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Physics Condensed Matter

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Sunday 9 November

Mesoscale and Nanoscale Physics

Active Noise Reduction in Si/SiGe Gated Quantum Dots

Solid-state quantum technologies such as quantum dot qubits and quantum electrical metrology circuits rely on quantum phenomena at ultra-low energies, making them highly sensitive to various forms of environmental noise. Conventional passive filtering schemes can reduce high-frequency noise but are often ineffective against low-frequency interference, like powerline or instrument-induced. Extending such filters to lower frequencies causes practical issues such as longer stabilization times, slower system response, and increased Johnson noise, which impede low-frequency transport measurements. To address these limitations, we propose and experimentally demonstrate a generalized active noise cancellation scheme for quantum devices operating at sub-Kelvin temperatures. Our approach compensates periodic environmental interference by dynamically injecting a phase-coherent anti-noise signal directly into the device. We employ an automated feedback protocol featuring beat-frequency reduction and adaptive phase-amplitude tuning, enabling real-time compensation without any manual intervention. Unlike post-processing or passive filtering, this method suppresses noise at the device level without introducing additional time constants. We implement the scheme on a gate-defined Si/SiGe quantum dot subject to strong 50 Hz powerline interference and validate its effectiveness through acquiring Coulomb Blockade Oscillations and Coulomb diamond plots. The technique achieves substantial suppression of both the targeted interference and the overall noise floor, thereby stabilizing transport characteristics and enhancing device fidelity. While demonstrated on a quantum dot, the proposed framework is broadly applicable to a wide class of solid-state quantum devices where deterministic noise presents a critical bottleneck.
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All authors Rajat Bharadwaj, Parvathy Gireesan, Harikrishnan Sundaresan, Chithra H Sharma, Lucky Donald L Kynshi, Prasad Muragesh, D. Bougeard, Madhu Thalakulam

Strongly Correlated Electrons

Linear tetramer formation in nonmagnetic pyrochlore niobate

We investigate displacive short-range order in pyrochlore Y2Nb2O7, which exhibits a nonmagnetic insulating state despite the presence of formally tetravalent Nb4+ (S = 1/2) ions on the pyrochlore network. Synchrotron x-ray diffraction on a single crystal reveals a characteristic x-ray diffuse scattering (XDS) pattern primarily around q = {0.5, 0.5, 2}. Reverse Monte Carlo (RMC) simulations uncover local Nb displacements along the <111> axes, leading to the formation of linear Nb4 tetramers. Our findings highlight a crucial role of molecular orbital degrees of freedom in stabilizing the nonmagnetic insulating state. This study demonstrates that RMC analysis of XDS provides a powerful approach for elucidating short-range correlations and the underlying mechanisms governing the physical properties of crystalline materials.
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All authors Shota Nishida, Shunsuke Kitou, Shingo Toyoda, Yuiga Nakamura, Yusuke Tokunaga, Taka-hisa Arima

Other Condensed Matter · Cross-listed from quant-ph

Equivalence and Divergence of Imaginary-Time Evolution and Gradient Descent for Gaussian Variational States

Imaginary-time evolution (ITE) is one of the most widely used numerical techniques for obtaining ground states of many-body Hamiltonians. In this work, we compare ITE with gradient descent (GD) within the framework of Gaussian wavefunction ansatze. We show that while ITE and GD are formally equivalent for fermionic systems, GD exhibits consistently faster convergence for bosonic systems, challenging the common assumption of their complete equivalence.
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Superconductivity

Robustness of bipolaronic superconductivity to electron-density-phonon coupling

We study bipolaron formation and bipolaronic superconductivity on a square lattice, where electrons couple to both local Holstein phonons via on-site charge density and nonlocal bond Su-Schrieffer-Heeger phonons via modulation of hopping amplitudes. Using an unbiased Diagrammatic Monte Carlo method, we investigate how the interplay between these two types of electron-phonon coupling affects the bipolaron binding energy, effective mass, spatial extent (quantified by the mean-squared radius), and the superconducting transition temperature $T_c$. We find that, in some parameter space, the moderate Holstein coupling, though detrimental to $T_c$ when acting alone, can enhance superconductivity when combined with the bond SSH coupling by further compressing the bipolaron without significantly increasing its mass. Similarly, introducing bond SSH coupling into a Holstein bipolaron reduces its size while keeping the effective mass nearly unchanged, leading a higher $T_c$. These effects give rise to nonmonotonic behavior and reveal a cooperative regime in which both couplings work together to enhance superconductivity. We further examine phonon frequency asymmetry, particularly the case $\omega_H/t = 2\omega_B/t$, and show that in the deep adiabatic regime, adding Holstein coupling can even raise $T_c$ when combined with bond SSH coupling. These results highlight the distinct and complementary roles of local Holstein and non-local bond SSH electron-phonon couplings, and suggest strategies for optimizing high-$T_c$ superconductivity in systems with multiple phonon modes.
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Materials Science

