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Physics Condensed Matter

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Wednesday 12 August

Statistical Mechanics · Cross-listed from physics.chem-ph

Diffusion and Solvation Dynamics of Ions in Water: Beyond the Brownian Approximation

The coupled dynamics of ions and water molecules in their first hydration shell impact a variety of processes including ion diffusion, selective ion transport in water-filled nanopores, and the kinetics of ion-pairing, ion adsorption, and metal-ligand binding reactions. In this work, we study these coupled dynamics for alkali metals (Li, Na, K, Rb, Cs), alkaline Earth metals (Mg, Ca, Sr, Ba), and chloride through the lens of their dependence on ion isotopic mass. Results are validated against previous measurements of the isotopic mass-dependence of ion diffusion coefficients in water and previous ab initio calculations of ion high-frequency dynamics in water. We find that the vibrational power spectra of ions in water consistently exhibit either two or three peaks, i.e., ions have several rattling frequencies within their solvations shells as previously reported for a subset of the species examined here. These frequencies have different sensititivies to isotopic mass that may serve as signatures of ion solvation processes (such as the tendency of ions to orient their first-shell water molecules) and that also may relate to Hofmeister-like effects including the relative affinity of different metals for ribonucleic acid (RNA).
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All authors Ian C. Bourg, Minh Thê Hoang Ngoc, Thomas R. Underwood, Carlos Vega

Strongly Correlated Electrons · Cross-listed from quant-ph

Pulse Engineering of Quantum Many-Body Dynamics: Emergent Scar States, Entanglement, and Nonstabilizerness

Understanding and coherently controlling the properties of interacting quantum many-body systems is a central challenge in non-equilibrium quantum physics. While in the past decades, a wide range of many-body Hamiltonians have been introduced to study quantum chaos, atypical eigenstates, and quantum resources, systematically engineering and continuously tuning these properties within a single microscopic model remains largely unexplored. Here, we employ a pulse engineering scheme to construct an effective Hamiltonian that continuously interpolates between a chaotic Heisenberg (XXX) chain with a local impurity and the ZX Hamiltonian. Along this interpolation, we identify several families of analytically tractable atypical eigenstates embedded in the excited-state spectrum with distinct entanglement and nonstabilizerness properties. In the XXX limit, these states exhibit exact plateaus in both entanglement and stabilizer Rényi entropy and correspond to coherent superpositions of long-range valence-bond solid (VBS) states. As the pulse strength increases, the effective Hamiltonians exhibit a hierarchy of new set of approximate entanglement plateaus in the low-energy spectrum. Interestingly, in the fully pulse-engineered ZX limit, we uncover a distinct pair of long-range entangled stabilizer eigenstates, corresponding to rainbow scar states. We further show that pulse engineering preserves the distinct chaotic and non-chaotic regimes of the original model, while that is largely absent in the dynamical generation of entanglement and nonstabilizerness. The pulse-engineered models generate nearly identical quantum resources in both regimes, revealing a partial decoupling between quantum chaos and quantum-resource generation. Our results establish pulse engineering as a versatile framework for generating many-body Hamiltonians with structured eigenstates and tunable quantum resources.
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Mesoscale and Nanoscale Physics

Resonant Far-Infrared Spectroscopy of Flat-Band Fermions in Magic Angle Graphene

Moiré engineering in twisted two-dimensional (2D) materials radically alters low-energy bands, interactions and topological quantum states. Despite extensive studies, optical spectroscopy of interacting moiré bands in the characteristic far-infrared (FIR) regime has remained largely unexplored due to extreme experimental challenges. Using a newly developed millikelvin FIR platform, we report the observation of the long-sought-after characteristic FIR resonances of flat-band electrons in magic-angle twisted bilayer graphene (MATBG). We observe highly tunable spectroscopic signatures of interacting light and heavy fermions that constitute the flat bands in MATBG. Using the topological heavy-fermion model (THF), we show that itinerant topological electrons act as an "antenna" that couples strongly to the optical field, with resonant frequencies renormalized by the hybridization with localized heavy electrons. We establish optical selection rules of MATBG which uncovers the key symmetry governing light-heavy fermion hybridization. At charge neutrality, we observe pronounced resonances at energies below the on-site Coulomb energy, implying the emergence of new many-body modes. Our experiments and modeling provide a fundamental understanding of light-matter interactions in MATBG and enable resonant optical spectroscopy of moiré bands down to millikelvin temperatures.
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All authors Ayelet J. Uzan-Narovlansky, Ipsita Das, Juan F. Mendez Valderrama, Yue Tang, Jonah Herzog-Arbeitman, Haoyu Hu, Pengjie Wang, Zhaoyi Joy Zheng, Haosen Guan, Kenji Watanabe, Takashi Taniguchi, B. Andrei Bernevig, Sanfeng Wu

Superconductivity

The nature of the "pseudogap" in the insulating phase of highly disordered superconductors

