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Physics Condensed Matter Statistical Mechanics

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Monday 28 September

Statistical Mechanics · Cross-listed from nlin.AO

Delay-induced multistability in one-dimensional swarmalators with common intrinsic frequency

We study the delayed one-dimensional swarmalator model when all units share a common intrinsic frequency {\omega}. Unlike the zero-frequency case, {\omega} cannot be removed by a rotating-frame transformation because delayed interactions retain the phase accumulated over the lag. The result is a two-order-parameter analogue of the delayed Kuramoto model: the asynchronous state acquires incoherence lobes, the synchronized state becomes a rotating branch stable even when both the spatial and phase couplings are repulsive, and the phase wave develops narrow resonant stability bands. These delay-selected windows overlap to produce broad branch coexistence, including a narrow window near K=-J where all three canonical states-asynchronous, phase wave, and synchronized-are simultaneously stable. In regions where no canonical branch is stable, the order parameters oscillate persistently.
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Statistical Mechanics

Derivation of Fokker-Planck equation and its entropy production

We derive the Fokker-Planck equation and its entropy production from the master equation. To this end we consider a discrete space of states where the master equation is defined and appropriate transition rates are introduced. A transition rate has two parts, one of which is the ordinary term proportional to the inverse of the spacing and the other is inversely proportional to the square of the spacing corresponding to the variance of the independent stochastic variable. In the continuous space limit, we obtain the Fokker-Planck as well as the rate of entropy production and the flux of entropy. We also consider the case where the space of states is the phase space and discuss the equations appropriate for systems in contact with several heat reservoirs and for isolated systems.
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Statistical Mechanics

Autonomous self-harmonic drift in Langevin dynamics causes a compaction of underlying domain for the density of Stochastic Localization

Our recent research on Langevin dynamics with self-harmonic drift and classical spins has revealed a strong connection to “Stochastic Localization," a concept attracting attention in the fields of mathematical geometry and data science. Roughly speaking, the former can be viewed as a version of the latter in which the $n$-dimensional Euclidean space - the domain of the probability distribution function appearing in the latter - is “compactified” to the surface of an $n$-dimensional sphere. By comparing the two frameworks, we argue that this compactification is a consequence of requiring the drift to be autonomous. The relationship between the two approaches may expand the scope of Stochastic Localization.
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Statistical Mechanics · Cross-listed from quant-ph

Collectivity limits quantum entanglement

Understanding what limits many-body quantum entanglement is a central problem in physics. Spatial locality has long provided a fundamental mechanism: correlations between a region and its complement must be mediated through a small spatial interface, thereby constraining their entanglement. Here we show that universal constraints on entanglement can persist even when interactions are strongly nonlocal, through collectivity: many weak interactions generate fluctuations controlled by their square-summed, rather than total, strength. We establish this mechanism rigorously for generic gapped Hamiltonians with Kac-normalized power-law interactions $r^{-\alpha}$ on a $D$-dimensional lattice. For arbitrary bipartitions, we prove that the ground-state entanglement scales at most logarithmically with system size for $\alpha<D/2$ and subextensively for $D/2<\alpha<D$, due to suppressed collective fluctuations around individual sites. For spatially regular bipartitions with codimension-one boundaries, we use a renormalization-group construction to extend this suppression to larger length scales, yielding polylogarithmic scaling for $D/2 < \alpha < (D+1) / 2$ and parametrically stronger subvolume bounds for $(D+1)/2<\alpha<D$. We also establish the corresponding optimality results: for arbitrary bipartitions, the logarithmic scaling for $\alpha<D/2$ is optimal and $\alpha=D/2$ marks the optimal threshold for universal logarithmic bounds, while for regular bipartitions the threshold at $\alpha=(D+1)/2$ is likewise optimal for universal polylogarithmic bounds when $D\ge2$. Together, these results reveal collectivity as a fundamental mechanism for constraining many-body entanglement alongside spatial locality.
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Statistical Mechanics · Cross-listed from quant-ph