Magnetic and structural properties of epitaxial Er-substituted yttrium iron garnet films grown by pulsed laser deposition

Er-substituted yttrium iron garnet (Er:YIG) holds the potential of combining the low magnetic damping of YIG with the telecom-band optical transitions of $\text{Er}^{3+}$ ions, making it a suitable material for hybrid optomagnonic devices and microwave-to-optical quantum transduction. We report the epitaxial growth of $\text{Er}_{x}\text{Y}_{3-x}\text{Fe}_{5}\text{O}_{12}$ films with $x=0.008-0.20$ on (111)-oriented gadolinium gallium garnet (GGG) substrates using pulsed laser deposition. X-ray diffraction, reciprocal space mapping, and scanning transmission electron microscopy confirm single-phase, fully coherent growth with atomically sharp interfaces across the entire substitution range. Magnetometry reveals a gradual decrease in saturation magnetization with increasing Er content, consistent with antiparallel coupling between Er$^{3+}$ spins and the net Fe$^{3+}$ moments, along with the emergence of an in-plane uniaxial magnetic anisotropy. The ferromagnetic resonance broadens with Er concentration due to increased Gilbert damping and inhomogeneous linewidth broadening. Films with low Er content ($x=0.008$), most relevant for optomagnonic applications, retain nearly isotropic magnetization and exhibit a damping parameter only slightly higher than that of undoped YIG. These results identify growth and substitution conditions that preserve YIG's low-loss magnetic properties while introducing optical functionality, establishing Er:YIG as a viable platform for hybrid quantum magnonics and microwave-to-optical transduction.
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All authors Lukas Flajsman, Lars Peeters, Armi Kosunen, Lide Yao, Ionela Vrejoiu, Sebastiaan van Dijken

Materials Science · Cross-listed from physics.chem-ph

Modeling the precipitation distribution by radius and pore size during drying of an impregnated sphere

The process of preparing heterogeneous catalysts on porous supports includes a drying stage, in which the porous material, impregnated with an aqueous solution of the catalyst precursor, is dried, and the precursor is precipitated on the pore walls. The precipitate distribution throughout the support volume strongly influences the catalyst performance and durability within industrial reactors. This paper presents a mathematical model for simulating the precipitation distribution during the drying of a porous sphere. Examples of calculations are given demonstrating the influence of some parameters on the distribution by space and by pore size.17
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Mesoscale and Nanoscale Physics · Cross-listed from quant-ph

Spontaneous emission of a three-level artificial atom in a one-dimensional open waveguide

We study the dynamical and spectral characteristics of a quantum three-level ladder system, interacting with a continuous electromagnetic field in one-dimensional open waveguide. Common realization of such systems is a waveguide QED setup - a superconducting artificial atom (transmon), coupled to an open microwave transmission line. We derive an analytical solution for spontaneous emission of initially excited atom, and use it to study the probability of state detection and spectral density of output photon states. We find that for strong coupling of transmon to a waveguide emitted photons show correlation in frequency and can have the same energies, even if the three-level system is anharmonic.
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Materials Science

Phonon-Dominated Thermal Transport and Large Violation of the Wiedemann-Franz Law in Topological Semimetal CoSi

The Wiedemann-Franz (WF) law, relating the electronic thermal conductivity ($\kappa_{\rm e}$) to the electrical conductivity, is vital in numerous applications such as in the design of thermoelectric materials and in the experimental determination of the lattice thermal conductivity ($\kappa_{\rm L}$). While the WF law is generally robust, violations are frequently observed, typically manifesting in a reduced Lorenz number ($L$) relative to the Sommerfeld value ($L_0$) due to inelastic scattering. Here, we report a pronounced departure from the WF law in the topological semimetal CoSi, where the electronic Lorenz number ($L_{\rm e}$) instead rises up to $\sim40\%$ above $L_0$. We demonstrate that this anomaly arises from strong bipolar diffusive transport, enabled by topological band-induced electron-hole compensation, which allows electrons and holes to flow cooperatively and additively enhance the heat current. Concurrently, we unveil that the lattice contribution to thermal conductivity is anomalously large and becomes the dominant component below room temperature. As a result, if $\kappa_{\rm L}$ is assumed negligible – as conventional in metals, the resulting $L$ from the total thermal conductivity ($\kappa_{\rm tot}=\kappa_{\rm L}+\kappa_{\rm e}$) deviates from $L_0$ by more than a factor of three. Our work provides deeper insight into the unconventional thermal transport physics in topological semimetals.
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All authors Luyao Zhong, Xin Jin, Mingquan He, Rui Wang, Xiaoyuan Zhou, Tianqi Deng, Xiaolong Yang