Disordered thin films undergoing a superconductor-insulator transition provide a controlled setting for studying pseudogap physics in the absence of competing electronic orders. Although theory predicts that local Cooper pairing can survive deep into the insulating phase, direct spectroscopic confirmation has remained experimentally inaccessible because tunneling measurements in highly insulating films require ultra-high-resistance junctions and picoampere current sensitivity. Here we combine ultra-high-resistance planar tunneling spectroscopy on amorphous indium oxide films with quantum Monte Carlo simulations of the attractive Hubbard model to probe the single-particle excitation spectrum deep in the insulating regime. We find striking agreement between experiment and theory: the single-particle gap not only survives across the superconductor-insulator transition, but increases substantially with disorder, reaching values more than twice those observed on the superconducting side. With increasing temperature, the gap fills rather than closes, while coherence peaks are suppressed and spectral weight redistributes to energies far exceeding the gap scale. Our results provide direct quantitative experimental confirmation of the theoretically predicted Cooper-pair insulating state with localized Cooper pairs and establish a unified connection between the pseudogap above $T_c$ and the insulating gap as manifestations of pairing without global phase coherence.
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All authors Mark Nikolaevsky, Abhisek Samanta, Nandini Trivedi, Aviad Frydman

Strongly Correlated Electrons

Defect-induced optical magnons and local magnetic correlations in MnSb2Te4

Magnetic defect engineering offers a route to manipulate and control magnetic and electronic states in quantum materials. In the Mn(Bi,Sb)2Te4 family of topological magnetic insulators, Sb substitution facilitates site mixing between Mn and Sb atoms that affects magnetic order and band topology. Here we directly probe these defect-induced magnetic interactions using inelastic neutron scattering on single crystals of MnSb2Te4. We find that antisite mixing generates inequivalent and disordered magnetic sublattices where strong defect-induced antiferromagnetic coupling produces an optical magnon with a large gap. Semi-classical spin-dynamics simulations accurately capture magnetic excitations in the ordered and paramagnetic states and identify that linear Mn-Te-Mn bonds mediate coupling to antisite magnetic defects.
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All authors Dhurba R. Jaishi, Bing Li, Tianxiong Han, S. X. M. Riberolles, D. M. Pajerowski, Jiaqiang Yan, R. J. McQueeney

Quantum Gases

Dual Gauge Theory for Two Dimensional Superfluid Turbulence

We describe turbulent hydrodynamics of superfluids in two spatial dimensions via the dynamics of point-like vortices coupled to an emergent 2+1 dimensional $U(1)$ gauge field. The cascade of superfluid kinetic energy is equivalently described by a cascade of dual electric field energies. We study superfluid turbulence using the equations of motion of the dual gauge theory in the presence of a drive and dissipation. In the limit that the vortices are point-like, the dual equations of motion directly yield the hydrodynamical equations of the superfluid. We obtain a turbulent cascade consistent with Kolmogorov's scaling law for two dimensional fluid turbulence. We observe clustering of like-signed vortices and compute the kinetic energy flux to show that the turbulent regime exhibits an inverse energy cascade.
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Mesoscale and Nanoscale Physics

Emergent trans-moiré orbitals and topology in rhombohedral graphene

The fractional quantum anomalous Hall effect (FQAHE) exhibited in fractional Chern insulators has recently been demonstrated in twisted MoTe2 and rhombohedral graphene/hBN moiré superlattices, promising new routes toward topological quantum computation. Central to realizing this promise is the understanding of the underlying microscopic mechanism. This, however, remains elusive in the case of rhombohedral graphene, with the crux being its two seemingly paradoxical conditions: a pronounced small-twist-angle ({\theta}) moiré interface, yet only when electrons are kept distant from it. Here, by scanning tunnelling microscopic imaging with both conditions fulfilled, we capture dramatic electronic structure reshaping in rhombohedral hexalayer graphene by unforeseen 'trans-moiré orbitals', which emerge on the other, distant side of the moiré interface but nevertheless enforce the moiré periodicity at all measured fillings. We visualize a hierarchy of spatially and energetically distinct trans-moiré orbitals which doped electrons must sequentially occupy–the lowest-energy orbital, expectedly responsible for the FQAHE at small fillings, carries a hollow-cage-like shape. Remarkably, these trans-moiré orbitals vanish at {\theta} {\gtrsim} 1{\deg}, and so do QAHE plateaus in similar devices. Simulations reveal an interaction-driven charge-redistribution mechanism which shapes the trans-moiré orbitals and corresponding Chern minibands. With our findings providing the missing microscopic link, the paradoxical conditions find a natural explanation: electrons are not simply kept distant from a small-{\theta} moiré interface; they are forced into topological trans-moiré orbitals, forged precisely under such conditions. Our microscopic diagnostics unlocks a wide range of possible 'synthetic' FQAHE platforms.
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All authors Yuqin Wang, Jian Xie, Yi-Jie Wang, Jiajun Zhang, Yiting Gao, Zaizhe Zhang, Da Yi, Yan Xie, Jingjing Shi, Guanqin Zhao, Chengyu Xiong, Kenji Watanabe, Takashi Taniguchi, Zhi-Da Song, Xiaobo Lu, Yi Chen

