group adopts a uniform planetesimal mass distribution, whereas the other features a bimodal distribution with massive embryos embedded in a swarm of smaller planetesimals. At 1 Myr, 40% of systems (8/20) exhibit near-resonant period ratios, but this fraction drops to 25% (5/20) by 10 Myr as higher-order commensurabilities dissolve. Resonant-angle tracking shows that all persistent systems have circulating resonant angles at 10 Myr, although one system undergoes a transient libration phase between about 2 and 7 Myr before returning to circulation. These results demonstrate that collisional merging can drive MMR formation even without a gas disk, although in this scenario near-resonant configurations are strongly favored over true resonances. Furthermore, this mechanism produces similar MMR fractions in both groups, suggesting that MMR formation is insensitive to the initial mass distribution, although the latter may modulate the formation pathway to a limited extent.
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Quantum Physics
Frequency- and Power-Dependent Optical Response of a Cesium Rydberg Microwave Receiver
We show experimentally obtained frequency- and power-dependent optical response of a room-temperature cesium vapor cell used as a Rydberg microwave receiver based on electromagnetically induced transparency. An applied microwave field couples the ${70S_{1/2}}$ Rydberg state to the nearby ${70P_{1/2}}$, ${70P_{3/2}}$, ${69P_{1/2}}$, and ${69P_{3/2}}$ states, modifying the probe-transmission spectrum. Probe transmission is recorded over a 800 MHz range of coupling laser detunings. These EIT spectra are measured for RF frequencies from 9 to 13.5 GHz and over a 40 dB range of RF power. We analyze the RF induced splittings in the recorded EIT spectra. We observe both limiting cases, where the EIT peak separation is either dominated by the RF detuning or by the RF power. At higher powers we are also able to observe complex features due to coupling of multiple nearby Rydberg states. We further analyze the probe-transmission signal at zero coupling-laser detuning. Sigmoidal fits to the power-response curves are used to determine the midpoint power and the 10-90% transition interval as functions of RF frequency.
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Materials Science
First-principles calculations of the thermodynamic factor of multicomponent alloys
Computing non-dilute diffusion coefficients from Onsager transport coefficients of a multicomponent alloy requires the thermodynamic factor, which measures the curvature of the free energy with respect to composition. As diffusion in metals is mediated by vacancies, the curvature that matters is not that of the vacancy-free alloy, which is straightforward to compute, but that of an alloy carrying a dilute concentration of vacancies. The resulting matrix is nearly singular, and composition fluctuations from which it is obtained converge slowly in Monte Carlo simulations. Here we develop two routes that avoid sampling vacancy composition fluctuations. The first constructs the thermodynamic factor from two quantities, the free-energy curvature of the vacancy-free alloy and the vacancy concentration. The second truncates the semi-grand canonical partition function at a single vacancy and recovers the full thermodynamic factor of the vacancy-containing alloy. The same separation shows that the largest eigenvalue of the diffusion matrix is the vacancy tracer diffusion coefficient for any number of components and any degree of non-ideality, while the remaining eigenvalues scale with the vacancy concentration. Across binary through quinary alloys of the Hf–Mo–Nb–Ti–Zr system, both routes reproduce eigenvalues and eigenvectors of diffusion matrices obtained from fully converged Monte Carlo simulations. The single-vacancy expansion reaches this accuracy with roughly one tenth of the sampling effort. A scaling relation extends both routes to local vacancy chemical potentials away from equilibrium, without additional simulations. These results allow thermodynamic descriptions from atomistic models or CALPHAD assessments to be used directly in mesoscale simulations of mass transport.