Out-of-Time-Ordered Correlators Beyond Lindblad

Out-of-time-ordered correlators (OTOCs) provide a powerful probe of quantum chaos and scrambling. While the Lindblad formalism is often used to describe OTOCs in open systems, microscopic mechanisms that give rise to the Lindblad equation at the level of time-ordered correlation functions do not necessarily justify this approach at the level of OTOCs. Starting from a microscopic model of a subsystem coupled to a random bath, we show that the resulting OTOC dynamics contains an additional contribution compared to the standard Lindblad approach. This contribution, induced by correlations between different replicas, allows key properties of the underlying unitary dynamics such as long-time freeness to be retained and information scrambling to be captured more faithfully. As an application, we show that this extended formalism can be used to numerically study OTOCs in large closed systems by replacing part of the system with a dissipative boundary, offering a way to study operator spreading and higher-order correlations beyond directly accessible system sizes.
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Statistical Mechanics · Cross-listed from quant-ph

Entanglement spectrum and magic in higher-dimensional free fermionic systems

We study fermionic non-local magic in higher-dimensional free-fermion systems through the lens of the entanglement spectrum. For translationally invariant Gaussian states in strip geometries, dimensional reduction maps the problem to independent lower-dimensional momentum sectors, leading in two dimensions to a multiplicative logarithmic violation of the boundary law analogous to Gioev-Klich-Widom scaling. We further show that the second Rényi fermionic non-local magic is bounded by the capacity of entanglement and introduce an entanglement-temperature deformation that probes the low-energy structure of the entanglement Hamiltonian. Applied to the matter-Majorana sector of the Kitaev model, this response is exponentially suppressed in the Abelian phase and algebraic in the non-Abelian phase, where its ratio with the capacity approaches a universal constant. Out of equilibrium, we extend the quasi-particle description to fermionic non-local magic in higher-dimensional quenches and show that random Gaussian circuits exhibit diffusive spreading in two spatial dimensions.
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Statistical Mechanics

Nonreciprocal Chiral Automata

Odd pressure is a parity-odd transport coefficient that gives an isotropic pressure response to vorticity in compressible two-dimensional fluids. By asymmetrically coupling vortical and compressional modes, it provides a direct mechanism for a nonreciprocal hydrodynamic response reminiscent of several biological systems. Yet microscopic models realizing odd pressure as a transport coefficient are relatively scarce. Here, we construct one such model using a lattice-gas cellular automaton based on the Frisch-Hasslacher-Pomeau II model with rest particles and chiral collisions, whose Chapman-Enskog coarse-graining produces a nonzero odd pressure coefficient. The key ingredient is a local parity-breaking collision that weakly rotates moving particles in the presence of a rest particle. At hydrodynamic scales, this microscopic rule acts as an effective magnetic field, converting the model's bulk viscosity into odd pressure. More generally, we derive expressions relating Hall viscosity, odd pressure, and odd torque to their parity-even counterparts in our model.
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All authors Andrew A. Allocca, Armin Rahmani, Pouyan Ghaemi, Sriram Ganeshan

Statistical Mechanics · Cross-listed from quant-ph

Characterizing quantum precision enhancement for multiple currents in open quantum systems

The kinetic uncertainty relation (KUR) constrains fluctuations of individual currents in classical nonequilibrium systems in terms of the dynamical activity, which quantifies the average number of transitions per unit of time. Here, we derive a multi-current KUR (MKUR) establishing the precision limit for multiple currents generated in classical stochastic processes in the nonequilibrium steady state. We then apply our theory to identify quantum devices whose correlated current fluctuations surpass this classical limit by comparing the quantum system to a classical emulator with the same average currents in the steady state. In this way, violations of the emulator's MKUR have a clear physical meaning, i.e., that the quantum-coherent evolution reduces joint current fluctuations below what is possible for a classical Markovian system with the same energy-level structure and incoherent resources. Since the MKUR incorporates correlations between currents, its violation pinpoints nonclassical fluctuations in parameter regimes where the single-current KUR is satisfied. We illustrate the essential and complementary role of these bounds for characterizing joint current precision with two examples: a coherently driven two-level system and an experimentally motivated model of a three-level heat engine subject to parasitic environmental couplings.
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All authors Khalak Mahadeviya, Sheikh Parvez Mandal, Mahasweta Pandit, Javier Prior, Mark T. Mitchison, Saulo V. Moreira