Statistical Mechanics

Ordering in statistical systems on the way to the thermodynamic limit

It is well known that the mathematically accurate description of ordering and related symmetry breaking in statistical systems requires to consider the thermodynamic limit. But the order does not appear from nowhere, and yet before the thermodynamic limit is reached, there should exist some kind of preordering that appears and grows in the process of increasing the system size. The quantitative description of growing order, under the growing system size, is developed by introducing the notion of order indices. The rigorous proof of the phase transition existence is a separate difficult problem that is not the topic of the present paper. We illustrate the approach resorting to several models in the mean-field approximation, which makes it possible to demonstrate the notion of order indices for finite systems in a clear way. We show how the order grows on the way to the thermodynamic limit for Bose-Einstein condensation, arising superconductivity, magnetization, and crystallization phenomena.
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Mesoscale and Nanoscale Physics · Cross-listed from physics.class-ph

Do Discrete Fine-Scale Mechanical Models with Rotational Degrees of Freedom Homogenize Into a Cosserat or a Cauchy Continuum?

This article answers the question of whether homogenization of discrete fine-scale mechanical models, such as particle or lattice models, gives rise to an equivalent continuum that is of Cauchy-type or Cosserat-type. The study employs the machinery of asymptotic expansion homogenization to analyze discrete mechanical models with rotational degrees of freedom commonly used to simulate the mechanical behavior of heterogeneous solids. The proposed derivation has general validity in both stationary (steady-state) and transient conditions (assuming wavelength much larger that particle size) and for arbitrary nonlinear, inelastic fine-scale constitutive equations. The results show that the unit cell problem is always stationary, and the only inertia term appears in the linear momentum balance equation at the coarse scale. Depending on the magnitude of the local bending stiffness, mathematical homogenization rigorously identifies two limiting conditions that correspond to the Cauchy continuum and the Cosserat continuum. A heuristic combination of these two limiting conditions provides very accurate results also in the transition from one limiting case to the other. Finally, the study demonstrates that cases for which the Cosserat character of the homogenized response is significant are associated with non-physically high fine-scale bending stiffness and, as such, are of no interest in practice.
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Statistical Mechanics

The number of spanning trees as an indicator of critical phenomena: When Kirchhoff meets Ising

Visibility graphs are spatial interpretations of time series. When derived from the time evolution of physical systems, the graphs associated with such series may exhibit properties that can reflect aspects such as ergodicity, criticality, or other dynamical behaviors. It is important to describe how the criticality of a system is manifested in the structure of the corresponding graphs or, in a particular way, in the spectra of certain matrices constructed from them. In this paper, we show how the critical behavior of an Ising spin system manifests in the spectra of the adjacency and Laplacian matrices constructed from an ensemble of time evolutions simulated via Monte Carlo (MC) Markov Chains, even for small systems and short MC steps. In particular, we show that the number of spanning trees – or its logarithm – , which represents a kind of structural entropy or topological complexity here obtained from Kirchhoff's theorem, can, in an alternative way, describe the criticality of the spin system. These findings parallel those obtained from the spectra of correlation matrices, which similarly encode signatures of critical and chaotic behavior.
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All authors Roberto da Silva, Henrique A. Fernandes, Paulo G. Freitas, Sebastian Gonçalves, E. V. Stock, A. Alves

Soft Condensed Matter · Cross-listed from physics.flu-dyn

Global Buckley-Leverett theory for multicomponent flow in fractured media: Isothermal equation-of-state coupling and dynamic capillarity