Mesoscale and Nanoscale Physics

Exceptional activated mode theory for generalized real-complex transitions

Real-to-complex spectral transitions mark the onset of amplification in non-Hermitian systems, but their thresholds are often treated as model-specific quantities. Here we develop a general, non-perturbative activated-mode principle that governs the real-to-complex threshold across broad classes of non-Hermitian systems. A central insight is that only a small Hilbert subspace is “activated" at the transition onset, which can be variationally determined through the competition between spectral detuning and mode-level projected non-Hermitian couplings. The result is a closed-form exceptional-activation condition for arbitrarily large “disturbances", rather than a perturbative estimate. We apply our framework to three contrasting illustrative problems, establishing (i) a closed-form threshold for critical non-Hermitian skin amplification at all system sizes; (ii) a new link between impurity tunneling threshold and exceptional point switching; and (iii) activation channel switching without underlying topological phase transition. Overall, our findings recast real-to-complex transitions as generic mode-selection problems independent of any specific symmetry.
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Strongly Correlated Electrons

Superconductivity in the $t$-$t'$ Hubbard Model from Symmetry-Preserving Neural-Network Quantum States

Despite its fundamental importance in the theory of strongly correlated electrons, the nature of the ground state of the two-dimensional doped Hubbard model remains intensely debated. Variational approaches provide a powerful route to this problem, but their conclusions can depend sensitively on the chosen wave-function parameterization, the mean-field initialization, or the pinning fields used to guide the optimization, as well as on boundary conditions. This can favor one type of symmetry breaking over another, making it difficult to distinguish the genuine interplay of intertwined or competing orders from biases induced by the variational parameterization. Here, we introduce the Symmetry-Preserving Backflow Pairing (SBP) ansatz, a neural-network wave function that respects translational symmetry by construction and thereby avoids these broken-symmetry minima. The SBP ansatz reaches state-of-the-art variational energies for the $t$-$t'$ Hubbard model on lattices up to $24\times24$ with $504$ electrons, below those of competing pure stripe solutions. By extrapolating to the thermodynamic limit, we find robust evidence for $d$-wave superconducting order, resolving a long-standing question about the $1/8$-doped model at $t'/t=-0.2$ and $U/t=8.0$. Built on general principles of symmetry and locality, the SBP wave function provides a broadly applicable variational representation for challenging interacting fermionic systems.
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Superconductivity

Finite-momentum coupling of Higgs and Bardasis–Schrieffer modes in superconductors with competing pairing channels

In superconductors with competing pairing channels, two well defined excitations exist below the pair-breaking edge: the Higgs mode of the condensed $s$-wave channel and the Bardasis–Schrieffer (BS) exciton of the subdominant $d$-wave channel. Their mixing is doubly forbidden — by point-group symmetry at zero momentum and because the two reside in the amplitude and phase sectors of the order parameter respectively, by particle–hole symmetry at every momentum. Working in a Nambu–Keldysh quasiclassical framework extended to leading $1/\varepsilon_F$ corrections and including the self-consistently screened Coulomb potential, we show that finite momentum combined with particle–hole asymmetry generates a direct coupling which we obtain in closed form. Whether this coupling produces an avoided crossing is decided, however, not by its magnitude but by kinematics. In the clean limit the Higgs is not a sub-gap pole but a resonance pinned to the pair-breaking edge, which disperses with coefficient unity in $(v_Fq)^2$, while the bound BS mode disperses more slowly: the two branches therefore separate rather than converge and never become degenerate. The obstruction is specific to the clean limit: exact dirty-limit results show that disorder detaches the amplitude resonance from the edge and reverses its dispersion, which can result in an avoided crossing with the BS mode at intermediate scattering. In that regime, the coupling computed here would set the splitting between the hybridized branches. We discuss the experimental implications of these results.
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Strongly Correlated Electrons

Revisiting magnon bound states: ferro-antiferromagnetic $J_1\!-\!J_2$ square-lattice model

A comprehensive analysis of pairing and bound states of magnons in the Heisenberg $S\!=\!1/2$ square-lattice $J_1\!-\!J_2$ ferro-antiferromagnetic model is presented. We highlight the similarities and differences between the bound states of spin flips on a lattice and those of particles in the continuum. Magnon bound states at finite pair momentum are studied throughout the Brillouin zone and a convenient lattice partial-wave nomenclature is advocated. The mechanisms of enhanced stability or fragility of these bound states for the high-symmetry pair momenta are identified and quantified as relating to the effective dimensional reduction or enhancement, respectively. These effects are also shown to control the evolution of the bound states with the model parameters, providing a transparent framework for understanding magnon pairing in a more general setting. A method to determine the bound state phase boundaries is presented.
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Strongly Correlated Electrons