Statistical Mechanics · Cross-listed from quant-ph

One-dimensional quantum Gibbs states in constant circuit depth

We prove that the Gibbs state of any spin chain can be exactly decomposed into a mixture of product states over contiguous blocks of qubits with bounded length, at any constant temperature. As a consequence, any such Gibbs state can be prepared by local unitary circuits of constant depth, with efficient classical preprocessing. We place strong limits on the spatial structure of thermal entanglement: both the entanglement depth and entanglement width (measures of multiparticle entanglement) are bounded by constants, while the localizable entanglement (the bipartite entanglement that can be generated with the aid of local measurements and classical communication) vanishes exactly beyond a constant threshold distance. Our result also has implications for quantum thermalization: for any translation-invariant spin-chain Hamiltonian with nondegenerate spectral gaps, typical low-complexity pure states drawn from a maximally entropic ensemble at any constant effective temperature become locally indistinguishable from the Gibbs state upon unitary evolution. Additionally, we obtain an analogous decomposition for fermionic systems: the Gibbs state of any 1D local fermionic Hamiltonian is exactly a mixture of constant-depth local fermionic circuits acting on Gaussian states.
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All authors Saúl Pilatowsky-Cameo, Georgios Styliaris, Ainesh Bakshi, Daniel Malz

Statistical Mechanics · Cross-listed from cond-mat.str-el

Advancing Fuzzy-Sphere CFTs: $\mathrm{SO}(3)$-Rotation-Resolving Exact Diagonalization, 3D Ising Heavy Primaries, and Quasi-Hole-Space Projection

Fuzzy-sphere regularization has recently emerged as a powerful framework for studying three-dimensional conformal field theories (CFTs). In this work, we exploit symmetry and Hilbert-space structures to substantially advance this framework. We develop an exact-diagonalization algorithm that resolves the full $\mathrm{SO}(3)$ rotational symmetry, reducing computational costs by factors of several hundred. For the three-dimensional Ising CFT, we identify around 100 primary operators, including a large number of previously unknown heavy scalar primaries up to scaling dimension $\Delta\approx16.5$. We also resolve the tension between previous fuzzy-sphere and bootstrap results regarding the parity-odd scalar primary. Furthermore, we identify a branch of scalar primaries associated with $\phi^n$ operators in the $\phi^4$ Lagrangian description, beginning with the identity, $\sigma$, $\epsilon$, $\epsilon'$, and $\sigma'$. Their wave functions exhibit a semi-classical structure closely related to states invariant under area-preserving diffeomorphisms of the sphere. Finally, we show that critical points involving fractional quantum Hall states can be studied within a substantially reduced Hilbert space spanned by quasi-hole states of the corresponding model quantum Hall wave functions like the Laughlin state. This suggests a general strategy for exploring CFTs intertwined with topologically ordered phases.
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Statistical Mechanics · Cross-listed from cond-mat.dis-nn

Discrete Scale Invariance of Ising Mesons

Discrete scale invariance often arises from resonant few-body or singular scale-invariant dynamics. We show that it can instead emerge in the internal motion of a composite excitation in an ordered quantum magnet. In the marginal $1/r^4$ transverse-field Ising chain, long-range bonds generate an asymptotic inverse-square attraction between dressed domain walls, with strength fixed by the spontaneous magnetization. The dressed two-kink threshold curvature sets the relative kinetic scale. Together, these independently accessible quantities determine the scale-anomaly exponent and hence the meson hierarchy. In the supercritical regime, the same exponent governs geometric binding-energy and size ratios, logarithmic level accumulation, and log-periodic threshold scattering. Full-spin exact diagonalization and a fourth-order weak-field Hamiltonian support the coupled energy–size scaling in the finite window between core and ring effects. This provides a microscopic many-body realization of quantum limit-cycle physics, with its universal scaling fixed by magnetic order and kink mobility.
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Statistical Mechanics

Speed-Fisher Information: Chaos and Irreversibility in Classical and Quantum Dynamics