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Quantum Physics
Chiral Transfer and Entanglement Generation of Even-Parity Bell States with Engineered Two-Photon Loss
We investigate chiral transfer and dissipative generation of even-parity Bell states in a two-qubit system with coherent two-photon driving and engineered two-photon loss. We find that adiabatic encirclement of a second-order exceptional point induces direction-dependent transfer between the Bell states $|\Phi^+\rangle$ and $|\Phi^-\rangle$, governed by a time-integrated low-loss branch-selection mechanism. We develop a hybrid-Liouvillian description with a control parameter $q$ that interpolates between conditional no-jump dynamics and unconditional Lindblad evolution, and use it to assess how exceptional-point-induced chirality survives in the presence of quantum jumps. When the same parameter loop is initialized in the separable state $|00\rangle$, it directly generates strong even-parity entanglement. Together, these results extend dissipative Bell-state control beyond the single-excitation manifold. They further demonstrate that exceptional-point-based protocols can unify chiral state transfer and entanglement generation within a single engineered two-photon platform.
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Geophysics
Wave-Propagation Geometry Emerges from Scalar Travel-Time Relations
Scalar travel-time relations can identify propagation geometry without velocity inputs, ray labels or equation supervision during learning. Physical interpretation is applied after learning through the high-frequency isotropic eikonal relation (Aki and Richards, 2002). Here we show that local value differences constrain derivatives through sampling geometry and smoothness. Controlled neural fields recover propagation directions with $5.34\pm0.07^{\circ}$ median angular error, and local P- and S-wave velocities in a prospectively locked, test-sealed realization. Classical representations also recover geometry. Scalar-matched perturbations separate value accuracy from derivative reliability; regularized inversion can recover structure when direct gradients fail. A field trained on 2.90 million Chinese arrivals retains continental crust–mantle boundary structure: correlation with a withheld reference is $\rho=0.910$ raw and 0.592 after quadratic detrending (spatial-shift $p=0.020$). Direct catalogue values yield $\rho=0.909$, and thickness contrasts are compressed. Manual-only California arrivals support broad velocity organization with limited lateral fidelity. Synthetic quantum fields containing phase information support probability-flow and trajectory readouts without supervising those quantities. These results establish conditional identification across representations and physical settings: informative scalar relations can constrain geometry, while known physical relations supply its interpretation. They do not imply that accurate scalar fitting alone guarantees reliable physical derivatives.
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High Energy Physics (Theory)
Conformal correlator systems
In critical limits of statistical models, there exist non-local correlators that are conformally covariant without belonging to a conformal field theory. To describe such correlators, we define conformal correlator systems, whose axioms are weaker than those of CFT. As a result, $N$-point correlators are determined by $4$-point correlators, instead of $3$-point correlators in CFT. In two dimensions, conformal spins may take arbitrary complex values, leading to correlators with nontrivial monodromies. We show that sphere $4$-point correlators and torus $1$-point correlators obey nontrivial monodromy constraints. We construct correlators with abelian monodromies in free bosonic theories and in critical loop models.
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Geophysics
From Image Morphology to Multiphysics Earth Posteriors
Structural learning and physical-property inference can draw on different sources of knowledge. We learn morphology from 33,140 natural, satellite, and texture images, without geological training models, then infer Earth properties from physical observations. Identical frozen weights map 128 coordinates into each $256\times256$ compressional-velocity, shear-velocity, or density field. Fixed adapters assign physical meaning; observation-specific likelihoods determine new posteriors without retraining. Across 256 unseen Earth models, image coordinates reduce projection error fourfold relative to a dimension-matched cosine basis. Matched inversions favor image coordinates for the tested curved-velocity targets and a smooth radial basis for the tested faulted targets. A simplified 2.5-dimensional application with 915 measured observations along one 120.9-km southern-California profile constrains a velocity–density contrast. Grouped arrival-time and gravity errors fall by 43% and 44% relative to the pretrained image prior, although the matched smooth radial basis predicts better. Direct layered-Rayleigh updating reduces blind phase-velocity error by 28% at five sites, whereas P-and-gravity-only sharing worsens it, distinguishing reusable morphology from beneficial cross-property coupling. These results establish a practical separation: images supply structural alternatives, and heterogeneous physical observations determine their experiment-specific posterior probabilities.