We present an isothermal Global Buckley–Leverett framework for multicomponent, multiphase flow in porous and fractured media that retains the interpretability of classical Buckley–Leverett while incorporating essential physics: equation of state-based phase behavior, multicomponent Maxwell–Stefan diffusion, dynamic capillarity, stress-sensitive permeability, and non-Darcy fracture flow. The formulation yields a single global-pressure equation driving the total Darcy flux and an exact fractional-flow decomposition of phase velocities with buoyancy and capillary drifts; inertial effects enter as per-phase damping that renormalizes mobilities. Crucially, the combination of Maxwell–Stefan diffusion and dynamic capillarity renders transport pseudo-parabolic, resolving the loss of strict hyperbolicity that plagues three-phase Buckley–Leverett and ensuring a well-posed initial-value problem. In practice, each time step solves the scalar global-pressure equation, reconstructs phase fluxes via the split, and advances strictly conservative component balances; axisymmetric (cylindrical) forms for radial injection with vertical buoyancy are provided. The model reduces exactly to classical Buckley–Leverett when added physics are disabled, making it a practical backbone for carbon storage, geothermal exchange, and contaminant transport in fractured, compositionally complex reservoirs.
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Materials Science · Cross-listed from math.DS

A Bilayer Cathode Design Procedure for Li ion Batteries Using the Multilayer Doyle-Fuller-Newman Model (M-DFN)

Heterogeneities in lithium ion batteries can be significant factors in electrode under utilisation and degradation while charging. Bilayer electrodes have been proposed as a convenient and scalable way to homogenise the electrode response. In this paper, the design of a bilayer cathode for Li-ion batteries composed of separate layers of lithium nickel manganese cobalt oxide (NMC622) and lithium iron phosphate (LFP) is optimised using the multilayer Doyle-Fuller-Newman (M-DFN) model. Changes to the carbon binder domain, electrolyte volume fraction, and tortuosity provided the greatest control for improving Li-ion charge mobility. The optimised bilayer design was able to charge at 3C between 0-90% SOC in 18.6 minutes, achieving 4.4 mAh/cm2. Comparing the optimal bilayer to the LFP-only electrode, the bilayer achieved 41% higher capacity. Through mechanistic physics-based modelling, it was shown that the 3C charging improvement of the optimised bilayer was achieved by enabling a more homogeneous current density distribution through the thickness of the electrode and electrolyte depletion prevention. The findings were confirmed on a high-fidelity X-ray computed tomography (CT) based microstructural model. The results illustrate how modelling can be used to rapidly search novel electrode designs
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All authors E. C. Tredenick, A. M. Boyce, R. Drummond, S. R. Duncan

Strongly Correlated Electrons · Cross-listed from hep-lat

Chiral Anomaly of Kogut-Susskind Fermion in the (3+1)-dimensional Hamiltonian formalism

We consider Kogut-Susskind fermions (also known as staggered fermions) in a $(3+1)$-dimensional Hamiltonian formalism and examine a chiral transformation and its associated chiral anomaly. The Hamiltonian of the massless Kogut-Susskind fermion has symmetry under the shift transformations in each space direction $S_k \, (k=1,2,3)$, and the product of the three shift transformations in particular (the odd shifts in general) may be regarded as a unitary discrete chiral transformation, modulo two-site translations. The hermitian part of the transformation kernel $\Gamma = i S_1 S_2 S_3$ can define an axial charge as $Q_A = (1/2)\sum_x \chi^\dagger(x) \left(\Gamma+\Gamma^\dagger \right)\chi(x)$, which is non-onsite, nonquantized, and commutative with the vector charge, analogous to $\tilde{Q}_A = (1/2) \sum_n ( \chi^\dagger_n \chi_{n+1} + \chi^\dagger_{n+1} \chi_{n} )$ for the $(1+1)$ dimensional Kogut-Susskind fermion. However, our $Q_A$ cannot be expressed in terms of any quantized charges in a generalized Onsager algebra. Although $Q_A$ does not commute with the fermion Hamiltonian in general when coupled to background link gauge fields, we show that they become commutative for a class of $U(1)$ link configurations carrying nontrivial magnetic and electric fields. We then verify numerically that the vacuum expectation value of $Q_A$ satisfies the anomalous conservation law of axial charge in the continuum two-flavor theory under an adiabatic evolution of the link gauge field.
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Statistical Mechanics · Cross-listed from physics.soc-ph

Two variants of the friendship paradox: The condition for inequality between them

The friendship paradox – the observation that, on average, one's friends have more friends than oneself – admits two common formulations depending on whether averaging is performed over edges or over nodes. These two definitions, the "alter-based" and "ego-based" means, are often treated as distinct but related quantities. This paper establishes their exact analytical relationship, showing that the difference between them is governed by the degree-degree covariance normalized by the mean degree. Explicit examples demonstrate the three possible cases of positive, zero, and negative covariance, corresponding respectively to assortative, neutral, and disassortative mixing patterns. The derivation further connects the covariance form to the moment-based expression introduced by Kumar, Krackhardt, and Feld [Proc. Natl. Acad. Sci. 121, e2306412121 (2024)], which involves the (-1)st, 1st, 2nd, and 3rd moments of the degree distribution. The two formulations are shown to be equivalent, as they should be: the moment-based representation expands the same structural dependence that the covariance form expresses in its most compact and interpretable form. The analysis thus unifies node-level and moment-level perspectives on the friendship paradox, offering both a pedagogically transparent derivation and a direct bridge to recent theoretical developments.
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Saturday 8 November