We propose a unified perspective on classical and quantum chaos based on the sensitivity of a system's stationary states to slow driving. We probe this sensitivity via the system's susceptibility to the average protocol speed, which we call the “speed-Fisher information," and relate it to irreversible entropy production in the system. We show that chaotic dynamics manifests as a divergence of the speed-Fisher information with the protocol time, and that this response is controlled by the perturbation's low-frequency spectral weight. This approach to chaos applies to both classical and quantum Hamiltonian systems, and naturally extends to non-Hamiltonian classical flows. Additionally, we identify a quantum regime at times shorter than the Planckian timescale, in which the speed-Fisher information exhibits a uniquely quantum scaling. We illustrate this framework with simple classical and quantum examples
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All authors Nachiket Karve, Nathan Rose, David Campbell, Anatoli Polkovnikov

Statistical Mechanics · Cross-listed from quant-ph

Optimal performance in a chaotic Floquet quantum battery

We study a quantum battery consisting of $N$ qubits interacting uniformly with each other. Starting from its ground state, the battery is charged by introducing periodic kicks in the transverse direction along with adding disorder in the interaction direction. Although the battery Hamiltonian along with the initial state preserves the permutation symmetry, the dynamics in presence of disorder during the charging phase takes the system out of the permutation symmetric subspace, resulting to a larger amount of stored energy as compared to that without disorder. In the limit of large disorder, this interplay brings in a possibility of a chaotic charging phase when stored energy can be exactly calculated using random matrix theory. More importantly, we also find that the energy fluctuations decrease and become negligible in the limit of large disorder, which is also when the energy stored is maximum, a condition highly desirable for the optimum functioning of the battery. We complete the battery cycle by considering the storage phase in the presence of dephasing noise. We find that for larger disorder strengths, the ergotropy remains close to the stored energy, indicating nearly complete energy extractability with an efficiency approaching unity.
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Statistical Mechanics

Out-of-equilibrium finite-time percolation transitions and spinodal-like behaviors after quenches across magnetic first-order transitions of Ising systems

We analyze the out-of-equilibrium relaxational dynamics of ferromagnetic Ising-like systems driven across their low-temperature magnetic first-order transition (FOT) line, by sudden and slow variations of an external homogenous magnetic field $h$. As a paradigmatic example, we consider a two-dimensional Ising system driven across its low-temperature FOT line by suddently quenching $h$ from $h_i<0$ to $h>0$, inducing a transition from the negatively to the positively magnetized phase. We show the emergence of a dynamic percolation transition at a finite critical time $t_c(h)$ along the post-quench evolution for finite (sufficiently small) values of $h$, which is marked by the percolation of the largest positive-spin cluster and the antipercolation of the largest negative-spin cluster. This out-of-equilibrium percolation transition displays a finite-size scaling behavior as in the standard random-percolation case. However, while the fractal dimension of the percolating clusters is consistent with the random-percolation value, the exponent controlling the approach to criticality differs and depends on $h$. We also show that the percolation transition marks the passage from the metastable negatively-magnetized phase to the stable positively-magnetized one. Therefore, in the small-$h$ limit, the percolation critical behavior is related to the spinodal-like behavior of the magnetization, implying that the percolation time $t_c(h)$ exhibits a spinodal-like exponential dependence on $h$. The existence of percolation transitions is likely a generic phenomenon at magnetic Ising-like FOTs. For example, we observe an analogous behavior in dynamic (Kibble-Zurek-like) protocols entailing slow variations of the magnetic field driving the crossing of the FOT line.
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Statistical Mechanics · Cross-listed from cond-mat.soft

A Unified Rational-Function Approximation for Square-Well, Square-Shoulder, and Nonadditive Hard-Sphere Mixtures

We develop a rational-function approximation for the structural properties of multicomponent fluids with narrow square-well and square-shoulder interactions, together with weakly nonadditive hard-sphere mixtures. The theory is obtained by reformulating the analytical Percus–Yevick solution for additive sticky hard-sphere mixtures so as to account for finite interaction widths, leading to a unified semianalytical framework for these classes of fluids. The approximation satisfies the exact low-density limit and preserves the continuity of the cavity functions; a simple local correction restores the continuity of their first derivatives. Comparison with Monte Carlo simulations for binary mixtures shows that the theory accurately describes both the radial distribution functions and their Fourier transforms for narrow wells and shoulders and for weak nonadditivity. The proposed formulation extends previous sticky-hard-sphere-based approaches while retaining their analytical simplicity.
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All authors Andrés Santos, Santos B. Yuste, Ana M. Montero, Mariano López de Haro