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General Relativity and Quantum Cosmology
Charged Letelier–Alencar Black Strings with a Quintessence and the Cosmolgical Constant
This study derives charged black string solutions in the presence of a Letelier–Alencar cloud of strings and quintessence within Einstein–Maxwell–$\Lambda$ theory. We study the curvature scalars in order to investigate the asymptotical behavior of these solutions. We calculate the relevant conserved and thermodynamic quantities, confirming their compliance with the first law of thermodynamics. System stability is rigorously analyzed through heat capacity and Gibbs free energy, identifying regimes of local and global equilibrium. Additionally, by interpreting the cosmological constant as thermodynamic pressure within an extended phase space, we establish the validity of the extended first law and derive the corresponding Smarr relation for these solutions. We also investigate the null geodesic structure, deriving the equation for the photon cylinder radius, which generalizes the known result for charged black strings by incorporating the effects of the Letelier–Alencar cloud of strings and quintessence. The numerical analysis of this equation determines the existence and location of photon cylinders as functions of the model parameters.
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Astrophysics of Galaxies
ATLASGAL: The HCN-IR Star Formation Relation for the Milky Way
We examine the relation between star formation and dense gas, traced by HCN(1-0), using a sample of 343 Galactic clumps spanning the full range of evolutionary stages representative of high-mass and cluster formation, including quiescent, protostellar, young stellar object (YSO), and HII regions. Earlier Galactic studies, based primarily on luminous HII regions, reported a linear correlation between infrared (IR) and HCN luminosities, consistent with extragalactic surveys, and interpreted it as a universal star formation law. Our larger evolutionary sample yields a significantly steeper slope of $1.80\pm0.08$, inconsistent with extragalactic trends. However, we find that each of the star-forming evolutionary stages individually has a shallower slope ($\sim$1.2) than that of the full sample, with quiescent clumps showing no correlation. We estimate the Milky Way's total IR and HCN luminosities from dense clumps by integrating the bolometric luminosities and clump masses of Hi-GAL sources. Both fall significantly below extragalactic values, demonstrating that clumps alone cannot account for the IR-HCN relation. Only $\sim$5-25 per cent of Galactic HCN luminosity arises from dense clumps, implying that most extragalactic HCN traces gas that is not involved in star formation. Additionally, dense clumps contribute only $\sim$2-3 per cent of the Milky Way's IR luminosity, which is dominated instead by extended HII regions and PDRs tracing longer star formation timescales. As a result, the observed linear relation in nearby galaxies reflects a nearly constant star formation efficiency averaged over large areas and long timescales, rather than a direct link between SFR and dense gas mass.
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Quantum Physics
Quantum interaction can superactivate cheating under parallel repetition
We study interactive multiprover games and many-round protocols in which the communication between the verifier and the provers is quantum. Parallel repetition is known to suppress soundness error of classical two-prover games arbitrarily close to zero, as shown by Raz (STOC '95), even with quantum strategies as shown by Yuen (ICALP '16), and Bavarian, Vidick and Yuen (STOC '17). Yet, we show that quantum communication can have the opposite, unexpected effect. Specifically, we exhibit a one-round quantum game and two-round $\mathsf{QMIP}$ protocols whose local (unentangled) value is strictly less than one for a single instance, yet equals one under $n$-fold parallel repetition for every $n \geq 2$. The key is that parallel repetition not only imposes additional winning conditions but also supplies additional quantum resources as entanglement in the exchanged states can be exploited jointly across copies. Our multiround examples build on superactivation of zero-error capacities of quantum channels. To establish this connection, we introduce quantum games and interactive protocols which capture the one-shot zero-error classical and quantum capacities, both with and without entanglement assistance. Our constructions use quantum-state verification and a teleportation-based reduction from two rounds to one. In contrast, when shared entanglement is allowed, we show that parallel repetition cannot increase the entangled value when at most $3$ messages are exchanged, consistent with classical results of Bellare, Impagliazzo and Naor (FOCS '97), and that of single-prover systems by Kitaev and Watrous (STOC '00). Combining this monotonicity with our quantum game-channel correspondence, we show that entanglement-assisted zero-error classical and quantum capacities cannot be superactivated.