Fermionic Anomalies of Finite Symmetries on Lattices

We develop a lattice characterization of fermionic 't Hooft anomalies of finite internal symmetries in one and two spatial dimensions, formulated in terms of obstructions to symmetric short-range-entangled (SRE) states. We consider lattice systems formed by tensor product of onsite fermionic and bosonic local degrees of freedom, and finite internal symmetry given by a central extension $\mathbb Z_2^F\to G_f\to G_b$. We extract a hierarchy of fermionic anomaly indices for a given symmetry operator in both (1+1)D and (2+1)D. In (1+1)D, an exact lattice symmetry is characterized by a pair of cohomological data $(n_2,\nu_3)$. For $G_f=G_b\times\mathbb Z_2^F$, we further show that a symmetry with trivial lattice anomaly indices $(n_2,\nu_3)$ is onsiteable and hence admits a symmetric SRE state, establishing that these indices faithfully detect the lattice anomaly. Comparing with continuum fermionic QFT, we find that exact lattice symmetries do not realize the additional $H^1(BG_b,\mathbb Z_2)$ anomaly layer in continuum QFT. In particular, for $G_b=\mathbb Z_2$, exact lattice symmetries realize only the even $\mathbb Z_4$ subgroup of the continuum $\mathbb Z_8$ classification. In (2+1)D, we identify three successive anomaly layers of cohomological data $(n_2,n_3,\nu_4)$. We show that a nontrivial value of any layer obstructs a symmetric SRE state. For $G_f=G_b\times\mathbb Z_2^F$, it also forbids a symmetric invertible state. We also construct a non-onsite $\mathbb Z_4^F$ lattice symmetry in (2+1)D with nontrivial lattice anomaly index that forbids any symmetric invertible states with $c_-\in\mathbb{Z}$, therefore forbids any invertible states compatible with onsite $\mathbb{Z}_4^F$ symmetry. Our results motivate a systematic study of which continuum anomalies admit exact microscopic lattice realizations.
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Superconductivity

Floquet Quasiparticle Poisoning of Frozonium

Periodic driving can suppress the Josephson nonlinearity of a fluxonium superconducting circuit, producing a nearly harmonic Floquet spectrum at isolated freezing points [K. Lewellen et al., Newton 2, 100434 (2026)]. Here we show that this dynamically frozen behavior does not generically suppress quasiparticle-induced dissipation in the resulting frozonium circuit. We formulate quasiparticle processes in the frozonium using a Floquet framework and analyze both drive-assisted Cooper-pair breaking and tunneling of pre-existing quasiparticles. Pair generation is controlled by gap-breaking thresholds at high drive frequencies, while multiphoton resonances produce pronounced rate enhancements at lower frequencies. Quasiparticle tunneling exhibits connected resonance structures organized by the harmonic Floquet-Magnus spectrum near the freezing point, with resonant hybridization generating characteristic avoided crossings. Our results show that suitable operating regimes must balance dynamical freezing against quasiparticle loss and provide a framework for identifying experimental drive parameters away from harmful resonances.
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Strongly Correlated Electrons

Boundary phases and thermodynamics of the Kondo spin-$s$ chain: from overscreened Kondo to boundary-bound states

We study a spin-$\frac12$ impurity coupled to the boundary of a strongly correlated spin-$s$ Takhtajan–Babujian chain, an integrable model whose low-energy physics is described by a perturbed $SU(2)_{2s}$ Wess–Zumino–Witten conformal field theory. While boundary conformal field theory determines the low-energy universality class of the weak-coupling regime, exact Bethe Ansatz methods reveal a sequence of boundary quantum phase transitions in which impurity-bound states emerge and reorganize the Hilbert space into multiple excitation towers built on distinct boundary configurations. This tower restructuring provides the organizing principle for a rich boundary phase diagram extending beyond the conventional Kondo regime. Weak antiferromagnetic coupling realizes the overscreened $2s$-channel Kondo universality class, whereas stronger couplings generate localized boundary modes and qualitatively new screening mechanisms. To describe the resulting thermodynamics, we develop a generalized thermodynamic Bethe Ansatz framework that captures the multi-tower structure across all regimes. The impurity entropy reproduces the boundary conformal field theory prediction in the overscreened Kondo regime but develops pronounced nonmonotonic temperature dependence once boundary-bound states appear, in quantitative agreement with large-scale finite-temperature matrix-product-operator simulations. Complementary dynamical calculations reveal sharp threshold features in the impurity spectral function that directly track the underlying tower structure. Together, boundary conformal field theory, exact Bethe Ansatz, generalized thermodynamic Bethe Ansatz, and tensor-network simulations provide a unified description of impurity screening, boundary-bound-state formation, and excitation-tower reconstruction in a correlated spin-$s$ chain.
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All authors Abay Zhakenov, Pradip Kattel, Andreas Gleis, Natan Andrei

Strongly Correlated Electrons

The "Moiré Capacitor Effect" and Stabilization of Fractional Chern Insulators in Rhombohedral Graphene Superlattices