Statistical Mechanics · Cross-listed from quant-ph

Correlation measure for statistical systems

A measure of correlations for statistical systems is advanced, called correlation index. The measure is general, being applicable to quantum and classical, equilibrium and nonequilibrium statistical systems. After formulating the general notion of correlation indices for arbitrary trace-class operators, the calculation of the correlation indices are illustrated by several examples of density operators and reduced density matrices. The computation of the correlation indices for equilibrium systems is exemplified for bosonic systems with the Bose-Einstein condensate, superconducting systems, and for spin systems. Correlation indices for nonequilibrium systems are considered for nonlinear dynamics of spin and pseudospin systems.
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Statistical Mechanics · Cross-listed from nlin.AO

Global synchronization of topological signals with time-delayed interactions

Topological signals are dynamical variables supported on higher-order structures such as simplicial or cell complexes. In this work, we investigate the impact of time-delayed interactions on the emergence of global synchronization of topological oscillators, with application to the Stuart-Landau system. We first examine the case where signals are supported on simplexes, or cells, of a given dimension and coupled through the Hodge-Laplace matrix. We derive the Master Stability Function and we prove that for suitable discrete delay values, the stability of the synchronous solution becomes analytically tractable and can be solved by using the Lambert W-function. This analysis yields explicit spectral conditions for Global Topological Synchronization to emerge and shows that admissible delays may either promote or suppress synchronization. We then study delayed interactions between signals supported on simplexes, or cells, of different dimensions coupled by the Dirac operator. Under analogous admissible time delays the variational problem, still related to the Master Stability Function, can again be simplified, however in this case we prove that Global Topological Dirac Synchronization cannot emerge. Numerical simulations on simplicial and cell complexes corroborate and complement these findings.
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All authors Wilfried Segnou, Thierry Njougouo, Diego Garlaschelli, Timoteo Carletti

Statistical Mechanics · Cross-listed from hep-th

Cylinder Defect Casimir Energy and Weyl Anomalies

We distinguish two Casimir observables associated with a conformal surface defect. A circular cylinder embedded in flat space has a logarithmic contribution to its Casimir energy, $-d_1\log(R/\epsilon)/(24R)$, fixed by the displacement anomaly. A great cylinder obtained by radial quantization of the ambient theory instead has Casimir energy $-b/(12R)$ in the conformal defect vacuum with a fixed local anomaly convention. Free-field and holographic calculations provide checks of the proposed relations in both embeddings.
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Statistical Mechanics

Fluctuations and multifractality in stochastic models of interface growth and population dynamics

This thesis studies how disorder and fluctuations shape large-scale growth phenomena in three related settings: fluctuating interfaces, random spring chains, and random multiplicative growth. The first part concerns interface growth and a phenomenon denoted anomalous scaling, where local and global exponents differ.To clarify its origin, we study two models in which this mismatch has different causes. The first is a heterogeneous elastic line, where we show that the apparent anomaly is a purely statistical effect. The second is the stochastic porous medium equation, a strongly nonlinear model in which the anomaly is genuine. The second part concerns Anderson localization, which appears here through the spectral properties of the heterogeneous elastic lines. We study chains with both random masses and random spring constants, with particular emphasis on the strong-disorder regime, where standard weak-disorder expansions break down. We develop a new combinatorial method to probe this regime. The last part concerns random multiplicative growth with redistribution. In such models, changes in wealth, population, or mass, for instance, are proportional to the amount already present, so that small differences are amplified over time. This naturally generates broad distributions and provides a simple mechanism for the emergence of inequality and concentration, with applications to population dynamics, wealth distribution, city growth, and ecology. We in particular study models in which each site has its own quenched growth rate, representing a persistent advantage or disadvantage, and is also subject to transient fluctuations. Redistribution competes with these mechanisms by homogenizing the system. This competition leads to rich phase diagrams.
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Statistical Mechanics