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Quantum Physics
Distinct Feedback-Strength Requirements for Quantum-State Ensemble Preparation under Channel-Equivalent Monitoring
Different measurements of the same environment can preserve the average quantum channel yet change the feedback strength needed to prepare a state ensemble. We establish this distinction for a multiqubit register under complete Pauli monitoring, targeting the uniform ensemble of real-amplitude pure states. With unit detection efficiency, public records, and bounded Hamiltonian feedback, fixed transverse noise requires a minimum peak strength proportional to $\epsilon^{-1}$ at distributional error $\epsilon$. Tangent noise instead admits a construction requiring only $O[\sqrt{\log(1/\epsilon)}]$. At fixed preparation time, we determine the optimum over all allowed feedback policies and derive a geometric lower bound beyond radial symmetry. The separation identifies the measurement realization as part of the control-resource specification for monitored ensemble preparation.
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Soft Condensed Matter
The Paper-Stack Trampoline: Acoustic Restitution in Layered Media
A ball bouncing on a thicker cushion should bounce less. We show that this is not always so . Measuring the coefficient of restitution $e$ of a steel ball dropped on a stack of $N$ sheets of standard A4 printer paper, we find that $e$ first drops, then rises to a pronounced maximum, and only then decreases towards a minimum. The maximum occurs where the acoustic round trip through the stack matches the contact time of the impact. For a contact set by the stack itself, one recovers the classical bar-impact condition of a stack-to-ball mass ratio of order one. Bar impact, however, predicts only a weak recovery, insensitive to the surrounding gas. For paper stacks, the recovery is large and no maximum is resolved when the stack is evacuated: the air trapped between the sheets, not the paper alone, makes the stack a trampoline.
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Applied Physics
Black silicon avalanche photodiode with dopant-free multiplication region achieves >98% EQE
Conventional silicon avalanche photodiodes (Si APDs) rely on highly doped regions to enable impact ionization and achieve internal gain. However, inefficient charge collection in these regions, combined with front surface reflection, degrades the external quantum efficiency (EQE) of these devices. In this work, we mitigate both loss mechanisms by integrating black silicon (b-Si) surface nanostructuring with Al2O3 induced carrier collection in an inverted-mesa Si APD architecture. This design confines the electric field and defines the multiplication region without requiring ion implantation. The resulting devices display near-ideal responsivity (at M = 1) across the UV-visible spectrum, with EQE exceeding 100% at 200-400 nm (peak ~130%) and exhibiting 92-100% at 400-700 nm. Avalanche gains of M ~ 4 at 80 V, M ~ 10 at 100 V, and M ~ 23 near breakdown at ~110 V are obtained. Dark current remains in the picoampere range up to ~80 V but rises to the nanoampere range near breakdown, narrowing the practical bias window. Capacitance-limited rise times of ~30-570 ns are measured for device diameters of 1-5 mm. The results demonstrate that the developed architecture enables APDs capable of detecting every single photon over wide range of wavelengths.