While the necessity of a moiré potential for fractional Chern insulators (FCIs) in rhombohedral graphene-hBN superlattices, first predicted in Ref. 1, is now grounded in experiments, a theory of its origin and importance remains at large. We present a mechanism—the moiré capacitor effect—that enhances the moiré potential by electrostatically imprinting the valence charge density onto the conduction bands. We derive the analytical form of this term and reveal its crucial role in stabilizing a parent state with Chern number $C=1$ at filling $\nu=1$. We propose a parent state theory which posits that stability of the Chern insulator and flatness of its hole excitations are necessary for obtaining FCIs upon doping. We then perform multi-band exact diagonalization calculations to confirm the emergence of FCIs at $\nu = 2/3$ in the presence of the moiré capacitor effect. Our FCI state is stabilized by inter-band fluctuations, unlike in the moire-free case which collapses with band-mixing. We provide the first consistent theory for this state in aligned samples and explain its absence in unaligned ones.
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All authors Nicolas Regnault, Heqiu Li, Yves H. Kwan, B. Andrei Bernevig, Jonah Herzog-Arbeitman

Materials Science

Mechanisms of Nanoscroll Formation and Particle Encapsulation in Janus MXenes

Morphology transfer of 2D Janus MXenes into nanoscrolls unlocks unusual properties. Although a scalable synthesis route has been experimentally verified, the atomistic mechanism underlying nanoscroll formation remains poorly understood. We use large-scale reactive molecular dynamics simulations, validated against density functional theory (DFT) and experimental structural and elastic properties, to investigate stability and quantify the driving forces and geometry governing nanoscroll formation in three Janus MXenes, (Tx)Ti2C(Ty), where (Tx) and (Ty) denote the bottom and top surface terminations among bare (-b), -O, and -OH. Both square and infinitely wide flakes with lengths ranging from 10 to over 120 nm are simulated. We find that 1-7% lattice-induced strain generates a bending moment in these structures. The sheet scrolls, curves, or forms a nanotube depending on the resulting curvature and initial sheet size. For MXenes with an initial length of 120 nm, multiwalled nanoscrolls form with interlayer distances of around 0.7 nm and inner diameters of about 7 nm for (O)Ti2C(OH) and (b)Ti2C(OH), whereas (b)Ti2C(O) instead produces a much larger interlayer distance of around 1.7 nm and an inner diameter exceeding 20 nm. We show that spontaneous scrolling of a Janus MXene in the presence of an anchored nanoparticle produces a core@shell composite, in which the particle locally deforms the nanoscroll and widens the interlayer channels. This locally tunable, enlarged interlayer spacing offers a promising design route for MXene-based energy-storage electrodes. However, our simulations reveal H2 gas release during encapsulation, which promotes nanobubble formation that can reduce battery life.
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All authors Sasan Rezaee, Fatemeh Mohammad Dezashibi, Ould el Moctar, Hossein Darban

Mesoscale and Nanoscale Physics

Is the Aharonov-Casher phase geometrical or dynamical?

We consider two two-dimensional (2D) electronic systems in the presence of a perpendicular homogeneous electric field that generates a Rashba spin-orbit interaction (RSOI): a system of non-interacting electrons in a 2D conductor, modeled using the 2D Schrödinger equation (SE), and a single-layer graphene system, modeled using a 2D Dirac equation (DE) for massless fermions. In both cases the RSOI is expressed via an $SU(2)$ Rashba vector potential ${\bf A}_{R}$. We demonstrate that ${\bf A}_{R}$ cannot be eliminated from either the 2D SE or the 2D DE via a gauge transformation. Nevertheless, for a plane wave solution, an $SU(2)$ matrix exists that eliminates ${\bf A}_{R}$ from the resulting 1D SE. This unitary matrix is an Aharonov-Casher (AC) phase factor, and facilitates the calculation of the AC phase in the Schrödinger scheme. The plane wave solution for the DE contains two components of ${\bf A}_{R}$: $A_{R, k}$ in the direction of the wave vector ${\bf k}$, and $A_{R, n}$ normal to ${\bf k}$. The latter generates an effective electron mass that cannot be eliminated from the DE. The former generates an AC phase that can be eliminated by a time-dependent unitary transformation. Thus, the Dirac AC phase is time-dependent, i.e., it is a dynamical phase. This is in contradistinction to the Schrödinger AC phase which is geometrical.
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Statistical Mechanics

Intermediate scattering function of Brownian particles in a tilted cosine potential

We solve the Fokker-Planck equation for a Brownian particle in a tilted cosine potential and derive the intermediate scattering function (ISF), which captures the full spatio-temporal dynamics of the system. The model consists of a single overdamped Brownian particle in one dimension. We derive a generalized ISF comprising two wave vectors to describe correlations in the periodic potential. Exploiting the periodicity via Bloch's theorem, we formulate the problem within a spectral-theoretical framework and numerically compute the corresponding eigenfunctions and eigenvalues, from which we obtain the ISF and the probability density. Using time-dependent perturbation theory, we expand the ISF and derive low-order moments, including the mean-square displacement, time-dependent diffusivity, skewness, and the non-Gaussian parameter. Our analytical results are validated by Brownian-dynamics simulations and analyzed focussing on different regimes of the tilting force. The results are compared to a harmonic approximation and the deterministic limit.
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Strongly Correlated Electrons

Emergent heavy fermion and superconductivity near Mott transition in twisted bilayer graphene