Second largest eigenvalue does not bound stationary entropy production

We examine the spectral dissipation-coherence trade-off inequality conjectured by Oberreiter et al. [Phys. Rev. E 106, 014106 (2022)], stating that the coherent number, defined from the second largest eigenvalue, provides a lower bound on the stationary entropy production per unit oscillation. We disprove this conjecture by explicitly constructing a counterexample, which accompanies finite coherent number with vanishing stationary entropy production. This model also excludes a wide class of thermodynamic bound with the real and imaginary parts of the second largest eigenvalue of the transition rate matrix. Our result implies that the second largest eigenvalue does not necessarily characterize the degree of coherent oscillation.
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Statistical Mechanics · Cross-listed from math-ph

The equivalence of topological indices for $\mathrm{U}(1)\rtimes\mathbb{Z}_2$-symmetric quantum spin chains

Symmetry-protected topological (SPT) phases in quantum spin chains are distinguished by topological indices. Ogata's operator-algebraic indices apply to a broad range of symmetry classes without requiring continuous symmetry, whereas the elementary twist index of Tasaki requires $\mathrm{U}(1)$ symmetry. We prove their equivalence in the common setting of integer-spin chains with on-site $\mathrm{U}(1)\rtimes\mathbb{Z}_2$ symmetry and a symmetric locally-unique gapped ground state, without assuming translation invariance or a matrix product representation. A charge-fluctuation estimate yields a strong-limit construction of half-chain rotations with their phases fixed. An exact group commutator identity then identifies the Ogata index with the limit of local twist expectations and gives an explicit error bound. This provides a computable formula for the index when a lower bound on the gap and the relevant ground-state expectations are available. Combining the equivalence with a recent boundary-field gap theorem of OpenAI and our earlier twist-index calculation, we obtain a spin-rotation-invariant locally-unique gapped ground state of the infinite $S=1$ antiferromagnetic Heisenberg chain with both indices equal to $-1$, without assuming infinite-volume uniqueness. The author formulated the problem and proposed the basic strategy, while ChatGPT Astra made substantial contributions to the development of the proof.
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Sunday 27 September

Statistical Mechanics · Cross-listed from quant-ph

Swapping Quantum Annealing Errors into a Cavity

Quantum annealing is a promising form of quantum computation, but it slows down at a small energy gap $\Delta$ during the anneal, and the errors it makes there remain undetected. We introduce cavity quantum annealing, in which a cavity mode of frequency $O(1)\gg\Delta$, coupled mid-schedule, swaps these errors into photons. In the $p$-spin model, this reduces the annealing time to nearly the square root of that required without the cavity. Moreover, counting the photons certifies the result: high-photon runs, with an $O(1)$ yield, reach a ground-state fidelity above $99.99\%$ orders of magnitude sooner, a gain that grows exponentially with system size. A pre-loaded photon instead runs the swap in reverse, preparing an excited state. More broadly, our work shows that cavities can enhance computations performed with qubits, paving the way toward high-fidelity quantum state preparation by quantum annealing.
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Statistical Mechanics · Cross-listed from nlin.AO

Rare but stable: hidden states in the 1D swarmalator model

The one-dimensional swarmalator model is usually understood through three macroscopic states: synchrony, the phase wave, and asynchrony. We show that the identical model also contains a much larger set of hidden stable equilibria - families of q-twisted and m-clustered states - which random initial conditions almost never reach, because many are embedded in a degenerate neutral manifold of vanishing global basin. They are nonetheless locally robust: under Gaussian perturbations of per-coordinate amplitude {\epsilon} their survival radii shrink only algebraically, as 1/q and 1/m, in sharp contrast to the Gaussian basins and winding ceiling of twisted states on a nearest-neighbour Kuramoto ring, both removed by mean-field coupling. A block-circulant Jacobian fixes the stability in closed form, and far-kick experiments indicate the basins are compact cores rather than tentacled sets. Several patterns reported in extended swarmalator models thus already exist, stable or neutrally stable, in the minimal one.
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Statistical Mechanics