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Quantum Physics
Bypassing no-go theorems on mixed classical-quantum systems: the (counter)example of hybrid van Hove theory
Motivated by models of mixed quantum-classical hybrid theories, we consider the representation of classical observables as Hilbert-space operators based on van Hove's unitary representation of contact transformations. This leads to a reformulation of classical mechanics where the phase space density satisfies the Liouville equation and, more importantly, classical observables are represented by van Hove operators that satisfy a commutation algebra isomorphic to the classical Poisson algebra of functions in phase space. Thus, this Hilbert space approach captures all the essential features of the phase space formulation of classical mechanics in that it reproduces its algebraic structure – something that is not achieved by other approaches such as the Koopman-von Neumann theory. As an important feature, the definition of appropriate physical states in this formalism imposes certain natural requirements on the phase of the classical wave function, which ensure correct expectation values for the observables. Furthermore, we discuss how to extend the approach to the hybrid van Hove theory of mixed classical-quantum systems and illustrate its application with the example of interacting classical and quantum oscillators. Finally, we focus on the question of how hybrid van Hove theory evades no-go theorems on mixed classical-quantum systems and point to the various assumptions of the no-go theorems that do not apply to our approach. This demonstrates that these no-go theorems are not universally applicable, contrary to their original claims.
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Materials Science
Electron paramagnetic resonance of Dy${^3+}$-doped CaWO$_4$: spin Hamiltonian, crystal-field analysis, and linear electric field effect
We report an electron paramagnetic resonance (EPR) study of Dy${^3+}$ in CaWO$_4$ single crystals spanning dopant concentrations from 80~ppb to 247~ppm. The $g$ factors of the ground Kramers doublet at the $S_4$ point-group site, $g_\parallel = 7.22 \pm 0.01$ and $g_\perp = 5.45 \pm 0.01$, and the hyperfine constants of \ce{^{161}Dy} and $^{163}$Dy are determined with an order-of-magnitude improvement in precision over the only previous report. A crystal-field analysis constrained jointly by published optical levels and by the measured $g$ tensor identifies the ground doublet as the lower branch of an anticrossing between the near-degenerate $\|{\pm}11/2>$ and $\|{\mp}13/2>$ states, and explains why optical data alone left the $g$ values unconstrained. \add{The same parameter set, tested on the excited multiplets of the $^6H$ term, reproduces the ${}^6H_{13/2}$ crystal-field levels better than the optical parameters themselves.} The angular dependence of the linewidth in the $ab$ plane reveals broadening by random internal electric fields through the linear electric field effect. Calibrating these fields with the residual Er$^{3+}$ present in the same crystals yields the first electric-field coupling parameters of Dy$^3+$, $(B_{31}^2+B_{36}^2)^{1/2} = (34\pm5)\times10^{-6}$~cm/V, three times the Er$^{3+}$ value and the largest reported for a rare-earth ion in this host.The residual linewidth and the concentration-dependent lineshape asymmetry follow the quadratic field scaling expected for a second-order Stark shift, which escapes the inversion-site cancellation constraining the linear effect. Both couplings trace back to the $\sim 20$~cm$^{-1}$ gap to the first opposite-symmetry doublet, a consequence of the dense crystal-field structure of the $J=15/2$ manifold.
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Space Physics · Cross-listed from cs.LG
Self-Supervised Representation Learning: From Spectral Foundation Models to Auroral Emission Spectra
Auroral spectrographs such as the Auroral Spectrograph In Skibotn (ASIS) record hundreds of thousands of emission spectra, but only a few hundred can be labelled by an expert. To exploit the rest, we pretrain a 1D Vision Transformer with a masked autoencoder on 223,000 unlabelled spectra. Without labels, its representation recovers the emission-line intensity ratios that physicists use to diagnose the precipitating particles (R^2 0.91 vs. 0.77 for an untrained control) and, under one linear probe, classifies as well as 13 features designed by experts. Fine-tuned, the model outperforms the previous supervised auroral classifier on its own benchmark (macro-AP 88.5 vs. 77.8), reaches 0.870 mAP, and exceeds the same architecture trained from scratch by +0.159 with 10% of the labels; attribution shows that it uses both N2+ bands. Could an existing pretrained model replace it? Two astronomical spectral foundation models and a time-series model transfer according to their spectral window: SpectraFM, trained in the infrared, falls below the untrained control, whereas SpecFormer, trained in the optical, approaches in-domain pretraining without reaching it.