Near a bandwidth-tuned Mott transition, the Fermi velocity $v_F$ and quasiparticle residue $Z$ of a metal often vanish. Here, we show that analogous phenomena emerge in twisted bilayer graphene (TBG) at integer fillings and can be captured by an emergent heavy-fermion framework within a projective active-band limit. Unlike models incorporating remote bands, our effective heavy-fermion description arises from mixed-valence Mott physics via decoupled charge and local-moment sectors. In the charge sector, active bands $c(\mathbf{k})$ hybridize with an emergent orthogonal fermion $\psi(\mathbf{k})$ to open a large Mott gap at $|\mathbf{k}| > k_*$ ($k_*$ sets the momentum-patch size) and a quadratic band-touching semimetal near $\mathbf{k}=0$ at neutrality ($\nu=0$). The orthogonal fermion is a linear combination of the doublon and holon excitations and may be written as $\psi_i \sim (\delta n^f_i+\frac{1}{2})^{-1} f_i$. An emergent Kondo coupling $J_K \sim U$ ($U$ is the local Hubbard interaction) between $\psi$ and local moments $\psi'$ frames the Mott transition as a Kondo screening transition, tuned by the twist angle $\theta$. Away from the magic angle, a Kondo-screened heavy semimetal develops below $T_K$ (the Kondo temperature) with vanishing $Z$. Introducing anti-Hund's coupling $J_A$ generates an s-wave fully gapped or nematic, nodally gapped superconducting dome near the Mott boundary even at $\nu=0$. At other integer fillings $\nu = \pm 1, \pm 2$, increasing bandwidth first drives the small-gap Mott state into an intermediate quadratic band-touching semimetal before entering a heavy Fermi liquid with large Fermi surfaces. Our results establish a unified framework for emergent heavy fermion physics with both itinerant carriers and local moments from the $f$ orbital.
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Strongly Correlated Electrons

Probing Impurity Quantum Criticality with Entanglement Witnesses

Entanglement is a defining feature of quantum mechanics, and its relation to quantum criticality is of considerable current interest. Here we show that measurable spin and charge fluctuations provide an entanglement witness of quantum criticality in the two-impurity Kondo model, which has experimental realizations in terms of coupled quantum dots and magnetic impurities added to surfaces. We use density-matrix renormalization group and numerical renormalization group calculations to resolve the non-Fermi-liquid critical point separating two independently Kondo-screened impurities from an inter-impurity singlet and interpret it as a change in the dominant entanglement partner of each local moment: from entanglement of the local moment with an extended set of conduction-electron degrees of freedom to entanglement with the other impurity. This reorganization is accompanied by a singular response of the impurity-bath entanglement and the inter-impurity susceptibility. We show how the same structure is encoded in the quantum Fisher information of collective spin and charge operators at zero and finite temperatures, connecting the entanglement picture to experimentally accessible dynamical response functions. Our results establish impurity systems as controlled settings in which quantum-critical entanglement can be detected through measurable correlations, and provide further insight into the possibility of understanding heavy-fermion physics in terms of entanglement.
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Statistical Mechanics

Interface phases and dynamics in two-dimensional quantum magnets: A "holographic" approach from universality to quantum simulation

We introduce a framework to classify quantum phases, phase transitions, and non-equilibrium dynamics of interfaces separating ordered bulk domains in 2D quantum magnets - equivalently, confining strings in dual lattice gauge theories - based on effective 1D Hamiltonians governing geometric fluctuations. Building on a "holographic" approach from [Phys. Rev. Lett. 129, 120601 (2022)], here reinterpreted as an exact bosonization, we uncover a rich quantum phase structure, with a variety of stiff and rough interface phases described by gapped and gapless 1D ground states, respectively, all distinguishable through the statistics of 2D wave-function snapshots. Our framework allows us to predict distinct spatiotemporal scaling laws for non-equilibrium curvature-driven interface dynamics across parameter space, which can be readily probed in existing experiments. We finally show that our approach enables the unprecedented experimental opportunity of directly measuring charge full counting statistics and symmetry-resolved properties of an encoded 1D system, as we explicitly demonstrate by numerically simulating a neutral-atom array experiment.
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All authors Abhishodh Prakash, Jaydev Singh Rao, Siddharth A. Parameswaran, Alessio Lerose

Strongly Correlated Electrons

Proliferation Transitions for Non-Abelian Anyons

We construct phase transitions that proliferate condensable anyons in general 2+1d topological orders, including non-abelian ones. The central tool that provides a systematic approach to this question is the Symmetry Topological Field Theory (SymTFT). For a given topological order, we identify the relevant symmetry from the transparent lines generated by the condensable anyons, and thereby realize the topological order in terms of a 3+1d SymTFT sandwich. The proliferation phase transition is realized by coupling scalar fields to the anyons purely on the symmetry boundary of the SymTFT. We illustrate the construction for abelian theories, as well as non-abelian ones, $D(S_3)$ and $SU(2)_k$ Chern-Simons theories, and extend it to anomalous anyons.
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Statistical Mechanics

Finite-depth scaling and an exact Bernoulli-leaf identity for the min-plus process on the binary tree