Materials Science

Transition from MOS to Ideal Capacitor Behavior Triggered by Tunneling in the Inversion Population Regime

An analytical solution to the nonlinear Poisson equation governing the inversion layer in metal-oxide-semiconductor (MOS) structures has recently been obtained, resolving a fundamental challenge in semiconductor theory first identified in 1955. This breakthrough enables the derivation of explicit expressions for relevant physical quantities, such as the inversion-layer width, electric potential, and charge distribution, as functions of gate voltage $V_G$, distance from oxide-semiconductor interface and impurity concentration. These quantities exhibit rapid variation during early-stage inversion but saturate once the gate voltage exceeds the threshold voltage by a few tenths of a volt signaling a transition in the MOS response to $V_G$. The onset of tunneling through the Esaki barrier leads to increased charge accumulation near the interface, reshaping the charge distribution into a two-dimensional profile and shifting the potential drop from the semiconductor to the oxide layer. This reconfiguration resembles the behavior of an ideal parallel-plate capacitor, with charge confined at the interface and the voltage drop localized across the oxide. We analyze this mechanism in detail and demonstrate, through explicit calculations, that the tunneling current through the Esaki-like barrier formed during inversion becomes dominant, effectively superseding classical inversion behavior. These results offer a new analytical foundation for quantum-aware device modeling and inform the design of next-generation MOSFET and tunneling FET architectures.
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Mesoscale and Nanoscale Physics · Cross-listed from quant-ph

Converting coherence into work with a fully quantum engine

Heat engines convert thermal energy into mechanical work. We here report the experimental realization of a fully quantum engine that converts quantum coherence into work. A single solid-state spin in diamond is fueled by a coherent bath and cyclically stores energy in a spin quantum battery. We establish quantum-enhanced performance by showing that almost 200$\%$ more work is produced after a few cycle compared to the corresponding classical engine. We obtain concrete criteria for successful coherence-to-work conversion, and highlight the importance of a coherent motor-battery interaction. This device harnesses nonclassical features during all stages of its cycle, and demonstrates the functionality of a nanomachine whose parts are all quantum coherent.
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All authors MinSik Kwon, Tobias Denzler, Rouven Maier, Vadim Vorobyov, Durga Bhaktavatsala Rao Dasari, Eric Lutz, Jörg Wrachtrup

Strongly Correlated Electrons

Magneto-Optical Study of Chiral Magnetic Modes in NiI$_{2}$: Direct Evidence for Kitaev Interactions

Bond-dependent magnetic interactions, particularly those described by the Kitaev model, have emerged as a key pathway toward realizing unconventional magnetic states such as quantum spin liquids and topologically nontrivial excitations, including skyrmions. These interactions frustrate conventional magnetic order and give rise to rich collective behavior that continues to challenge both theory and experiment. While Kitaev physics has been extensively explored in the context of honeycomb magnets, direct evidence for its role in real materials remains scarce. Magnetic van der Waals (vdW) materials have emerged as a versatile platform for exploring low-dimensional electrical, magnetic, and correlated electronic phenomena, and provide a fertile ground for potential applications ranging from spintronics to multiferroic devices and quantum information technologies. Here, we demonstrate, through magneto-transmission, Faraday angle rotation, and magnetic circular dichroism measurements, that the magnetic excitation spectrum of NiI$_2$, a van der Waals multiferroic material, is more accurately captured by a Kitaev-based spin model than by the previously invoked helical spin framework.
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All authors Kartik Panda, Chaebin Kim, Daniel Bazyliansky, Javier Taboada-Gutiérrez, Florian Le Mardelé, Jan Dzian, Guy Levy, Jae Ha Kim, Youjin Lee, Bumchan Park, Martin Mourigal, Jae Hoon Kim, Alexey B. Kuzmenko, Milan Orlita, Je-Geun Park, Nimrod Bachar

Materials Science

Targeted synthesis of polycrystalline vanadium dioxide thin films via post-deposition annealing