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Mesoscale and Nanoscale Physics
Orbital photoinduced Faraday effect in a lattice of conducting disks
We present a theoretical study of pump-induced Faraday and Kerr rotation in a two-dimensional lattice of conducting disks. We propose a mechanism of Faraday and Kerr responses in which a circularly polarized pump directly induces a high-frequency Hall component $\sigma_{xy}=-\sigma_{yx}$ of the electron conductivity tensor at the probe frequency. Microscopically, $\sigma_{xy}$ originates from the third-order nonlinear response of the electron gas rather than from the real magnetic field created by solenoidal charge currents in the inverse Faraday effect. We show that the Faraday and Kerr rotation angles are significantly enhanced when the pump and probe frequencies are tuned close to the plasmon resonance of the disks, reaching $\sim 0.1^\circ$ per 1~kW/cm$^2$ of incident pump intensity in the terahertz range. This mechanism can explain recently observed giant pump-induced Faraday rotation in graphene disk lattices.
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Mathematical Physics · Cross-listed from math.SP
Dirac measures can be quantum limits on the Sierpinski gasket
Fluid Dynamics
Zero-Mean Oscillations Drive Recirculations in Potential Flows at Vanishing Reynolds Number
Recirculating flows are central to transport phenomena, but their generation in potential flows requires additional physical mechanisms. We show experimentally that recirculation at vanishing Reynolds number can be produced at prescribed locations by coupling oscillations of a Hele-Shaw cell ceiling with an off-center passive obstacle. The net drift is well described by a potential flow model with no adjustable parameters. The resulting flows are localized around the obstacles and can be combined to generate programmable flow patterns at the microscale.
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Quantum Physics
Optical characterization of excited-state spin Hamiltonians and clock transitions at telecommunication wavelength in Tm3+:YAlO3
The zero-phonon line (ZPL) between the two excited-state manifolds 3F4 and 3H4 of the trivalent thulium ion in yttrium aluminum perovskite (Tm3+:YAlO3) lies within the telecom E-band at around 1451 nm and exhibits an optical coherence time of a few {\mu}s at cryogenic temperatures. To improve this time in view of potential applications, e.g. single-photon sources and optical quantum memory, we characterized the magnetic properties of the lowest Stark levels of these two manifolds. Varying the external magnetic field amplitude and orientation, we measured the enhanced nuclear Zeeman splitting by probing the field-dependent frequency detuning of side holes created by means of spectral hole burning, and we characterized the inhomogeneous line shift caused by the quadratic Zeeman interaction. Together, this allowed us to establish the spin Hamiltonians for the lowest Stark level of the 3F4 and 3H4 manifolds, and to predict optical clock transitions for particular orientations and magnitudes of the magnetic field
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Mathematical Physics
Differential Recursions, Projective Discriminants, and Algebraic Generating Functions
We study two hierarchies of bivariate generating functions defined by differential recursions: a self-dual hierarchy and a reduced-symmetry hierarchy. Their rational coefficient functions produce palindromic and anti-palindromic triangles, including OEIS A336110 and A140136. For general differential order $p$, the reduced hierarchy decomposes into $p-1$ Horn-type companions. An explicit differential intertwiner of order $p-3$ relates the last companion to the normalized self-dual generating function. The companions share a principal symbol and a rationally parametrized characteristic curve with a projective $S_3$ action. At $p=2$ this construction yields the Narayana quadratic. At $p=3$ the symmetry lifts to $S_4$: two algebraic sectors are edge resolvents of one quartic root configuration, and the nonsymmetric Gross–Witten–Wadia generating function has degree four. For $p=4$ and $p=5$ we derive algebraic equations of degrees six and eight, respectively, and find Galois groups $S_6$ and $S_8$ at generic specializations. At $p=6$ we verify a degree-ten specialization with Galois group $S_{10}$. Their discriminants exhibit a universal cubic characteristic factor and a squared lower-order factor. A boundary factorization explains the observed algebraic degrees and discriminant monomials. We formulate conjectures on algebraicity and Galois groups in the reduced hierarchy and identify a possible mechanism for transcendence in the higher self-dual hierarchy.