The min-plus process is a stochastic coagulation-annihilation-type process on the binary tree, of interest in mathematics, physics, and computer science as a tractable instance of max-type recursive distributional equations. We carry out large Monte Carlo simulations at effective tree depths up to $N=60$ that provide finite-depth corroboration of the Beta(2,1) stretched-exponential limit for its root value $X_{N}$ at $p=1/2$, on the asymmetric $\sqrt{N}$ side of the random-homogeneous-systems classification recently introduced by Chen, Duquesne, and Shi and by Morfe. Off criticality, our simulations confirm the sub-critical closed form $\mathbb{P}(X_{\infty}=1)=(1-2p)/(1-p)$ within Monte Carlo error and document a super-critical mean growth exceeding the elementary $(2p)^{N}$ lower bound at the depths we reach. For a Bernoulli($q$)-initial-condition variant, we identify an elementary closed-form identity at $p=1/2$ that pins down the order parameter $\mathbb{P}(X_{N}=0)=q$ exactly, locates the absorbing-state phase transition at $p_{c}=1/2$ in the operator-mixing probability rather than in the initial-zero density, and shows that the conditional law on positives deforms substantially with $q$. Our simulations use a level-wise recursion and an FFT-based precomputed leaf table which reduce the effective simulation depth while preserving the recursive tree law and may be useful for the simulation of related recursive equations on large trees.
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Soft Condensed Matter

Revisiting Safe Temperature for Environmental Accelerated Aging of Additively Manufactured Polymers

Accelerated aging is widely used to study the long-term behavior of materials within laboratory time scales, particularly for materials exposed to solvent environments over extended periods. This is especially important for additively manufactured (AM) polymers, whose increasing use in naval and commercial undersea applications requires reliable methodologies for assessing durability under in-service conditions. A common approach relies on elevating the temperature below the glass transition or melting temperature to accelerate degradation. However, the temperature limits for accelerated aging of AM polymers remain poorly understood, particularly because temperatures beyond a threshold may activate deformation and degradation mechanisms that are absent under service conditions. To address this gap, this paper investigates fused deposition modeling (FDM) Acrylonitrile Butadiene Styrene (ABS) exposed to saltwater and deionized (DI) water to establish a temperature threshold for accelerated aging in aqueous environments and propose a methodology for determining such thresholds. Controlled geometries and varying print directions were employed to explicitly probe the underlying mechanisms. We show that samples exposed to temperatures above the threshold exhibit pronounced shrinkage and warping along the printing direction due to the relaxation of process-induced internal stresses. These observations establish an accelerated-aging temperature threshold of 50$^\circ$C for ABS, beyond which additional mechanisms absent under service conditions become active. Additionally, the resulting geometric distortions are masked in thick geometries but become highly pronounced in thin structures. Moreover, solvent ionic content strongly influences water uptake, with saltwater reaching saturation in 1 day, whereas DI water did not reach saturation even after 30 days and exhibited greater mass uptake.
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All authors Kevin LoGiudice, Keven Alkhoury, Nikash Long, Justin Moustouka, Nour Mousbah, Irine Chenwi, James LeBlanc, Vikas Srivastava

Mesoscale and Nanoscale Physics

Wormhole Geometry from a Magnetic Vortex

Strong coupling to a magnetic texture makes an electron propagate through an emergent curved space. We show that an elementary vortex realizes the exterior spatial geometry of an Ellis wormhole: an ultrastatic throat with radius fixed by the topological charge and Hund exchange, cut off at short distances by the microscopic core. Two separable signatures follow directly: the electron deflection collapses onto a single Ellis curve governed by the vortex winding and exchange coupling, while the spin Berry phase produces a half-flux Aharonov–Bohm response switched on and off by winding parity. The same metric can be emulated in a designer honeycomb lattice, where the valley-symmetrized wave-packet response follows the predicted exterior geodesic. These signatures are accessible through real-space electron deflection and scattering, providing experimentally distinct probes of the emergent geometry and Berry flux. The magnetic vortex thus turns a topological defect into a tunable curved-space lens for electrons in quantum materials and designer lattices.
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Materials Science

PACE-SIMS: Checkpoint-Gated Autonomous SIMS Characterization with AI-Agent Quality Control

Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is widely used for local chemical investigations across a broad range of materials and systems. However, its operation is expensive in expert time: a trained researcher must supervise the acquisition continuously, tuning parameters as the experiment proceeds, often across a campaign spanning multiple days. Here, we present PACE-SIMS (Pause-Assess-Correct-Execute for SIMS), an agentic workflow that runs a SIMS study as a human-AI collaboration. In this workflow, the researcher specifies the scientific questions and quality requirements, and an AI agent builds the plan and, after approval, executes it autonomously, pausing at checkpoints to judge each measurement and to correct, retry, or escalate. To validate the approach, we applied it to a study of chemical composition in 18O-enriched WOx films. During this randomized, blind two-polarity study (8.1 hours, 35 measurements), the agent applied three rule-governed corrections and diagnosed an unanticipated source excursion without requiring event-specific control logic to be programmed in advance. The same run returned transferable measurement science, including a composition calibration and the deposition's tracer-delivery mechanism, from less than two hours of researcher attention. The developed agentic architecture is not specific to SIMS and can be applied to other analytical techniques, with the primary target being destructive measurements, for which optimization-based methods are poorly suited.
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All authors Anton V Ievlev, Heather Hare, Yiyang Li, Sergei V Kalinin