Implementation of neuromorphic hardware is a promising way to improve the computing efficiency and decrease the energy consumption of artificial neural networks. For this purpose, electronic elements emulating the behavior of synapses and neurons have to be developed. In order to realize electronic artificial neurons, threshold resistive switches or memristors can be efficiently used. One of the most widespread materials for threshold switches is vanadium dioxide due to its property to demonstrate the metal-insulator transition at a temperature about 70 {\deg}C. However, the processes of VO$_{2}$ synthesis are quite restrictive in temperature and gas atmosphere conditions, which hinders its integration into CMOS fabrication. In this work, we propose a new method of VO$_{2}$ synthesis: reactive pulsed laser deposition from metallic V target in oxygen atmosphere at room temperature, followed by vacuum annealing. Our method enables target synthesis of an appropriate VO$_{2}$ phase in a polycrystalline thin film form by finely tuning oxygen pressure during room temperature deposition, which allows to relax the equipment demands, such as high temperature heating in oxygen. Successful targeted VO$_{2}$ synthesis under fabrication conditions close to back-end-of-line CMOS production, achieved in this work, show the way toward its large-scale microelectronic integration for neuromorphic hardware creation.
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All authors Kirill Trunov, Yuri Lebedinskii, Ilya Zavidovskiy, Sergey Novikov, Alexander Morozov, Petr Shvets, Ksenia Maksimova, Andrei Zenkevich, Anton Khanas

Materials Science

Strain-Tunable Spin Filtering and Valley Splitting Coexisting with Anomalous Hall Effect in 2D Half-Metallic VSe2/VN Heterostructure: Toward a Unified Spintronic-Valleytronic Platform

Rapid progress in valleytronics and spintronics is limited by the scarcity of two-dimensional materials that simultaneously provide robust valley splitting and strong spin selectivity. Here we showed that a van der Waals heterostructure (VSe2/VN) built from hexagonal VSe2 and hexagonal VN addressed this gap. Using first-principles density functional theory, phonon, ab initio molecular dynamics stability tests, Bader charge analysis, and Wannier-based Berry-curvature calculations, we demonstrated an energetically and dynamically stable heterostructure that exhibited interlayer charge transfer and a work function intermediate between the constituent monolayers. The electronic structure showed small indirect PBE gap (108.9 meV), with HSE06 indicating a half-metallic tendency; a sizable conduction-band valley splitting (\Delta CKK' = 22.9 meV for spin-up and \Delta CKK' = 61.3 meV for spin-down); and pronounced spin asymmetry, where the spin-down channel showed a wide semiconducting gap (0.64 eV) while the spin-up channel was nearly gapless. These features yielded a high zero-strain spin-filter efficiency P = 75.4%, tunable to 82.5% under +4% biaxial tensile strain. The heterostructure also supported non-zero, valley-contrasting Berry curvature, and a large anomalous Hall conductivity (peak sigmaxy = 568.33 S/cm). Importantly, mean-field estimation placed the ferromagnetic Curie temperature near room temperature at zero strain (Tc = 284.04 K), while Tc decreased to 183.9 K at +4% strain, the magnetic order remained robust to cryogenic temperatures, providing a beneficial tuning knob to balance spin-filter performance with thermal stability in device-relevant regimes. These results identified VSe2/VN as a practical, strain-tunable platform for integrated valleytronic, spintronic devices, and for exploring anomalous Hall and valley-dependent transport phenomena.
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Materials Science · Cross-listed from physics.optics

Unveiling architectural and optoelectronic synergies in lead-free perovskite/perovskite/kesterite triple-junction monolithic tandem solar cells

The widespread use of lead-based materials in tandem solar cells raises critical environmental and health concerns due to their inherent toxicity and risk of contamination. To address this challenge, we focused on lead-free tandem architectures based on non-toxic, environmentally benign materials such as tin-based perovskites and kesterites, which are essential for advancing sustainable photovoltaic technologies. In this study, we present the proposition, design, and optimization of two distinct lead-free monolithic tandem solar cell architectures - an all-perovskite dual-junction device employing potassium tin iodide (KSnI3) and formamidinium tin triiodide (FASnI3) as absorbers for the top and bottom subcells, respectively, and a triple-junction monolithic tandem structure incorporating KSnI3, FASnI3, and Ag-doped copper zinc tin selenide (ACZTSe) as absorbers for the top, middle, and bottom subcells, respectively. We simulated the optical and electrical characteristics of these devices using the finite-difference time-domain and finite element methods, explicitly considering radiative, non-radiative, and surface recombination mechanisms. The optimized all-perovskite dual-junction solar cell achieved a power conversion efficiency (PCE) of 27.3%, with short-circuit current density (Jsc) of 14.74 mA/cm2, open-circuit voltage (Voc) of 2.227 V, and fill factor (FF) of 83.14%. Conversely, the optimized triple-junction hybrid perovskite-kesterite architecture secured an elevated PCE of 30.69%, along with Jsc of 13.184 mA/cm2, Voc of 2.766 V, and FF of 84.18%. These findings reveal the strong potential of lead-free perovskite and kesterite material based absorbers in promoting high-performance hybrid tandem solar cells, highlighting their importance in advancing sustainable and efficient photovoltaic technologies.
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All authors Md. Faiaad Rahman, Md. Ashaduzzaman Niloy, Ehsanur Rahman, Ahmed Zubair