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Earth and Planetary Astrophysics
JWST detection of methane emission from a young brown dwarf
In recent studies, we have used low-resolution spectroscopy (R~100) with the James Webb Space Telescope (JWST) to uncover low-mass brown dwarfs (2-10 MJup) in the young cluster IC 348 that exhibit the so-called 3.4um absorption band from aliphatic hydrocarbons. Atmospheric models have not predicted the presence of that band in brown dwarfs at any age. Instead, methane absorption was expected in the coolest newborn brown dwarfs, but it was not detected. We have performed JWST spectroscopy at higher resolution (R~1000) on one of the brown dwarfs in IC 348, LRL 11001 (~6 MJup). The new measurement of the 3.4um band is fit well with four Gaussians that represent the CH stretching modes of CH2 and CH3 groups, indicating that the carrier is a large alkane (CnH2n+2). In addition, the spectrum contains emission lines at 3.324 and 3.333um, which we attribute to Q branches of CH4 hot bands between the octad and dyad regions (primarily nu3+nu4->nu4) and the tetradecad and pentad regions. This is the first detection of 3.33um CH4 emission from a young brown dwarf. The emission probably arises from the photosphere rather than a circumstellar disk given that no disks around stars or brown dwarfs are known to exhibit emission in these transitions. Modeling of the emission is needed to constrain the excitation mechanism, which could be either thermal (e.g., an accretion shock) or pumping by external radiation (e.g., neighboring cluster members). We speculate that vertical mixing has suppressed CH4 and enhanced large alkanes in the photosphere, but CH4 survives in the upper atmosphere, where it is available to experience the observed emission.
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Materials Science
Current-voltage characteristics and resistive switching in epitaxial La$_{0.67}$Sr$_{0.33}$MnO$_3$/SrMnO$_3$/La$_{0.67}$Sr$_{0.33}$MnO$_3$ multilayer
In present study, we investigate the structural properties and current-voltage ($I$-$V$) characteristics of an epitaxial multilayer composed of La$_{0.67}$Sr$_{0.33}$MnO$_3$ (25 nm)/SrMnO$_3$ (70 nm)/La$_{0.67}$Sr$_{0.33}$MnO$_3$ (25 nm), grown on different substrates i.e., SrTiO$_3$(100), LaAlO$_3$(100), Si (100). The used substrates not only have different chemical compositions in line with the film materials, also they have different lattice parameters which would tune the material chemistry and lattice strain at the interface significantly. Our $I$-$V$ measurements reveal distinct electrical behaviors depending on the substrate. The multilayers grown on oxide SrTiO$_3$(100) and LaAlO$_3$(100) substrates exhibit regular $I$-$V$ with slight nonlinearity at low applied voltages. In contrast, $I$-$V$ in multilayer with Si(100) substrate exhibits large asymmetry and notable resistive switching (RS) behavior at room temperature, where a resistance ratio around 10 between the high resistance state (HRS) and low resistance state (LRS) is observed. While the observed $I$-$V$ behavior is sensitive to substrate-induced interfacial disorder and formation of trap bands within bandgap of SrMnO$_3$, the present results have potential applications in future memory and memristive devices.
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Materials Science
Modern triad for magnetic material science: geometric shape, electronic bands and spin textures
To enable novel concepts in nanotechnologies, it is insightful to design materials with qualitatively new performances originating from recent discoveries in fundamental material science and physics. Curvilinear magnetism emerged as a tool to design chiral and anisotropic responses of materials at the nanoscale using the effects of the geometric shape and topology of the object. This concept is distinct yet complementary to material screening, which is primarily based on the optimization of intrinsic microscopic properties to modify magnetic textures for specific applications. Contemporary curvilinear magnetism focuses on mean-field micromagnetics, while the explicit contribution of the lattice structure and electronic degrees of freedom remains beyond consideration. In this review, we will emphasize on the effects which appear when this coupling is accounted for and that have resulted in novel concepts for the design of “metageometric” materials. Further development of this field will provide appealing technological prospects for fundamental understanding of curvilinear magnetic nanostructures and their applications in energy efficient and scalable nanoelectronics.