Mesoscale and Nanoscale Physics

Exact solution for stationary states of a closed memristor with mobile charged vacancies

A nonlinear model of a memristor based on charged mobile vacancies is considered taking into account the electrostatic interaction between them. This interaction significantly affects the stationary (limiting) vacancy distributions formed under the action of the electric current flowing through the memristor, for which analytical expressions are obtained in this work. Between the regions with reduced and increased vacancy concentrations, an intermediate electrically neutral region is formed due to the electrostatic interaction. Interestingly, the limiting resistances in the “on” and “off” states of such a memristor do not depend on the strength of the electrostatic interaction, at least in the leading first order in the vacancy concentration.
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Statistical Mechanics · Cross-listed from quant-ph

Conditional dependence and Scrooge ensembles in shallow random quantum circuits

The output state of a 2D geometrically local shallow random quantum circuit does not have long range correlations due to its lightcone structure. But this changes if one measures a subset of the qubits: long-range entanglement can be induced by the measurement process, leading to conditional correlations between distant qubits. In this paper we investigate the structure of conditional dependence in these circuits and its consequences for quantum advantage. For a tripartition $ABC$ of the qubits, we consider the ensemble of post-measurement states on $A$ that is conditioned on a specific measurement outcome on $B$ and ranges over all possible measurement outcomes on $C$. For circuit depths exceeding a constant critical value $d^*$, we conjecture that this ensemble is well approximated by a certain generalization of the Haar ensemble, called the Scrooge ensemble~[Jozsa et al., \href{https://doi.org/10.1103/PhysRevA.49.668}{Phys. Rev. A 49, 668 (1994)}]; we also provide supporting numerical and analytical evidence. Our conjecture describes a precise sense in which the state retains its lightcone structure on the remaining unmeasured qubits, but also develops some globally random features arising from the measurement. A consequence is that $n$-qubit shallow random quantum circuits in two dimensions are classically efficiently simulable in the presence of a tiny depolarizing noise rate $\Omega(\log(n)/n)$.
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All authors Yinchen Liu, Max McGinley, Thomas Schuster, David Gosset

Materials Science · Cross-listed from physics.app-ph

Measurement of third-order elastic constants using thermal modulation of ultrasonic waves

Third-order elastic constants (TOEC) play an important role in nonlinear material characterization, but measurements of TOEC are laborious with large error margins. This Letter presents the equations of wave velocity changes caused by homogeneous temperature variation and uniaxial stress in isotropic media and the expression of TOEC in terms of thermally induced velocity change and thermal strain. TOEC of an aluminum sample were experimentally determined by measuring ultrasonic wave velocity changes in the uniaxial loading test and the thermal modulation test. Experimental results showed good agreement between the two test methods. Owing to the simple test setup and high measurement sensitivity, the thermal modulation test is a potential experimental method to determine TOEC and absolute acoustic nonlinearity parameters.
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2608.12244 · 12 Aug · 1. Corrected a sign typo in Eq. (6d) relative to the original APL publication. 2. The final TOEC values might be affected by minor temperature variations during testing; for further discussion, see Zhu et al., Nondestructive Testing and Evaluation, 41(7), 4066-4089 (2026), DOI: 10.1080/10589759.2025.2551866

Soft Condensed Matter

Random close packing at extreme size ratios with an Adam-based inflation protocol

We present rcpgenerator, an openly available code for generating $d$-dimensional dense, disordered, non-overlapping close packings from an arbitrary prescribed list of particle diameters. The method adapts the Clarke–Wiley inflation protocol, but instead uses the Adam optimizer to relax the particle configuration. Typically, particle coordinates are advanced with a single, global step size, which must shrink as the size ratio $S\equiv D_{\max}/D_{\min}$ grows, generally stalling the optimization. Adam instead gives each coordinate its own adaptive step size, stabilizing the optimization time across a broader range of $S$. We demonstrate this in three-dimensional periodic tests that reach $S\sim5\times10^{5}$ for a continuous lognormal distribution ($N\sim10^{6}$ diameters) and particle numbers up to $N\approx5.6\times10^{6}$ for power-law distributions, with the densest packings reaching $\phi\simeq0.87$, each completed in minutes to hours on a multicore machine. Across truncated-lognormal, truncated-power-law, and Weibull distributions, the resulting $\phi$ reproduces trends such as the locations of peaks and knees with distribution shape and $S$ found in prior numerical results and in the parameter-free Farr–Groot prediction, with a remaining offset typically $0.005$–$0.01$. Additionally, results are commensurate with multimodal packing densities measured in vibrated-bed experiments. The code and the complete per-case census behind every figure are released with the paper.
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