Soft Condensed Matter

Design of an engaging-disengaging compliant mechanism by using bistable arches

Compliant mechanisms utilise elastic deformation of their segments to transmit motion or force. The utility and behaviour of specific compliant mechanisms can be enhanced by introducing an engaging and disengaging ability with its elastic segments. Towards this, we present an engaging-disengaging compliant mechanism (EDCM) that can switch its stiffness between infinite and zero. The design of the EDCM is based on bistable arches and a locking mechanism. We describe its working, identify its design parameters, and use analytical expressions to arrive at its dimension. The design is verified by detailed finite element analysis and experiments on a 3D-printed prototype. Three alternate designs that lead us to the final mechanism are also briefly discussed.
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All authors Mehul Srivastava, Trishna Gunna, Makarand Kandiyaped Serkad, Manu Sebastian, Safvan Palathingal

Strongly Correlated Electrons

Large Spontaneous Nonreciprocal Charge Transport in a Zero-Magnetization Antiferromagnet

Spontaneous breaking of time-reversal and spatial-inversion symmetries in solids triggers diverse intriguing phenomena. Although these phenomena have been extensively studied in insulators, similar investigations for metals remain limited. Herein, we report the observation and properties of spontaneous (i.e., zero-magnetic field) nonreciprocal charge transport in the zigzag intermetallic compound NdRu2Al10. This effect is attributed to the antiferromagnetic (AF) order, which can be interpreted as a magnetic toroidal dipole order. Our results reveal an excessively large nonreciprocal coefficient for this material, attributed to the strong effective magnetic field generated through c-f exchange interactions. The results also suggest that the nonreciprocal response of this material depends on the spin configurations of the AF domains. Overall, our findings are distinct from those previously reported for field-induced nonreciprocal charge transport and contribute to a comprehensive understanding of cross-correlations in symmetry-broken metals.
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All authors Kenta Sudo, Yuki Yanagi, Mitsuru Akaki, Hiroshi Tanida, Motoi Kimata

Strongly Correlated Electrons

Magnetic field-induced degenerate ground state in the classical antiferromagnetic XX model on the icosahedron

The ground state of the classical antiferromagnetic XX model in a magnetic field is calculated for spins mounted on the vertices of the icosahedron. The magnetization is characterized by two discontinuities as a function of the external field. For a wide field range above the first discontinuity the ground state is degenerate, with two spins related by spatial inversion aligned with the field and the rest forming two magnetization units in the form of pentagons. It is shown that the degeneracy originates from the coupling of the two pentagons, which introduces the triangle, associated with ground-state degeneracy, as an interaction unit in the icosahedron. The magnetization discontinuities are shown to evolve first from the coupling of isolated triangles and then from the coupling of the two spins related by spatial inversion.
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Strongly Correlated Electrons

Prevailing orbital excitations in paramagnetic kagome superconductor Cs(V$_{0.95}$Ti$_{0.05}$)$_3$Sb$_5$

Using the muon as a sensitive local magnetic probe, we investigated the layered kagome superconductor Cs(V$_{0.95}$Ti$_{0.05}$)$_3$Sb$_5$, a material notably devoid of both static magnetic moments and long-range charge order. Our transverse-field $\mu$SR measurements reveal that the local magnetic susceptibility, obtained via the muon Knight shift, is dominated by orbital excitations with a split energy levels around 20 meV. Meanwhile, the persistence of itinerant electron paramagnetism down to 5 K and 7 T confirms the absence of static magnetism within this regime. In addition, zero-field (ZF) $\mu$SR experiments detect a significant increase in the inhomogeneous nuclear dipolar field distribution below a featured temperature at 70 K. We attribute this ZF-$\mu$SR feature to the emergence of local lattice distortions at low temperatures, potentially arising from orbital ordering. Significantly, our study establishes that orbital excitations constitute an intrinsic property of the layered V-Sb kagome lattice. Despite its small magnitude, spin-orbit coupling plays a crucial role in governing the lattice dynamics, potentially driving the emergence of novel phenomena such as phonon carrying angular momentum in crystals with non-chiral point groups.
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All authors Chennan Wang, Yuhang Zhang, Zhen Zhao, Zhouyouwei Lu, Hui Chen, Ziqiang Wang, Haitao Yang, Christian Bernhard, Xiaoli Dong, Hong-Jun Gao