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Optics
Probing temperature dependent non-radiative decay channels in CrSBr with nonlinear optics
Among the recently discovered layered magnetic materials, the antiferromagnet CrSBr has attracted considerable interest thanks to its stability, quasi-one-dimensional crystal structure, and direct near-infrared band gap. These properties make it a suitable platform for combined electrical, magnetic, and optical measurements, and thus for studying exciton dynamics and transport across different magnetic phases. In this work, we investigate the optical response of CrSBr across its paramagnetic and antiferromagnetic phases by combining nonlinear optical spectroscopy, including second-harmonic generation, third-harmonic generation, and two-photon photoluminescence, with linear photoluminescence measurements. The observation of a clear difference in the temperature dependence of third-harmonic generation and photoluminescence intensities allows us to identify the onset of non-radiative recombination channels in the antiferromagnetic phase.
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Statistical Mechanics
Slow-fast dynamics of the McKean model with stochastic resetting and diffusion
In this paper we investigate the combined effects of stochastic resetting and diffusion on a slow–fast dynamical system given by the piecewise-linear McKean model. That is, the fast variable $v$ is subject to Gaussian white noise with effective diffusivity $D$ and is reset to a fixed value $v_r$ at a random sequence of times generated from a Poisson process with rate $r$. Assuming that resetting occurs on the fast timescale, we freeze the slow variable \(w\) under an adiabatic approximation and determine the resulting non-equilibrium stationary state (NESS) of the fast variable as the solution of a modified Fokker–Planck equation. We show that the NESS can be expressed in terms of parabolic cylinder functions, whose asymptotic behavior allows us to recover the corresponding NESS without diffusion in the small-diffusion limit. The NESS is used to derive an averaged equation for the slow dynamics, whose solution converges to a stable fixed point \(w^*\) that depends on \(D\), \(r\) and \(v_r\). This fixed point effectively determines the long-time behaviour of the full system. Finally, we analyze the regime in which resetting occurs on the same timescale as the slow variable. We show how the slow variable now undergoes noisy oscillations due to resetting-induced switching between branches of the fast nullcline and derive the corresponding NESS for $w$ in the non-diffusive case.
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Computational Physics · Cross-listed from cs.MS
KnottedGraph: Scalable knotted-graph topology for scientific and mathematical discovery
Scientific data span heterogeneous structures, including coordinates, networks, surfaces, volumes and fields, yet their topology can be quantified within a common framework through graph connectivity, cycle structure, genus and spatial embedding. Graph- and homology-based summaries do not determine spatial embedding, while standard knot and link polynomials require extensions to accommodate branching graphs. Here, we introduce KnottedGraph, a computational framework that converts such scientific representations to knotted graphs that retain graph connectivity and spatial embedding together. It constructs projected diagrams and PD codes, enabling various topological analyses, including Yamada-polynomial evaluation for topological classification. For scalable exact evaluation, it combines partial resolutions that leave the same unresolved connections and optimizes their processing order; the resulting algorithm is verified against published topological invariants of knotted graphs with up to 500 crossings. This scalability enables us to introduce an LLM-assisted mathematical-discovery methodology, in which computational topological data generated across knotted-graph families are used to identify candidate closed-form formulas. With this approach, we identify analytical Yamada-polynomials for generic graph motif families exhibiting Abelian and non-Abelian word sequences. Together, these scalable capabilities make knotted-graph topology computationally accessible across scientific domains, enabling large-scale classification and introducing a route from topological data to LLM-assisted AI4Math discovery.