Hall conductance of dilute electrolytes from odd stochastic density functional theory

Electrolytes under an external magnetic field exhibit a Hall conductivity, much like metals and semiconductors. However, existing theories fail to quantitatively account for their measured Hall conductivities. To make progress toward such a theory, we develop a stochastic density functional framework for electrolytes in a magnetic field. This framework, which we dub odd SDFT, extends the celebrated stochastic density functional theory (SDFT) to incorporate transverse mobilities and chiral time-correlated noise. Using this framework, we calculate the Hall conductivity in the absence of hydrodynamic solvent effects through three approaches: (i) direct response, (ii) Green-Kubo relation, and (iii) a hybrid fluctuation-dissipation relation. We further show that odd SDFT applies more broadly to fluids with broken time-reversal and mirror symmetry, including odd-diffusive fluids and chiral active matter. Our results generalize the relaxation correction of Debye-Hückel-Onsager theory to magnetized electrolytes and provide a foundation for incorporating additional effects mediated by the solvent that could quantitatively reconcile theory and experiments.
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All authors Yael Avni, Michel Fruchart, David Martin, Tali Khain, Vincenzo Vitelli

Statistical Mechanics · Cross-listed from cond-mat.soft

On mechanistically accessible copolymer sequences

Structural observations in polymer chemistry are often rationalized through underlying mechanistic insights. The study of families of mechanisms - and the phenomenology and lawlike behavior that can accompany them - is less common. Here we construct a theory that links a mechanistic feature - the number of nearest neighbors $k$ that influence monomer incorporation - with the accessible copolymer sequence space. We find that the reaction mechanisms can be mapped 1-to-1 to a regular de Bruijn graph of degree $k$. We calculate the periodic copolymer sequences as function of neighbor index $k$, and number of monomers $s$. We show that the number of periodic sequences grows explosively with $s,k$, bounded from below by $s!^{s^{k-1}}/s^k$. We find that periodic k-polymerization is governed by several simple laws describing allowed sequences, number of specific reactions, repeating unit length and the allowed and disallowed sequence coexistence in block copolymers. We formulate Simple Assembly Rules (SAR) that capture commonly observed behavior and design of literature systems, and characterize the possible k-polymerizations they are allowed to access ($k\leq2$) as function of symmetries and illustrate our findings with reported examples from the coordination chemistry and supramolecular chemistry literature. We discuss chemical-structural contributions by which nontrivial ($k>1$) sequences are formed, highlighting the importance steric hindrance, long-range interactions and degrees of freedom.
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Statistical Mechanics

Non-stationary Statistics and Energetics of Brownian Motion under Stochastic Harmonic Confinement

We investigate the positional statistics and thermodynamic properties of a Brownian particle confined in a Harmonic trap. The stiffness of the particle fluctuates in time as the square of the Brownian process. First, in the absence of a thermal bath, we investigate the probability density function of the position of the particle at time $t$. Then, we provide an expression to compute the $n$th positional moment. We evaluate the first four positional moments and discuss their asymptotic behavior in the long-time limit. In contrast to previously studied models of fluctuating stiffness, the current model describes a non-stationary process. Furthermore, we provide the exact expression for the average work performed on the system and the average heat exchanged by the particle with the bath. Their long time behavior again reflects the non-stationary nature of the process. Our theoretical predictions are supported by numerical simulations.
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Statistical Mechanics

Quantum Dynamics of Full Counting Statistics in Fermionic Lattices with Localized Gain

We investigate the dynamics of full counting statistics (FCS) of the growth of the total number of fermions in a one-dimensional non-interacting lattice subjected to a localized particle gain (source) at one edge. The dynamics of the setup is modeled by the Gorini–Kossakowski–Sudarshan–Lindblad (GKSL) quantum master equation. We recast the counting problem that involves counting particle number at every lattice site to a problem where only the local injected site is involved. We employ the Schwinger-Keldysh path integral formalism within the GKSL framework and derive an analytical expression for the cumulant generating function at arbitrary times and obtain a Levitov-Lesovik type formula in the long-time limit, earlier derived for boundary driven setups in the steady-state. For clean lattices with either short- or long-range hopping, supporting single-particle delocalized eigenstates, we show that all cumulants grow linearly with time in the asymptotic regime. Our analytical results are in excellent agreement with direct numerical simulations. These findings establish a general framework for characterizing FCS and quantum fluctuations in driven open fermionic systems with localized particle injection.
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Statistical Mechanics