Mesoscale and Nanoscale Physics

Properties of multiterminal superconducting nanostructure with double quantum dot

We study the charge transport and thermoelectric properties of the junction, comprising double quantum dot embedded in T-shaped geometry on the interface between two normal/ferromagnetic electrodes and superconducting lead. We show that the interdot coupling plays major role in controlling the local and nonlocal transport properties of this setup. For the weak interdot coupling limit, we obtain the interferometric (Fano-type) lineshapes imprinted in the quasiparticle spectra, conductances and Seebeck coefficients. In contrast, for the strong interdot coupling, we predict that the local and nonlocal transport coefficients are primarily dependent on the molecular Andreev bound states induced by superconducting proximity effect, simultaneously in both quantum dots.
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Strongly Correlated Electrons

Unveiling the critical role of interfacial strain in adjusting electronic phase transitions in correlated vanadium dioxide

Thermally activated abrupt switching between localized and itinerant electronic states during the insulator-metal transition (IMT) in correlated oxide systems serves as a powerful platform for exploring exotic physical phenomena and device functionality. One ongoing focal challenge lies in the realization of the broadly tunable IMT property in correlated system, to satisfy the demands of practical applications across diverse environments. Here, we unveil the overwhelming advantage associated with interfacial strain in bridging the bandwidth and band-filling control over the IMT property of VO2. Tailoring the orbital overlapping through strain-mediated bandwidth control enables a widely tunable thermally-driven IMT property in VO2. Benefiting from adjustable defect dynamics, filling-controlled Mott phase modulations from electron-localized t2g1eg0 state to electron-itinerant t2g1+{\Delta}eg0 state through oxygen vacancies can be facilitated by using in-plane tensile distortion, overcoming the high-speed bottlenecks in iontronic devices. Defect-engineered electronic phase transitions are primarily governed by the electron filling in t2g band of VO2, showcasing a definitive relationship with the incorporated defect concentration. Our findings provide fundamentally new insights into the on-demand design of emergent electronic states and transformative functionalities in correlated oxide system by unifying two fundamental control paradigms of bandwidth and band-filling control.
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Statistical Mechanics

Ground states of the Ising model at fixed magnetization on a triangular ladder with three-spin interactions

We study the Ising model at fixed magnetization on a triangular ladder with three-spin interactions. By recasting the ground-state determination as a linear programming (LP) problem, we solve it exactly using standard LP techniques. We construct the phase diagram for arbitrary fixed magnetization and identify three types of ground states: periodic, phase-separated, and ordered but aperiodic. When magnetization is treated as a free parameter, the ground state adopts only periodic configurations with the average magnetization per site $0$, $\pm 1/3$ or $\pm 1$, except for the phase boundaries.
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Mesoscale and Nanoscale Physics

Exploiting Negative Capacitance for Unconventional Coulomb Engineering

The many-body ground state of a two-dimensional electron system can be tuned by Coulomb engineering through control of the dielectric environment. However, in conventional dielectrics the static permittivity is restricted to positive values, limiting the accessible interaction regimes. Here we argue that the negative capacitance demonstrated in appropriately engineered structures can open new vistas for Coulomb engineering. The associated negative permittivity could transform the natural repulsive interaction of electrons into an attractive one, raising the intriguing possibility of nontrivial ground states, including superconductivity. Using models of two-dimensional electron systems with linear and parabolic dispersion relations coupled to environments with negative capacitance, we estimate the strength and sign of the engineered Coulomb interaction and outline parameter regimes that could stabilize correlated electronic phases.
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Mesoscale and Nanoscale Physics

Antiferromagnetic skyrmion as a magnonic lens

A lens, a device transforming propagation directions in an organized fashion, is one of the fundamental tools for wave manipulation. Spin wave, the collective excitation of ordered magnetizations, stands out as a promising candidate for future energy-saving information technologies. Here we propose theoretically and verify by micromagnetic simulations, that an antiferromagnetic skyrmion naturally serves as a lens for spin wave, when the Dzyaloshinskii-Moriya strength exceeds a threshold. The underlying mechanism is the spin wave deflection caused by Dzyaloshinskii-Moriya interaction, a mechanism that is ordinarily overshadowed by the magnetic topology.
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