Boolean Cumulants and Exact Reduced Descriptions of Renewal-Driven Systems

Reduced descriptions of unresolved fluctuations are commonly based on Gaussian processes, although many realistic forcings have finite correlation times and a renewal structure. For memoryless step (Kubo–Anderson) noise, we show that the reduced dynamics admit two exact and complementary descriptions: a kernel representation governed by the Boolean cumulants of the jump distribution, and a frozen-noise representation adapted to stationary probability densities. For exponentially distributed waiting times, the totally time-ordered $G$-cumulants coincide with the Boolean cumulants of the jump law, and the memory kernel is resummed exactly as the Boolean generator $\eta$ evaluated on a resolvent operator. Second-order closure is exact if and only if the jump law is symmetric Bernoulli; otherwise, the leading closure error is controlled by $(b_4/b_2)\lambda^2$. The Boolean hierarchy, however, acts on the kernel, not on the stationary measure. Stationary densities are approximated by replacing the jump law with its $N$-point Gauss quadrature: each surrogate preserves all multi-time correlations up to order $2N-1$ for any waiting-time law, its kernel is a Padé resummation of the Boolean one, and it is itself an exactly solvable renewal problem. For the linear system with linear multiplicative interaction (LIMI/CAM), the frozen-noise representation reduces the dynamics to a random affine recursion and yields exact support boundaries, singularity exponents and Kesten tail indices, confirmed numerically. Rates, moments and closure errors are governed by the Boolean hierarchy, whereas stationary densities are determined by the geometry of the jump distribution. For memoryless renewal noise, the combinatorial structure controlling finite-correlation reductions is Boolean.
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Statistical Mechanics · Cross-listed from quant-ph

Temperature–Hamiltonian Ambiguity in Strong-Coupling Quantum Equilibrium

Strong coupling generally drives a subsystem away from the Gibbs state of its bare Hamiltonian at the bath temperature. We formulate a temperature–Hamiltonian ambiguity: the reduced equilibrium state fixes the dimensionless Gibbs generator, but does not by itself uniquely determine the local Hamiltonian and temperature entering a Gibbs representation. We propose an operational resolution in which the local Hamiltonian is identified from physical information independent of the stationary Gibbs parametrization. Whenever the exact reduced state is compatible with the Gibbs family generated by that independently identified Hamiltonian, it then determines a unique local temperature. An exactly solvable two-level-system–oscillator model makes the ambiguity explicit through state-equivalent descriptions based on temperature renormalization relative to a specified local Hamiltonian and Hamiltonian-of-mean-force level renormalization at the bath temperature. An exact bosonic model provides the complementary case in which retarded dynamics independently fixes a renormalized local excitation scale and thereby specifies the local Hamiltonian before the stationary populations determine the temperature. These results distinguish state representation from thermodynamic assignment and provide an operational framework for local thermodynamics beyond weak coupling.
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Statistical Mechanics

Criticality without Temperature in an Ising Spin System

Criticality in the Ising model is conventionally generated by Hamiltonian dynamics and controlled by temperature. Here we show that critical like behavior can emerge in an Ising system whose dynamics is completely independent of the Ising Hamiltonian and contains no temperature like parameter. We introduce an adaptive cluster dynamics in which spin connectivity is controlled by a local quiet time variable, the time elapsed since a spin was last updated. The Ising Hamiltonian enters only as an observable characterizing the resulting configurations. As the parameter $\alpha$, controlling the connectivity strength, is varied, the system undergoes spontaneous symmetry breaking accompanied by strong collective fluctuations. The cluster size distribution develops an extended power law regime, terminated by a small finite size hump at the largest scales, while the Ising energy exhibits a singular response to the variation of $\alpha$. These results show that memory dependent connectivity alone can generate collective critical behavior, revealing a route to nonequilibrium criticality without energy based dynamics.
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